Mixture of Ethyl Acetate + Nonane

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (4)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)
5. Excess molar volume, m3/mol (2)

Mole fraction of Ethyl Acetate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Mole fraction of Ethyl Acetate (1) - Gas
0.0000	0.0000
0.0100	0.1180
0.0170	0.1890
0.0310	0.3030
0.0450	0.3900
0.0550	0.4440
0.0730	0.5230
0.0930	0.5830
0.1200	0.6520
0.1590	0.7260
0.1870	0.7620
0.2270	0.8040
0.2610	0.8260
0.3380	0.8640
0.4120	0.8790
0.4860	0.9000
0.5640	0.9150
0.6350	0.9300
0.7120	0.9420
0.7920	0.9530
0.8540	0.9650
0.8970	0.9740
0.9400	0.9850
0.9640	0.9910
0.9810	0.9950
1.0000	1.0000

Mole fraction of Ethyl Acetate (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Mole fraction of Ethyl Acetate (1) - Gas
0.0000	0.0000
0.0100	0.1180
0.0170	0.1890
0.0310	0.3030
0.0450	0.3900
0.0550	0.4440
0.0730	0.5230
0.0930	0.5830
0.1200	0.6520
0.1590	0.7260
0.1870	0.7620
0.2270	0.8040
0.2610	0.8260
0.3380	0.8640
0.4120	0.8790
0.4860	0.9000
0.5640	0.9150
0.6350	0.9300
0.7120	0.9420
0.7920	0.9530
0.8540	0.9650
0.8970	0.9740
0.9400	0.9850
0.9640	0.9910
0.9810	0.9950
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 318.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0596	0.3637
0.1310	0.7182
0.2117	1.0579
0.2950	1.3229
0.3664	1.5128
0.4360	1.6493
0.4899	1.6992
0.5447	1.7064
0.5881	1.6688
0.6166	1.6349
0.6290	1.6044
0.6629	1.5591
0.7061	1.4529
0.7520	1.3387
0.7991	1.1608
0.8421	0.9837
0.8875	0.7420
0.9312	0.4925
0.9672	0.2471

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 291.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0872	0.5510
0.1735	0.9420
0.2499	1.25
0.3159	1.468
0.3746	1.604
0.4330	1.689
0.4869	1.732
0.5340	1.742
0.5836	1.724
0.6005	1.697
0.6419	1.645
0.6885	1.564
0.7366	1.447
0.7846	1.298
0.8345	1.099
0.8779	0.8560
0.9237	0.5880
0.9619	0.3070

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 318.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0596	0.3637
0.1310	0.7182
0.2117	1.0579
0.2950	1.3229
0.3664	1.5128
0.4360	1.6493
0.4899	1.6992
0.5447	1.7064
0.5881	1.6688
0.6166	1.6349
0.6290	1.6044
0.6629	1.5591
0.7061	1.4529
0.7520	1.3387
0.7991	1.1608
0.8421	0.9837
0.8875	0.7420
0.9312	0.4925
0.9672	0.2471

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 291.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0872	0.5510
0.1735	0.9420
0.2499	1.25
0.3159	1.468
0.3746	1.604
0.4330	1.689
0.4869	1.732
0.5340	1.742
0.5836	1.724
0.6005	1.697
0.6419	1.645
0.6885	1.564
0.7366	1.447
0.7846	1.298
0.8345	1.099
0.8779	0.8560
0.9237	0.5880
0.9619	0.3070

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl Acetate (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	719.2
291.15	0.0328	721.88
291.15	0.0796	726.0
291.15	0.1292	730.54
291.15	0.2225	740.13
291.15	0.3076	750.0
291.15	0.3932	761.25
291.15	0.4659	771.77
291.15	0.5694	788.99
291.15	0.6015	794.91
291.15	0.6514	804.7
291.15	0.7041	815.84
291.15	0.7547	827.59
291.15	0.8076	840.96
291.15	0.8502	852.64
291.15	0.8954	866.2
291.15	0.9307	877.58
291.15	0.9918	899.59
291.15	1.0000	902.88
298.15	0.0000	713.85
298.15	0.0652	719.2
298.15	0.1102	723.17
298.15	0.1906	730.94
298.15	0.2667	739.14
298.15	0.3377	747.65
298.15	0.4128	757.7
298.15	0.4737	766.6
298.15	0.5212	774.12
298.15	0.5875	785.5
298.15	0.6305	793.54
298.15	0.6743	802.32
298.15	0.7212	812.53
298.15	0.7670	823.2
298.15	0.8024	832.16
298.15	0.8428	843.01
298.15	0.8654	849.38
298.15	0.9419	873.16
298.15	0.9564	878.07
298.15	1.0000	894.4
318.15	0.0000	698.09
318.15	0.0372	700.83
318.15	0.1287	708.3
318.15	0.2206	717.0
318.15	0.3125	726.84
318.15	0.3941	736.68
318.15	0.4659	746.38
318.15	0.5311	756.19
318.15	0.5965	767.1
318.15	0.6714	781.02
318.15	0.7111	789.15
318.15	0.7598	799.77
318.15	0.8122	812.28
318.15	0.8596	824.75
318.15	0.8955	835.04
318.15	0.9360	847.56
318.15	0.9808	862.66
318.15	1.0000	869.6
328.15	0.0000	690.4
328.15	0.0202	691.7
328.15	0.1246	699.9
328.15	0.2225	708.81
328.15	0.3109	717.88
328.15	0.3923	727.35
328.15	0.4644	736.84
328.15	0.5377	747.63
328.15	0.6125	759.98
328.15	0.7233	781.1
328.15	0.7593	788.8
328.15	0.8102	800.56
328.15	0.8505	810.9
328.15	0.8934	822.54
328.15	0.9507	840.17
328.15	0.9876	852.64
328.15	1.0000	857.17

