Mixture of Acetic acid, methyl ester + Methyl Alcohol

Datasets

1. Mole fraction (16)
2. η - Viscosity, Pa*s (4)
3. n₀ - Refractive index (Na D-line) (2)
4. ρ_l - Mass density, kg/m3 (4)
5. T_boil - Boiling temperature at pressure P, K (16)
6. Vapor or sublimation pressure, kPa (4)
7. Excess molar volume, m3/mol (2)

Mole fraction of Methyl Alcohol (2) [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Methyl Alcohol (2) - Gas	Mole fraction of Methyl Alcohol (2) - Liquid
0.0436	0.0251
0.1744	0.1238
0.1773	0.1259
0.2730	0.2376
0.3212	0.3117
0.3720	0.4014
0.4199	0.4963
0.4641	0.5791
0.5103	0.6671
0.6318	0.8213
0.7061	0.8777
0.7886	0.9280

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Temperature, K = 322.32 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0500	0.1660
0.1010	0.2690
0.2000	0.3920
0.3000	0.4590
0.4000	0.5240
0.5000	0.5740
0.5980	0.6290
0.6460	0.6570
0.7000	0.6870
0.7490	0.7220
0.7980	0.7600
0.8500	0.8070
0.9000	0.8590
0.9490	0.9240

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0000	0.0000
0.0100	0.0330
0.0300	0.0910
0.0610	0.1660
0.0810	0.2080
0.1210	0.2790
0.1620	0.3360
0.2120	0.3940
0.2630	0.4400
0.3030	0.4720
0.3540	0.5060
0.4240	0.5460
0.4950	0.5810
0.5760	0.6200
0.6470	0.6560
0.7370	0.7070
0.8280	0.7720
0.9100	0.8560
0.9500	0.9110
0.9800	0.9600
1.0000	1.0000

Azeotropic composition: mole fraction of Acetic acid, methyl ester (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of Acetic acid, methyl ester (1) - Liquid
40.00	0.7171
53.33	0.7041
66.66	0.6931
79.99	0.6838
93.32	0.6749
101.30	0.6700
40.00	0.7101
53.33	0.6969
66.66	0.6821
79.99	0.6734
93.32	0.6651
101.30	0.6591

Mole fraction of Methyl Alcohol (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Gas)

Mole fraction of Methyl Alcohol (2) - Liquid	Mole fraction of Methyl Alcohol (2) - Gas
0.0000	0.0000
0.0975	0.1510
0.2110	0.2570
0.3090	0.3230
0.3880	0.3590
0.4830	0.4070
0.5970	0.4640
0.6860	0.5200
0.8210	0.6340
0.8800	0.7130
0.9290	0.8100
0.9490	0.8530
1.0000	1.0000

Mole fraction of Acetic acid, methyl ester (1) [ref]

Fixed		Measured
Temperature, K - Gas	Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
334.65	0.0600	0.1570
333.20	0.1060	0.2370
331.85	0.1520	0.3080
330.80	0.1920	0.3610
330.10	0.2310	0.3980
329.30	0.2730	0.4380
328.89	0.3060	0.4570
328.44	0.3470	0.4850
328.08	0.3750	0.5120
327.83	0.4170	0.5320
327.48	0.4550	0.5540
327.13	0.4910	0.5730
326.98	0.5290	0.5920
326.94	0.5630	0.6120
326.78	0.6020	0.6310
326.69	0.6430	0.6530
326.64	0.6760	0.6730
326.68	0.7160	0.6920
326.84	0.7550	0.7170
327.08	0.7940	0.7460
327.39	0.8380	0.7780
327.88	0.8810	0.8210
328.38	0.9240	0.8680

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0000	0.0000
0.1020	0.2600
0.2030	0.3790
0.2990	0.4680
0.4060	0.5350
0.5110	0.5730
0.6030	0.6280
0.7060	0.6870
0.8060	0.7480
0.9020	0.8450
1.0000	1.0000

