Mixture of Formamide, N,N-dimethyl- + Butane, 1-chloro-

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. P_vap - Vapor or sublimation pressure, kPa (2)
4. ρ_l - Mass density, kg/m3 (2)

Mole fraction of Formamide, N,N-dimethyl- (1) [ref]

Fixed		Measured
Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Temperature, K - Gas	Mole fraction of Formamide, N,N-dimethyl- (1) - Gas
0.1591	323.15	0.0233
0.1596	313.15	0.0239
0.2601	323.15	0.0329
0.2718	313.15	0.0331
0.3669	323.15	0.0415
0.3792	313.15	0.0412
0.4758	323.15	0.0527
0.4827	313.15	0.0540
0.5544	323.15	0.0621
0.5825	313.15	0.0627
0.6522	323.15	0.0661
0.6526	313.15	0.0671
0.6951	323.15	0.0844
0.7111	313.15	0.0850
0.7550	313.15	0.0886
0.7568	323.15	0.0899
0.8224	323.15	0.1139

Mole fraction of Formamide, N,N-dimethyl- (1) [ref]

Fixed		Measured
Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Temperature, K - Gas	Mole fraction of Formamide, N,N-dimethyl- (1) - Gas
0.1591	323.15	0.0233
0.1596	313.15	0.0239
0.2601	323.15	0.0329
0.2718	313.15	0.0331
0.3669	323.15	0.0415
0.3792	313.15	0.0412
0.4758	323.15	0.0527
0.4827	313.15	0.0540
0.5544	323.15	0.0621
0.5825	313.15	0.0627
0.6522	323.15	0.0661
0.6526	313.15	0.0671
0.6951	323.15	0.0844
0.7111	313.15	0.0850
0.7550	313.15	0.0886
0.7568	323.15	0.0899
0.8224	323.15	0.1139

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
298.15	0.0560	0.1230
298.15	0.1060	0.2390
298.15	0.2070	0.4040
298.15	0.3080	0.5090
298.15	0.4070	0.5640
298.15	0.5070	0.5710
298.15	0.6060	0.5400
298.15	0.7050	0.4670
298.15	0.8030	0.3520
298.15	0.9010	0.1920
298.15	0.9500	0.0980
308.15	0.0580	0.1170
308.15	0.1080	0.2310
308.15	0.2070	0.4000
308.15	0.3060	0.5080
308.15	0.4040	0.5680
308.15	0.5030	0.5800
308.15	0.6020	0.5520
308.15	0.7010	0.4810
308.15	0.7990	0.3640
308.15	0.8980	0.2010
308.15	0.9470	0.1030
308.15	0.9670	0.0610

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
298.15	0.0560	0.1230
298.15	0.1060	0.2390
298.15	0.2070	0.4040
298.15	0.3080	0.5090
298.15	0.4070	0.5640
298.15	0.5070	0.5710
298.15	0.6060	0.5400
298.15	0.7050	0.4670
298.15	0.8030	0.3520
298.15	0.9010	0.1920
298.15	0.9500	0.0980
308.15	0.0580	0.1170
308.15	0.1080	0.2310
308.15	0.2070	0.4000
308.15	0.3060	0.5080
308.15	0.4040	0.5680
308.15	0.5030	0.5800
308.15	0.6020	0.5520
308.15	0.7010	0.4810
308.15	0.7990	0.3640
308.15	0.8980	0.2010
308.15	0.9470	0.1030
308.15	0.9670	0.0610

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.1591	323.15	33.95
0.1596	313.15	22.80
0.2601	323.15	31.23
0.2718	313.15	21.06
0.3669	323.15	28.72
0.3792	313.15	19.35
0.4758	323.15	26.05
0.4827	313.15	17.67
0.5544	323.15	23.83
0.5825	313.15	15.87
0.6522	323.15	21.19
0.6526	313.15	14.42
0.6951	323.15	19.71
0.7111	313.15	13.19
0.7550	313.15	11.85
0.7568	323.15	17.60
0.8224	323.15	14.67
0.8647	313.15	7.93
0.9220	323.15	8.65
0.9223	313.15	5.37