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Ethyl Acetate (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	719.2
291.15	0.0328	721.88
291.15	0.0796	726.0
291.15	0.1292	730.54
291.15	0.2225	740.13
291.15	0.3076	750.0
291.15	0.3932	761.25
291.15	0.4659	771.77
291.15	0.5694	788.99
291.15	0.6015	794.91
291.15	0.6514	804.7
291.15	0.7041	815.84
291.15	0.7547	827.59
291.15	0.8076	840.96
291.15	0.8502	852.64
291.15	0.8954	866.2
291.15	0.9307	877.58
291.15	0.9918	899.59
291.15	1.0000	902.88
298.15	0.0000	713.85
298.15	0.0652	719.2
298.15	0.1102	723.17
298.15	0.1906	730.94
298.15	0.2667	739.14
298.15	0.3377	747.65
298.15	0.4128	757.7
298.15	0.4737	766.6
298.15	0.5212	774.12
298.15	0.5875	785.5
298.15	0.6305	793.54
298.15	0.6743	802.32
298.15	0.7212	812.53
298.15	0.7670	823.2
298.15	0.8024	832.16
298.15	0.8428	843.01
298.15	0.8654	849.38
298.15	0.9419	873.16
298.15	0.9564	878.07
298.15	1.0000	894.4
318.15	0.0000	698.09
318.15	0.0372	700.83
318.15	0.1287	708.3
318.15	0.2206	717.0
318.15	0.3125	726.84
318.15	0.3941	736.68
318.15	0.4659	746.38
318.15	0.5311	756.19
318.15	0.5965	767.1
318.15	0.6714	781.02
318.15	0.7111	789.15
318.15	0.7598	799.77
318.15	0.8122	812.28
318.15	0.8596	824.75
318.15	0.8955	835.04
318.15	0.9360	847.56
318.15	0.9808	862.66
318.15	1.0000	869.6
328.15	0.0000	690.4
328.15	0.0202	691.7
328.15	0.1246	699.9
328.15	0.2225	708.81
328.15	0.3109	717.88
328.15	0.3923	727.35
328.15	0.4644	736.84
328.15	0.5377	747.63
328.15	0.6125	759.98
328.15	0.7233	781.1
328.15	0.7593	788.8
328.15	0.8102	800.56
328.15	0.8505	810.9
328.15	0.8934	822.54
328.15	0.9507	840.17
328.15	0.9876	852.64
328.15	1.0000	857.17

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	423.94
0.0100	420.00
0.0170	417.06
0.0310	412.10
0.0450	407.91
0.0550	405.01
0.0730	400.40
0.0930	396.55
0.1200	391.49
0.1590	385.31
0.1870	381.80
0.2270	377.45
0.2610	374.65
0.3380	369.47
0.4120	367.15
0.4860	363.75
0.5640	361.50
0.6350	359.01
0.7120	357.15
0.7920	355.50
0.8540	354.15
0.8970	353.00
0.9400	351.92
0.9640	351.19
0.9810	350.70
1.0000	350.15

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	423.94
0.0100	420.00
0.0170	417.06
0.0310	412.10
0.0450	407.91
0.0550	405.01
0.0730	400.40
0.0930	396.55
0.1200	391.49
0.1590	385.31
0.1870	381.80
0.2270	377.45
0.2610	374.65
0.3380	369.47
0.4120	367.15
0.4860	363.75
0.5640	361.50
0.6350	359.01
0.7120	357.15
0.7920	355.50
0.8540	354.15
0.8970	353.00
0.9400	351.92
0.9640	351.19
0.9810	350.70
1.0000	350.15

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 318.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0916	4.9400e-07
0.1769	8.5300e-07
0.2442	1.0490e-06
0.3108	1.2280e-06
0.3462	1.2890e-06
0.4363	1.4180e-06
0.4938	1.4460e-06
0.5469	1.4470e-06
0.5934	1.4260e-06
0.6418	1.3610e-06
0.6869	1.2920e-06
0.7308	1.2020e-06
0.7614	1.1420e-06
0.8417	8.4900e-07
0.9044	5.7800e-07
0.9558	2.9400e-07

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 318.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of Ethyl Acetate (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0916	4.9400e-07
0.1769	8.5300e-07
0.2442	1.0490e-06
0.3108	1.2280e-06
0.3462	1.2890e-06
0.4363	1.4180e-06
0.4938	1.4460e-06
0.5469	1.4470e-06
0.5934	1.4260e-06
0.6418	1.3610e-06
0.6869	1.2920e-06
0.7308	1.2020e-06
0.7614	1.1420e-06
0.8417	8.4900e-07
0.9044	5.7800e-07
0.9558	2.9400e-07

Sources

• Thermodynamic properties of (an ester + an alkane). XVI. Experimental HEm and V Em values and a new correlation method for (an alkyl ethanoate + an n-alkane) at 318.15 K
• Measurements of the Excess Properties and Vapor-Liquid Equilibria at 101.32 kPa for Mixtures of Ethyl Ethanoate + Alkanes (from C5 to C10)