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Pressure, kPa = 100 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0000	0.0000
0.0330	0.1000
0.0690	0.1920
0.1090	0.2690
0.1500	0.3280
0.1930	0.3720
0.2350	0.4130
0.2780	0.4470
0.3210	0.4850
0.3680	0.5130
0.4120	0.5370
0.4430	0.5560
0.4860	0.5750
0.5340	0.5990
0.5830	0.6200
0.6240	0.6420
0.6550	0.6560
0.6830	0.6760
0.7200	0.6950
0.7490	0.7130
0.7680	0.7270
0.7880	0.7430
0.8080	0.7570
0.8290	0.7750
0.8520	0.7960
0.8750	0.8180
0.9210	0.8710
0.9670	0.9400
1.0000	1.0000

Mole fraction of Methyl Alcohol (2) [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Methyl Alcohol (2) - Gas	Mole fraction of Methyl Alcohol (2) - Liquid
0.0436	0.0251
0.1744	0.1238
0.1773	0.1259
0.2730	0.2376
0.3212	0.3117
0.3720	0.4014
0.4199	0.4963
0.4641	0.5791
0.5103	0.6671
0.6318	0.8213
0.7061	0.8777
0.7886	0.9280

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Temperature, K = 322.32 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0500	0.1660
0.1010	0.2690
0.2000	0.3920
0.3000	0.4590
0.4000	0.5240
0.5000	0.5740
0.5980	0.6290
0.6460	0.6570
0.7000	0.6870
0.7490	0.7220
0.7980	0.7600
0.8500	0.8070
0.9000	0.8590
0.9490	0.9240

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0000	0.0000
0.0100	0.0330
0.0300	0.0910
0.0610	0.1660
0.0810	0.2080
0.1210	0.2790
0.1620	0.3360
0.2120	0.3940
0.2630	0.4400
0.3030	0.4720
0.3540	0.5060
0.4240	0.5460
0.4950	0.5810
0.5760	0.6200
0.6470	0.6560
0.7370	0.7070
0.8280	0.7720
0.9100	0.8560
0.9500	0.9110
0.9800	0.9600
1.0000	1.0000

Azeotropic composition: mole fraction of Acetic acid, methyl ester (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of Acetic acid, methyl ester (1) - Liquid
40.00	0.7171
53.33	0.7041
66.66	0.6931
79.99	0.6838
93.32	0.6749
101.30	0.6700
40.00	0.7101
53.33	0.6969
66.66	0.6821
79.99	0.6734
93.32	0.6651
101.30	0.6591

Mole fraction of Methyl Alcohol (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Gas)

Mole fraction of Methyl Alcohol (2) - Liquid	Mole fraction of Methyl Alcohol (2) - Gas
0.0000	0.0000
0.0975	0.1510
0.2110	0.2570
0.3090	0.3230
0.3880	0.3590
0.4830	0.4070
0.5970	0.4640
0.6860	0.5200
0.8210	0.6340
0.8800	0.7130
0.9290	0.8100
0.9490	0.8530
1.0000	1.0000

Mole fraction of Acetic acid, methyl ester (1) [ref]

Fixed		Measured
Temperature, K - Gas	Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
334.65	0.0600	0.1570
333.20	0.1060	0.2370
331.85	0.1520	0.3080
330.80	0.1920	0.3610
330.10	0.2310	0.3980
329.30	0.2730	0.4380
328.89	0.3060	0.4570
328.44	0.3470	0.4850
328.08	0.3750	0.5120
327.83	0.4170	0.5320
327.48	0.4550	0.5540
327.13	0.4910	0.5730
326.98	0.5290	0.5920
326.94	0.5630	0.6120
326.78	0.6020	0.6310
326.69	0.6430	0.6530
326.64	0.6760	0.6730
326.68	0.7160	0.6920
326.84	0.7550	0.7170
327.08	0.7940	0.7460
327.39	0.8380	0.7780
327.88	0.8810	0.8210
328.38	0.9240	0.8680

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0000	0.0000
0.1020	0.2600
0.2030	0.3790
0.2990	0.4680
0.4060	0.5350
0.5110	0.5730
0.6030	0.6280
0.7060	0.6870
0.8060	0.7480
0.9020	0.8450
1.0000	1.0000

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Pressure, kPa = 100 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Gas
0.0000	0.0000
0.0330	0.1000
0.0690	0.1920
0.1090	0.2690
0.1500	0.3280
0.1930	0.3720
0.2350	0.4130
0.2780	0.4470
0.3210	0.4850
0.3680	0.5130
0.4120	0.5370
0.4430	0.5560
0.4860	0.5750
0.5340	0.5990
0.5830	0.6200
0.6240	0.6420
0.6550	0.6560
0.6830	0.6760
0.7200	0.6950
0.7490	0.7130
0.7680	0.7270
0.7880	0.7430
0.8080	0.7570
0.8290	0.7750
0.8520	0.7960
0.8750	0.8180
0.9210	0.8710
0.9670	0.9400
1.0000	1.0000

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methyl Alcohol (2) - Liquid	Viscosity, Pa*s - Liquid
293.15	0.0000	0.0004
293.15	0.0471	0.0004
293.15	0.0982	0.0004
293.15	0.1983	0.0004
293.15	0.2912	0.0004
293.15	0.4015	0.0004
293.15	0.5006	0.0004
293.15	0.5878	0.0004
293.15	0.7017	0.0004
293.15	0.8015	0.0005
293.15	0.9008	0.0005
293.15	0.9504	0.0006
293.15	1.0000	0.0006
298.15	0.0000	0.0004
298.15	0.0471	0.0004
298.15	0.0982	0.0004
298.15	0.1983	0.0004
298.15	0.2912	0.0004
298.15	0.4015	0.0004
298.15	0.5006	0.0004
298.15	0.5878	0.0004
298.15	0.7017	0.0004
298.15	0.8015	0.0004
298.15	0.9008	0.0005
298.15	0.9504	0.0005
298.15	1.0000	0.0005
303.15	0.0000	0.0003
303.15	0.0471	0.0003
303.15	0.0982	0.0003
303.15	0.1983	0.0003
303.15	0.2912	0.0003
303.15	0.4015	0.0004
303.15	0.5006	0.0004
303.15	0.5878	0.0004
303.15	0.7017	0.0004
303.15	0.8015	0.0004
303.15	0.9008	0.0005
303.15	0.9504	0.0005
303.15	1.0000	0.0005

Viscosity, Pa*s [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Viscosity, Pa*s - Liquid
0.0939	0.0005
0.1986	0.0005
0.3009	0.0004
0.4016	0.0004
0.4943	0.0004
0.5851	0.0004
0.6941	0.0004
0.7694	0.0004
0.8875	0.0004

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methyl Alcohol (2) - Liquid	Viscosity, Pa*s - Liquid
293.15	0.0000	0.0004
293.15	0.0471	0.0004
293.15	0.0982	0.0004
293.15	0.1983	0.0004
293.15	0.2912	0.0004
293.15	0.4015	0.0004
293.15	0.5006	0.0004
293.15	0.5878	0.0004
293.15	0.7017	0.0004
293.15	0.8015	0.0005
293.15	0.9008	0.0005
293.15	0.9504	0.0006
293.15	1.0000	0.0006
298.15	0.0000	0.0004
298.15	0.0471	0.0004
298.15	0.0982	0.0004
298.15	0.1983	0.0004
298.15	0.2912	0.0004
298.15	0.4015	0.0004
298.15	0.5006	0.0004
298.15	0.5878	0.0004
298.15	0.7017	0.0004
298.15	0.8015	0.0004
298.15	0.9008	0.0005
298.15	0.9504	0.0005
298.15	1.0000	0.0005
303.15	0.0000	0.0003
303.15	0.0471	0.0003
303.15	0.0982	0.0003
303.15	0.1983	0.0003
303.15	0.2912	0.0003
303.15	0.4015	0.0004
303.15	0.5006	0.0004
303.15	0.5878	0.0004
303.15	0.7017	0.0004
303.15	0.8015	0.0004
303.15	0.9008	0.0005
303.15	0.9504	0.0005
303.15	1.0000	0.0005

Viscosity, Pa*s [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Viscosity, Pa*s - Liquid
0.0939	0.0005
0.1986	0.0005
0.3009	0.0004
0.4016	0.0004
0.4943	0.0004
0.5851	0.0004
0.6941	0.0004
0.7694	0.0004
0.8875	0.0004

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Refractive index (Na D-line) - Liquid
0.0939	1.3322
0.1986	1.3376
0.3009	1.3419
0.4016	1.3456
0.4943	1.3485
0.5851	1.351
0.6941	1.3535
0.7694	1.355
0.8875	1.3571