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.1591	323.15	33.95
0.1596	313.15	22.80
0.2601	323.15	31.23
0.2718	313.15	21.06
0.3669	323.15	28.72
0.3792	313.15	19.35
0.4758	323.15	26.05
0.4827	313.15	17.67
0.5544	323.15	23.83
0.5825	313.15	15.87
0.6522	323.15	21.19
0.6526	313.15	14.42
0.6951	323.15	19.71
0.7111	313.15	13.19
0.7550	313.15	11.85
0.7568	323.15	17.60
0.8224	323.15	14.67
0.8647	313.15	7.93
0.9220	323.15	8.65
0.9223	313.15	5.37

Mass density, kg/m3 [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Fixed		Measured
Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Pressure, kPa - Liquid	Mass density, kg/m3 - Liquid
0.0998	100.00	885.5
0.0998	2000.00	887.4
0.0998	4000.00	889.3
0.0998	6000.00	891.2
0.0998	8000.00	893.1
0.0998	10000.00	895.1
0.0998	12000.00	896.9
0.0998	14000.00	898.6
0.0998	16000.00	900.4
0.0998	18000.00	902.1
0.0998	20000.00	903.8
0.1981	100.00	890.7
0.1981	2000.00	892.5
0.1981	4000.00	894.4
0.1981	6000.00	896.3
0.1981	8000.00	898.1
0.1981	10000.00	900.0
0.1981	12000.00	901.6
0.1981	14000.00	903.4
0.1981	16000.00	905.1
0.1981	18000.00	906.8
0.1981	20000.00	908.7
0.2988	100.00	896.3
0.2988	2000.00	898.0
0.2988	4000.00	899.8
0.2988	6000.00	901.6
0.2988	8000.00	903.3
0.2988	10000.00	905.1
0.2988	12000.00	906.8
0.2988	14000.00	908.4
0.2988	16000.00	910.1
0.2988	18000.00	911.7
0.2988	20000.00	913.1
0.4019	100.00	902.3
0.4019	2000.00	903.9
0.4019	4000.00	905.7
0.4019	6000.00	907.3
0.4019	8000.00	908.9
0.4019	10000.00	910.7
0.4019	12000.00	912.2
0.4019	14000.00	913.8
0.4019	16000.00	915.3
0.4019	18000.00	916.7
0.4019	20000.00	918.3
0.5010	100.00	908.6
0.5010	2000.00	910.1
0.5010	4000.00	911.7
0.5010	6000.00	913.3
0.5010	8000.00	914.9
0.5010	10000.00	916.6
0.5010	11900.00	918.0
0.5010	14000.00	919.5
0.5010	16000.00	921.0
0.5010	18000.00	922.4
0.5010	20000.00	924.0
0.6087	100.00	915.5
0.6087	2000.00	917.0
0.6087	4000.00	918.5
0.6087	6000.00	920.0
0.6087	8000.00	921.5
0.6087	10000.00	923.0
0.6087	12000.00	924.4
0.6087	14000.00	925.9
0.6087	16000.00	927.21
0.6087	18100.00	928.6
0.6087	20000.00	930.2
0.7008	100.00	921.8
0.7008	2000.00	923.1
0.7008	4000.00	924.6
0.7008	6000.00	926.0
0.7008	7900.00	927.5
0.7008	10000.00	928.8
0.7008	12000.00	930.3
0.7008	14000.00	931.7
0.7008	16000.00	933.0
0.7008	18000.00	934.3
0.7008	20000.00	935.6
0.8163	100.00	930.2
0.8163	2000.00	931.5
0.8163	4000.00	932.8
0.8163	6000.00	934.2
0.8163	8000.00	935.4
0.8163	10000.00	936.8
0.8163	12000.00	938.1
0.8163	14000.00	939.3
0.8163	16000.00	940.6
0.8163	18000.00	941.8
0.8163	20000.00	943.3
0.9007	100.00	936.6
0.9007	2000.00	937.8
0.9007	4000.00	939.1
0.9007	6000.00	940.3
0.9007	8000.00	941.5
0.9007	10000.00	942.9
0.9007	12000.00	944.1
0.9007	14000.00	945.3
0.9007	16000.00	946.4
0.9007	18000.00	947.5
0.9007	20000.00	949.1

