Mixture of Diethyl carbonate + Water

Datasets

1. Mole fraction (30)
2. P_vap - Vapor or sublimation pressure, kPa (2)

Mole fraction of Water (2) [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid	Temperature, K - Liquid	Mole fraction of Water (2) - Gas
0.0000	353.15	0.0000
0.0059	353.15	0.1699
0.0123	353.15	0.2964
0.0181	353.15	0.3670
0.0294	353.15	0.4613
0.0471	353.15	0.5311
0.0970	353.15	0.6356
0.1971	353.15	0.6956
0.2982	353.15	0.7081
0.3604	353.15	0.7087
0.9486	353.15	0.7087
0.9802	353.15	0.7540
0.9905	353.15	0.8019
1.0000	353.15	1.0000
0.0000	363.15	0.0000
0.0061	363.15	0.1760
0.0120	363.15	0.2571
0.0178	363.15	0.3273
0.0247	363.15	0.3876
0.0469	363.15	0.4928
0.0964	363.15	0.6098
0.1900	363.15	0.7023
0.3017	363.15	0.7053
0.3631	363.15	0.5459
0.9650	363.15	0.5459
0.9807	363.15	0.7613
0.9905	363.15	0.8646
1.0000	363.15	1.0000

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
353.15	63.98	0.3604
363.15	90.45	0.3631

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
353.15	63.98	0.9486
363.15	90.45	0.9650

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
293.15	0.0539
308.15	0.0857
313.15	0.0928
298.15	0.0601
303.15	0.0778

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
293.15	0.9974
308.15	0.9974
313.15	0.9972
298.15	0.9975
303.15	0.9975

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
293.15	0.0655
303.15	0.0747
313.15	0.0851
298.15	0.0720

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
293.15	0.9986
303.15	0.9982
313.15	0.9986
298.15	0.9985

Mole fraction of Diethyl carbonate (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 2
303.15	100.00	0.0025

Mole fraction of Diethyl carbonate (1) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 1
100.00	303.15	0.9216

Mole fraction of Diethyl carbonate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 2
303.15	0.0027
313.15	0.0022
323.15	0.0011
333.15	0.0021

Mole fraction of Diethyl carbonate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 1
303.15	0.9155
313.15	0.9153
323.15	0.8982
333.15	0.8776

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
318.15	0.2426
323.15	0.2578
333.15	0.2464
296.15	0.2134
303.15	0.2241

Mole fraction of Diethyl carbonate (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 1
318.15	0.0087
323.15	0.0083
333.15	0.0082
296.15	0.0075
303.15	0.0096

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
303.15	101.00	0.0530

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
303.15	101.00	0.9990

Mole fraction of Water (2) [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid	Temperature, K - Liquid	Mole fraction of Water (2) - Gas
0.0000	353.15	0.0000
0.0059	353.15	0.1699
0.0123	353.15	0.2964
0.0181	353.15	0.3670
0.0294	353.15	0.4613
0.0471	353.15	0.5311
0.0970	353.15	0.6356
0.1971	353.15	0.6956
0.2982	353.15	0.7081
0.3604	353.15	0.7087
0.9486	353.15	0.7087
0.9802	353.15	0.7540
0.9905	353.15	0.8019
1.0000	353.15	1.0000
0.0000	363.15	0.0000
0.0061	363.15	0.1760
0.0120	363.15	0.2571
0.0178	363.15	0.3273
0.0247	363.15	0.3876
0.0469	363.15	0.4928
0.0964	363.15	0.6098
0.1900	363.15	0.7023
0.3017	363.15	0.7053
0.3631	363.15	0.5459
0.9650	363.15	0.5459
0.9807	363.15	0.7613
0.9905	363.15	0.8646
1.0000	363.15	1.0000

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
353.15	63.98	0.3604
363.15	90.45	0.3631

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
353.15	63.98	0.9486
363.15	90.45	0.9650

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
293.15	0.0539
308.15	0.0857
313.15	0.0928
298.15	0.0601
303.15	0.0778

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
293.15	0.9974
308.15	0.9974
313.15	0.9972
298.15	0.9975
303.15	0.9975