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Refractive index (Na D-line) - Liquid
0.0939	1.3322
0.1986	1.3376
0.3009	1.3419
0.4016	1.3456
0.4943	1.3485
0.5851	1.351
0.6941	1.3535
0.7694	1.355
0.8875	1.3571

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methyl Alcohol (2) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	933.56
293.15	0.0471	930.26
293.15	0.0982	926.48
293.15	0.1983	918.39
293.15	0.2912	909.97
293.15	0.4015	898.52
293.15	0.5006	886.79
293.15	0.5878	875.07
293.15	0.7017	857.33
293.15	0.8015	838.91
293.15	0.9008	817.51
293.15	0.9504	805.16
293.15	1.0000	791.9
298.15	0.0000	926.98
298.15	0.0471	923.71
298.15	0.0982	919.95
298.15	0.1983	911.96
298.15	0.2912	903.65
298.15	0.4015	892.35
298.15	0.5006	880.78
298.15	0.5878	869.25
298.15	0.7017	851.73
298.15	0.8015	833.57
298.15	0.9008	812.45
298.15	0.9504	800.29
298.15	1.0000	787.2
303.15	0.0000	920.34
303.15	0.0471	917.1
303.15	0.0982	913.37
303.15	0.1983	905.46
303.15	0.2912	897.26
303.15	0.4015	886.12
303.15	0.5006	874.71
303.15	0.5878	863.35
303.15	0.7017	846.09
303.15	0.8015	828.19
303.15	0.9008	807.37
303.15	0.9504	795.38
303.15	1.0000	782.48

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
0.0939	810.62
0.1986	833.17
0.3009	851.78
0.4016	867.5
0.4943	880.02
0.5851	890.77
0.6941	902.17
0.7694	909.19
0.8875	918.93

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Methyl Alcohol (2) - Liquid	Mass density, kg/m3 - Liquid
293.15	0.0000	933.56
293.15	0.0471	930.26
293.15	0.0982	926.48
293.15	0.1983	918.39
293.15	0.2912	909.97
293.15	0.4015	898.52
293.15	0.5006	886.79
293.15	0.5878	875.07
293.15	0.7017	857.33
293.15	0.8015	838.91
293.15	0.9008	817.51
293.15	0.9504	805.16
293.15	1.0000	791.9
298.15	0.0000	926.98
298.15	0.0471	923.71
298.15	0.0982	919.95
298.15	0.1983	911.96
298.15	0.2912	903.65
298.15	0.4015	892.35
298.15	0.5006	880.78
298.15	0.5878	869.25
298.15	0.7017	851.73
298.15	0.8015	833.57
298.15	0.9008	812.45
298.15	0.9504	800.29
298.15	1.0000	787.2
303.15	0.0000	920.34
303.15	0.0471	917.1
303.15	0.0982	913.37
303.15	0.1983	905.46
303.15	0.2912	897.26
303.15	0.4015	886.12
303.15	0.5006	874.71
303.15	0.5878	863.35
303.15	0.7017	846.09
303.15	0.8015	828.19
303.15	0.9008	807.37
303.15	0.9504	795.38
303.15	1.0000	782.48

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
0.0939	810.62
0.1986	833.17
0.3009	851.78
0.4016	867.5
0.4943	880.02
0.5851	890.77
0.6941	902.17
0.7694	909.19
0.8875	918.93

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Liquid)

Mole fraction of Methyl Alcohol (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.1870	320.35
0.2610	320.15
0.4180	320.25
0.7430	322.85
0.8520	325.65

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Gas)

Mole fraction of Methyl Alcohol (2) - Gas	Boiling temperature at pressure P, K - Liquid
0.1870	320.35
0.2610	320.15
0.4180	320.25
0.7430	322.85
0.8520	325.65

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	337.69
0.0100	337.10
0.0300	336.03
0.0610	334.62
0.0810	333.81
0.1210	332.41
0.1620	331.28
0.2120	330.16
0.2630	329.28
0.3030	328.72
0.3540	328.16
0.4240	327.58
0.4950	327.17
0.5760	326.89
0.6470	326.77
0.7370	326.85
0.8280	327.27
0.9100	328.14
0.9500	328.87
0.9800	329.60
1.0000	330.20

