Mixture of 1-Butanol + Acetic acid + Water

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1-Butanol

Name
1-Butanol
InChI
InChI=1S/C4H10O/c1-2-3-4-5/h5H,2-4H2,1H3
InChI Key
LRHPLDYGYMQRHN-UHFFFAOYSA-N
Formula
C4H10O
SMILES
CCCCO
Mol. Weight (g/mol)
74.12
CAS
71-36-3

Acetic acid

Name
Acetic acid
InChI
InChI=1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)
InChI Key
QTBSBXVTEAMEQO-UHFFFAOYSA-N
Formula
C2H4O2
SMILES
CC(=O)O
Mol. Weight (g/mol)
60.05
CAS
64-19-7

Water

Name
Water
InChI
InChI=1S/H2O/h1H2
InChI Key
XLYOFNOQVPJJNP-UHFFFAOYSA-N
Formula
H2O
SMILES
O
Mol. Weight (g/mol)
18.02
CAS
7732-18-5
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Datasets

  1. Mole fraction (12)
  2. n0 - Refractive index (Na D-line) (6)
  3. ρl - Mass density, kg/m3 (6)
  4. csound,fluid - Speed of Sound, m/s (6)
  5. Tc - Critical temperature, K (2)

Mole fraction [ref]

Operational conditions:

Fixed Measured
Mole fraction of 1-Butanol (1) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 2 Mole fraction of 1-Butanol (1) - Liquid mixture 2
0.0170 0.0000 0.0000 0.4760
0.0170 0.0090 0.0170 0.4140
0.0230 0.0190 0.0430 0.3560
0.0290 0.0290 0.0640 0.2940
0.0370 0.0320 0.0700 0.2730
0.0460 0.0400 0.0780 0.2250
0.0600 0.0480 0.0790 0.1810

Mole fraction in LLG critical state of Acetic acid (2) [ref]

Fixed Measured
Mole fraction of 1-Butanol (1) - Liquid Temperature, K - Liquid Mole fraction in LLG critical state of Acetic acid (2) - Liquid
0.1090 308.15 0.0630

Mole fraction of Acetic acid (2) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 1
293.20 0.5064 0.0000
293.20 0.5362 0.0278
293.20 0.5603 0.0497
293.20 0.6285 0.0739
293.20 0.7013 0.0823
293.20 0.7896 0.0748
293.20 0.8379 0.0661
293.20 0.8954 0.0528
293.20 0.9280 0.0396
293.20 0.9547 0.0218
293.20 0.9798 0.0000
313.20 0.5304 0.0000
313.20 0.5697 0.0307
313.20 0.5925 0.0463
313.20 0.6593 0.0692
313.20 0.7296 0.0745
313.20 0.7663 0.0720
313.20 0.8009 0.0668
313.20 0.8741 0.0538
313.20 0.9267 0.0387
313.20 0.9478 0.0273
313.20 0.9648 0.0154
313.20 0.9829 0.0000

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 2 Mole fraction of Acetic acid (2) - Liquid mixture 2 Mole fraction of Acetic acid (2) - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1
293.20 0.9625 0.0158 0.0542 0.5705
293.20 0.9485 0.0259 0.0698 0.6076
293.20 0.9337 0.0351 0.0786 0.6519
313.20 0.9701 0.0115 0.0236 0.5572
313.20 0.9650 0.0151 0.0463 0.5921
313.20 0.9551 0.0216 0.0715 0.6855
313.20 0.9395 0.0306 0.0731 0.7199

Mole fraction of Acetic acid (2) [ref]

Operational conditions:

Mole fraction of 1-Butanol (1) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 1
0.4210 0.0280
0.4120 0.0340
0.3850 0.0440
0.3520 0.0550
0.3150 0.0650
0.2860 0.0710
0.2580 0.0720
0.2410 0.0740
0.2160 0.0760
0.1800 0.0740
0.1630 0.0720
0.1440 0.0690
0.1190 0.0640
0.1190 0.0640
0.1030 0.0600
0.0880 0.0570
0.0770 0.0550

Mole fraction [ref]

Operational conditions:

Fixed Measured
Mole fraction of Acetic acid (2) - Liquid mixture 2 Mole fraction of 1-Butanol (1) - Liquid mixture 2 Mole fraction of Acetic acid (2) - Liquid mixture 1 Mole fraction of 1-Butanol (1) - Liquid mixture 1
0.0080 0.0230 0.0250 0.4180
0.0180 0.0330 0.0560 0.3230
0.0270 0.0470 0.0650 0.2630

