Mixture of Isopropyl Alcohol + Carbonic acid, dimethyl ester

Datasets

1. Mole fraction (6)
2. Excess molar enthalpy (molar enthalpy (2)
3. T_boil - Boiling temperature at pressure P, K (6)

Mole fraction of Isopropyl Alcohol (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Isopropyl Alcohol (1) - Liquid	Mole fraction of Isopropyl Alcohol (1) - Gas
0.0246	0.0939
0.0630	0.1646
0.0780	0.1950
0.1226	0.2611
0.1582	0.3118
0.2217	0.3882
0.3041	0.4597
0.3368	0.4844
0.3553	0.4883
0.3839	0.5103
0.4136	0.5299
0.4483	0.5459
0.4782	0.5562
0.5102	0.5721
0.5419	0.5877
0.5789	0.6051
0.6086	0.6235
0.6382	0.6422
0.6854	0.6622
0.7177	0.6813
0.7507	0.7084
0.7829	0.7256
0.8117	0.7458
0.8277	0.7613
0.8478	0.7826
0.8696	0.8002
0.8908	0.8223
0.9111	0.8498
0.9352	0.8774
0.9585	0.9157
0.9769	0.9556
0.9791	0.9596

Azeotropic composition: mole fraction of Isopropyl Alcohol (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of Isopropyl Alcohol (1) - Liquid
40.00	0.5510
53.33	0.5810
66.66	0.6040
79.99	0.6230
93.32	0.6400

Azeotropic composition: mole fraction of Isopropyl Alcohol (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Isopropyl Alcohol (1) - Liquid
328.46	0.5510
335.37	0.5810
340.97	0.6040
345.71	0.6230
349.82	0.6400

Mole fraction of Isopropyl Alcohol (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Isopropyl Alcohol (1) - Liquid	Mole fraction of Isopropyl Alcohol (1) - Gas
0.0246	0.0939
0.0630	0.1646
0.0780	0.1950
0.1226	0.2611
0.1582	0.3118
0.2217	0.3882
0.3041	0.4597
0.3368	0.4844
0.3553	0.4883
0.3839	0.5103
0.4136	0.5299
0.4483	0.5459
0.4782	0.5562
0.5102	0.5721
0.5419	0.5877
0.5789	0.6051
0.6086	0.6235
0.6382	0.6422
0.6854	0.6622
0.7177	0.6813
0.7507	0.7084
0.7829	0.7256
0.8117	0.7458
0.8277	0.7613
0.8478	0.7826
0.8696	0.8002
0.8908	0.8223
0.9111	0.8498
0.9352	0.8774
0.9585	0.9157
0.9769	0.9556
0.9791	0.9596

Azeotropic composition: mole fraction of Isopropyl Alcohol (1) [ref]

Pressure, kPa - Liquid	Azeotropic composition: mole fraction of Isopropyl Alcohol (1) - Liquid
40.00	0.5510
53.33	0.5810
66.66	0.6040
79.99	0.6230
93.32	0.6400

Azeotropic composition: mole fraction of Isopropyl Alcohol (1) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of Isopropyl Alcohol (1) - Liquid
328.46	0.5510
335.37	0.5810
340.97	0.6040
345.71	0.6230
349.82	0.6400