Mass density, kg/m3 [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Fixed		Measured
Mole fraction of Formamide, N,N-dimethyl- (1) - Liquid	Pressure, kPa - Liquid	Mass density, kg/m3 - Liquid
0.0998	100.00	885.5
0.0998	2000.00	887.4
0.0998	4000.00	889.3
0.0998	6000.00	891.2
0.0998	8000.00	893.1
0.0998	10000.00	895.1
0.0998	12000.00	896.9
0.0998	14000.00	898.6
0.0998	16000.00	900.4
0.0998	18000.00	902.1
0.0998	20000.00	903.8
0.1981	100.00	890.7
0.1981	2000.00	892.5
0.1981	4000.00	894.4
0.1981	6000.00	896.3
0.1981	8000.00	898.1
0.1981	10000.00	900.0
0.1981	12000.00	901.6
0.1981	14000.00	903.4
0.1981	16000.00	905.1
0.1981	18000.00	906.8
0.1981	20000.00	908.7
0.2988	100.00	896.3
0.2988	2000.00	898.0
0.2988	4000.00	899.8
0.2988	6000.00	901.6
0.2988	8000.00	903.3
0.2988	10000.00	905.1
0.2988	12000.00	906.8
0.2988	14000.00	908.4
0.2988	16000.00	910.1
0.2988	18000.00	911.7
0.2988	20000.00	913.1
0.4019	100.00	902.3
0.4019	2000.00	903.9
0.4019	4000.00	905.7
0.4019	6000.00	907.3
0.4019	8000.00	908.9
0.4019	10000.00	910.7
0.4019	12000.00	912.2
0.4019	14000.00	913.8
0.4019	16000.00	915.3
0.4019	18000.00	916.7
0.4019	20000.00	918.3
0.5010	100.00	908.6
0.5010	2000.00	910.1
0.5010	4000.00	911.7
0.5010	6000.00	913.3
0.5010	8000.00	914.9
0.5010	10000.00	916.6
0.5010	11900.00	918.0
0.5010	14000.00	919.5
0.5010	16000.00	921.0
0.5010	18000.00	922.4
0.5010	20000.00	924.0
0.6087	100.00	915.5
0.6087	2000.00	917.0
0.6087	4000.00	918.5
0.6087	6000.00	920.0
0.6087	8000.00	921.5
0.6087	10000.00	923.0
0.6087	12000.00	924.4
0.6087	14000.00	925.9
0.6087	16000.00	927.21
0.6087	18100.00	928.6
0.6087	20000.00	930.2
0.7008	100.00	921.8
0.7008	2000.00	923.1
0.7008	4000.00	924.6
0.7008	6000.00	926.0
0.7008	7900.00	927.5
0.7008	10000.00	928.8
0.7008	12000.00	930.3
0.7008	14000.00	931.7
0.7008	16000.00	933.0
0.7008	18000.00	934.3
0.7008	20000.00	935.6
0.8163	100.00	930.2
0.8163	2000.00	931.5
0.8163	4000.00	932.8
0.8163	6000.00	934.2
0.8163	8000.00	935.4
0.8163	10000.00	936.8
0.8163	12000.00	938.1
0.8163	14000.00	939.3
0.8163	16000.00	940.6
0.8163	18000.00	941.8
0.8163	20000.00	943.3
0.9007	100.00	936.6
0.9007	2000.00	937.8
0.9007	4000.00	939.1
0.9007	6000.00	940.3
0.9007	8000.00	941.5
0.9007	10000.00	942.9
0.9007	12000.00	944.1
0.9007	14000.00	945.3
0.9007	16000.00	946.4
0.9007	18000.00	947.5
0.9007	20000.00	949.1

Sources

• (Vapour + liquid) equilibria and excess molar enthalpies for binary mixtures containing N,N-dialkylamides and 1-chloroalkanes
• Densities and Isothermal Compressibilities at Pressures up to 20 MPa of the Systems N,N-Dimethylformamide or N,N-Dimethylacetamide + 1-Chloroalkane