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
40.00	0.0000	315.49
40.00	0.0998	310.28
40.00	0.2001	307.38
40.00	0.2999	305.58
40.00	0.4047	304.53
40.00	0.5001	303.72
40.00	0.6000	303.21
40.00	0.7003	302.92
40.00	0.8004	303.05
40.00	0.8996	304.13
40.00	1.0000	305.65
53.33	0.0000	321.98
53.33	0.0998	316.91
53.33	0.2001	314.07
53.33	0.2999	312.31
53.33	0.4047	311.22
53.33	0.5001	310.41
53.33	0.6000	309.98
53.33	0.7003	309.67
53.33	0.8004	309.99
53.33	0.8996	311.05
53.33	1.0000	312.68
66.66	0.0000	327.23
66.66	0.0998	322.29
66.66	0.2001	319.52
66.66	0.2999	317.75
66.66	0.4047	316.65
66.66	0.5001	315.90
66.66	0.6000	315.52
66.66	0.7003	315.30
66.66	0.8004	315.63
66.66	0.8996	316.68
66.66	1.0000	318.45
79.99	0.0000	331.66
79.99	0.0998	326.86
79.99	0.2001	324.09
79.99	0.2999	322.39
79.99	0.4047	321.29
79.99	0.5001	320.60
79.99	0.6000	320.28
79.99	0.7003	320.13
79.99	0.8004	320.45
79.99	0.8996	321.48
79.99	1.0000	323.36
93.32	0.0000	335.51
93.32	0.0998	330.85
93.32	0.2001	328.08
93.32	0.2999	326.45
93.32	0.4047	325.34
93.32	0.5001	324.74
93.32	0.6000	324.45
93.32	0.7003	324.38
93.32	0.8004	324.74
93.32	0.8996	325.68
93.32	1.0000	327.68
101.30	0.0000	337.60
101.30	0.0998	333.01
101.30	0.2001	330.25
101.30	0.2999	328.65
101.30	0.4047	327.53
101.30	0.5001	326.96
101.30	0.6000	326.67
101.30	0.7003	326.66
101.30	0.8004	327.00
101.30	0.8996	327.97
101.30	1.0000	330.04
40.00	0.0000	315.49
40.00	0.0998	310.28
40.00	0.2001	307.38
40.00	0.2999	305.58
40.00	0.4047	304.53
40.00	0.5001	303.72
40.00	0.6000	303.21
40.00	0.7003	302.92
40.00	0.8004	303.05
40.00	0.8996	304.13
40.00	1.0000	305.65
53.33	0.0000	321.98
53.33	0.0998	316.91
53.33	0.2001	314.07
53.33	0.2999	312.31
53.33	0.4047	311.22
53.33	0.5001	310.41
53.33	0.6000	309.98
53.33	0.7003	309.67
53.33	0.8004	309.99
53.33	0.8996	311.05
53.33	1.0000	312.68
66.66	0.0000	327.23
66.66	0.0998	322.29
66.66	0.2001	319.52
66.66	0.2999	317.75
66.66	0.4047	316.65
66.66	0.5001	315.90
66.66	0.6000	315.52
66.66	0.7003	315.30
66.66	0.8004	315.63
66.66	0.8996	316.68
66.66	1.0000	318.45
79.99	0.0000	331.66
79.99	0.0998	326.86
79.99	0.2001	324.09
79.99	0.2999	322.39
79.99	0.4047	321.29
79.99	0.5001	320.60
79.99	0.6000	320.28
79.99	0.7003	320.13
79.99	0.8004	320.45
79.99	0.8996	321.48
79.99	1.0000	323.36
93.32	0.0000	335.51
93.32	0.0998	330.85
93.32	0.2001	328.08
93.32	0.2999	326.45
93.32	0.4047	325.34
93.32	0.5001	324.74
93.32	0.6000	324.45
93.32	0.7003	324.38
93.32	0.8004	324.74
93.32	0.8996	325.68
93.32	1.0000	327.68
101.30	0.0000	337.60
101.30	0.0998	333.01
101.30	0.2001	330.25
101.30	0.2999	328.65
101.30	0.4047	327.53
101.30	0.5001	326.96
101.30	0.6000	326.67
101.30	0.7003	326.66
101.30	0.8004	327.00
101.30	0.8996	327.97
101.30	1.0000	330.04