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
298.15	1000.00	0.0500	0.5027
298.15	1000.00	0.1000	0.9288
298.15	1000.00	0.1500	1.2671
298.15	1000.00	0.2000	1.5458
298.15	1000.00	0.2500	1.7612
298.15	1000.00	0.3000	1.9244
298.15	1000.00	0.3500	2.0495
298.15	1000.00	0.4000	2.1325
298.15	1000.00	0.4500	2.1806
298.15	1000.00	0.5000	2.2026
298.15	1000.00	0.5500	2.1719
298.15	1000.00	0.6000	2.1122
298.15	1000.00	0.6500	2.0105
298.15	1000.00	0.7000	1.8657
298.15	1000.00	0.7500	1.6788
298.15	1000.00	0.8000	1.4332
298.15	1000.00	0.9500	0.4470
313.15	100.00	0.0483	0.4672
313.15	100.00	0.0998	0.9317
313.15	100.00	0.1507	1.3164
313.15	100.00	0.2011	1.6235
313.15	100.00	0.2509	1.8713
313.15	100.00	0.3002	2.0603
313.15	100.00	0.3489	2.2077
313.15	100.00	0.4005	2.3159
313.15	100.00	0.4515	2.376
313.15	100.00	0.4986	2.3925
313.15	100.00	0.5485	2.3644
313.15	100.00	0.6011	2.3022
313.15	100.00	0.6498	2.1941
313.15	100.00	0.7012	2.0449
313.15	100.00	0.7488	1.8489
313.15	100.00	0.8486	1.3127
313.15	100.00	0.9007	0.9352
313.15	100.00	0.9492	0.4835
313.15	1000.00	0.0483	0.4635
313.15	1000.00	0.0998	0.9334
313.15	1000.00	0.1507	1.3122
313.15	1000.00	0.2010	1.6196
313.15	1000.00	0.2508	1.868
313.15	1000.00	0.3000	2.0633
313.15	1000.00	0.3487	2.2105
313.15	1000.00	0.4003	2.3154
313.15	1000.00	0.4513	2.3606
313.15	1000.00	0.4984	2.3759
313.15	1000.00	0.5516	2.3522
313.15	1000.00	0.6009	2.2911
313.15	1000.00	0.6497	2.1846
313.15	1000.00	0.7011	2.0333
313.15	1000.00	0.7487	1.8431
313.15	1000.00	0.8486	1.301
313.15	1000.00	0.9007	0.9243
313.15	1000.00	0.9491	0.4909
313.15	10000.00	0.0517	0.4582
313.15	10000.00	0.0992	0.8869
313.15	10000.00	0.1499	1.2679
313.15	10000.00	0.2000	1.5765
313.15	10000.00	0.2497	1.822
313.15	10000.00	0.2988	2.0139
313.15	10000.00	0.3508	2.1659
313.15	10000.00	0.3989	2.2622
313.15	10000.00	0.4499	2.325
313.15	10000.00	0.5003	2.342
313.15	10000.00	0.5501	2.3168
313.15	10000.00	0.5995	2.2562
313.15	10000.00	0.6515	2.147
313.15	10000.00	0.6998	2.0083
313.15	10000.00	0.7507	1.8096
313.15	10000.00	0.8011	1.56
313.15	10000.00	0.8509	1.2777
313.15	10000.00	0.9001	0.9323
313.15	10000.00	0.9488	0.5267
328.15	1000.00	0.0500	0.5412
328.15	1000.00	0.1000	0.9787
328.15	1000.00	0.1500	1.372
328.15	1000.00	0.2000	1.6955
328.15	1000.00	0.2500	1.9556
328.15	1000.00	0.3000	2.1573
328.15	1000.00	0.3500	2.3251
328.15	1000.00	0.4000	2.4358
328.15	1000.00	0.4500	2.4945
328.15	1000.00	0.5000	2.5246
328.15	1000.00	0.5500	2.5069
328.15	1000.00	0.6000	2.4481
328.15	1000.00	0.6500	2.3257
328.15	1000.00	0.7000	2.1454
328.15	1000.00	0.7500	1.9575
328.15	1000.00	0.8000	1.6879
328.15	1000.00	0.8500	1.3625
328.15	1000.00	0.9000	0.9621
328.15	1000.00	0.9500	0.4865

