Mixture of n-Hexane + 1-Hexene

Datasets

1. Activity coefficient (4)
2. Mole fraction (2)
3. T_boil - Boiling temperature at pressure P, K (2)
4. Vapor Liquid Equilibrium at Constant Pressure
5. Vapor Liquid Equilibrium at Constant Temperature (2)

Activity coefficient of n-Hexane (1) [ref]

Fixed		Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Activity coefficient of n-Hexane (1) - Liquid
30.00	302.92	1.058
30.00	303.01	1.05
30.00	303.21	1.029
30.00	303.44	1.018
30.00	303.81	1.026
30.00	304.07	1.022
30.00	304.33	1.012
30.00	304.61	1.016
30.00	304.91	1.02
30.00	305.14	1.014
30.00	305.43	1.006
30.00	305.61	1.006
30.00	305.84	1.005
30.00	306.02	1.007
30.00	306.29	1.007
30.00	306.59	1.002
30.00	306.82	0.9990
30.00	307.00	1.001
30.00	307.24	0.9980
30.00	307.40	1.0000
30.00	307.52	1.0000
60.00	321.13	1.032
60.00	321.19	1.03
60.00	321.39	1.024
60.00	321.66	1.026
60.00	321.92	1.017
60.00	322.25	1.006
60.00	322.46	1.009
60.00	322.70	1.009
60.00	322.97	1.013
60.00	323.22	1.006
60.00	323.62	1.002
60.00	323.91	1.005
60.00	324.21	1.001
60.00	324.42	1.001
60.00	324.76	0.9980
60.00	324.97	0.9990
60.00	325.23	0.9980
60.00	325.32	0.9960
60.00	325.60	0.9960
60.00	325.88	0.9960
60.00	325.99	0.9960
101.30	336.67	1.035
101.30	336.79	1.051
101.30	337.03	1.037
101.30	337.27	1.023
101.30	337.51	1.016
101.30	337.68	1.013
101.30	337.96	1.014
101.30	338.29	1.015
101.30	338.43	1.012
101.30	338.73	1.012
101.30	339.03	1.009
101.30	339.27	1.01
101.30	339.57	1.006
101.30	339.76	1.005
101.30	340.24	0.9970
101.30	340.54	1.0000
101.30	340.83	0.9980
101.30	341.14	0.9980
101.30	341.40	0.9980
101.30	341.57	1.001
101.30	341.73	1.001

Activity coefficient of 1-Hexene (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Activity coefficient of 1-Hexene (2) - Liquid
30.00	302.92	0.9870
30.00	303.01	0.9880
30.00	303.21	0.9910
30.00	303.44	0.9950
30.00	303.81	0.9930
30.00	304.07	0.9950
30.00	304.33	1.001
30.00	304.61	0.9970
30.00	304.91	0.9930
30.00	305.14	0.9960
30.00	305.43	1.003
30.00	305.61	1.006
30.00	305.84	1.01
30.00	306.02	1.01
30.00	306.29	1.007
30.00	306.59	1.007
30.00	306.82	1.015
30.00	307.00	1.01
30.00	307.24	1.019
30.00	307.40	1.013
30.00	307.52	0.9970
60.00	321.13	0.9950
60.00	321.19	0.9970
60.00	321.39	0.9990
60.00	321.66	0.9970
60.00	321.92	0.9980
60.00	322.25	0.9980
60.00	322.46	1.0000
60.00	322.70	1.0000
60.00	322.97	0.9970
60.00	323.22	1.004
60.00	323.62	1.003
60.00	323.91	0.9990
60.00	324.21	1.003
60.00	324.42	1.008
60.00	324.76	1.009
60.00	324.97	1.004
60.00	325.23	1.005
60.00	325.32	1.011
60.00	325.60	1.015
60.00	325.88	1.012
60.00	325.99	1.006
101.30	336.67	0.9970
101.30	336.79	0.9960
101.30	337.03	0.9960
101.30	337.27	0.9980
101.30	337.51	0.9970
101.30	337.68	1.0000
101.30	337.96	0.9990
101.30	338.29	0.9960
101.30	338.43	1.002
101.30	338.73	1.001
101.30	339.03	1.001
101.30	339.27	0.9980
101.30	339.57	1.003
101.30	339.76	1.007
101.30	340.24	1.006
101.30	340.54	1.001
101.30	340.83	1.005
101.30	341.14	1.008
101.30	341.40	1.017
101.30	341.57	1.021
101.30	341.73	1.028

