Mixture of Toluene + Pyrazine, methyl-
Datasets
-
Mole fraction (2)
-
Excess molar enthalpy (molar enthalpy (2)
-
Pvap - Vapor or sublimation pressure, kPa (2)
Mole fraction of Pyrazine, methyl- (2)
[ref]
| Fixed |
Measured |
| Mole fraction of Pyrazine, methyl- (2) - Liquid |
Temperature, K - Liquid |
Mole fraction of Pyrazine, methyl- (2) - Gas |
| 0.1346 |
263.15 |
0.0384 |
| 0.2424 |
263.15 |
0.0736 |
| 0.3729 |
263.15 |
0.1208 |
| 0.5050 |
263.15 |
0.1783 |
| 0.6416 |
263.15 |
0.2624 |
| 0.7642 |
263.15 |
0.3866 |
| 0.1346 |
273.15 |
0.0425 |
| 0.2424 |
273.15 |
0.0807 |
| 0.3729 |
273.15 |
0.1318 |
| 0.5050 |
273.15 |
0.1943 |
| 0.6416 |
273.15 |
0.2848 |
| 0.7642 |
273.15 |
0.4151 |
| 0.1346 |
283.15 |
0.0465 |
| 0.2424 |
283.15 |
0.0876 |
| 0.3729 |
283.15 |
0.1424 |
| 0.5050 |
283.15 |
0.2094 |
| 0.6416 |
283.15 |
0.3056 |
| 0.7642 |
283.15 |
0.4408 |
| 0.1346 |
293.15 |
0.0504 |
| 0.2424 |
293.15 |
0.0942 |
| 0.3729 |
293.15 |
0.1525 |
| 0.5050 |
293.15 |
0.2236 |
| 0.6416 |
293.15 |
0.3248 |
| 0.7642 |
293.15 |
0.4638 |
| 0.1346 |
303.15 |
0.0541 |
| 0.2424 |
303.15 |
0.1006 |
| 0.3729 |
303.15 |
0.1622 |
| 0.5050 |
303.15 |
0.2371 |
| 0.6416 |
303.15 |
0.3426 |
| 0.7642 |
303.15 |
0.4845 |
| 0.1346 |
313.15 |
0.0576 |
| 0.2424 |
313.15 |
0.1069 |
| 0.3729 |
313.15 |
0.1716 |
| 0.5050 |
313.15 |
0.2499 |
| 0.6416 |
313.15 |
0.3590 |
| 0.7642 |
313.15 |
0.5031 |
| 0.1346 |
323.15 |
0.0613 |
| 0.2424 |
323.15 |
0.1130 |
| 0.3729 |
323.15 |
0.1808 |
| 0.5050 |
323.15 |
0.2622 |
| 0.6416 |
323.15 |
0.3743 |
| 0.7642 |
323.15 |
0.5198 |
| 0.1346 |
333.15 |
0.0646 |
| 0.2424 |
333.15 |
0.1189 |
| 0.3729 |
333.15 |
0.1897 |
| 0.5050 |
333.15 |
0.2740 |
| 0.6416 |
333.15 |
0.3887 |
| 0.7642 |
333.15 |
0.5348 |
| 0.1346 |
343.15 |
0.0670 |
| 0.2424 |
343.15 |
0.1247 |
| 0.3729 |
343.15 |
0.1984 |
| 0.5050 |
343.15 |
0.2853 |
| 0.6416 |
343.15 |
0.4021 |
| 0.7642 |
343.15 |
0.5485 |
| 0.1346 |
353.15 |
0.0711 |
| 0.2424 |
353.15 |
0.1304 |
| 0.3729 |
353.15 |
0.2069 |
| 0.5050 |
353.15 |
0.2964 |
| 0.6416 |
353.15 |
0.4148 |
| 0.7642 |
353.15 |
0.5609 |
| 0.1346 |
363.15 |
0.0741 |
| 0.2424 |
363.15 |
0.1360 |
| 0.3729 |
363.15 |
0.2153 |
| 0.5050 |
363.15 |
0.3071 |
| 0.6416 |
363.15 |
0.4269 |
| 0.7642 |
363.15 |
0.5723 |
Mole fraction of Pyrazine, methyl- (2)