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Carbonic acid, dimethyl ester (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
298.15	1000.00	0.0500	0.5027
298.15	1000.00	0.1000	0.9288
298.15	1000.00	0.1500	1.2671
298.15	1000.00	0.2000	1.5458
298.15	1000.00	0.2500	1.7612
298.15	1000.00	0.3000	1.9244
298.15	1000.00	0.3500	2.0495
298.15	1000.00	0.4000	2.1325
298.15	1000.00	0.4500	2.1806
298.15	1000.00	0.5000	2.2026
298.15	1000.00	0.5500	2.1719
298.15	1000.00	0.6000	2.1122
298.15	1000.00	0.6500	2.0105
298.15	1000.00	0.7000	1.8657
298.15	1000.00	0.7500	1.6788
298.15	1000.00	0.8000	1.4332
298.15	1000.00	0.9500	0.4470
313.15	100.00	0.0483	0.4672
313.15	100.00	0.0998	0.9317
313.15	100.00	0.1507	1.3164
313.15	100.00	0.2011	1.6235
313.15	100.00	0.2509	1.8713
313.15	100.00	0.3002	2.0603
313.15	100.00	0.3489	2.2077
313.15	100.00	0.4005	2.3159
313.15	100.00	0.4515	2.376
313.15	100.00	0.4986	2.3925
313.15	100.00	0.5485	2.3644
313.15	100.00	0.6011	2.3022
313.15	100.00	0.6498	2.1941
313.15	100.00	0.7012	2.0449
313.15	100.00	0.7488	1.8489
313.15	100.00	0.8486	1.3127
313.15	100.00	0.9007	0.9352
313.15	100.00	0.9492	0.4835
313.15	1000.00	0.0483	0.4635
313.15	1000.00	0.0998	0.9334
313.15	1000.00	0.1507	1.3122
313.15	1000.00	0.2010	1.6196
313.15	1000.00	0.2508	1.868
313.15	1000.00	0.3000	2.0633
313.15	1000.00	0.3487	2.2105
313.15	1000.00	0.4003	2.3154
313.15	1000.00	0.4513	2.3606
313.15	1000.00	0.4984	2.3759
313.15	1000.00	0.5516	2.3522
313.15	1000.00	0.6009	2.2911
313.15	1000.00	0.6497	2.1846
313.15	1000.00	0.7011	2.0333
313.15	1000.00	0.7487	1.8431
313.15	1000.00	0.8486	1.301
313.15	1000.00	0.9007	0.9243
313.15	1000.00	0.9491	0.4909
313.15	10000.00	0.0517	0.4582
313.15	10000.00	0.0992	0.8869
313.15	10000.00	0.1499	1.2679
313.15	10000.00	0.2000	1.5765
313.15	10000.00	0.2497	1.822
313.15	10000.00	0.2988	2.0139
313.15	10000.00	0.3508	2.1659
313.15	10000.00	0.3989	2.2622
313.15	10000.00	0.4499	2.325
313.15	10000.00	0.5003	2.342
313.15	10000.00	0.5501	2.3168
313.15	10000.00	0.5995	2.2562
313.15	10000.00	0.6515	2.147
313.15	10000.00	0.6998	2.0083
313.15	10000.00	0.7507	1.8096
313.15	10000.00	0.8011	1.56
313.15	10000.00	0.8509	1.2777
313.15	10000.00	0.9001	0.9323
313.15	10000.00	0.9488	0.5267
328.15	1000.00	0.0500	0.5412
328.15	1000.00	0.1000	0.9787
328.15	1000.00	0.1500	1.372
328.15	1000.00	0.2000	1.6955
328.15	1000.00	0.2500	1.9556
328.15	1000.00	0.3000	2.1573
328.15	1000.00	0.3500	2.3251
328.15	1000.00	0.4000	2.4358
328.15	1000.00	0.4500	2.4945
328.15	1000.00	0.5000	2.5246
328.15	1000.00	0.5500	2.5069
328.15	1000.00	0.6000	2.4481
328.15	1000.00	0.6500	2.3257
328.15	1000.00	0.7000	2.1454
328.15	1000.00	0.7500	1.9575
328.15	1000.00	0.8000	1.6879
328.15	1000.00	0.8500	1.3625
328.15	1000.00	0.9000	0.9621
328.15	1000.00	0.9500	0.4865

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Isopropyl Alcohol (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0246	361.68
0.0630	360.09
0.0780	359.69
0.1226	358.28
0.1582	357.07
0.2217	355.48
0.3041	354.18
0.3368	353.77
0.3553	353.67
0.3839	353.29
0.4136	353.01
0.4483	352.82
0.4782	352.72
0.5102	352.57
0.5419	352.46
0.5789	352.35
0.6086	352.28
0.6382	352.27
0.6854	352.25
0.7177	352.29
0.7507	352.36
0.7829	352.50
0.8117	352.66
0.8277	352.75
0.8478	352.93
0.8696	353.15
0.8908	353.36
0.9111	353.66
0.9352	353.96
0.9585	354.46
0.9769	354.97
0.9791	355.05

