Mixture of Methyl formate + Methyl valerate

Name: Methyl formate
InChI: InChI=1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI Key: TZIHFWKZFHZASV-UHFFFAOYSA-N
Formula: C2H4O2
SMILES: COC=O
Mol. Weight (g/mol): 60.05
CAS: 107-31-3

Name: Methyl valerate
InChI: InChI=1S/C6H12O2/c1-3-4-5-6(7)8-2/h3-5H2,1-2H3
InChI Key: HNBDRPTVWVGKBR-UHFFFAOYSA-N
Formula: C6H12O2
SMILES: CCCCC(=O)OC
Mol. Weight (g/mol): 116.16
CAS: 624-24-8

Cheméo is a service of Céondo GmbH, since 2007, we provide simulation, modelling and software development services for the industry. Do not hesitate to contact us for your projects.

Datasets

Excess molar enthalpy (molar enthalpy (2)
ρ_l - Mass density, kg/m3 (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Pressure, kPa = 100 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Methyl valerate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0272	0.0590
0.0583	0.1120
0.0932	0.1710
0.1292	0.2300
0.1720	0.2910
0.2104	0.3400
0.2533	0.3790
0.2946	0.4010
0.3096	0.4130
0.3486	0.4220
0.3982	0.4310
0.4522	0.4310
0.5232	0.4090
0.6056	0.3660
0.6943	0.3040
0.7968	0.2190
0.8656	0.1450
0.9300	0.0840

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Pressure, kPa = 100 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Methyl valerate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0272	0.0590
0.0583	0.1120
0.0932	0.1710
0.1292	0.2300
0.1720	0.2910
0.2104	0.3400
0.2533	0.3790
0.2946	0.4010
0.3096	0.4130
0.3486	0.4220
0.3982	0.4310
0.4522	0.4310
0.5232	0.4090
0.6056	0.3660
0.6943	0.3040
0.7968	0.2190
0.8656	0.1450
0.9300	0.0840

Mass density, kg/m3 [ref]

Operational conditions:

Pressure, kPa = 100 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Methyl valerate (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	966.28
0.0555	956.19
0.1040	948.47
0.1464	942.39
0.2093	934.27
0.2537	929.22
0.3106	923.46
0.3493	919.84
0.4011	915.46
0.4572	911.17
0.5000	908.17
0.5539	904.69
0.6081	901.55
0.6522	899.15
0.7258	895.5
0.7765	893.24
0.8360	890.8
0.9031	888.23
1.0000	884.78

Mass density, kg/m3 [ref]

Operational conditions:

Pressure, kPa = 100 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Methyl valerate (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	966.28
0.0555	956.19
0.1040	948.47
0.1464	942.39
0.2093	934.27
0.2537	929.22
0.3106	923.46
0.3493	919.84
0.4011	915.46
0.4572	911.17
0.5000	908.17
0.5539	904.69
0.6081	901.55
0.6522	899.15
0.7258	895.5
0.7765	893.24
0.8360	890.8
0.9031	888.23
1.0000	884.78

Sources

Mixing thermodynamic properties of ester-containing solutions: A study on the ternary (methyl alkanoate (pentanoate and methanoate) + methanol) and the corresponding binaries. New contributions to the (ester + ester) interactions