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
293.15	0.0655
303.15	0.0747
313.15	0.0851
298.15	0.0720

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
293.15	0.9986
303.15	0.9982
313.15	0.9986
298.15	0.9985

Mole fraction of Diethyl carbonate (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 2
303.15	100.00	0.0025

Mole fraction of Diethyl carbonate (1) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 1
100.00	303.15	0.9216

Mole fraction of Diethyl carbonate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 2
303.15	0.0027
313.15	0.0022
323.15	0.0011
333.15	0.0021

Mole fraction of Diethyl carbonate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid mixture 2)

Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 1
303.15	0.9155
313.15	0.9153
323.15	0.8982
333.15	0.8776

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
318.15	0.2426
323.15	0.2578
333.15	0.2464
296.15	0.2134
303.15	0.2241

Mole fraction of Diethyl carbonate (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Diethyl carbonate (1) - Liquid mixture 1
318.15	0.0087
323.15	0.0083
333.15	0.0082
296.15	0.0075
303.15	0.0096

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
303.15	101.00	0.0530

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 2
303.15	101.00	0.9990

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	353.15	20.74
0.0059	353.15	24.68
0.0123	353.15	28.27
0.0181	353.15	31.98
0.0294	353.15	37.88
0.0471	353.15	46.16
0.0970	353.15	56.57
0.1971	353.15	61.76
0.2982	353.15	62.44
0.3604	353.15	63.98
0.9486	353.15	63.98
0.9802	353.15	57.29
0.9905	353.15	54.85
1.0000	353.15	47.33
0.0000	363.15	30.23
0.0061	363.15	32.60
0.0120	363.15	40.44
0.0178	363.15	45.02
0.0247	363.15	50.11
0.0469	363.15	63.87
0.0964	363.15	77.62
0.1900	363.15	85.53
0.3017	363.15	88.46
0.3631	363.15	90.45
0.9650	363.15	90.45
0.9807	363.15	86.41
0.9905	363.15	80.04
1.0000	363.15	70.07

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	353.15	20.74
0.0059	353.15	24.68
0.0123	353.15	28.27
0.0181	353.15	31.98
0.0294	353.15	37.88
0.0471	353.15	46.16
0.0970	353.15	56.57
0.1971	353.15	61.76
0.2982	353.15	62.44
0.3604	353.15	63.98
0.9486	353.15	63.98
0.9802	353.15	57.29
0.9905	353.15	54.85
1.0000	353.15	47.33
0.0000	363.15	30.23
0.0061	363.15	32.60
0.0120	363.15	40.44
0.0178	363.15	45.02
0.0247	363.15	50.11
0.0469	363.15	63.87
0.0964	363.15	77.62
0.1900	363.15	85.53
0.3017	363.15	88.46
0.3631	363.15	90.45
0.9650	363.15	90.45
0.9807	363.15	86.41
0.9905	363.15	80.04
1.0000	363.15	70.07

Sources

• Isothermal vapor liquid and vapor liquid liquid equilibrium for the ternary system ethanol + water + diethyl carbonate and constituent binary systems at different temperatures
• Ternary (liquid + liquid) equilibria for (water + 1-propanol + dimethyl carbonate, or diethyl carbonate) systems at several temperatures
• Phase equilibria of the ternary systems of (water + diethyl carbonate) with acetone, or 2-butanone at four temperatures
• Determination of Ternary Liquid Liquid Equilibria for Dimethyl Carbonate + 2-Methyl-1-propanol or 2-Methyl-2-propanol + Water Systems at T = 303.15 and 313.15 K
• Atmospheric Ternary Liquid-Liquid Equilibrium for the Diethyl Carbonate + 1-Propanol + Water System at Temperature of 303.15, 313.15, 323.15, and 333.15 K
• Liquid Liquid Equilibrium for the Water + Diethyl Carbonate + Ethanol System at Different Temperatures
• Liquid Liquid Equilibria for Quaternary Systems of Water + Ethanol + Diethyl Carbonate + Methylbenzene or Heptane