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Isopropyl Alcohol (1) - Liquid	Boiling temperature at pressure P, K - Liquid
40.00	0.0000	336.68
40.00	0.1020	332.55
40.00	0.1990	330.48
40.00	0.2980	329.33
40.00	0.3480	328.99
40.00	0.3970	328.76
40.00	0.4450	328.59
40.00	0.4940	328.50
40.00	0.5490	328.46
40.00	0.5990	328.50
40.00	0.6450	328.57
40.00	0.6940	328.73
40.00	0.7440	328.99
40.00	0.7980	329.41
40.00	0.8470	329.94
40.00	0.8940	330.68
40.00	1.0000	333.92
53.33	0.0000	344.38
53.33	0.1020	340.08
53.33	0.1990	337.83
53.33	0.2980	336.52
53.33	0.3480	336.09
53.33	0.3970	335.82
53.33	0.4450	335.60
53.33	0.4940	335.47
53.33	0.5490	335.37
53.33	0.5990	335.38
53.33	0.6450	335.42
53.33	0.6940	335.56
53.33	0.7440	335.78
53.33	0.7980	336.16
53.33	0.8470	336.63
53.33	0.8940	337.32
53.33	1.0000	340.21
66.66	0.0000	350.66
66.66	0.1020	346.23
66.66	0.1990	343.81
66.66	0.2980	342.38
66.66	0.3480	341.91
66.66	0.3970	341.56
66.66	0.4450	341.31
66.66	0.4940	341.14
66.66	0.5490	341.03
66.66	0.5990	340.97
66.66	0.6450	340.98
66.66	0.6940	341.10
66.66	0.7440	341.29
66.66	0.7980	341.62
66.66	0.8470	342.06
66.66	0.8940	342.66
66.66	1.0000	345.29
79.99	0.0000	356.01
79.99	0.1020	351.47
79.99	0.1990	348.91
79.99	0.2980	347.36
79.99	0.3480	346.81
79.99	0.3970	346.43
79.99	0.4450	346.15
79.99	0.4940	345.94
79.99	0.5490	345.79
79.99	0.5990	345.71
79.99	0.6450	345.72
79.99	0.6940	345.79
79.99	0.7440	345.95
79.99	0.7980	346.24
79.99	0.8470	346.64
79.99	0.8940	347.20
79.99	1.0000	349.60
93.32	0.0000	360.68
93.32	0.1020	356.07
93.32	0.1990	353.41
93.32	0.2980	351.72
93.32	0.3480	351.13
93.32	0.3970	350.69
93.32	0.4450	350.39
93.32	0.4940	350.13
93.32	0.5490	349.94
93.32	0.5990	349.84
93.32	0.6450	349.81
93.32	0.6940	349.87
93.32	0.7440	350.00
93.32	0.7980	350.26
93.32	0.8470	350.62
93.32	0.8940	351.14
93.32	1.0000	353.34

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 95.8 (Liquid)

Mole fraction of Isopropyl Alcohol (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	361.25
0.1805	354.25
0.3050	352.35
0.3970	351.55
0.4670	351.25
0.5220	350.95
0.6680	350.85
0.7511	351.05
0.8580	351.75
0.9240	352.45
1.0000	354.05

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Mole fraction of Isopropyl Alcohol (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0246	361.68
0.0630	360.09
0.0780	359.69
0.1226	358.28
0.1582	357.07
0.2217	355.48
0.3041	354.18
0.3368	353.77
0.3553	353.67
0.3839	353.29
0.4136	353.01
0.4483	352.82
0.4782	352.72
0.5102	352.57
0.5419	352.46
0.5789	352.35
0.6086	352.28
0.6382	352.27
0.6854	352.25
0.7177	352.29
0.7507	352.36
0.7829	352.50
0.8117	352.66
0.8277	352.75
0.8478	352.93
0.8696	353.15
0.8908	353.36
0.9111	353.66
0.9352	353.96
0.9585	354.46
0.9769	354.97
0.9791	355.05