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Methyl Alcohol (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	330.05
0.0975	327.85
0.2110	326.95
0.3090	326.70
0.3880	326.75
0.4830	326.95
0.5970	327.65
0.6860	328.60
0.8210	330.75
0.8800	332.45
0.9290	334.15
0.9490	335.10
1.0000	337.65

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0600	334.65
0.1060	333.20
0.1520	331.85
0.1920	330.80
0.2310	330.10
0.2730	329.30
0.3060	328.89
0.3470	328.44
0.3750	328.08
0.4170	327.83
0.4550	327.48
0.4910	327.13
0.5290	326.98
0.5630	326.94
0.6020	326.78
0.6430	326.69
0.6760	326.64
0.7160	326.68
0.7550	326.84
0.7940	327.08
0.8380	327.39
0.8810	327.88
0.9240	328.38

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	337.57
0.1020	332.82
0.2030	330.08
0.2990	328.51
0.4060	327.65
0.5110	326.96
0.6030	326.79
0.7060	326.60
0.8060	326.96
0.9020	327.89
1.0000	329.97

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 100 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	337.41
0.0330	335.44
0.0690	333.70
0.1090	332.14
0.1500	330.89
0.1930	329.95
0.2350	329.18
0.2780	328.53
0.3210	327.99
0.3680	327.55
0.4120	327.20
0.4430	326.92
0.4860	326.71
0.5340	326.54
0.5830	326.42
0.6240	326.35
0.6550	326.32
0.6830	326.35
0.7200	326.39
0.7490	326.46
0.7680	326.54
0.7880	326.63
0.8080	326.74
0.8290	326.89
0.8520	327.07
0.8750	327.28
0.9210	327.90
0.9670	328.82
1.0000	329.72

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Liquid)

Mole fraction of Methyl Alcohol (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.1870	320.35
0.2610	320.15
0.4180	320.25
0.7430	322.85
0.8520	325.65

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 77.3 (Gas)

Mole fraction of Methyl Alcohol (2) - Gas	Boiling temperature at pressure P, K - Liquid
0.1870	320.35
0.2610	320.15
0.4180	320.25
0.7430	322.85
0.8520	325.65

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	337.69
0.0100	337.10
0.0300	336.03
0.0610	334.62
0.0810	333.81
0.1210	332.41
0.1620	331.28
0.2120	330.16
0.2630	329.28
0.3030	328.72
0.3540	328.16
0.4240	327.58
0.4950	327.17
0.5760	326.89
0.6470	326.77
0.7370	326.85
0.8280	327.27
0.9100	328.14
0.9500	328.87
0.9800	329.60
1.0000	330.20

