Mixture of n-Propyl acetate + Water

Datasets

1. Activity coefficient (4)
2. Mole fraction (18)
3. Excess molar enthalpy (molar enthalpy (2)
4. ρ_l - Mass density, kg/m3 (2)
5. γ - Surface tension liquid-gas, N/m (2)

Activity coefficient of n-Propyl acetate (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of n-Propyl acetate (1) - Liquid
273.35	172.0
283.15	217.0
293.15	274.0
293.15	257.0
298.15	261.0
298.15	270.0
303.15	281.0
313.15	302.0
323.15	319.0
333.15	321.0

Activity coefficient of n-Propyl acetate (1) [ref]

Operational conditions:

• Pressure, kPa = 101.325 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of n-Propyl acetate (1) - Liquid
303.25	297.0
313.25	325.0
323.25	341.0
333.25	351.0
343.25	348.0

Activity coefficient of n-Propyl acetate (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of n-Propyl acetate (1) - Liquid
273.35	172.0
283.15	217.0
293.15	274.0
293.15	257.0
298.15	261.0
298.15	270.0
303.15	281.0
313.15	302.0
323.15	319.0
333.15	321.0

Activity coefficient of n-Propyl acetate (1) [ref]

Operational conditions:

• Pressure, kPa = 101.325 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of n-Propyl acetate (1) - Liquid
303.25	297.0
313.25	325.0
323.25	341.0
333.25	351.0
343.25	348.0

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
298.20	101.32	0.1445

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
101.32	298.20	0.9959

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
288.15	0.0139
288.15	0.9785
288.15	0.9780
298.15	0.0154
298.15	0.9795
313.15	0.0224
313.15	0.9799
313.15	0.9808

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 2
288.15	0.0145
313.15	0.0227

Mole fraction of n-Propyl acetate (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of n-Propyl acetate (1) - Liquid mixture 1
288.20	0.0046
303.20	0.0038

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
288.20	0.0805
303.20	0.1033

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
298.20	0.9800
298.20	0.0125
308.20	0.9729
308.20	0.0173
318.20	0.9641
318.20	0.0207

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
363.65	101.33	0.1374

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
363.65	101.33	0.9969

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
298.20	101.32	0.1445

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
101.32	298.20	0.9959

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
288.15	0.0139
288.15	0.9785
288.15	0.9780
298.15	0.0154
298.15	0.9795
313.15	0.0224
313.15	0.9799
313.15	0.9808

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 2
288.15	0.0145
313.15	0.0227

Mole fraction of n-Propyl acetate (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of n-Propyl acetate (1) - Liquid mixture 1
288.20	0.0046
303.20	0.0038

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
288.20	0.0805
303.20	0.1033

Mass fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
298.20	0.9800
298.20	0.0125
308.20	0.9729
308.20	0.0173
318.20	0.9641
318.20	0.0207

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
363.65	101.33	0.1374

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
363.65	101.33	0.9969

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
288.15	0.0009	-0.0114
288.15	0.0012	-0.0152
288.15	0.0012	-0.0152
288.15	0.0016	-0.0189
288.15	0.0016	-0.0187
288.15	0.0019	-0.0224
288.15	0.0019	-0.0223
288.15	0.0022	-0.0259
288.15	0.0022	-0.0258
288.15	0.0025	-0.0294
288.15	0.0025	-0.0296
298.15	0.0009	-0.0086
298.15	0.0009	-0.0088
298.15	0.0009	-0.0089
298.15	0.0012	-0.0115
298.15	0.0012	-0.0116
298.15	0.0012	-0.0116
298.15	0.0016	-0.0145
298.15	0.0016	-0.0143
298.15	0.0019	-0.0169
298.15	0.0019	-0.0170
298.15	0.0019	-0.0169
298.15	0.0022	-0.0198
298.15	0.0022	-0.0195
298.15	0.0025	-0.0225
298.15	0.0016	-0.0144
298.15	0.0022	-0.0198
308.15	0.0009	-0.0062
308.15	0.0012	-0.0082
308.15	0.0016	-0.0103
308.15	0.0019	-0.0120
308.15	0.0022	-0.0139
308.15	0.0025	-0.0155
308.15	0.0009	-0.0062
308.15	0.0012	-0.0082
308.15	0.0016	-0.0102
308.15	0.0019	-0.0122
308.15	0.0022	-0.0140
308.15	0.0025	-0.0155
318.15	0.0009	-0.0038
318.15	0.0009	-0.0039
318.15	0.0012	-0.0050
318.15	0.0012	-0.0051
318.15	0.0016	-0.0062
318.15	0.0016	-0.0062
318.15	0.0019	-0.0073
318.15	0.0019	-0.0072
318.15	0.0022	-0.0084
318.15	0.0022	-0.0083
318.15	0.0025	-0.0092
318.15	0.0025	-0.0092

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
288.15	0.0009	-0.0114
288.15	0.0012	-0.0152
288.15	0.0012	-0.0152
288.15	0.0016	-0.0189
288.15	0.0016	-0.0187
288.15	0.0019	-0.0224
288.15	0.0019	-0.0223
288.15	0.0022	-0.0259
288.15	0.0022	-0.0258
288.15	0.0025	-0.0294
288.15	0.0025	-0.0296
298.15	0.0009	-0.0086
298.15	0.0009	-0.0088
298.15	0.0009	-0.0089
298.15	0.0012	-0.0115
298.15	0.0012	-0.0116
298.15	0.0012	-0.0116
298.15	0.0016	-0.0145
298.15	0.0016	-0.0143
298.15	0.0019	-0.0169
298.15	0.0019	-0.0170
298.15	0.0019	-0.0169
298.15	0.0022	-0.0198
298.15	0.0022	-0.0195
298.15	0.0025	-0.0225
298.15	0.0016	-0.0144
298.15	0.0022	-0.0198
308.15	0.0009	-0.0062
308.15	0.0012	-0.0082
308.15	0.0016	-0.0103
308.15	0.0019	-0.0120
308.15	0.0022	-0.0139
308.15	0.0025	-0.0155
308.15	0.0009	-0.0062
308.15	0.0012	-0.0082
308.15	0.0016	-0.0102
308.15	0.0019	-0.0122
308.15	0.0022	-0.0140
308.15	0.0025	-0.0155
318.15	0.0009	-0.0038
318.15	0.0009	-0.0039
318.15	0.0012	-0.0050
318.15	0.0012	-0.0051
318.15	0.0016	-0.0062
318.15	0.0016	-0.0062
318.15	0.0019	-0.0073
318.15	0.0019	-0.0072
318.15	0.0022	-0.0084
318.15	0.0022	-0.0083
318.15	0.0025	-0.0092
318.15	0.0025	-0.0092

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (1) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0009	999.019
288.15	0.0012	998.986
288.15	0.0012	998.988
288.15	0.0016	998.959
288.15	0.0016	998.962
288.15	0.0019	998.934
288.15	0.0019	998.936
288.15	0.0022	998.909
288.15	0.0022	998.906
288.15	0.0025	998.876
288.15	0.0025	998.882
298.15	0.0009	996.903
298.15	0.0009	996.9
298.15	0.0009	996.898
298.15	0.0012	996.856
298.15	0.0012	996.852
298.15	0.0012	996.848
298.15	0.0016	996.807
298.15	0.0016	996.803
298.15	0.0019	996.762
298.15	0.0019	996.758
298.15	0.0019	996.748
298.15	0.0022	996.714
298.15	0.0022	996.703
298.15	0.0025	996.669
298.15	0.0025	996.669
298.15	0.0025	996.655
298.15	0.0016	996.805
298.15	0.0022	996.709
308.15	0.0009	993.831
308.15	0.0012	993.761
308.15	0.0016	993.691
308.15	0.0019	993.628
308.15	0.0022	993.559
308.15	0.0025	993.5
308.15	0.0009	993.832
308.15	0.0012	993.761
308.15	0.0016	993.692
308.15	0.0019	993.621
308.15	0.0022	993.557
308.15	0.0025	993.503
318.15	0.0009	989.957
318.15	0.0009	989.951
318.15	0.0012	989.872
318.15	0.0012	989.86
318.15	0.0016	989.782
318.15	0.0016	989.779
318.15	0.0019	989.693
318.15	0.0019	989.698
318.15	0.0022	989.605
318.15	0.0022	989.612
318.15	0.0025	989.536
318.15	0.0025	989.532

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (1) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0009	999.019
288.15	0.0012	998.986
288.15	0.0012	998.988
288.15	0.0016	998.959
288.15	0.0016	998.962
288.15	0.0019	998.934
288.15	0.0019	998.936
288.15	0.0022	998.909
288.15	0.0022	998.906
288.15	0.0025	998.876
288.15	0.0025	998.882
298.15	0.0009	996.903
298.15	0.0009	996.9
298.15	0.0009	996.898
298.15	0.0012	996.856
298.15	0.0012	996.852
298.15	0.0012	996.848
298.15	0.0016	996.807
298.15	0.0016	996.803
298.15	0.0019	996.762
298.15	0.0019	996.758
298.15	0.0019	996.748
298.15	0.0022	996.714
298.15	0.0022	996.703
298.15	0.0025	996.669
298.15	0.0025	996.669
298.15	0.0025	996.655
298.15	0.0016	996.805
298.15	0.0022	996.709
308.15	0.0009	993.831
308.15	0.0012	993.761
308.15	0.0016	993.691
308.15	0.0019	993.628
308.15	0.0022	993.559
308.15	0.0025	993.5
308.15	0.0009	993.832
308.15	0.0012	993.761
308.15	0.0016	993.692
308.15	0.0019	993.621
308.15	0.0022	993.557
308.15	0.0025	993.503
318.15	0.0009	989.957
318.15	0.0009	989.951
318.15	0.0012	989.872
318.15	0.0012	989.86
318.15	0.0016	989.782
318.15	0.0016	989.779
318.15	0.0019	989.693
318.15	0.0019	989.698
318.15	0.0022	989.605
318.15	0.0022	989.612
318.15	0.0025	989.536
318.15	0.0025	989.532

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of n-Propyl acetate (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0000	0.0716
0.0002	0.0659
0.0002	0.0645
0.0003	0.0626
0.0003	0.0632
0.0004	0.0616
0.0004	0.0614
0.0005	0.0603
0.0005	0.0594
0.0006	0.0590
0.0007	0.0575
0.0007	0.0569
0.0008	0.0562
0.0010	0.0544
0.0010	0.0537
0.0011	0.0535
0.0012	0.0532
0.0014	0.0509
0.0014	0.0511
0.0016	0.0492
0.0016	0.0493
0.0021	0.0468
0.0024	0.0454
0.0032	0.0427
0.0036	0.0413
0.0037	0.0406
0.0038	0.0406
1.0000	0.0242

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of n-Propyl acetate (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0000	0.0716
0.0002	0.0659
0.0002	0.0645
0.0003	0.0626
0.0003	0.0632
0.0004	0.0616
0.0004	0.0614
0.0005	0.0603
0.0005	0.0594
0.0006	0.0590
0.0007	0.0575
0.0007	0.0569
0.0008	0.0562
0.0010	0.0544
0.0010	0.0537
0.0011	0.0535
0.0012	0.0532
0.0014	0.0509
0.0014	0.0511
0.0016	0.0492
0.0016	0.0493
0.0021	0.0468
0.0024	0.0454
0.0032	0.0427
0.0036	0.0413
0.0037	0.0406
0.0038	0.0406
1.0000	0.0242

Sources

• (Liquid + liquid) equilibria of (water + 1-propanol + solvent) at T = 298.2K
• Liquid-liquid equilibrium for the ternary systems of water + acetyl acetone + propyl acetate at several temperatures
• Experimental and calculated liquid-liquid equilibrium data for water + furfural + solvents
• Temperature dependence of limiting activity coefficients, Henry's law constants, and related infinite dilution properties of C4-C6 isomeric n-alkyl ethanoates/ethyl n-alkanoates in water. Measurement, critical compilation, correlation, and recommended data
• Experimental and correlated liquid-liquid equilibrium data for water-phosphoric acid-ester
• Measurement of Activity Coefficients at Infinite Dilution of Benzene, Toluene, Ethanol, Esters, Ketones, and Ethers at Various Temperatures in Water Using the Dilutor Technique
• Liquid-Liquid Equilibria for the Ternary System Water + Acetic Acid + Propyl Acetate
• Thermal and Volumetric Properties of Four Aqueous Aroma Compounds at Infinite Dilution
• Surface Tension Data of Aqueous Binary Mixtures of Methyl, Ethyl, Propyl, and Butyl Acetates at 298.15 K