[ref]
| Fixed |
Measured |
| Mole fraction of Pyrazine, methyl- (2) - Liquid |
Temperature, K - Liquid |
Mole fraction of Pyrazine, methyl- (2) - Gas |
| 0.1346 |
263.15 |
0.0384 |
| 0.2424 |
263.15 |
0.0736 |
| 0.3729 |
263.15 |
0.1208 |
| 0.5050 |
263.15 |
0.1783 |
| 0.6416 |
263.15 |
0.2624 |
| 0.7642 |
263.15 |
0.3866 |
| 0.1346 |
273.15 |
0.0425 |
| 0.2424 |
273.15 |
0.0807 |
| 0.3729 |
273.15 |
0.1318 |
| 0.5050 |
273.15 |
0.1943 |
| 0.6416 |
273.15 |
0.2848 |
| 0.7642 |
273.15 |
0.4151 |
| 0.1346 |
283.15 |
0.0465 |
| 0.2424 |
283.15 |
0.0876 |
| 0.3729 |
283.15 |
0.1424 |
| 0.5050 |
283.15 |
0.2094 |
| 0.6416 |
283.15 |
0.3056 |
| 0.7642 |
283.15 |
0.4408 |
| 0.1346 |
293.15 |
0.0504 |
| 0.2424 |
293.15 |
0.0942 |
| 0.3729 |
293.15 |
0.1525 |
| 0.5050 |
293.15 |
0.2236 |
| 0.6416 |
293.15 |
0.3248 |
| 0.7642 |
293.15 |
0.4638 |
| 0.1346 |
303.15 |
0.0541 |
| 0.2424 |
303.15 |
0.1006 |
| 0.3729 |
303.15 |
0.1622 |
| 0.5050 |
303.15 |
0.2371 |
| 0.6416 |
303.15 |
0.3426 |
| 0.7642 |
303.15 |
0.4845 |
| 0.1346 |
313.15 |
0.0576 |
| 0.2424 |
313.15 |
0.1069 |
| 0.3729 |
313.15 |
0.1716 |
| 0.5050 |
313.15 |
0.2499 |
| 0.6416 |
313.15 |
0.3590 |
| 0.7642 |
313.15 |
0.5031 |
| 0.1346 |
323.15 |
0.0613 |
| 0.2424 |
323.15 |
0.1130 |
| 0.3729 |
323.15 |
0.1808 |
| 0.5050 |
323.15 |
0.2622 |
| 0.6416 |
323.15 |
0.3743 |
| 0.7642 |
323.15 |
0.5198 |
| 0.1346 |
333.15 |
0.0646 |
| 0.2424 |
333.15 |
0.1189 |
| 0.3729 |
333.15 |
0.1897 |
| 0.5050 |
333.15 |
0.2740 |
| 0.6416 |
333.15 |
0.3887 |
| 0.7642 |
333.15 |
0.5348 |
| 0.1346 |
343.15 |
0.0670 |
| 0.2424 |
343.15 |
0.1247 |
| 0.3729 |
343.15 |
0.1984 |
| 0.5050 |
343.15 |
0.2853 |
| 0.6416 |
343.15 |
0.4021 |
| 0.7642 |
343.15 |
0.5485 |
| 0.1346 |
353.15 |
0.0711 |
| 0.2424 |
353.15 |
0.1304 |
| 0.3729 |
353.15 |
0.2069 |
| 0.5050 |
353.15 |
0.2964 |
| 0.6416 |
353.15 |
0.4148 |
| 0.7642 |
353.15 |
0.5609 |
| 0.1346 |
363.15 |
0.0741 |
| 0.2424 |
363.15 |
0.1360 |
| 0.3729 |
363.15 |
0.2153 |
| 0.5050 |
363.15 |
0.3071 |
| 0.6416 |
363.15 |
0.4269 |
| 0.7642 |
363.15 |
0.5723 |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Operational conditions:
- Temperature, K = 303.15 (Liquid)
- Pressure, kPa = 100 (Liquid)
| Mole fraction of Pyrazine, methyl- (2) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
| 0.1560 |
0.0280 |
| 0.2560 |
0.0480 |
| 0.4210 |
0.0730 |
| 0.4650 |
0.0750 |
| 0.4750 |
0.0750 |
| 0.5610 |
0.0690 |
| 0.6980 |
0.0390 |
| 0.7600 |
0.0290 |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol
[ref]
Operational conditions:
- Temperature, K = 303.15 (Liquid)
- Pressure, kPa = 100 (Liquid)
| Mole fraction of Pyrazine, methyl- (2) - Liquid |
Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid |
| 0.1560 |
0.0280 |
| 0.2560 |
0.0480 |
| 0.4210 |
0.0730 |
| 0.4650 |
0.0750 |
| 0.4750 |
0.0750 |
| 0.5610 |
0.0690 |
| 0.6980 |
0.0390 |
| 0.7600 |
0.0290 |
Vapor or sublimation pressure, kPa
[ref]
| Fixed |
Measured |
| Mole fraction of Pyrazine, methyl- (2) - Liquid |
Temperature, K - Liquid |
Vapor or sublimation pressure, kPa - Liquid |
| 0.1346 |
263.15 |
0.42 |
| 0.2424 |
263.15 |
0.38 |
| 0.3729 |
263.15 |
0.34 |
| 0.5050 |
263.15 |
0.30 |
| 0.6416 |
263.15 |
0.25 |
| 0.7642 |
263.15 |
0.20 |
| 0.1346 |
273.15 |
0.83 |
| 0.2424 |
273.15 |
0.75 |
| 0.3729 |
273.15 |
0.68 |
| 0.5050 |
273.15 |
0.60 |
| 0.6416 |
273.15 |
0.50 |
| 0.7642 |
273.15 |
0.41 |
| 0.1346 |
283.15 |
1.53 |
| 0.2424 |
283.15 |
1.39 |
| 0.3729 |
283.15 |
1.26 |
| 0.5050 |
283.15 |
1.11 |
| 0.6416 |
283.15 |
0.94 |
| 0.7642 |
283.15 |
0.78 |
| 0.1346 |
293.15 |
2.68 |
| 0.2424 |
293.15 |
2.44 |
| 0.3729 |
293.15 |
2.23 |
| 0.5050 |
293.15 |
1.98 |
| 0.6416 |
293.15 |
1.69 |
| 0.7642 |
293.15 |
1.41 |
| 0.1346 |
303.15 |
4.51 |
| 0.2424 |
303.15 |
4.12 |
| 0.3729 |
303.15 |
3.78 |
| 0.5050 |
303.15 |
3.37 |
| 0.6416 |
303.15 |
2.89 |
| 0.7642 |
303.15 |
2.44 |
| 0.1346 |
313.15 |
7.29 |
| 0.2424 |
313.15 |
6.68 |
| 0.3729 |
313.15 |
6.16 |
| 0.5050 |
313.15 |
5.52 |
| 0.6416 |
313.15 |
4.77 |
| 0.7642 |
313.15 |
4.06 |
| 0.1346 |
323.15 |
11.38 |
| 0.2424 |
323.15 |
10.49 |
| 0.3729 |
323.15 |
9.69 |
| 0.5050 |
323.15 |
8.72 |
| 0.6416 |
323.15 |
7.59 |
| 0.7642 |
323.15 |
6.51 |
| 0.1346 |
333.15 |
17.23 |
| 0.2424 |
333.15 |
15.95 |
| 0.3729 |
333.15 |
14.78 |
| 0.5050 |
333.15 |
13.35 |
| 0.6416 |
333.15 |
11.71 |
| 0.7642 |
333.15 |
10.13 |
| 0.1346 |
343.15 |
25.38 |
| 0.2424 |
343.15 |
23.58 |
| 0.3729 |
343.15 |
21.92 |
| 0.5050 |
343.15 |
19.87 |
| 0.6416 |
343.15 |
17.55 |
| 0.7642 |
343.15 |
15.30 |
| 0.1346 |
353.15 |
36.45 |
| 0.2424 |
