Mixture of Benzene + Carbonic acid, dimethyl ester

Datasets

1. Mole fraction (2)
2. n₀ - Refractive index (Na D-line) (2)
3. ρ_l - Mass density, kg/m3 (4)
4. Excess molar volume, m3/mol (2)

Mole fraction of Benzene (1) [ref]

Operational condition: Temperature, K = 333.15 (Liquid)

Mole fraction of Benzene (1) - Liquid	Mole fraction of Benzene (1) - Gas
0.0169	0.0282
0.0338	0.0449
0.0498	0.0785
0.0999	0.1204
0.1499	0.2126
0.1999	0.2882
0.2497	0.3641
0.2998	0.4267
0.3498	0.4800
0.3997	0.5186
0.4497	0.5798
0.4996	0.6049
0.5499	0.6425
0.5996	0.6871
0.6499	0.7218
0.6999	0.7790
0.7499	0.8104
0.7999	0.8415
0.8500	0.8864
0.9000	0.9216
0.9501	0.9604
0.9659	0.9734
0.9831	0.9866

Mole fraction of Benzene (1) [ref]

Operational condition: Temperature, K = 333.15 (Liquid)

Mole fraction of Benzene (1) - Liquid	Mole fraction of Benzene (1) - Gas
0.0169	0.0282
0.0338	0.0449
0.0498	0.0785
0.0999	0.1204
0.1499	0.2126
0.1999	0.2882
0.2497	0.3641
0.2998	0.4267
0.3498	0.4800
0.3997	0.5186
0.4497	0.5798
0.4996	0.6049
0.5499	0.6425
0.5996	0.6871
0.6499	0.7218
0.6999	0.7790
0.7499	0.8104
0.7999	0.8415
0.8500	0.8864
0.9000	0.9216
0.9501	0.9604
0.9659	0.9734
0.9831	0.9866

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Refractive index (Na D-line) - Liquid
0.0518	1.4902
0.0988	1.4836
0.1995	1.4699
0.2994	1.4565
0.4010	1.4431
0.5002	1.4301
0.6003	1.417
0.6990	1.4044
0.7981	1.3918
0.9000	1.3789
0.9497	1.3727

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Refractive index (Na D-line) - Liquid
0.0518	1.4902
0.0988	1.4836
0.1995	1.4699
0.2994	1.4565
0.4010	1.4431
0.5002	1.4301
0.6003	1.417
0.6990	1.4044
0.7981	1.3918
0.9000	1.3789
0.9497	1.3727

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0518	882.09
0.0988	889.99
0.1995	907.42
0.2994	925.15
0.4010	943.6
0.5002	962.07
0.6003	981.15
0.6990	1000.51
0.7981	1020.48
0.9000	1041.49
0.9497	1052.0

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	873.56
0.0499	882.0
0.1000	890.57
0.1500	899.18
0.2001	907.93
0.2499	916.61
0.3000	925.59
0.3498	934.53
0.4000	943.7
0.4500	952.89
0.5001	962.25
0.5500	971.69
0.6000	981.28
0.6499	990.96
0.7001	1000.84
0.7501	1010.88
0.8001	1021.01
0.8498	1031.36
0.8999	1041.69
0.9501	1052.35
1.0000	1063.19

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0518	882.09
0.0988	889.99
0.1995	907.42
0.2994	925.15
0.4010	943.6
0.5002	962.07
0.6003	981.15
0.6990	1000.51
0.7981	1020.48
0.9000	1041.49
0.9497	1052.0

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	873.56
0.0499	882.0
0.1000	890.57
0.1500	899.18
0.2001	907.93
0.2499	916.61
0.3000	925.59
0.3498	934.53
0.4000	943.7
0.4500	952.89
0.5001	962.25
0.5500	971.69
0.6000	981.28
0.6499	990.96
0.7001	1000.84
0.7501	1010.88
0.8001	1021.01
0.8498	1031.36
0.8999	1041.69
0.9501	1052.35
1.0000	1063.19

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0518	8.0600e-08
0.0988	1.4050e-07
0.1995	2.2810e-07
0.2994	2.8890e-07
0.4010	3.2570e-07
0.5002	3.3640e-07
0.6003	3.2700e-07
0.6990	2.8590e-07
0.7981	2.2120e-07
0.9000	1.3600e-07
0.9497	8.1500e-08

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0518	8.0600e-08
0.0988	1.4050e-07
0.1995	2.2810e-07
0.2994	2.8890e-07
0.4010	3.2570e-07
0.5002	3.3640e-07
0.6003	3.2700e-07
0.6990	2.8590e-07
0.7981	2.2120e-07
0.9000	1.3600e-07
0.9497	8.1500e-08

Sources

• Isothermal vapor-liquid equilibrium at T = 333.15 K and excess volumes and molar refractivity deviation at T = 298.15 K for the ternary mixtures {di-methyl carbonate (DMC) + ethanol + benzene} and {DMC+ ethanol + toluene}
• Excess Molar Volumes at 298.15 K and Isothermal Vapor-Liquid Equilibria at 333.15 K for the Binary Mixtures of Dimethyl Carbonate with Benzene, Toluene, n-Heptane, and Isooctane