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
40.00	0.0000	315.49
40.00	0.0998	310.28
40.00	0.2001	307.38
40.00	0.2999	305.58
40.00	0.4047	304.53
40.00	0.5001	303.72
40.00	0.6000	303.21
40.00	0.7003	302.92
40.00	0.8004	303.05
40.00	0.8996	304.13
40.00	1.0000	305.65
53.33	0.0000	321.98
53.33	0.0998	316.91
53.33	0.2001	314.07
53.33	0.2999	312.31
53.33	0.4047	311.22
53.33	0.5001	310.41
53.33	0.6000	309.98
53.33	0.7003	309.67
53.33	0.8004	309.99
53.33	0.8996	311.05
53.33	1.0000	312.68
66.66	0.0000	327.23
66.66	0.0998	322.29
66.66	0.2001	319.52
66.66	0.2999	317.75
66.66	0.4047	316.65
66.66	0.5001	315.90
66.66	0.6000	315.52
66.66	0.7003	315.30
66.66	0.8004	315.63
66.66	0.8996	316.68
66.66	1.0000	318.45
79.99	0.0000	331.66
79.99	0.0998	326.86
79.99	0.2001	324.09
79.99	0.2999	322.39
79.99	0.4047	321.29
79.99	0.5001	320.60
79.99	0.6000	320.28
79.99	0.7003	320.13
79.99	0.8004	320.45
79.99	0.8996	321.48
79.99	1.0000	323.36
93.32	0.0000	335.51
93.32	0.0998	330.85
93.32	0.2001	328.08
93.32	0.2999	326.45
93.32	0.4047	325.34
93.32	0.5001	324.74
93.32	0.6000	324.45
93.32	0.7003	324.38
93.32	0.8004	324.74
93.32	0.8996	325.68
93.32	1.0000	327.68
101.30	0.0000	337.60
101.30	0.0998	333.01
101.30	0.2001	330.25
101.30	0.2999	328.65
101.30	0.4047	327.53
101.30	0.5001	326.96
101.30	0.6000	326.67
101.30	0.7003	326.66
101.30	0.8004	327.00
101.30	0.8996	327.97
101.30	1.0000	330.04
40.00	0.0000	315.49
40.00	0.0998	310.28
40.00	0.2001	307.38
40.00	0.2999	305.58
40.00	0.4047	304.53
40.00	0.5001	303.72
40.00	0.6000	303.21
40.00	0.7003	302.92
40.00	0.8004	303.05
40.00	0.8996	304.13
40.00	1.0000	305.65
53.33	0.0000	321.98
53.33	0.0998	316.91
53.33	0.2001	314.07
53.33	0.2999	312.31
53.33	0.4047	311.22
53.33	0.5001	310.41
53.33	0.6000	309.98
53.33	0.7003	309.67
53.33	0.8004	309.99
53.33	0.8996	311.05
53.33	1.0000	312.68
66.66	0.0000	327.23
66.66	0.0998	322.29
66.66	0.2001	319.52
66.66	0.2999	317.75
66.66	0.4047	316.65
66.66	0.5001	315.90
66.66	0.6000	315.52
66.66	0.7003	315.30
66.66	0.8004	315.63
66.66	0.8996	316.68
66.66	1.0000	318.45
79.99	0.0000	331.66
79.99	0.0998	326.86
79.99	0.2001	324.09
79.99	0.2999	322.39
79.99	0.4047	321.29
79.99	0.5001	320.60
79.99	0.6000	320.28
79.99	0.7003	320.13
79.99	0.8004	320.45
79.99	0.8996	321.48
79.99	1.0000	323.36
93.32	0.0000	335.51
93.32	0.0998	330.85
93.32	0.2001	328.08
93.32	0.2999	326.45
93.32	0.4047	325.34
93.32	0.5001	324.74
93.32	0.6000	324.45
93.32	0.7003	324.38
93.32	0.8004	324.74
93.32	0.8996	325.68
93.32	1.0000	327.68
101.30	0.0000	337.60
101.30	0.0998	333.01
101.30	0.2001	330.25
101.30	0.2999	328.65
101.30	0.4047	327.53
101.30	0.5001	326.96
101.30	0.6000	326.67
101.30	0.7003	326.66
101.30	0.8004	327.00
101.30	0.8996	327.97
101.30	1.0000	330.04

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Methyl Alcohol (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	330.05
0.0975	327.85
0.2110	326.95
0.3090	326.70
0.3880	326.75
0.4830	326.95
0.5970	327.65
0.6860	328.60
0.8210	330.75
0.8800	332.45
0.9290	334.15
0.9490	335.10
1.0000	337.65

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0600	334.65
0.1060	333.20
0.1520	331.85
0.1920	330.80
0.2310	330.10
0.2730	329.30
0.3060	328.89
0.3470	328.44
0.3750	328.08
0.4170	327.83
0.4550	327.48
0.4910	327.13
0.5290	326.98
0.5630	326.94
0.6020	326.78
0.6430	326.69
0.6760	326.64
0.7160	326.68
0.7550	326.84
0.7940	327.08
0.8380	327.39
0.8810	327.88
0.9240	328.38

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	337.57
0.1020	332.82
0.2030	330.08
0.2990	328.51
0.4060	327.65
0.5110	326.96
0.6030	326.79
0.7060	326.60
0.8060	326.96
0.9020	327.89
1.0000	329.97

