Mixture of Acetonitrile + 1-Hexanol

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Acetonitrile (1) [ref]

Fixed		Measured
Mole fraction of Acetonitrile (1) - Liquid	Temperature, K - Liquid	Mole fraction of Acetonitrile (1) - Gas
0.0000	428.45	0.0000
0.0846	376.35	0.8718
0.1877	369.95	0.9071
0.2502	368.25	0.9156
0.2938	367.35	0.9293
0.3563	366.05	0.9264
0.4282	364.75	0.9330
0.4907	363.55	0.9388
0.5552	362.15	0.9449
0.6177	361.15	0.9512
0.7892	357.75	0.9703
0.8517	356.15	0.9783
0.9142	354.65	0.9869
0.9767	353.15	0.9963
1.0000	352.55	1.0000

Mole fraction of Acetonitrile (1) [ref]

Fixed		Measured
Mole fraction of Acetonitrile (1) - Liquid	Temperature, K - Liquid	Mole fraction of Acetonitrile (1) - Gas
0.0000	428.45	0.0000
0.0846	376.35	0.8718
0.1877	369.95	0.9071
0.2502	368.25	0.9156
0.2938	367.35	0.9293
0.3563	366.05	0.9264
0.4282	364.75	0.9330
0.4907	363.55	0.9388
0.5552	362.15	0.9449
0.6177	361.15	0.9512
0.7892	357.75	0.9703
0.8517	356.15	0.9783
0.9142	354.65	0.9869
0.9767	353.15	0.9963
1.0000	352.55	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Mole fraction of 1-Hexanol (2) - Liquid	Temperature, K - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0402	288.15	0.4380
0.0405	298.15	0.5060
0.0408	313.15	0.5510
0.0410	323.15	0.5700
0.0809	288.15	0.7880
0.0815	298.15	0.9530
0.0819	313.15	0.9950
0.0823	323.15	1.026
0.1219	288.15	1.069
0.1226	298.15	1.294
0.1233	313.15	1.332
0.1239	323.15	1.379
0.1629	288.15	1.286
0.1639	298.15	1.595
0.1648	313.15	1.596
0.1655	323.15	1.674
0.2038	288.15	1.464
0.2050	298.15	1.811
0.2060	313.15	1.84
0.2069	323.15	1.9
0.2445	288.15	1.615
0.2457	298.15	1.984
0.2470	313.15	2.034
0.2479	323.15	2.113
0.2846	288.15	1.75
0.2860	298.15	2.118
0.2874	313.15	2.155
0.2884	323.15	2.285
0.3241	288.15	1.855
0.3257	298.15	2.192
0.3271	313.15	2.254
0.3282	323.15	2.406
0.3628	288.15	1.951
0.3849	298.15	2.271
0.3888	313.15	2.387
0.3900	323.15	2.619
0.4145	288.15	2.079
0.4178	313.15	2.419
0.4190	323.15	2.671
0.4227	298.15	2.318
0.4465	288.15	2.104
0.4498	313.15	2.441
0.4510	323.15	2.685
0.4554	298.15	2.329
0.4819	288.15	2.092
0.4853	313.15	2.444
0.4865	323.15	2.658
0.4916	298.15	2.325
0.5214	288.15	2.055
0.5248	313.15	2.415
0.5260	323.15	2.607
0.5321	298.15	2.298
0.5657	288.15	1.998
0.5690	313.15	2.341
0.5702	323.15	2.511
0.5774	298.15	2.242
0.6156	288.15	1.91
0.6188	313.15	2.222
0.6199	323.15	2.384
0.6286	298.15	2.116
0.6722	288.15	1.778
0.6752	313.15	2.043
0.6762	323.15	2.178
0.6866	298.15	1.967
0.7368	288.15	1.595
0.7395	313.15	1.82
0.7404	323.15	1.895
0.7530	298.15	1.711
0.8114	288.15	1.29
0.8134	313.15	1.479
0.8142	323.15	1.49
0.8295	298.15	1.293
0.8980	288.15	0.7980
0.8993	313.15	0.9370
0.8997	323.15	0.9330
0.9187	298.15	0.6900
0.9580	298.15	0.3900

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Mole fraction of 1-Hexanol (2) - Liquid	Temperature, K - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0402	288.15	0.4380
0.0405	298.15	0.5060
0.0408	313.15	0.5510
0.0410	323.15	0.5700
0.0809	288.15	0.7880
0.0815	298.15	0.9530
0.0819	313.15	0.9950
0.0823	323.15	1.026
0.1219	288.15	1.069
0.1226	298.15	1.294
0.1233	313.15	1.332
0.1239	323.15	1.379
0.1629	288.15	1.286
0.1639	298.15	1.595
0.1648	313.15	1.596
0.1655	323.15	1.674
0.2038	288.15	1.464
0.2050	298.15	1.811
0.2060	313.15	1.84
0.2069	323.15	1.9
0.2445	288.15	1.615
0.2457	298.15	1.984
0.2470	313.15	2.034
0.2479	323.15	2.113
0.2846	288.15	1.75
0.2860	298.15	2.118
0.2874	313.15	2.155
0.2884	323.15	2.285
0.3241	288.15	1.855
0.3257	298.15	2.192
0.3271	313.15	2.254
0.3282	323.15	2.406
0.3628	288.15	1.951
0.3849	298.15	2.271
0.3888	313.15	2.387
0.3900	323.15	2.619
0.4145	288.15	2.079
0.4178	313.15	2.419
0.4190	323.15	2.671
0.4227	298.15	2.318
0.4465	288.15	2.104
0.4498	313.15	2.441
0.4510	323.15	2.685
0.4554	298.15	2.329
0.4819	288.15	2.092
0.4853	313.15	2.444
0.4865	323.15	2.658
0.4916	298.15	2.325
0.5214	288.15	2.055
0.5248	313.15	2.415
0.5260	323.15	2.607
0.5321	298.15	2.298
0.5657	288.15	1.998
0.5690	313.15	2.341
0.5702	323.15	2.511
0.5774	298.15	2.242
0.6156	288.15	1.91
0.6188	313.15	2.222
0.6199	323.15	2.384
0.6286	298.15	2.116
0.6722	288.15	1.778
0.6752	313.15	2.043
0.6762	323.15	2.178
0.6866	298.15	1.967
0.7368	288.15	1.595
0.7395	313.15	1.82
0.7404	323.15	1.895
0.7530	298.15	1.711
0.8114	288.15	1.29
0.8134	313.15	1.479
0.8142	323.15	1.49
0.8295	298.15	1.293
0.8980	288.15	0.7980
0.8993	313.15	0.9370
0.8997	323.15	0.9330
0.9187	298.15	0.6900
0.9580	298.15	0.3900

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 95.6 (Liquid)

Mole fraction of Acetonitrile (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	428.45
0.0846	376.35
0.1877	369.95
0.2502	368.25
0.2938	367.35
0.3563	366.05
0.4282	364.75
0.4907	363.55
0.5552	362.15
0.6177	361.15
0.7892	357.75
0.8517	356.15
0.9142	354.65
0.9767	353.15
1.0000	352.55

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 95.6 (Liquid)

Mole fraction of Acetonitrile (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	428.45
0.0846	376.35
0.1877	369.95
0.2502	368.25
0.2938	367.35
0.3563	366.05
0.4282	364.75
0.4907	363.55
0.5552	362.15
0.6177	361.15
0.7892	357.75
0.8517	356.15
0.9142	354.65
0.9767	353.15
1.0000	352.55

Sources

• Bubble point measurements of binary mixtures formed by 1-hexanol with selected nitro-compounds and substituted benzenes at 95.6 kPa
• ERAS modeling of the excess molar enthalpies of binary liquid mixtures of 1-pentanol and 1-hexanol with acetonitrile at atmospheric pressure and 288, 298, 313 and 323K