Mixture of 2-Methylpiperidine + Water

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2-Methylpiperidine

Name
2-Methylpiperidine
InChI
InChI=1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3
InChI Key
NNWUEBIEOFQMSS-UHFFFAOYSA-N
Formula
C6H13N
SMILES
CC1CCCCN1
Mol. Weight (g/mol)
99.17
CAS
109-05-7

Water

Name
Water
InChI
InChI=1S/H2O/h1H2
InChI Key
XLYOFNOQVPJJNP-UHFFFAOYSA-N
Formula
H2O
SMILES
O
Mol. Weight (g/mol)
18.02
CAS
7732-18-5
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Datasets

  1. Cp,liquid - Molar heat capacity at constant pressure, J/K/mol (2)
  2. Excess molar enthalpy (molar enthalpy (2)
  3. Liquid-liquid equilibrium temperature, K (4)
  4. ρl - Mass density, kg/m3 (2)
  5. Excess molar volume, m3/mol (2)

Molar heat capacity at constant pressure, J/K/mol [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Molar heat capacity at constant pressure, J/K/mol - Liquid
283.15 1.0000 215.38
288.15 1.0000 216.85
293.15 1.0000 217.34
298.15 1.0000 218.00
303.16 1.0000 218.99
308.15 1.0000 219.60
313.16 1.0000 220.18
318.15 1.0000 221.03
323.15 1.0000 221.40
328.15 1.0000 222.07
333.15 1.0000 222.76
283.15 0.8503 211.33
288.15 0.8503 212.82
293.15 0.8503 213.59
298.15 0.8503 214.56
303.16 0.8503 215.66
308.15 0.8503 216.50
313.16 0.8503 217.36
318.15 0.8503 218.40
323.15 0.8503 219.15
328.15 0.8503 219.94
333.15 0.8503 220.89
283.15 0.7262 186.76
288.15 0.7262 188.95
293.15 0.7262 190.95
298.15 0.7262 192.44
303.16 0.7262 194.17
308.15 0.7262 195.97
313.16 0.7262 197.81
318.15 0.7262 198.26
323.15 0.7262 200.09
328.15 0.7262 201.13
333.15 0.7262 202.26
283.15 0.3726 139.21
288.15 0.3726 141.02
293.15 0.3726 142.81
298.15 0.3726 144.60
303.16 0.3726 146.44
308.15 0.3726 147.98
313.16 0.3726 149.55
318.15 0.3726 150.82
323.15 0.3726 152.15
328.15 0.3726 153.44
333.15 0.3726 154.60
283.15 0.1830 108.96
288.15 0.1830 110.08
293.15 0.1830 110.85
298.15 0.1830 111.88
303.16 0.1830 112.59
308.15 0.1830 113.52
313.16 0.1830 114.35
318.15 0.1830 114.79
323.15 0.1830 115.72
328.15 0.1830 116.25
333.15 0.1830 116.69

Molar heat capacity at constant pressure, J/K/mol [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Molar heat capacity at constant pressure, J/K/mol - Liquid
283.15 1.0000 215.38
288.15 1.0000 216.85
293.15 1.0000 217.34
298.15 1.0000 218.00
303.16 1.0000 218.99
308.15 1.0000 219.60
313.16 1.0000 220.18
318.15 1.0000 221.03
323.15 1.0000 221.40
328.15 1.0000 222.07
333.15 1.0000 222.76
283.15 0.8503 211.33
288.15 0.8503 212.82
293.15 0.8503 213.59
298.15 0.8503 214.56
303.16 0.8503 215.66
308.15 0.8503 216.50
313.16 0.8503 217.36
318.15 0.8503 218.40
323.15 0.8503 219.15
328.15 0.8503 219.94
333.15 0.8503 220.89
283.15 0.7262 186.76
288.15 0.7262 188.95
293.15 0.7262 190.95
298.15 0.7262 192.44
303.16 0.7262 194.17
308.15 0.7262 195.97
313.16 0.7262 197.81
318.15 0.7262 198.26
323.15 0.7262 200.09
328.15 0.7262 201.13
333.15 0.7262 202.26
283.15 0.3726 139.21
288.15 0.3726 141.02
293.15 0.3726 142.81
298.15 0.3726 144.60
303.16 0.3726 146.44
308.15 0.3726 147.98
313.16 0.3726 149.55
318.15 0.3726 150.82
323.15 0.3726 152.15
328.15 0.3726 153.44
333.15 0.3726 154.60
283.15 0.1830 108.96
288.15 0.1830 110.08
293.15 0.1830 110.85
298.15 0.1830 111.88
303.16 0.1830 112.59
308.15 0.1830 113.52
313.16 0.1830 114.35
318.15 0.1830 114.79
323.15 0.1830 115.72
328.15 0.1830 116.25
333.15 0.1830 116.69

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 500 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
303.15 0.0295 -0.5600
303.15 0.0366 -0.6530
303.15 0.0921 -1.176
303.15 0.1320 -1.3
303.15 0.2337 -2.231
303.15 0.3139 -2.478
308.15 0.0149 -0.3160
308.15 0.0212 -0.4100
308.15 0.0294 -0.5190
308.15 0.0365 -0.6030
308.15 0.0365 -0.6680
308.15 0.0481 -0.7350
308.15 0.0661 -0.9020
308.15 0.0704 -0.9150
308.15 0.0755 -0.9900
318.15 0.0150 -0.2630
318.15 0.0214 -0.3440
318.15 0.0248 -0.3850
318.15 0.0368 -0.5140
318.15 0.0485 -0.6350
318.15 0.0666 -0.7820
318.15 0.0818 -0.9050
318.15 0.1089 -1.119
318.15 0.1439 -1.307
318.15 0.1549 -1.391
318.15 0.1865 -1.581
328.15 0.0101 -0.1740
328.15 0.0129 -0.2120
328.15 0.0180 -0.2740
328.15 0.0236 -0.3310
328.15 0.0297 -0.3920
328.15 0.0354 -0.4340
328.15 0.0438 -0.5120
328.15 0.0576 -0.6090
328.15 0.0840 -0.7860
328.15 0.1089 -0.9260
328.15 0.1325 -1.075
328.15 0.1865 -1.424
333.15 0.0361 -0.3100
333.15 0.0589 -0.5600
333.15 0.1234 -0.9990
333.15 0.1807 -1.328
333.15 0.2380 -1.612
333.15 0.3601 -1.975
338.15 0.0101 -0.1410
338.15 0.0129 -0.1720
338.15 0.0180 -0.2280
338.15 0.0236 -0.2820
338.15 0.0354 -0.3690
338.15 0.0466 -0.4480
338.15 0.0576 -0.5220
338.15 0.0840 -0.6840
338.15 0.1089 -0.8290
338.15 0.1325 -0.9700
338.15 0.1451 -1.035
303.15 0.3879 -2.621
303.15 0.4778 -2.628
303.15 0.5489 -2.493
303.15 0.6697 -2.044
303.15 0.7526 -1.616
308.15 0.1081 -1.209
308.15 0.1539 -1.53
308.15 0.1852 -1.779
308.15 0.2326 -1.99
308.15 0.3266 -2.385
308.15 0.3964 -2.547
308.15 0.4311 -2.5
308.15 0.6388 -2.095
308.15 0.7519 -1.552
318.15 0.2341 -1.842
318.15 0.2764 -2.019
318.15 0.3143 -2.13
318.15 0.3419 -2.233
318.15 0.3984 -2.284
318.15 0.4331 -2.287
318.15 0.4783 -2.271
318.15 0.5340 -2.192
318.15 0.6407 -1.892
318.15 0.7370 -1.505
318.15 0.7535 -1.441
328.15 0.1865 -1.408
328.15 0.2341 -1.667
328.15 0.3143 -1.975
328.15 0.3591 -2.133
328.15 0.4331 -2.175
328.15 0.4783 -2.148
328.15 0.5284 -2.066
328.15 0.5721 -1.941
328.15 0.6197 -1.775
328.15 0.6814 -1.582
328.15 0.7534 -1.248
333.15 0.4840 -1.99
333.15 0.5293 -1.926
333.15 0.5999 -1.802
333.15 0.6521 -1.631
333.15 0.7894 -1.06
338.15 0.1865 -1.256
338.15 0.2341 -1.502
338.15 0.3143 -1.792
338.15 0.3957 -1.9
338.15 0.4331 -1.937
338.15 0.4783 -1.941
338.15 0.5284 -1.826
338.15 0.5284 -1.822
338.15 0.5790 -1.72
338.15 0.6197 -1.619
338.15 0.6814 -1.374

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 500 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
303.15 0.0295 -0.5600
303.15 0.0366 -0.6530
303.15 0.0921 -1.176
303.15 0.1320 -1.3
303.15 0.2337 -2.231
303.15 0.3139 -2.478
308.15 0.0149 -0.3160
308.15 0.0212 -0.4100
308.15 0.0294 -0.5190
308.15 0.0365 -0.6030
308.15 0.0365 -0.6680
308.15 0.0481 -0.7350
308.15 0.0661 -0.9020
308.15 0.0704 -0.9150
308.15 0.0755 -0.9900
318.15 0.0150 -0.2630
318.15 0.0214 -0.3440
318.15 0.0248 -0.3850
318.15 0.0368 -0.5140
318.15 0.0485 -0.6350
318.15 0.0666 -0.7820
318.15 0.0818 -0.9050
318.15 0.1089 -1.119
318.15 0.1439 -1.307
318.15 0.1549 -1.391
318.15 0.1865 -1.581
328.15 0.0101 -0.1740
328.15 0.0129 -0.2120
328.15 0.0180 -0.2740
328.15 0.0236 -0.3310
328.15 0.0297 -0.3920
328.15 0.0354 -0.4340
328.15 0.0438 -0.5120
328.15 0.0576 -0.6090
328.15 0.0840 -0.7860
328.15 0.1089 -0.9260
328.15 0.1325 -1.075
328.15 0.1865 -1.424
333.15 0.0361 -0.3100
333.15 0.0589 -0.5600
333.15 0.1234 -0.9990
333.15 0.1807 -1.328
333.15 0.2380 -1.612
333.15 0.3601 -1.975
338.15 0.0101 -0.1410
338.15 0.0129 -0.1720
338.15 0.0180 -0.2280
338.15 0.0236 -0.2820
338.15 0.0354 -0.3690
338.15 0.0466 -0.4480
338.15 0.0576 -0.5220
338.15 0.0840 -0.6840
338.15 0.1089 -0.8290
338.15 0.1325 -0.9700
338.15 0.1451 -1.035
303.15 0.3879 -2.621
303.15 0.4778 -2.628
303.15 0.5489 -2.493
303.15 0.6697 -2.044
303.15 0.7526 -1.616
308.15 0.1081 -1.209
308.15 0.1539 -1.53
308.15 0.1852 -1.779
308.15 0.2326 -1.99
308.15 0.3266 -2.385
308.15 0.3964 -2.547
308.15 0.4311 -2.5
308.15 0.6388 -2.095
308.15 0.7519 -1.552
318.15 0.2341 -1.842
318.15 0.2764 -2.019
318.15 0.3143 -2.13
318.15 0.3419 -2.233
318.15 0.3984 -2.284
318.15 0.4331 -2.287
318.15 0.4783 -2.271
318.15 0.5340 -2.192
318.15 0.6407 -1.892
318.15 0.7370 -1.505
318.15 0.7535 -1.441
328.15 0.1865 -1.408
328.15 0.2341 -1.667
328.15 0.3143 -1.975
328.15 0.3591 -2.133
328.15 0.4331 -2.175
328.15 0.4783 -2.148
328.15 0.5284 -2.066
328.15 0.5721 -1.941
328.15 0.6197 -1.775
328.15 0.6814 -1.582
328.15 0.7534 -1.248
333.15 0.4840 -1.99
333.15 0.5293 -1.926
333.15 0.5999 -1.802
333.15 0.6521 -1.631
333.15 0.7894 -1.06
338.15 0.1865 -1.256
338.15 0.2341 -1.502
338.15 0.3143 -1.792
338.15 0.3957 -1.9
338.15 0.4331 -1.937
338.15 0.4783 -1.941
338.15 0.5284 -1.826
338.15 0.5284 -1.822
338.15 0.5790 -1.72
338.15 0.6197 -1.619
338.15 0.6814 -1.374

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of 2-Methylpiperidine (1) - Liquid mixture 1 Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.0700 339.30
0.1190 341.10
0.2000 352.10
0.2500 357.10
0.3000 376.60

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of 2-Methylpiperidine (1) - Liquid mixture 1 Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.0170 352.60
0.0500 343.00

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of 2-Methylpiperidine (1) - Liquid mixture 1 Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.0700 339.30
0.1190 341.10
0.2000 352.10
0.2500 357.10
0.3000 376.60

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mole fraction of 2-Methylpiperidine (1) - Liquid mixture 1 Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.0170 352.60
0.0500 343.00

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Mass density, kg/m3 - Liquid
288.15 0.0220 992.158
288.15 0.0488 982.491
288.15 0.0966 965.22
288.15 0.1901 940.03
288.15 0.3019 918.147
288.15 0.4006 904.274
288.15 0.4700 896.239
288.15 0.5900 883.489
288.15 0.6850 874.59
288.15 0.7750 866.186
288.15 0.8130 863.581
298.15 0.0506 976.147
298.15 0.0951 957.78
298.15 0.1955 930.75
298.15 0.2880 911.236
298.15 0.3958 894.275
298.15 0.4500 886.977
298.15 0.4708 884.952
298.15 0.5925 871.352
298.15 0.7000 860.793
298.15 0.8043 851.545
308.15 0.0506 969.86
308.15 0.0951 951.024
308.15 0.1955 921.38
308.15 0.2880 902.606
308.15 0.3880 886.089
308.15 0.4630 875.982
308.15 0.5850 861.756
308.15 0.6501 855.347
318.15 0.0506 963.421
318.15 0.0951 943.575
318.15 0.1955 912.95
318.15 0.2880 893.567
318.15 0.3880 876.681
318.15 0.4630 866.663
318.15 0.5850 852.312
318.15 0.6501 846.574
328.15 0.0500 957.601
328.15 0.0982 935.269
328.15 0.3019 883.044
328.15 0.4006 867.078
328.15 0.4585 859.202
328.15 0.5699 846.009
328.15 0.6591 836.942
328.15 0.7750 826.192
338.15 0.0951 926.141
338.15 0.1901 897.2
338.15 0.3019 873.469
338.15 0.3650 863.604
338.15 0.4585 850.39
338.15 0.5925 834.463
338.15 0.8043 816.519

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Mass density, kg/m3 - Liquid
288.15 0.0220 992.158
288.15 0.0488 982.491
288.15 0.0966 965.22
288.15 0.1901 940.03
288.15 0.3019 918.147
288.15 0.4006 904.274
288.15 0.4700 896.239
288.15 0.5900 883.489
288.15 0.6850 874.59
288.15 0.7750 866.186
288.15 0.8130 863.581
298.15 0.0506 976.147
298.15 0.0951 957.78
298.15 0.1955 930.75
298.15 0.2880 911.236
298.15 0.3958 894.275
298.15 0.4500 886.977
298.15 0.4708 884.952
298.15 0.5925 871.352
298.15 0.7000 860.793
298.15 0.8043 851.545
308.15 0.0506 969.86
308.15 0.0951 951.024
308.15 0.1955 921.38
308.15 0.2880 902.606
308.15 0.3880 886.089
308.15 0.4630 875.982
308.15 0.5850 861.756
308.15 0.6501 855.347
318.15 0.0506 963.421
318.15 0.0951 943.575
318.15 0.1955 912.95
318.15 0.2880 893.567
318.15 0.3880 876.681
318.15 0.4630 866.663
318.15 0.5850 852.312
318.15 0.6501 846.574
328.15 0.0500 957.601
328.15 0.0982 935.269
328.15 0.3019 883.044
328.15 0.4006 867.078
328.15 0.4585 859.202
328.15 0.5699 846.009
328.15 0.6591 836.942
328.15 0.7750 826.192
338.15 0.0951 926.141
338.15 0.1901 897.2
338.15 0.3019 873.469
338.15 0.3650 863.604
338.15 0.4585 850.39
338.15 0.5925 834.463
338.15 0.8043 816.519

Excess molar volume, m3/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Excess molar volume, m3/mol - Liquid
288.15 0.0220 -3.1000e-07
288.15 0.0488 -5.0000e-07
288.15 0.0966 -8.2000e-07
288.15 0.1901 -1.3000e-06
288.15 0.3019 -1.6500e-06
288.15 0.4006 -1.8600e-06
288.15 0.4700 -1.9500e-06
288.15 0.5900 -1.9200e-06
288.15 0.6850 -1.7600e-06
288.15 0.7750 -1.4300e-06
288.15 0.8130 -1.3400e-06
298.15 0.0506 -5.0000e-07
298.15 0.0951 -7.7000e-07
298.15 0.1955 -1.3300e-06
298.15 0.2880 -1.6100e-06
298.15 0.3958 -1.8100e-06
298.15 0.4500 -1.8400e-06
298.15 0.4708 -1.8800e-06
298.15 0.5925 -1.8000e-06
298.15 0.7000 -1.5400e-06
298.15 0.8043 -1.1500e-06
308.15 0.0506 -4.7000e-07
308.15 0.0951 -7.6000e-07
308.15 0.1955 -1.2800e-06
308.15 0.2880 -1.6200e-06
308.15 0.3880 -1.8000e-06
308.15 0.4630 -1.8500e-06
308.15 0.5850 -1.7500e-06
308.15 0.6501 -1.6400e-06
318.15 0.0506 -4.5000e-07
318.15 0.0951 -7.3000e-07
318.15 0.1955 -1.2500e-06
318.15 0.2880 -1.5900e-06
318.15 0.3880 -1.7600e-06
318.15 0.4630 -1.8200e-06
318.15 0.5850 -1.7100e-06
318.15 0.6501 -1.6600e-06
328.15 0.0500 -4.4000e-07
328.15 0.0982 -7.3000e-07
328.15 0.3019 -1.6100e-06
328.15 0.4006 -1.7800e-06
328.15 0.4585 -1.8200e-06
328.15 0.5699 -1.7500e-06
328.15 0.6591 -1.5800e-06
328.15 0.7750 -1.1700e-06
338.15 0.0951 -6.0000e-07
338.15 0.1901 -1.1100e-06
338.15 0.3019 -1.4900e-06
338.15 0.3650 -1.6400e-06
338.15 0.4585 -1.7100e-06
338.15 0.5925 -1.5400e-06
338.15 0.8043 -1.0500e-06

Excess molar volume, m3/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed Measured
Temperature, K - Liquid Mole fraction of 2-Methylpiperidine (1) - Liquid Excess molar volume, m3/mol - Liquid
288.15 0.0220 -3.1000e-07
288.15 0.0488 -5.0000e-07
288.15 0.0966 -8.2000e-07
288.15 0.1901 -1.3000e-06
288.15 0.3019 -1.6500e-06
288.15 0.4006 -1.8600e-06
288.15 0.4700 -1.9500e-06
288.15 0.5900 -1.9200e-06
288.15 0.6850 -1.7600e-06
288.15 0.7750 -1.4300e-06
288.15 0.8130 -1.3400e-06
298.15 0.0506 -5.0000e-07
298.15 0.0951 -7.7000e-07
298.15 0.1955 -1.3300e-06
298.15 0.2880 -1.6100e-06
298.15 0.3958 -1.8100e-06
298.15 0.4500 -1.8400e-06
298.15 0.4708 -1.8800e-06
298.15 0.5925 -1.8000e-06
298.15 0.7000 -1.5400e-06
298.15 0.8043 -1.1500e-06
308.15 0.0506 -4.7000e-07
308.15 0.0951 -7.6000e-07
308.15 0.1955 -1.2800e-06
308.15 0.2880 -1.6200e-06
308.15 0.3880 -1.8000e-06
308.15 0.4630 -1.8500e-06
308.15 0.5850 -1.7500e-06
308.15 0.6501 -1.6400e-06
318.15 0.0506 -4.5000e-07
318.15 0.0951 -7.3000e-07
318.15 0.1955 -1.2500e-06
318.15 0.2880 -1.5900e-06
318.15 0.3880 -1.7600e-06
318.15 0.4630 -1.8200e-06
318.15 0.5850 -1.7100e-06
318.15 0.6501 -1.6600e-06
328.15 0.0500 -4.4000e-07
328.15 0.0982 -7.3000e-07
328.15 0.3019 -1.6100e-06
328.15 0.4006 -1.7800e-06
328.15 0.4585 -1.8200e-06
328.15 0.5699 -1.7500e-06
328.15 0.6591 -1.5800e-06
328.15 0.7750 -1.1700e-06
338.15 0.0951 -6.0000e-07
338.15 0.1901 -1.1100e-06
338.15 0.3019 -1.4900e-06
338.15 0.3650 -1.6400e-06
338.15 0.4585 -1.7100e-06
338.15 0.5925 -1.5400e-06
338.15 0.8043 -1.0500e-06

Sources