Mixture of Cyclohexanone + Water

Datasets

1. Mass fraction (6)
2. Molar enthalpy (2)
3. Liquid-liquid equilibrium temperature, K (2)
4. Partial molar volume, m3/mol (2)

Mass fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
101.35	298.20	0.9115

Mass fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 2
298.20	101.35	0.0596

Mass fraction of Water (2) [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid mixture 1)
• Pressure, kPa = 101 (Liquid mixture 1)

Mass fraction of Water (2) - Liquid mixture 1
0.0594
0.9197

Mass fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 1
101.35	298.20	0.9115

Mass fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mass fraction of Water (2) - Liquid mixture 2
298.20	101.35	0.0596

Mass fraction of Water (2) [ref]

Operational conditions:

• Temperature, K = 298.2 (Liquid mixture 1)
• Pressure, kPa = 101 (Liquid mixture 1)

Mass fraction of Water (2) - Liquid mixture 1
0.0594
0.9197

Molar enthalpy of dilution, kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Fixed		Measured
Initial molality of solute, mol/kg - Liquid	Final molality of solute, mol/kg - Liquid	Molar enthalpy of dilution, kJ/mol - Liquid
0.1000	0.0492	-0.0819
0.1500	0.0737	-0.1208
0.1800	0.0883	-0.1476
0.2000	0.0980	-0.1607
0.2200	0.1077	-0.1808
0.2500	0.1222	-0.2043
0.2800	0.1366	-0.2342
0.3000	0.1462	-0.2500
0.3200	0.1558	-0.2683
0.3500	0.1702	-0.3009
0.3800	0.1845	-0.3302
0.4000	0.1940	-0.3467
0.4200	0.2035	-0.3607
0.4500	0.2178	-0.3886
0.5000	0.2414	-0.4430

Molar enthalpy of dilution, kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Fixed		Measured
Initial molality of solute, mol/kg - Liquid	Final molality of solute, mol/kg - Liquid	Molar enthalpy of dilution, kJ/mol - Liquid
0.1000	0.0492	-0.0819
0.1500	0.0737	-0.1208
0.1800	0.0883	-0.1476
0.2000	0.0980	-0.1607
0.2200	0.1077	-0.1808
0.2500	0.1222	-0.2043
0.2800	0.1366	-0.2342
0.3000	0.1462	-0.2500
0.3200	0.1558	-0.2683
0.3500	0.1702	-0.3009
0.3800	0.1845	-0.3302
0.4000	0.1940	-0.3467
0.4200	0.2035	-0.3607
0.4500	0.2178	-0.3886
0.5000	0.2414	-0.4430

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mass fraction of Water (2) - Liquid mixture 1	Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.0600	303.20
0.0660	313.20
0.0700	323.20
0.0850	343.20

Liquid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Mass fraction of Water (2) - Liquid mixture 1	Liquid-liquid equilibrium temperature, K - Liquid mixture 1
0.0600	303.20
0.0660	313.20
0.0700	323.20
0.0850	343.20

Partial molar volume, m3/mol of Cyclohexanone (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Partial molar volume, m3/mol of Cyclohexanone (1) - Liquid
298.17	15040.00	0.0001
298.17	30020.00	0.0001
318.14	15050.00	0.0001
318.14	30030.00	0.0001
338.18	15060.00	0.0001
338.18	30050.00	0.0001
358.14	15040.00	0.0001
358.14	30040.00	0.0001
373.17	15040.00	0.0001
373.17	30040.00	0.0001
398.17	1970.00	0.0001
398.17	15040.00	0.0001
398.17	30030.00	0.0001
423.17	15040.00	0.0001
423.18	1970.00	0.0001
423.18	30040.00	0.0001
448.15	1980.00	0.0001
448.15	15050.00	0.0001
448.15	29980.00	0.0001
473.16	15050.00	0.0001
473.17	1980.00	0.0001
473.17	29990.00	0.0001
498.14	30040.00	0.0001
498.15	2940.00	0.0001
498.15	15060.00	0.0001
523.14	5120.00	0.0001
523.16	15030.00	0.0001
523.16	30150.00	0.0001
548.18	7160.00	0.0002
548.18	15040.00	0.0002
548.25	30400.00	0.0001
573.17	15190.00	0.0002
573.17	30160.00	0.0002
573.18	10100.00	0.0002

Partial molar volume, m3/mol of Cyclohexanone (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Partial molar volume, m3/mol of Cyclohexanone (1) - Liquid
298.17	15040.00	0.0001
298.17	30020.00	0.0001
318.14	15050.00	0.0001
318.14	30030.00	0.0001
338.18	15060.00	0.0001
338.18	30050.00	0.0001
358.14	15040.00	0.0001
358.14	30040.00	0.0001
373.17	15040.00	0.0001
373.17	30040.00	0.0001
398.17	1970.00	0.0001
398.17	15040.00	0.0001
398.17	30030.00	0.0001
423.17	15040.00	0.0001
423.18	1970.00	0.0001
423.18	30040.00	0.0001
448.15	1980.00	0.0001
448.15	15050.00	0.0001
448.15	29980.00	0.0001
473.16	15050.00	0.0001
473.17	1980.00	0.0001
473.17	29990.00	0.0001
498.14	30040.00	0.0001
498.15	2940.00	0.0001
498.15	15060.00	0.0001
523.14	5120.00	0.0001
523.16	15030.00	0.0001
523.16	30150.00	0.0001
548.18	7160.00	0.0002
548.18	15040.00	0.0002
548.25	30400.00	0.0001
573.17	15190.00	0.0002
573.17	30160.00	0.0002
573.18	10100.00	0.0002

Sources

• Phase equilibria for ternary liquid systems of (water + levulinic acid + cyclic solvent) at T = 298.2 K: Thermodynamic modeling
• Partial molar volumes of organic solutes in water. XXIII. Cyclic ketones at T = (298 to 573) K and pressures up to 30 MPa
• Tie-line data for the aqueous solutions of phenol with organic solvents at T = 298.2 K
• Enthalpic interactions between some amino acids and cyclohexanone in aqueous solutions at 298.15K
• Solid-Liquid Equilibrium and Activity Coefficients for Caprolactam + 1-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide and Cyclohexanone Oxime + 1-Hexyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide