Mixture of Hexane, 1-chloro- + 1,4-Dioxane

Datasets

1. Mole fraction (4)
2. ν - Kinematic viscosity, m2/s (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)
4. ρ_l - Mass density, kg/m3 (2)
5. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of 1,4-Dioxane (2) [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Pressure, kPa - Gas	Mole fraction of 1,4-Dioxane (2) - Gas
0.0704	40.00	0.1937
0.0716	101.33	0.1782
0.0820	101.33	0.2407
0.0844	40.00	0.2429
0.1823	40.00	0.4243
0.1828	101.33	0.3851
0.2384	40.00	0.5070
0.2697	101.33	0.5343
0.3234	101.33	0.5814
0.3250	40.00	0.6087
0.4258	40.00	0.6906
0.4279	101.33	0.6841
0.5185	101.33	0.7423
0.5261	40.00	0.7611
0.6554	101.33	0.8273
0.6665	40.00	0.8368
0.7055	40.00	0.8585
0.7086	101.33	0.8509
0.7386	40.00	0.8734
0.7422	101.33	0.8678
0.8027	40.00	0.9020
0.8040	101.33	0.8981
0.8487	101.33	0.9209
0.8492	40.00	0.9239
0.8829	40.00	0.9385
0.8841	101.33	0.9380
0.9265	40.00	0.9596
0.9268	101.33	0.9587

Mole fraction of 1,4-Dioxane (2) [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Temperature, K - Gas	Mole fraction of 1,4-Dioxane (2) - Gas
0.0194	298.15	0.0981
0.0194	298.15	0.0981
0.0210	328.15	0.0862
0.0668	298.15	0.2731
0.0713	328.15	0.2474
0.1261	298.15	0.4301
0.1285	328.15	0.4130
0.1898	298.15	0.5421
0.1980	328.15	0.5086
0.2508	328.15	0.5794
0.2565	298.15	0.6252
0.3235	298.15	0.6889
0.3303	328.15	0.6558
0.3994	328.15	0.7119
0.4045	298.15	0.7429
0.4794	298.15	0.7857
0.4836	328.15	0.7644
0.5517	328.15	0.8013
0.5632	298.15	0.8252
0.6367	298.15	0.8532
0.6385	328.15	0.8402
0.7129	328.15	0.8721
0.7131	298.15	0.8819
0.7871	298.15	0.9089
0.7900	328.15	0.9021
0.8654	298.15	0.9376
0.8666	328.15	0.9350
0.9462	328.15	0.9705
0.9477	298.15	0.9725

Mole fraction of 1,4-Dioxane (2) [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Pressure, kPa - Gas	Mole fraction of 1,4-Dioxane (2) - Gas
0.0704	40.00	0.1937
0.0716	101.33	0.1782
0.0820	101.33	0.2407
0.0844	40.00	0.2429
0.1823	40.00	0.4243
0.1828	101.33	0.3851
0.2384	40.00	0.5070
0.2697	101.33	0.5343
0.3234	101.33	0.5814
0.3250	40.00	0.6087
0.4258	40.00	0.6906
0.4279	101.33	0.6841
0.5185	101.33	0.7423
0.5261	40.00	0.7611
0.6554	101.33	0.8273
0.6665	40.00	0.8368
0.7055	40.00	0.8585
0.7086	101.33	0.8509
0.7386	40.00	0.8734
0.7422	101.33	0.8678
0.8027	40.00	0.9020
0.8040	101.33	0.8981
0.8487	101.33	0.9209
0.8492	40.00	0.9239
0.8829	40.00	0.9385
0.8841	101.33	0.9380
0.9265	40.00	0.9596
0.9268	101.33	0.9587

Mole fraction of 1,4-Dioxane (2) [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Temperature, K - Gas	Mole fraction of 1,4-Dioxane (2) - Gas
0.0194	298.15	0.0981
0.0194	298.15	0.0981
0.0210	328.15	0.0862
0.0668	298.15	0.2731
0.0713	328.15	0.2474
0.1261	298.15	0.4301
0.1285	328.15	0.4130
0.1898	298.15	0.5421
0.1980	328.15	0.5086
0.2508	328.15	0.5794
0.2565	298.15	0.6252
0.3235	298.15	0.6889
0.3303	328.15	0.6558
0.3994	328.15	0.7119
0.4045	298.15	0.7429
0.4794	298.15	0.7857
0.4836	328.15	0.7644
0.5517	328.15	0.8013
0.5632	298.15	0.8252
0.6367	298.15	0.8532
0.6385	328.15	0.8402
0.7129	328.15	0.8721
0.7131	298.15	0.8819
0.7871	298.15	0.9089
0.7900	328.15	0.9021
0.8654	298.15	0.9376
0.8666	328.15	0.9350
0.9462	328.15	0.9705
0.9477	298.15	0.9725

Kinematic viscosity, m2/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1,4-Dioxane (2) - Liquid	Kinematic viscosity, m2/s - Liquid
298.15	0.0000	7.9480e-07
298.15	0.0469	8.0020e-07
298.15	0.1078	8.1000e-07
298.15	0.2033	8.1560e-07
298.15	0.3010	8.2770e-07
298.15	0.3944	8.4400e-07
298.15	0.5216	8.7270e-07
298.15	0.5965	8.9680e-07
298.15	0.7642	9.6670e-07
298.15	0.8007	9.8530e-07
298.15	0.9006	1.0538e-06
298.15	0.9527	1.1002e-06
298.15	1.0000	1.1487e-06
313.15	0.0000	6.7660e-07
313.15	0.0469	6.8040e-07
313.15	0.1078	6.8720e-07
313.15	0.2033	6.8990e-07
313.15	0.3010	6.9840e-07
313.15	0.3944	7.0880e-07
313.15	0.5216	7.2890e-07
313.15	0.5965	7.4580e-07
313.15	0.7642	7.9360e-07
313.15	0.8007	8.0700e-07
313.15	0.9006	8.5660e-07
313.15	0.9527	8.8590e-07
313.15	1.0000	9.2000e-07

Kinematic viscosity, m2/s [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1,4-Dioxane (2) - Liquid	Kinematic viscosity, m2/s - Liquid
298.15	0.0000	7.9480e-07
298.15	0.0469	8.0020e-07
298.15	0.1078	8.1000e-07
298.15	0.2033	8.1560e-07
298.15	0.3010	8.2770e-07
298.15	0.3944	8.4400e-07
298.15	0.5216	8.7270e-07
298.15	0.5965	8.9680e-07
298.15	0.7642	9.6670e-07
298.15	0.8007	9.8530e-07
298.15	0.9006	1.0538e-06
298.15	0.9527	1.1002e-06
298.15	1.0000	1.1487e-06
313.15	0.0000	6.7660e-07
313.15	0.0469	6.8040e-07
313.15	0.1078	6.8720e-07
313.15	0.2033	6.8990e-07
313.15	0.3010	6.9840e-07
313.15	0.3944	7.0880e-07
313.15	0.5216	7.2890e-07
313.15	0.5965	7.4580e-07
313.15	0.7642	7.9360e-07
313.15	0.8007	8.0700e-07
313.15	0.9006	8.5660e-07
313.15	0.9527	8.8590e-07
313.15	1.0000	9.2000e-07

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0194	298.15	1.38
0.0194	298.15	1.38
0.0210	328.15	6.51
0.0668	298.15	1.65
0.0713	328.15	7.67
0.1261	298.15	2.02
0.1285	328.15	8.84
0.1898	298.15	2.29
0.1980	328.15	10.12
0.2508	328.15	11.08
0.2565	298.15	2.66
0.3235	298.15	2.91
0.3303	328.15	12.42
0.3994	328.15	13.33
0.4045	298.15	3.23
0.4794	298.15	3.46
0.4836	328.15	14.47
0.5517	328.15	15.27
0.5632	298.15	3.73
0.6367	298.15	3.90
0.6385	328.15	16.24
0.7129	328.15	16.97
0.7131	298.15	4.14
0.7871	298.15	4.28
0.7900	328.15	17.73
0.8654	298.15	4.50
0.8666	328.15	18.42
0.9462	328.15	19.16
0.9477	298.15	4.67

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0194	298.15	1.38
0.0194	298.15	1.38
0.0210	328.15	6.51
0.0668	298.15	1.65
0.0713	328.15	7.67
0.1261	298.15	2.02
0.1285	328.15	8.84
0.1898	298.15	2.29
0.1980	328.15	10.12
0.2508	328.15	11.08
0.2565	298.15	2.66
0.3235	298.15	2.91
0.3303	328.15	12.42
0.3994	328.15	13.33
0.4045	298.15	3.23
0.4794	298.15	3.46
0.4836	328.15	14.47
0.5517	328.15	15.27
0.5632	298.15	3.73
0.6367	298.15	3.90
0.6385	328.15	16.24
0.7129	328.15	16.97
0.7131	298.15	4.14
0.7871	298.15	4.28
0.7900	328.15	17.73
0.8654	298.15	4.50
0.8666	328.15	18.42
0.9462	328.15	19.16
0.9477	298.15	4.67

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mass fraction of 1,4-Dioxane (2) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.0000	873.55
298.15	0.0469	877.66
298.15	0.1078	883.21
298.15	0.2033	892.72
298.15	0.3010	903.47
298.15	0.3944	914.69
298.15	0.5216	931.94
298.15	0.5965	943.35
298.15	0.7642	973.0
298.15	0.8007	980.31
298.15	0.9006	1002.47
298.15	0.9527	1015.27
298.15	1.0000	1027.86
313.15	0.0000	859.0
313.15	0.0469	863.17
313.15	0.1078	868.6
313.15	0.2033	877.95
313.15	0.3010	888.46
313.15	0.3944	899.55
313.15	0.5216	916.72
313.15	0.5965	928.0
313.15	0.7642	957.16
313.15	0.8007	964.44
313.15	0.9006	985.99
313.15	0.9527	998.53
313.15	1.0000	1010.65

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mass fraction of 1,4-Dioxane (2) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.0000	873.55
298.15	0.0469	877.66
298.15	0.1078	883.21
298.15	0.2033	892.72
298.15	0.3010	903.47
298.15	0.3944	914.69
298.15	0.5216	931.94
298.15	0.5965	943.35
298.15	0.7642	973.0
298.15	0.8007	980.31
298.15	0.9006	1002.47
298.15	0.9527	1015.27
298.15	1.0000	1027.86
313.15	0.0000	859.0
313.15	0.0469	863.17
313.15	0.1078	868.6
313.15	0.2033	877.95
313.15	0.3010	888.46
313.15	0.3944	899.55
313.15	0.5216	916.72
313.15	0.5965	928.0
313.15	0.7642	957.16
313.15	0.8007	964.44
313.15	0.9006	985.99
313.15	0.9527	998.53
313.15	1.0000	1010.65

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0704	40.00	372.20
0.0716	101.33	403.02
0.0820	101.33	401.86
0.0844	40.00	370.85
0.1823	40.00	365.52
0.1828	101.33	396.53
0.2384	40.00	362.99
0.2697	101.33	392.25
0.3234	101.33	389.61
0.3250	40.00	359.78
0.4258	40.00	356.23
0.4279	101.33	385.99
0.5185	101.33	383.41
0.5261	40.00	353.97
0.6554	101.33	380.08
0.6665	40.00	351.35
0.7055	40.00	350.84
0.7086	101.33	379.24
0.7386	40.00	350.32
0.7422	101.33	378.68
0.8027	40.00	349.44
0.8040	101.33	377.58
0.8487	101.33	376.86
0.8492	40.00	348.73
0.8829	40.00	348.29
0.8841	101.33	376.25
0.9265	40.00	347.74
0.9268	101.33	375.64
1.0000	101.33	374.47

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of 1,4-Dioxane (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0704	40.00	372.20
0.0716	101.33	403.02
0.0820	101.33	401.86
0.0844	40.00	370.85
0.1823	40.00	365.52
0.1828	101.33	396.53
0.2384	40.00	362.99
0.2697	101.33	392.25
0.3234	101.33	389.61
0.3250	40.00	359.78
0.4258	40.00	356.23
0.4279	101.33	385.99
0.5185	101.33	383.41
0.5261	40.00	353.97
0.6554	101.33	380.08
0.6665	40.00	351.35
0.7055	40.00	350.84
0.7086	101.33	379.24
0.7386	40.00	350.32
0.7422	101.33	378.68
0.8027	40.00	349.44
0.8040	101.33	377.58
0.8487	101.33	376.86
0.8492	40.00	348.73
0.8829	40.00	348.29
0.8841	101.33	376.25
0.9265	40.00	347.74
0.9268	101.33	375.64
1.0000	101.33	374.47

Sources

• Vapour liquid equilibrium of cyclic ethers with 1-chlorohexane: Experimental results and UNIFAC predictions
• Isothermal (vapour + liquid) equilibrium of (cyclic ethers + chlorohexane) mixtures: Experimental results and SAFT modelling
• Experimental and predicted viscosities of binary mixtures of cyclic ethers with 1-chloropentane or 1-chlorohexane at 283.15, 298.15, and 313.15K