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 100 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	337.41
0.0330	335.44
0.0690	333.70
0.1090	332.14
0.1500	330.89
0.1930	329.95
0.2350	329.18
0.2780	328.53
0.3210	327.99
0.3680	327.55
0.4120	327.20
0.4430	326.92
0.4860	326.71
0.5340	326.54
0.5830	326.42
0.6240	326.35
0.6550	326.32
0.6830	326.35
0.7200	326.39
0.7490	326.46
0.7680	326.54
0.7880	326.63
0.8080	326.74
0.8290	326.89
0.8520	327.07
0.8750	327.28
0.9210	327.90
0.9670	328.82
1.0000	329.72

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Methyl Alcohol (2) - Gas	Vapor or sublimation pressure, kPa - Gas
0.0000	79.21
0.0436	80.99
0.1744	85.82
0.1773	85.94
0.2730	88.46
0.3212	88.99
0.3720	88.82
0.4199	87.77
0.4641	86.16
0.5103	83.81
0.6318	76.24
0.7061	71.37
0.7886	66.36
1.0000	55.61

Azeotropic temperature, K [ref]

Pressure, kPa - Liquid	Azeotropic temperature, K - Liquid
40.00	303.10
53.33	309.88
66.66	315.44
79.99	320.19
93.32	324.38
101.30	326.60
40.00	303.15
53.33	309.98
66.66	315.52
79.99	320.22
93.32	324.32
101.30	326.55

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Methyl Alcohol (2) - Gas	Vapor or sublimation pressure, kPa - Gas
0.0000	79.21
0.0436	80.99
0.1744	85.82
0.1773	85.94
0.2730	88.46
0.3212	88.99
0.3720	88.82
0.4199	87.77
0.4641	86.16
0.5103	83.81
0.6318	76.24
0.7061	71.37
0.7886	66.36
1.0000	55.61

Azeotropic temperature, K [ref]

Pressure, kPa - Liquid	Azeotropic temperature, K - Liquid
40.00	303.10
53.33	309.88
66.66	315.44
79.99	320.19
93.32	324.38
101.30	326.60
40.00	303.15
53.33	309.98
66.66	315.52
79.99	320.22
93.32	324.32
101.30	326.55

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0939	-1.5000e-08
0.1986	-3.4000e-08
0.3009	-5.3000e-08
0.4016	-6.9000e-08
0.4943	-7.4000e-08
0.5851	-7.1000e-08
0.6941	-6.6000e-08
0.7694	-5.7000e-08
0.8875	-3.2000e-08

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0939	-1.5000e-08
0.1986	-3.4000e-08
0.3009	-5.3000e-08
0.4016	-6.9000e-08
0.4943	-7.4000e-08
0.5851	-7.1000e-08
0.6941	-6.6000e-08
0.7694	-5.7000e-08
0.8875	-3.2000e-08

Sources

• Isothermal vapour liquid equilibrium with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system, and in five binary subsystems
• Experimental measurements of vapor liquid equilibria at low pressure: Systems containing alcohols, esters and organic acids
• Vapor-liquid equilibria of ternary systems with 1-ethyl-3-methylimidazolium ethyl sulfate using headspace gas chromatography
• Separation of methyl acetate + methanol azeotropic mixture using ionic liquids as entrainers
• Vapor-liquid equilibria of binary and ternary mixtures containing ethyl lactate and effect of ethyl lactate as entrainer
• Isobaric vapor-liquid equilibrium for methanol + methyl acetate with ionic liquids [OMMIM][Tf2N] and [OMIM][Tf2N] as entrainers at 101.3 kPa
• Density, dynamic viscosity, and derived properties of binary mixtures of methanol or ethanol with water, ethyl acetate, and methyl acetate at T = (293.15, 298.15, and 303.15) K
• Physical and excess properties of (methyl acetate + methanol + 1-octyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide) and its binary mixtures at T = 298.15 K and atmospheric pressure
• Determination of Vapor Liquid Equilibrium of Methyl Acetate + Methanol + 1-Alkyl-3-methylimidazolium Dialkylphosphates at 101.3 kPa
• Vapor-Liquid Equilibrium and Liquid-Liquid Equilibrium of Methyl Acetate + Methanol + 1-Ethyl-3-methylimidazolium Acetate
• Isobaric Vapor-Liquid Equilibria for Methyl Acetate + Methanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa