Mixture of Acetic acid, methyl ester + Water

Datasets

1. Activity coefficient (2)
2. Mole fraction (14)
3. Interfacial tension, N/m (2)
4. ρ_l - Mass density, kg/m3 (4)
5. γ - Surface tension liquid-gas, N/m (2)
6. Vapor or sublimation pressure, kPa (4)

Activity coefficient of Acetic acid, methyl ester (1) [ref]

Operational conditions:

• Pressure, kPa = 101.325 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of Acetic acid, methyl ester (1) - Liquid
303.25	26.2
313.25	28.4
323.25	29.8
333.25	31.2
343.25	31.6

Activity coefficient of Acetic acid, methyl ester (1) [ref]

Operational conditions:

• Pressure, kPa = 101.325 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of Acetic acid, methyl ester (1) - Liquid
303.25	26.2
313.25	28.4
323.25	29.8
333.25	31.2
343.25	31.6

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
298.20	101.32	0.2636

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
298.20	101.32	0.9300

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Gas	Mole fraction of Acetic acid, methyl ester (1) - Liquid
0.0066	0.0001
0.0212	0.0002
0.0361	0.0004
0.8583	0.7393
0.8787	0.8466
0.9053	0.9012

Mole fraction of Acetic acid, methyl ester (1) [ref]

Temperature, K - Liquid mixture 1	Mole fraction of Acetic acid, methyl ester (1) - Liquid mixture 1
323.24	0.6594
343.15	0.5571

Mole fraction of Acetic acid, methyl ester (1) [ref]

Temperature, K - Liquid mixture 2	Mole fraction of Acetic acid, methyl ester (1) - Liquid mixture 2
323.24	0.0700
343.15	0.0770

Mole fraction of Acetic acid, methyl ester (1) [ref]

Temperature, K - Gas	Mole fraction of Acetic acid, methyl ester (1) - Gas
323.24	0.8613
343.15	0.8249

Henry's Law constant (molality scale), kPa*kg/mol of Acetic acid, methyl ester (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (molality scale), kPa*kg/mol of Acetic acid, methyl ester (1) - Liquid
274.15	1.062
294.65	5.3344
294.65	7.3947
296.15	7.5321
310.15	34.15
320.15	52.409
331.15	83.144
333.15	124.56

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
298.20	101.32	0.2636

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
298.20	101.32	0.9300

Mole fraction of Acetic acid, methyl ester (1) [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Gas	Mole fraction of Acetic acid, methyl ester (1) - Liquid
0.0066	0.0001
0.0212	0.0002
0.0361	0.0004
0.8583	0.7393
0.8787	0.8466
0.9053	0.9012

Mole fraction of Acetic acid, methyl ester (1) [ref]

Temperature, K - Liquid mixture 1	Mole fraction of Acetic acid, methyl ester (1) - Liquid mixture 1
323.24	0.6594
343.15	0.5571

Mole fraction of Acetic acid, methyl ester (1) [ref]

Temperature, K - Liquid mixture 2	Mole fraction of Acetic acid, methyl ester (1) - Liquid mixture 2
323.24	0.0700
343.15	0.0770

Mole fraction of Acetic acid, methyl ester (1) [ref]

Temperature, K - Gas	Mole fraction of Acetic acid, methyl ester (1) - Gas
323.24	0.8613
343.15	0.8249

Henry's Law constant (molality scale), kPa*kg/mol of Acetic acid, methyl ester (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (molality scale), kPa*kg/mol of Acetic acid, methyl ester (1) - Liquid
274.15	1.062
294.65	5.3344
294.65	7.3947
296.15	7.5321
310.15	34.15
320.15	52.409
331.15	83.144
333.15	124.56

Interfacial tension, N/m [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Interfacial tension, N/m - Liquid mixture 1
278.15	0.0019
288.15	0.0018
298.15	0.0017
308.15	0.0015
318.15	0.0012
328.15	0.0008

Interfacial tension, N/m [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Interfacial tension, N/m - Liquid mixture 1
278.15	0.0019
288.15	0.0018
298.15	0.0017
308.15	0.0015
318.15	0.0012
328.15	0.0008

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass density, kg/m3 - Liquid mixture 1
278.15	1011.05
288.15	1005.44
298.15	999.47
308.15	992.96
318.15	985.33
328.15	978.33

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mass density, kg/m3 - Liquid mixture 2
278.15	963.17
288.15	952.19
298.15	941.82
308.15	931.39
318.15	924.24
328.15	911.48

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass density, kg/m3 - Liquid mixture 1
278.15	1011.05
288.15	1005.44
298.15	999.47
308.15	992.96
318.15	985.33
328.15	978.33

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mass density, kg/m3 - Liquid mixture 2
278.15	963.17
288.15	952.19
298.15	941.82
308.15	931.39
318.15	924.24
328.15	911.48

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0000	0.0716
0.0040	0.0619
0.0047	0.0606
0.0056	0.0597
0.0069	0.0576
0.0093	0.0547
0.0115	0.0532
0.0147	0.0499
0.0183	0.0482
0.0214	0.0467
0.0245	0.0444
0.0290	0.0426
0.0341	0.0403
0.0433	0.0366
0.0523	0.0335
0.0586	0.0316
0.0702	0.0291
1.0000	0.0248

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Acetic acid, methyl ester (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0000	0.0716
0.0040	0.0619
0.0047	0.0606
0.0056	0.0597
0.0069	0.0576
0.0093	0.0547
0.0115	0.0532
0.0147	0.0499
0.0183	0.0482
0.0214	0.0467
0.0245	0.0444
0.0290	0.0426
0.0341	0.0403
0.0433	0.0366
0.0523	0.0335
0.0586	0.0316
0.0702	0.0291
1.0000	0.0248

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Gas	Vapor or sublimation pressure, kPa - Gas
0.0000	12.35
0.0066	12.41
0.0212	12.49
0.0361	12.86
0.8583	79.26
0.8787	80.39
0.9053	80.75
1.0000	79.21

Vapor or sublimation pressure, kPa [ref]

Temperature, K - Gas	Vapor or sublimation pressure, kPa - Gas
323.24	78.20
343.15	157.00

Vapor or sublimation pressure, kPa [ref]

Operational condition: Temperature, K = 323.15 (Gas)

Mole fraction of Acetic acid, methyl ester (1) - Gas	Vapor or sublimation pressure, kPa - Gas
0.0000	12.35
0.0066	12.41
0.0212	12.49
0.0361	12.86
0.8583	79.26
0.8787	80.39
0.9053	80.75
1.0000	79.21

Vapor or sublimation pressure, kPa [ref]

Temperature, K - Gas	Vapor or sublimation pressure, kPa - Gas
323.24	78.20
343.15	157.00

Sources

• (Liquid + liquid) equilibria of (water + 1-propanol + solvent) at T = 298.2K
• Isothermal vapour liquid equilibrium with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system, and in five binary subsystems
• Multiphase equilibria for mixtures containing water, acetic acid, propionic acid, methyl acetate and methyl propionate
• Densities and interfacial tensions for fatty acid methyl esters (from methyl formate to methyl heptanoate) + water demixed mixtures at atmospheric pressure conditions
• Measurement of Activity Coefficients at Infinite Dilution of Benzene, Toluene, Ethanol, Esters, Ketones, and Ethers at Various Temperatures in Water Using the Dilutor Technique
• Determination of Henry's Law Constants Using Internal Standards with Benchmark Values
• Surface Tension Data of Aqueous Binary Mixtures of Methyl, Ethyl, Propyl, and Butyl Acetates at 298.15 K