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Isopropyl Alcohol (1) - Liquid	Boiling temperature at pressure P, K - Liquid
40.00	0.0000	336.68
40.00	0.1020	332.55
40.00	0.1990	330.48
40.00	0.2980	329.33
40.00	0.3480	328.99
40.00	0.3970	328.76
40.00	0.4450	328.59
40.00	0.4940	328.50
40.00	0.5490	328.46
40.00	0.5990	328.50
40.00	0.6450	328.57
40.00	0.6940	328.73
40.00	0.7440	328.99
40.00	0.7980	329.41
40.00	0.8470	329.94
40.00	0.8940	330.68
40.00	1.0000	333.92
53.33	0.0000	344.38
53.33	0.1020	340.08
53.33	0.1990	337.83
53.33	0.2980	336.52
53.33	0.3480	336.09
53.33	0.3970	335.82
53.33	0.4450	335.60
53.33	0.4940	335.47
53.33	0.5490	335.37
53.33	0.5990	335.38
53.33	0.6450	335.42
53.33	0.6940	335.56
53.33	0.7440	335.78
53.33	0.7980	336.16
53.33	0.8470	336.63
53.33	0.8940	337.32
53.33	1.0000	340.21
66.66	0.0000	350.66
66.66	0.1020	346.23
66.66	0.1990	343.81
66.66	0.2980	342.38
66.66	0.3480	341.91
66.66	0.3970	341.56
66.66	0.4450	341.31
66.66	0.4940	341.14
66.66	0.5490	341.03
66.66	0.5990	340.97
66.66	0.6450	340.98
66.66	0.6940	341.10
66.66	0.7440	341.29
66.66	0.7980	341.62
66.66	0.8470	342.06
66.66	0.8940	342.66
66.66	1.0000	345.29
79.99	0.0000	356.01
79.99	0.1020	351.47
79.99	0.1990	348.91
79.99	0.2980	347.36
79.99	0.3480	346.81
79.99	0.3970	346.43
79.99	0.4450	346.15
79.99	0.4940	345.94
79.99	0.5490	345.79
79.99	0.5990	345.71
79.99	0.6450	345.72
79.99	0.6940	345.79
79.99	0.7440	345.95
79.99	0.7980	346.24
79.99	0.8470	346.64
79.99	0.8940	347.20
79.99	1.0000	349.60
93.32	0.0000	360.68
93.32	0.1020	356.07
93.32	0.1990	353.41
93.32	0.2980	351.72
93.32	0.3480	351.13
93.32	0.3970	350.69
93.32	0.4450	350.39
93.32	0.4940	350.13
93.32	0.5490	349.94
93.32	0.5990	349.84
93.32	0.6450	349.81
93.32	0.6940	349.87
93.32	0.7440	350.00
93.32	0.7980	350.26
93.32	0.8470	350.62
93.32	0.8940	351.14
93.32	1.0000	353.34

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 95.8 (Liquid)

Mole fraction of Isopropyl Alcohol (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	361.25
0.1805	354.25
0.3050	352.35
0.3970	351.55
0.4670	351.25
0.5220	350.95
0.6680	350.85
0.7511	351.05
0.8580	351.75
0.9240	352.45
1.0000	354.05

Sources

• VLE of the binary systems (dimethyl carbonate with 2-propanol or 2-butanol) and (diethyl carbonate with methylcyclohexane) at 101.3 kPa
• Ebulliometric determination and prediction of (vapor + liquid) equilibria for binary and ternary mixtures containing alcohols (C1 C4) and dimethyl carbonate
• Bubble Temperatures of the Binary Mixtures of Dimethylcarbonate with Some Alcohols at 95.8 kPa
• Excess Molar Enthalpies of Dimethyl Carbonate and (Methanol, Ethanol, 1-Propanol, and 2-Propanol) at T = (298.15, 313.15, and 328.15) K and p = (0.1, 1.0, and 10.0) MPa