Activity coefficient of n-Hexane (1) [ref]

Fixed		Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Activity coefficient of n-Hexane (1) - Liquid
30.00	302.92	1.058
30.00	303.01	1.05
30.00	303.21	1.029
30.00	303.44	1.018
30.00	303.81	1.026
30.00	304.07	1.022
30.00	304.33	1.012
30.00	304.61	1.016
30.00	304.91	1.02
30.00	305.14	1.014
30.00	305.43	1.006
30.00	305.61	1.006
30.00	305.84	1.005
30.00	306.02	1.007
30.00	306.29	1.007
30.00	306.59	1.002
30.00	306.82	0.9990
30.00	307.00	1.001
30.00	307.24	0.9980
30.00	307.40	1.0000
30.00	307.52	1.0000
60.00	321.13	1.032
60.00	321.19	1.03
60.00	321.39	1.024
60.00	321.66	1.026
60.00	321.92	1.017
60.00	322.25	1.006
60.00	322.46	1.009
60.00	322.70	1.009
60.00	322.97	1.013
60.00	323.22	1.006
60.00	323.62	1.002
60.00	323.91	1.005
60.00	324.21	1.001
60.00	324.42	1.001
60.00	324.76	0.9980
60.00	324.97	0.9990
60.00	325.23	0.9980
60.00	325.32	0.9960
60.00	325.60	0.9960
60.00	325.88	0.9960
60.00	325.99	0.9960
101.30	336.67	1.035
101.30	336.79	1.051
101.30	337.03	1.037
101.30	337.27	1.023
101.30	337.51	1.016
101.30	337.68	1.013
101.30	337.96	1.014
101.30	338.29	1.015
101.30	338.43	1.012
101.30	338.73	1.012
101.30	339.03	1.009
101.30	339.27	1.01
101.30	339.57	1.006
101.30	339.76	1.005
101.30	340.24	0.9970
101.30	340.54	1.0000
101.30	340.83	0.9980
101.30	341.14	0.9980
101.30	341.40	0.9980
101.30	341.57	1.001
101.30	341.73	1.001

Activity coefficient of 1-Hexene (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid	Temperature, K - Liquid	Activity coefficient of 1-Hexene (2) - Liquid
30.00	302.92	0.9870
30.00	303.01	0.9880
30.00	303.21	0.9910
30.00	303.44	0.9950
30.00	303.81	0.9930
30.00	304.07	0.9950
30.00	304.33	1.001
30.00	304.61	0.9970
30.00	304.91	0.9930
30.00	305.14	0.9960
30.00	305.43	1.003
30.00	305.61	1.006
30.00	305.84	1.01
30.00	306.02	1.01
30.00	306.29	1.007
30.00	306.59	1.007
30.00	306.82	1.015
30.00	307.00	1.01
30.00	307.24	1.019
30.00	307.40	1.013
30.00	307.52	0.9970
60.00	321.13	0.9950
60.00	321.19	0.9970
60.00	321.39	0.9990
60.00	321.66	0.9970
60.00	321.92	0.9980
60.00	322.25	0.9980
60.00	322.46	1.0000
60.00	322.70	1.0000
60.00	322.97	0.9970
60.00	323.22	1.004
60.00	323.62	1.003
60.00	323.91	0.9990
60.00	324.21	1.003
60.00	324.42	1.008
60.00	324.76	1.009
60.00	324.97	1.004
60.00	325.23	1.005
60.00	325.32	1.011
60.00	325.60	1.015
60.00	325.88	1.012
60.00	325.99	1.006
101.30	336.67	0.9970
101.30	336.79	0.9960
101.30	337.03	0.9960
101.30	337.27	0.9980
101.30	337.51	0.9970
101.30	337.68	1.0000
101.30	337.96	0.9990
101.30	338.29	0.9960
101.30	338.43	1.002
101.30	338.73	1.001
101.30	339.03	1.001
101.30	339.27	0.9980
101.30	339.57	1.003
101.30	339.76	1.007
101.30	340.24	1.006
101.30	340.54	1.001
101.30	340.83	1.005
101.30	341.14	1.008
101.30	341.40	1.017
101.30	341.57	1.021
101.30	341.73	1.028