353.15 |
34.00 |
| 0.3729 |
353.15 |
31.68 |
| 0.5050 |
353.15 |
28.84 |
| 0.6416 |
353.15 |
25.65 |
| 0.7642 |
353.15 |
22.52 |
| 0.1346 |
363.15 |
51.16 |
| 0.2424 |
363.15 |
47.92 |
| 0.3729 |
363.15 |
44.76 |
| 0.5050 |
363.15 |
40.89 |
| 0.6416 |
363.15 |
36.62 |
| 0.7642 |
363.15 |
32.37 |
Vapor or sublimation pressure, kPa
[ref]
| Fixed |
Measured |
| Mole fraction of Pyrazine, methyl- (2) - Liquid |
Temperature, K - Liquid |
Vapor or sublimation pressure, kPa - Liquid |
| 0.1346 |
263.15 |
0.42 |
| 0.2424 |
263.15 |
0.38 |
| 0.3729 |
263.15 |
0.34 |
| 0.5050 |
263.15 |
0.30 |
| 0.6416 |
263.15 |
0.25 |
| 0.7642 |
263.15 |
0.20 |
| 0.1346 |
273.15 |
0.83 |
| 0.2424 |
273.15 |
0.75 |
| 0.3729 |
273.15 |
0.68 |
| 0.5050 |
273.15 |
0.60 |
| 0.6416 |
273.15 |
0.50 |
| 0.7642 |
273.15 |
0.41 |
| 0.1346 |
283.15 |
1.53 |
| 0.2424 |
283.15 |
1.39 |
| 0.3729 |
283.15 |
1.26 |
| 0.5050 |
283.15 |
1.11 |
| 0.6416 |
283.15 |
0.94 |
| 0.7642 |
283.15 |
0.78 |
| 0.1346 |
293.15 |
2.68 |
| 0.2424 |
293.15 |
2.44 |
| 0.3729 |
293.15 |
2.23 |
| 0.5050 |
293.15 |
1.98 |
| 0.6416 |
293.15 |
1.69 |
| 0.7642 |
293.15 |
1.41 |
| 0.1346 |
303.15 |
4.51 |
| 0.2424 |
303.15 |
4.12 |
| 0.3729 |
303.15 |
3.78 |
| 0.5050 |
303.15 |
3.37 |
| 0.6416 |
303.15 |
2.89 |
| 0.7642 |
303.15 |
2.44 |
| 0.1346 |
313.15 |
7.29 |
| 0.2424 |
313.15 |
6.68 |
| 0.3729 |
313.15 |
6.16 |
| 0.5050 |
313.15 |
5.52 |
| 0.6416 |
313.15 |
4.77 |
| 0.7642 |
313.15 |
4.06 |
| 0.1346 |
323.15 |
11.38 |
| 0.2424 |
323.15 |
10.49 |
| 0.3729 |
323.15 |
9.69 |
| 0.5050 |
323.15 |
8.72 |
| 0.6416 |
323.15 |
7.59 |
| 0.7642 |
323.15 |
6.51 |
| 0.1346 |
333.15 |
17.23 |
| 0.2424 |
333.15 |
15.95 |
| 0.3729 |
333.15 |
14.78 |
| 0.5050 |
333.15 |
13.35 |
| 0.6416 |
333.15 |
11.71 |
| 0.7642 |
333.15 |
10.13 |
| 0.1346 |
343.15 |
25.38 |
| 0.2424 |
343.15 |
23.58 |
| 0.3729 |
343.15 |
21.92 |
| 0.5050 |
343.15 |
19.87 |
| 0.6416 |
343.15 |
17.55 |
| 0.7642 |
343.15 |
15.30 |
| 0.1346 |
353.15 |
36.45 |
| 0.2424 |
353.15 |
34.00 |
| 0.3729 |
353.15 |
31.68 |
| 0.5050 |
353.15 |
28.84 |
| 0.6416 |
353.15 |
25.65 |
| 0.7642 |
353.15 |
22.52 |
| 0.1346 |
363.15 |
51.16 |
| 0.2424 |
363.15 |
47.92 |
| 0.3729 |
363.15 |
44.76 |
| 0.5050 |
363.15 |
40.89 |
| 0.6416 |
363.15 |
36.62 |
| 0.7642 |
363.15 |
32.37 |
Sources