Mixture of n-Butyl ether + Pentane, 2,2,4-trimethyl-

Datasets

1. Mole fraction (4)
2. Excess molar enthalpy (molar enthalpy (4)
3. n₀ - Refractive index (Na D-line) (4)
4. ρ_l - Mass density, kg/m3 (4)
5. c_sound,fluid - Speed of Sound, m/s (2)
6. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Gas)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Gas
0.0000	0.0000
0.0573	0.1409
0.1073	0.2571
0.1720	0.3819
0.2112	0.4471
0.2447	0.4989
0.2813	0.5452
0.3351	0.6111
0.3688	0.6455
0.4286	0.7006
0.4879	0.7500
0.5543	0.7969
0.6397	0.8480
0.7206	0.8899
0.7913	0.9218
0.8366	0.9407
0.8988	0.9649
0.9907	0.9969
1.0000	1.0000

Mole fraction of n-Butyl ether (1) [ref]

Operational condition: Temperature, K = 333.15 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Mole fraction of n-Butyl ether (1) - Gas
0.0200	0.0000
0.0400	0.0100
0.0600	0.0200
0.0800	0.0200
0.1200	0.0300
0.1700	0.0400
0.2300	0.0600
0.2900	0.0800
0.3500	0.1000
0.4100	0.1200
0.4700	0.1500
0.5300	0.1800
0.5900	0.2100
0.6500	0.2500
0.7100	0.3100
0.7700	0.3700
0.8300	0.4600
0.8800	0.5600
0.9200	0.6600
0.9400	0.7300
0.9600	0.8000
0.9800	0.8900

Mole fraction of Pentane, 2,2,4-trimethyl- (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Gas)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Gas
0.0000	0.0000
0.0573	0.1409
0.1073	0.2571
0.1720	0.3819
0.2112	0.4471
0.2447	0.4989
0.2813	0.5452
0.3351	0.6111
0.3688	0.6455
0.4286	0.7006
0.4879	0.7500
0.5543	0.7969
0.6397	0.8480
0.7206	0.8899
0.7913	0.9218
0.8366	0.9407
0.8988	0.9649
0.9907	0.9969
1.0000	1.0000

Mole fraction of n-Butyl ether (1) [ref]

Operational condition: Temperature, K = 333.15 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Mole fraction of n-Butyl ether (1) - Gas
0.0200	0.0000
0.0400	0.0100
0.0600	0.0200
0.0800	0.0200
0.1200	0.0300
0.1700	0.0400
0.2300	0.0600
0.2900	0.0800
0.3500	0.1000
0.4100	0.1200
0.4700	0.1500
0.5300	0.1800
0.5900	0.2100
0.6500	0.2500
0.7100	0.3100
0.7700	0.3700
0.8300	0.4600
0.8800	0.5600
0.9200	0.6600
0.9400	0.7300
0.9600	0.8000
0.9800	0.8900

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0497	0.0269
0.0997	0.0510
0.1497	0.0712
0.1998	0.0861
0.2501	0.0999
0.2995	0.1095
0.3500	0.1172
0.3997	0.1211
0.4494	0.1235
0.4994	0.1230
0.5494	0.1205
0.5996	0.1154
0.6499	0.1079
0.6993	0.0990
0.7499	0.0877
0.7996	0.0740
0.8495	0.0574
0.8995	0.0393
0.9497	0.0196

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 313.15 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0497	0.0262
0.0996	0.0494
0.1496	0.0668
0.1998	0.0825
0.2501	0.0954
0.2995	0.1057
0.3500	0.1132
0.3997	0.1184
0.4495	0.1204
0.4994	0.1212
0.5495	0.1190
0.5996	0.1147
0.6499	0.1082
0.6993	0.0991
0.7499	0.0880
0.7996	0.0746
0.8495	0.0592
0.8995	0.0412
0.9497	0.0216

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0497	0.0269
0.0997	0.0510
0.1497	0.0712
0.1998	0.0861
0.2501	0.0999
0.2995	0.1095
0.3500	0.1172
0.3997	0.1211
0.4494	0.1235
0.4994	0.1230
0.5494	0.1205
0.5996	0.1154
0.6499	0.1079
0.6993	0.0990
0.7499	0.0877
0.7996	0.0740
0.8495	0.0574
0.8995	0.0393
0.9497	0.0196

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 313.15 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0497	0.0262
0.0996	0.0494
0.1496	0.0668
0.1998	0.0825
0.2501	0.0954
0.2995	0.1057
0.3500	0.1132
0.3997	0.1184
0.4495	0.1204
0.4994	0.1212
0.5495	0.1190
0.5996	0.1147
0.6499	0.1082
0.6993	0.0991
0.7499	0.0880
0.7996	0.0746
0.8495	0.0592
0.8995	0.0412
0.9497	0.0216

Refractive index (Na D-line) [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Refractive index (Na D-line) - Liquid
0.0000	1.3965
0.0503	1.3962
0.1016	1.3958
0.1493	1.3955
0.1972	1.3952
0.2496	1.3948
0.3005	1.3945
0.3509	1.3941
0.4013	1.3937
0.4510	1.3934
0.4994	1.393
0.5474	1.3927
0.5978	1.3923
0.6491	1.3919
0.7016	1.3915
0.7505	1.3911
0.8028	1.3906
0.8516	1.3902
0.8989	1.3898
0.9497	1.3894
1.0000	1.389

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Refractive index (Na D-line) - Liquid
0.0497	1.3894
0.1000	1.3898
0.1996	1.3906
0.3000	1.3914
0.4001	1.3922
0.5005	1.393
0.6003	1.3938
0.7000	1.3945
0.8000	1.3952
0.9000	1.3959
0.9500	1.3962

Refractive index (Na D-line) [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Refractive index (Na D-line) - Liquid
0.0000	1.3965
0.0503	1.3962
0.1016	1.3958
0.1493	1.3955
0.1972	1.3952
0.2496	1.3948
0.3005	1.3945
0.3509	1.3941
0.4013	1.3937
0.4510	1.3934
0.4994	1.393
0.5474	1.3927
0.5978	1.3923
0.6491	1.3919
0.7016	1.3915
0.7505	1.3911
0.8028	1.3906
0.8516	1.3902
0.8989	1.3898
0.9497	1.3894
1.0000	1.389

Refractive index (Na D-line) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Refractive index (Na D-line) - Liquid
0.0497	1.3894
0.1000	1.3898
0.1996	1.3906
0.3000	1.3914
0.4001	1.3922
0.5005	1.393
0.6003	1.3938
0.7000	1.3945
0.8000	1.3952
0.9000	1.3959
0.9500	1.3962

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	763.75
0.0503	760.07
0.1016	756.32
0.1493	752.81
0.1972	749.28
0.2496	745.31
0.3005	741.56
0.3509	737.8
0.4013	733.95
0.4510	730.21
0.4994	726.58
0.5474	722.91
0.5978	719.07
0.6491	715.12
0.7016	711.08
0.7505	707.28
0.8028	703.2
0.8516	699.4
0.8989	695.7
0.9497	691.68
1.0000	687.71

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Mass density, kg/m3 - Liquid
0.0497	692.1
0.1000	696.09
0.1996	703.9
0.3000	711.73
0.4001	719.45
0.5005	727.17
0.6003	734.81
0.7000	742.31
0.8000	749.75
0.9000	757.11
0.9500	760.7

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	763.75
0.0503	760.07
0.1016	756.32
0.1493	752.81
0.1972	749.28
0.2496	745.31
0.3005	741.56
0.3509	737.8
0.4013	733.95
0.4510	730.21
0.4994	726.58
0.5474	722.91
0.5978	719.07
0.6491	715.12
0.7016	711.08
0.7505	707.28
0.8028	703.2
0.8516	699.4
0.8989	695.7
0.9497	691.68
1.0000	687.71

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of n-Butyl ether (1) - Liquid	Mass density, kg/m3 - Liquid
0.0497	692.1
0.1000	696.09
0.1996	703.9
0.3000	711.73
0.4001	719.45
0.5005	727.17
0.6003	734.81
0.7000	742.31
0.8000	749.75
0.9000	757.11
0.9500	760.7

Speed of sound, m/s [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)
• Frequency, MHz = 3 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Speed of sound, m/s - Liquid
0.0000	1162.01
0.0503	1158.32
0.1016	1154.52
0.1493	1151.01
0.1972	1147.4
0.2496	1142.34
0.3005	1139.06
0.3509	1135.24
0.4013	1130.67
0.4510	1127.13
0.4994	1123.67
0.5474	1120.26
0.5978	1116.25
0.6491	1112.09
0.7016	1107.8
0.7505	1103.76
0.8028	1099.45
0.8516	1095.36
0.8989	1091.39
0.9497	1087.06
1.0000	1082.63

Speed of sound, m/s [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)
• Frequency, MHz = 3 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Speed of sound, m/s - Liquid
0.0000	1162.01
0.0503	1158.32
0.1016	1154.52
0.1493	1151.01
0.1972	1147.4
0.2496	1142.34
0.3005	1139.06
0.3509	1135.24
0.4013	1130.67
0.4510	1127.13
0.4994	1123.67
0.5474	1120.26
0.5978	1116.25
0.6491	1112.09
0.7016	1107.8
0.7505	1103.76
0.8028	1099.45
0.8516	1095.36
0.8989	1091.39
0.9497	1087.06
1.0000	1082.63

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	414.55
0.0573	410.11
0.1073	406.74
0.1720	402.77
0.2112	400.50
0.2447	398.52
0.2813	396.83
0.3351	394.04
0.3688	392.58
0.4286	390.08
0.4879	387.55
0.5543	385.04
0.6397	382.15
0.7206	379.54
0.7913	377.51
0.8366	376.21
0.8988	374.39
0.9907	372.21
1.0000	372.16

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	414.55
0.0573	410.11
0.1073	406.74
0.1720	402.77
0.2112	400.50
0.2447	398.52
0.2813	396.83
0.3351	394.04
0.3688	392.58
0.4286	390.08
0.4879	387.55
0.5543	385.04
0.6397	382.15
0.7206	379.54
0.7913	377.51
0.8366	376.21
0.8988	374.39
0.9907	372.21
1.0000	372.16

Sources

• Excess enthalpies of oxygenated compounds + hydrocarbon mixtures: Binary and ternary mixtures containing dibutyl ether (DBE), 1-butanol and 2,2,4-trimethylpentane at 298.15 K
• Ether + alcohol + hydrocarbon mixtures in fuels and bio-fuels: Excess enthalpies of binary mixtures containing dibutyl ether (DBE) or 1-butanol and 1-hexene or methylcyclohexane or toluene or cyclohexane or 2,2,4-trimethylpentane at 298.15K and 313.15K
• Isobaric vapor-liquid equilibrium, density and speed of sound of binary mixtures 2,2,4-trimethylpentane + 1-butanol or dibutyl ether (DBE) at 101.3 kPa
• Isothermal Vapor-Liquid Equilibrium at 333.15 K and Excess Volumes and Molar Refractivity Deviation at 298.15 K for Binary System Dibutyl Ether (DBE) + 2,2,4-Trimethylpentane and for Ternary System DBE + Ethanol + 2,2,4-Trimethylpentane