Mole fraction [ref]

Operational conditions:

Fixed Measured
Mole fraction of 1-Butanol (1) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 2 Mole fraction of 1-Butanol (1) - Liquid mixture 2
0.0170 0.0000 0.0000 0.4760
0.0170 0.0090 0.0170 0.4140
0.0230 0.0190 0.0430 0.3560
0.0290 0.0290 0.0640 0.2940
0.0370 0.0320 0.0700 0.2730
0.0460 0.0400 0.0780 0.2250
0.0600 0.0480 0.0790 0.1810

Mole fraction in LLG critical state of Acetic acid (2) [ref]

Fixed Measured
Mole fraction of 1-Butanol (1) - Liquid Temperature, K - Liquid Mole fraction in LLG critical state of Acetic acid (2) - Liquid
0.1090 308.15 0.0630

Mole fraction of Acetic acid (2) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 1
293.20 0.5064 0.0000
293.20 0.5362 0.0278
293.20 0.5603 0.0497
293.20 0.6285 0.0739
293.20 0.7013 0.0823
293.20 0.7896 0.0748
293.20 0.8379 0.0661
293.20 0.8954 0.0528
293.20 0.9280 0.0396
293.20 0.9547 0.0218
293.20 0.9798 0.0000
313.20 0.5304 0.0000
313.20 0.5697 0.0307
313.20 0.5925 0.0463
313.20 0.6593 0.0692
313.20 0.7296 0.0745
313.20 0.7663 0.0720
313.20 0.8009 0.0668
313.20 0.8741 0.0538
313.20 0.9267 0.0387
313.20 0.9478 0.0273
313.20 0.9648 0.0154
313.20 0.9829 0.0000

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 2 Mole fraction of Acetic acid (2) - Liquid mixture 2 Mole fraction of Acetic acid (2) - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1
293.20 0.9625 0.0158 0.0542 0.5705
293.20 0.9485 0.0259 0.0698 0.6076
293.20 0.9337 0.0351 0.0786 0.6519
313.20 0.9701 0.0115 0.0236 0.5572
313.20 0.9650 0.0151 0.0463 0.5921
313.20 0.9551 0.0216 0.0715 0.6855
313.20 0.9395 0.0306 0.0731 0.7199

Mole fraction of Acetic acid (2) [ref]

Operational conditions:

Mole fraction of 1-Butanol (1) - Liquid mixture 1 Mole fraction of Acetic acid (2) - Liquid mixture 1
0.4210 0.0280
0.4120 0.0340
0.3850 0.0440
0.3520 0.0550
0.3150 0.0650
0.2860 0.0710
0.2580 0.0720
0.2410 0.0740
0.2160 0.0760
0.1800 0.0740
0.1630 0.0720
0.1440 0.0690
0.1190 0.0640
0.1190 0.0640
0.1030 0.0600
0.0880 0.0570
0.0770 0.0550

Mole fraction [ref]

Operational conditions:

Fixed Measured
Mole fraction of Acetic acid (2) - Liquid mixture 2 Mole fraction of 1-Butanol (1) - Liquid mixture 2 Mole fraction of Acetic acid (2) - Liquid mixture 1 Mole fraction of 1-Butanol (1) - Liquid mixture 1
0.0080 0.0230 0.0250 0.4180
0.0180 0.0330 0.0560 0.3230
0.0270 0.0470 0.0650 0.2630

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Refractive index (Na D-line) - Liquid mixture 1
293.20 0.5064 1.3907
293.20 0.5362 1.3889
293.20 0.5603 1.3907
293.20 0.6285 1.3833
293.20 0.7013 1.3784
293.20 0.7896 1.3637
293.20 0.8379 1.3654
293.20 0.8954 1.3575
293.20 0.9280 1.3515
293.20 0.9547 1.3462
293.20 0.9798 1.3413
313.20 0.5304 1.3824
313.20 0.5697 1.3805
313.20 0.5925 1.3792
313.20 0.6593 1.3756
313.20 0.7296 1.3492
313.20 0.7663 1.3539
313.20 0.8009 1.3513
313.20 0.8741 1.3525
313.20 0.9267 1.3471
313.20 0.9478 1.3435
313.20 0.9648 1.3396
313.20 0.9829 1.3366

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Refractive index (Na D-line) - Liquid mixture 1
293.20 0.5705 1.3872
293.20 0.6076 1.3849
293.20 0.6519 1.382
313.20 0.5572 1.3808
313.20 0.5921 1.3793
313.20 0.6855 1.3434
313.20 0.7199 1.3467

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 2 Mole fraction of Water (3) - Liquid mixture 2 Refractive index (Na D-line) - Liquid mixture 2
293.20 0.9625 1.3449
293.20 0.9485 1.3473
293.20 0.9337 1.3502
313.20 0.9701 1.3387
313.20 0.9650 1.3404
313.20 0.9551 1.3427
313.20 0.9395 1.3456

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Refractive index (Na D-line) - Liquid mixture 1
293.20 0.5064 1.3907
293.20 0.5362 1.3889
293.20 0.5603 1.3907
293.20 0.6285 1.3833
293.20 0.7013 1.3784
293.20 0.7896 1.3637
293.20 0.8379 1.3654
293.20 0.8954 1.3575
293.20 0.9280 1.3515
293.20 0.9547 1.3462
293.20 0.9798 1.3413
313.20 0.5304 1.3824
313.20 0.5697 1.3805
313.20 0.5925 1.3792
313.20 0.6593 1.3756
313.20 0.7296 1.3492
313.20 0.7663 1.3539
313.20 0.8009 1.3513
313.20 0.8741 1.3525
313.20 0.9267 1.3471
313.20 0.9478 1.3435
313.20 0.9648 1.3396
313.20 0.9829 1.3366

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Refractive index (Na D-line) - Liquid mixture 1
293.20 0.5705 1.3872
293.20 0.6076 1.3849
293.20 0.6519 1.382
313.20 0.5572 1.3808
313.20 0.5921 1.3793
313.20 0.6855 1.3434
313.20 0.7199 1.3467

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 2 Mole fraction of Water (3) - Liquid mixture 2 Refractive index (Na D-line) - Liquid mixture 2
293.20 0.9625 1.3449
293.20 0.9485 1.3473
293.20 0.9337 1.3502
313.20 0.9701 1.3387
313.20 0.9650 1.3404
313.20 0.9551 1.3427
313.20 0.9395 1.3456

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Mass density, kg/m3 - Liquid mixture 1
293.20 0.5064 846.409
293.20 0.5362 857.712
293.20 0.5603 862.217
293.20 0.6285 892.724
293.20 0.7013 916.132
293.20 0.7896 943.915
293.20 0.8379 960.824
293.20 0.8954 984.207
293.20 0.9280 993.68
293.20 0.9547 994.076
293.20 0.9798 987.014
313.20 0.5304 833.784
313.20 0.5697 848.984
313.20 0.5925 858.013
313.20 0.6593 882.34
313.20 0.7296 904.503
313.20 0.7663 917.44
313.20 0.8009 917.315
313.20 0.8741 954.638
313.20 0.9267 980.205
313.20 0.9478 984.892
313.20 0.9648 984.937
313.20 0.9829 981.412

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Mass density, kg/m3 - Liquid mixture 1
293.20 0.5705 869.833
293.20 0.6076 883.627
293.20 0.6519 899.498
313.20 0.5572 844.584
313.20 0.5921 856.962
313.20 0.6855 872.064
313.20 0.7199 890.5

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 2 Mole fraction of Water (3) - Liquid mixture 2 Mass density, kg/m3 - Liquid mixture 2
293.20 0.9625 992.709
293.20 0.9485 994.732
293.20 0.9337 994.738
313.20 0.9701 982.487
313.20 0.9650 984.773
313.20 0.9551 985.513
313.20 0.9395 983.895

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Mass density, kg/m3 - Liquid mixture 1
293.20 0.5064 846.409
293.20 0.5362 857.712
293.20 0.5603 862.217
293.20 0.6285 892.724
293.20 0.7013 916.132
293.20 0.7896 943.915
293.20 0.8379 960.824
293.20 0.8954 984.207
293.20 0.9280 993.68
293.20 0.9547 994.076
293.20 0.9798 987.014
313.20 0.5304 833.784
313.20 0.5697 848.984
313.20 0.5925 858.013
313.20 0.6593 882.34
313.20 0.7296 904.503
313.20 0.7663 917.44
313.20 0.8009 917.315
313.20 0.8741 954.638
313.20 0.9267 980.205
313.20 0.9478 984.892
313.20 0.9648 984.937
313.20 0.9829 981.412

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Mass density, kg/m3 - Liquid mixture 1
293.20 0.5705 869.833
293.20 0.6076 883.627
293.20 0.6519 899.498
313.20 0.5572 844.584
313.20 0.5921 856.962
313.20 0.6855 872.064
313.20 0.7199 890.5

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 2 Mole fraction of Water (3) - Liquid mixture 2 Mass density, kg/m3 - Liquid mixture 2
293.20 0.9625 992.709
293.20 0.9485 994.732
293.20 0.9337 994.738
313.20 0.9701 982.487
313.20 0.9650 984.773
313.20 0.9551 985.513
313.20 0.9395 983.895

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Speed of sound, m/s - Liquid mixture 1
293.20 0.5064 1314.68
293.20 0.5362 1320.64
293.20 0.5603 1323.52
293.20 0.6285 1343.3
293.20 0.7013 1367.28
293.20 0.7896 1406.91
293.20 0.8379 1438.88
293.20 0.8954 1494.77
293.20 0.9280 1528.52
293.20 0.9547 1547.22
293.20 0.9798 1549.53
313.20 0.5304 1259.34
313.20 0.5697 1269.46
313.20 0.5925 1274.68
313.20 0.6593 1298.19
313.20 0.7296 1323.76
313.20 0.7663 1340.98
313.20 0.8009 1341.48
313.20 0.8741 1462.55
313.20 0.9267 1516.1
313.20 0.9478 1540.35
313.20 0.9648 1555.5
313.20 0.9829 1562.51

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Speed of sound, m/s - Liquid mixture 1
293.20 0.5705 1326.44
293.20 0.6076 1335.71
293.20 0.6519 1349.08
313.20 0.5572 1263.86
313.20 0.5921 1273.46
313.20 0.6855 1286.22
313.20 0.7199 1299.55

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 2 Mole fraction of Water (3) - Liquid mixture 2 Speed of sound, m/s - Liquid mixture 2
293.20 0.9625 1549.23
293.20 0.9485 1544.26
293.20 0.9337 1534.02
313.20 0.9701 1558.46
313.20 0.9650 1554.23
313.20 0.9551 1544.16
313.20 0.9395 1527.23

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Speed of sound, m/s - Liquid mixture 1
293.20 0.5064 1314.68
293.20 0.5362 1320.64
293.20 0.5603 1323.52
293.20 0.6285 1343.3
293.20 0.7013 1367.28
293.20 0.7896 1406.91
293.20 0.8379 1438.88
293.20 0.8954 1494.77
293.20 0.9280 1528.52
293.20 0.9547 1547.22
293.20 0.9798 1549.53
313.20 0.5304 1259.34
313.20 0.5697 1269.46
313.20 0.5925 1274.68
313.20 0.6593 1298.19
313.20 0.7296 1323.76
313.20 0.7663 1340.98
313.20 0.8009 1341.48
313.20 0.8741 1462.55
313.20 0.9267 1516.1
313.20 0.9478 1540.35
313.20 0.9648 1555.5
313.20 0.9829 1562.51

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Fixed Measured
Temperature, K - Liquid mixture 1 Mole fraction of Water (3) - Liquid mixture 1 Speed of sound, m/s - Liquid mixture 1
293.20 0.5705 1326.44
293.20 0.6076 1335.71
293.20 0.6519 1349.08
313.20 0.5572 1263.86
313.20 0.5921 1273.46
313.20 0.6855 1286.22
313.20 0.7199 1299.55

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 2)

Fixed Measured
Temperature, K - Liquid mixture 2 Mole fraction of Water (3) - Liquid mixture 2 Speed of sound, m/s - Liquid mixture 2
293.20 0.9625 1549.23
293.20 0.9485 1544.26
293.20 0.9337 1534.02
313.20 0.9701 1558.46
313.20 0.9650 1554.23
313.20 0.9551 1544.16
313.20 0.9395 1527.23

Critical temperature, K [ref]

Fixed Measured
Mole fraction of Acetic acid (2) - Liquid Mole fraction of 1-Butanol (1) - Liquid Critical temperature, K - Liquid
0.0630 0.1000 318.15

Critical temperature, K [ref]

Fixed Measured
Mole fraction of Acetic acid (2) - Liquid Mole fraction of 1-Butanol (1) - Liquid Critical temperature, K - Liquid
0.0630 0.1000 318.15

Sources