Mole fraction of 1-Hexene (2) [ref]

Fixed		Measured
Mole fraction of 1-Hexene (2) - Liquid	Pressure, kPa - Gas	Mole fraction of 1-Hexene (2) - Gas
0.0050	60.00	0.0070
0.0090	30.00	0.0100
0.0120	101.30	0.0140
0.0240	60.00	0.0290
0.0260	30.00	0.0320
0.0350	101.30	0.0410
0.0590	30.00	0.0720
0.0690	60.00	0.0830
0.0740	101.30	0.0890
0.0930	30.00	0.1120
0.1190	60.00	0.1400
0.1200	101.30	0.1410
0.1280	30.00	0.1540
0.1290	60.00	0.1510
0.1670	30.00	0.1980
0.1720	60.00	0.1990
0.1720	101.30	0.1990
0.2050	30.00	0.2400
0.2110	60.00	0.2440
0.2200	101.30	0.2510
0.2510	30.00	0.2920
0.2620	60.00	0.2980
0.2740	101.30	0.3110
0.2920	30.00	0.3370
0.3090	60.00	0.3490
0.3260	101.30	0.3660
0.3380	30.00	0.3850
0.3640	60.00	0.4050
0.3650	101.30	0.4050
0.3800	30.00	0.4290
0.4220	60.00	0.4660
0.4220	101.30	0.4610
0.4330	30.00	0.4790
0.4610	101.30	0.5010
0.4760	30.00	0.5210
0.4860	60.00	0.5300
0.5120	101.30	0.5520
0.5400	30.00	0.5860
0.5430	60.00	0.5820
0.5680	101.30	0.6070
0.5950	30.00	0.6420
0.6000	60.00	0.6400
0.6140	101.30	0.6490
0.6520	60.00	0.6890
0.6570	30.00	0.6970
0.6720	101.30	0.7050
0.7120	60.00	0.7450
0.7200	30.00	0.7540
0.7280	101.30	0.7580
0.7700	60.00	0.7970
0.7770	101.30	0.8020
0.8030	30.00	0.8310
0.8140	101.30	0.8360
0.8290	60.00	0.8490
0.8700	101.30	0.8840
0.8710	30.00	0.8890
0.8850	60.00	0.9000
0.9250	101.30	0.9330
0.9290	30.00	0.9380
0.9410	60.00	0.9490
0.9580	101.30	0.9630
0.9650	30.00	0.9700
0.9750	60.00	0.9790

Mole fraction of 1-Hexene (2) [ref]

Fixed		Measured
Mole fraction of 1-Hexene (2) - Liquid	Pressure, kPa - Gas	Mole fraction of 1-Hexene (2) - Gas
0.0050	60.00	0.0070
0.0090	30.00	0.0100
0.0120	101.30	0.0140
0.0240	60.00	0.0290
0.0260	30.00	0.0320
0.0350	101.30	0.0410
0.0590	30.00	0.0720
0.0690	60.00	0.0830
0.0740	101.30	0.0890
0.0930	30.00	0.1120
0.1190	60.00	0.1400
0.1200	101.30	0.1410
0.1280	30.00	0.1540
0.1290	60.00	0.1510
0.1670	30.00	0.1980
0.1720	60.00	0.1990
0.1720	101.30	0.1990
0.2050	30.00	0.2400
0.2110	60.00	0.2440
0.2200	101.30	0.2510
0.2510	30.00	0.2920
0.2620	60.00	0.2980
0.2740	101.30	0.3110
0.2920	30.00	0.3370
0.3090	60.00	0.3490
0.3260	101.30	0.3660
0.3380	30.00	0.3850
0.3640	60.00	0.4050
0.3650	101.30	0.4050
0.3800	30.00	0.4290
0.4220	60.00	0.4660
0.4220	101.30	0.4610
0.4330	30.00	0.4790
0.4610	101.30	0.5010
0.4760	30.00	0.5210
0.4860	60.00	0.5300
0.5120	101.30	0.5520
0.5400	30.00	0.5860
0.5430	60.00	0.5820
0.5680	101.30	0.6070
0.5950	30.00	0.6420
0.6000	60.00	0.6400
0.6140	101.30	0.6490
0.6520	60.00	0.6890
0.6570	30.00	0.6970
0.6720	101.30	0.7050
0.7120	60.00	0.7450
0.7200	30.00	0.7540
0.7280	101.30	0.7580
0.7700	60.00	0.7970
0.7770	101.30	0.8020
0.8030	30.00	0.8310
0.8140	101.30	0.8360
0.8290	60.00	0.8490
0.8700	101.30	0.8840
0.8710	30.00	0.8890
0.8850	60.00	0.9000
0.9250	101.30	0.9330
0.9290	30.00	0.9380
0.9410	60.00	0.9490
0.9580	101.30	0.9630
0.9650	30.00	0.9700
0.9750	60.00	0.9790

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of 1-Hexene (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0050	60.00	325.99
0.0090	30.00	307.52
0.0120	101.30	341.73
0.0240	60.00	325.88
0.0260	30.00	307.40
0.0350	101.30	341.57
0.0590	30.00	307.24
0.0690	60.00	325.60
0.0740	101.30	341.40
0.0930	30.00	307.00
0.1190	60.00	325.32
0.1200	101.30	341.14
0.1280	30.00	306.82
0.1290	60.00	325.23
0.1670	30.00	306.59
0.1720	60.00	324.97
0.1720	101.30	340.83
0.2050	30.00	306.29
0.2110	60.00	324.76
0.2200	101.30	340.54
0.2510	30.00	306.02
0.2620	60.00	324.42
0.2740	101.30	340.24
0.2920	30.00	305.84
0.3090	60.00	324.21
0.3260	101.30	339.76
0.3380	30.00	305.61
0.3640	60.00	323.91
0.3650	101.30	339.57
0.3800	30.00	305.43
0.4220	60.00	323.62
0.4220	101.30	339.27
0.4330	30.00	305.14
0.4610	101.30	339.03
0.4760	30.00	304.91
0.4860	60.00	323.22
0.5120	101.30	338.73
0.5400	30.00	304.61
0.5430	60.00	322.97
0.5680	101.30	338.43
0.5950	30.00	304.33
0.6000	60.00	322.70
0.6140	101.30	338.29
0.6520	60.00	322.46
0.6570	30.00	304.07
0.6720	101.30	337.96
0.7120	60.00	322.25
0.7200	30.00	303.81
0.7280	101.30	337.68
0.7700	60.00	321.92
0.7770	101.30	337.51
0.8030	30.00	303.44
0.8140	101.30	337.27
0.8290	60.00	321.66
0.8700	101.30	337.03
0.8710	30.00	303.21
0.8850	60.00	321.39
0.9250	101.30	336.79
0.9290	30.00	303.01
0.9410	60.00	321.19
0.9580	101.30	336.67
0.9650	30.00	302.92
0.9750	60.00	321.13

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of 1-Hexene (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0050	60.00	325.99
0.0090	30.00	307.52
0.0120	101.30	341.73
0.0240	60.00	325.88
0.0260	30.00	307.40
0.0350	101.30	341.57
0.0590	30.00	307.24
0.0690	60.00	325.60
0.0740	101.30	341.40
0.0930	30.00	307.00
0.1190	60.00	325.32
0.1200	101.30	341.14
0.1280	30.00	306.82
0.1290	60.00	325.23
0.1670	30.00	306.59
0.1720	60.00	324.97
0.1720	101.30	340.83
0.2050	30.00	306.29
0.2110	60.00	324.76
0.2200	101.30	340.54
0.2510	30.00	306.02
0.2620	60.00	324.42
0.2740	101.30	340.24
0.2920	30.00	305.84
0.3090	60.00	324.21
0.3260	101.30	339.76
0.3380	30.00	305.61
0.3640	60.00	323.91
0.3650	101.30	339.57
0.3800	30.00	305.43
0.4220	60.00	323.62
0.4220	101.30	339.27
0.4330	30.00	305.14
0.4610	101.30	339.03
0.4760	30.00	304.91
0.4860	60.00	323.22
0.5120	101.30	338.73
0.5400	30.00	304.61
0.5430	60.00	322.97
0.5680	101.30	338.43
0.5950	30.00	304.33
0.6000	60.00	322.70
0.6140	101.30	338.29
0.6520	60.00	322.46
0.6570	30.00	304.07
0.6720	101.30	337.96
0.7120	60.00	322.25
0.7200	30.00	303.81
0.7280	101.30	337.68
0.7700	60.00	321.92
0.7770	101.30	337.51
0.8030	30.00	303.44
0.8140	101.30	337.27
0.8290	60.00	321.66
0.8700	101.30	337.03
0.8710	30.00	303.21
0.8850	60.00	321.39
0.9250	101.30	336.79
0.9290	30.00	303.01
0.9410	60.00	321.19
0.9580	101.30	336.67
0.9650	30.00	302.92
0.9750	60.00	321.13

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 101.33 (VLE)

Fixed	Measured
T [K] - VLE	x1[mol/mol] of 1-Hexene (2) - Liquid	y1[mol/mol] of 1-Hexene (2) - Vapour
341.05	0.0970	0.1130
340.95	0.1050	0.1230
340.35	0.1930	0.2200
339.65	0.2920	0.3260
339.05	0.3860	0.4230
338.85	0.4120	0.4500
338.55	0.4770	0.5150
337.95	0.5870	0.6220
337.95	0.5920	0.6260
337.85	0.6030	0.6270
337.55	0.6760	0.7070
337.45	0.7150	0.7440
337.25	0.7800	0.8030
337.15	0.7860	0.8080
336.85	0.8840	0.8970
336.85	0.8920	0.9000

Vapor Liquid Equilibrium at Constant Temperature [ref]

Operational condition: Temperature, K = 333.15 (VLE)

Fixed	Measured
P [kPa] - VLE	x1[mol/mol] of 1-Hexene (2) - Liquid	y1[mol/mol] of 1-Hexene (2) - Vapour
78.434	0.1210	0.1420
78.407	0.1230	0.1430
78.82	0.1480	0.1730
80.327	0.2450	0.2810
80.353	0.2480	0.2830
82.553	0.3910	0.4310
84.313	0.5150	0.5560
86.42	0.6660	0.6980
88.353	0.8250	0.8450
89.099	0.8740	0.8890
89.126	0.8770	0.8910

Vapor Liquid Equilibrium at Constant Temperature [ref]

Operational condition: Temperature, K = 328.15 (VLE)

Fixed	Measured
P [kPa] - VLE	x1[mol/mol] of 1-Hexene (2) - Liquid	y1[mol/mol] of 1-Hexene (2) - Vapour
64.435	0.0000	0.0000
65.955	0.1020	0.1220
67.368	0.2000	0.2330
68.741	0.3000	0.3410
70.061	0.4000	0.4450
71.287	0.5000	0.5430
72.434	0.6000	0.6390
73.581	0.7000	0.7320
74.701	0.7990	0.8230
75.78	0.9000	0.9120
76.78	1.0000	1.0000

Sources

• Dortmund Data Bank Vapor-Liquid Equilibrium Data
• Isobaric vapor liquid equilibrium for binary mixtures of 1-hexene + n-hexane and cyclohexane + cyclohexene at 30, 60 and 101.3 kPa