Mixture of Methyl formate + Methyl valerate + Methyl Alcohol

Excel

Methyl formate

Name
Methyl formate
InChI
InChI=1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI Key
TZIHFWKZFHZASV-UHFFFAOYSA-N
Formula
C2H4O2
SMILES
COC=O
Mol. Weight (g/mol)
60.05
CAS
107-31-3

Methyl valerate

Name
Methyl valerate
InChI
InChI=1S/C6H12O2/c1-3-4-5-6(7)8-2/h3-5H2,1-2H3
InChI Key
HNBDRPTVWVGKBR-UHFFFAOYSA-N
Formula
C6H12O2
SMILES
CCCCC(=O)OC
Mol. Weight (g/mol)
116.16
CAS
624-24-8

Methyl Alcohol

Name
Methyl Alcohol
InChI
InChI=1S/CH4O/c1-2/h2H,1H3
InChI Key
OKKJLVBELUTLKV-UHFFFAOYSA-N
Formula
CH4O
SMILES
CO
Mol. Weight (g/mol)
32.04
CAS
67-56-1
Cheméo is a service of Céondo GmbH, since 2007, we provide simulation, modelling and software development services for the industry. Do not hesitate to contact us for your projects.

Datasets

  1. Molar enthalpy of mixing with solvent, kJ/mol (2)
  2. ρl - Mass density, kg/m3 (2)

Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) [ref]

Operational conditions:

Fixed Measured
Mole fraction of Methyl valerate (2) - Liquid Mole fraction of Methyl formate (1) - Liquid Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) - Liquid
0.0335 0.8498 0.6470
0.0343 0.8463 0.6950
0.0377 0.8312 0.7460
0.0416 0.8135 0.8060
0.0469 0.7900 0.8680
0.0532 0.7618 0.9280
0.0606 0.7286 0.9830
0.0693 0.6898 1.033
0.0799 0.6421 1.063
0.0925 0.5855 1.069
0.1068 0.5214 1.046
0.1232 0.4480 0.9780
0.1387 0.3785 0.8760
0.1555 0.3032 0.7410
0.1730 0.2249 0.5830
0.1900 0.1488 0.3760
0.2056 0.0788 0.1720
0.0804 0.7786 0.7360
0.0881 0.7574 0.7810
0.0977 0.7310 0.8260
0.1098 0.6977 0.8710
0.1249 0.6561 0.9050
0.1419 0.6092 0.9230
0.1602 0.5588 0.9260
0.1811 0.5012 0.9060
0.2042 0.4377 0.8580
0.2281 0.3719 0.7880
0.2507 0.3096 0.7020
0.2711 0.2533 0.5980
0.2968 0.1827 0.4480
0.3231 0.1102 0.2760
0.3461 0.0468 0.1210
0.0987 0.7864 0.6440
0.1091 0.7638 0.6870
0.1218 0.7363 0.7290
0.1363 0.7049 0.7680
0.1529 0.6690 0.8010
0.1720 0.6276 0.8250
0.1930 0.5821 0.8350
0.2163 0.5317 0.8270
0.2401 0.4802 0.8020
0.2644 0.4275 0.7620
0.2909 0.3702 0.7030
0.3214 0.3042 0.6120
0.3518 0.2383 0.4970
0.3828 0.1712 0.3610
0.4143 0.1030 0.2160
0.4412 0.0448 0.0870
0.1103 0.7725 0.6540
0.1216 0.7492 0.6910
0.1342 0.7232 0.7420
0.1538 0.6827 0.7840
0.1766 0.6357 0.8090
0.2012 0.5850 0.8230
0.2328 0.5198 0.8090
0.2691 0.4449 0.7570
0.3085 0.3637 0.6650
0.3509 0.2762 0.5360
0.3939 0.1875 0.3770
0.4331 0.1067 0.2130
0.4617 0.0477 0.0890
0.1668 0.7482 0.5530
0.1844 0.7216 0.5940
0.2077 0.6864 0.6330
0.2362 0.6434 0.6630
0.2689 0.5940 0.6810
0.3063 0.5375 0.6880
0.3523 0.4680 0.6710
0.4046 0.3891 0.6210
0.4580 0.3084 0.5380
0.5182 0.2175 0.4190
0.5693 0.1404 0.2970
0.6206 0.0629 0.1630
0.2334 0.7002 0.4650
0.2615 0.6641 0.4920
0.2953 0.6207 0.5110
0.3339 0.5711 0.5200
0.3808 0.5109 0.5140
0.4322 0.4449 0.4890
0.4889 0.3721 0.4440
0.5529 0.2898 0.3740
0.6205 0.2030 0.2770
0.6870 0.1176 0.1620
0.7469 0.0407 0.0570

Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) [ref]

Operational conditions:

Fixed Measured
Mole fraction of Methyl valerate (2) - Liquid Mole fraction of Methyl formate (1) - Liquid Molar enthalpy of mixing with solvent, kJ/mol of Methyl formate (1) - Liquid
0.0335 0.8498 0.6470
0.0343 0.8463 0.6950
0.0377 0.8312 0.7460
0.0416 0.8135 0.8060
0.0469 0.7900 0.8680
0.0532 0.7618 0.9280
0.0606 0.7286 0.9830
0.0693 0.6898 1.033
0.0799 0.6421 1.063
0.0925 0.5855 1.069
0.1068 0.5214 1.046
0.1232 0.4480 0.9780
0.1387 0.3785 0.8760
0.1555 0.3032 0.7410
0.1730 0.2249 0.5830
0.1900 0.1488 0.3760
0.2056 0.0788 0.1720
0.0804 0.7786 0.7360
0.0881 0.7574 0.7810
0.0977 0.7310 0.8260
0.1098 0.6977 0.8710
0.1249 0.6561 0.9050
0.1419 0.6092 0.9230
0.1602 0.5588 0.9260
0.1811 0.5012 0.9060
0.2042 0.4377 0.8580
0.2281 0.3719 0.7880
0.2507 0.3096 0.7020
0.2711 0.2533 0.5980
0.2968 0.1827 0.4480
0.3231 0.1102 0.2760
0.3461 0.0468 0.1210
0.0987 0.7864 0.6440
0.1091 0.7638 0.6870
0.1218 0.7363 0.7290
0.1363 0.7049 0.7680
0.1529 0.6690 0.8010
0.1720 0.6276 0.8250
0.1930 0.5821 0.8350
0.2163 0.5317 0.8270
0.2401 0.4802 0.8020
0.2644 0.4275 0.7620
0.2909 0.3702 0.7030
0.3214 0.3042 0.6120
0.3518 0.2383 0.4970
0.3828 0.1712 0.3610
0.4143 0.1030 0.2160
0.4412 0.0448 0.0870
0.1103 0.7725 0.6540
0.1216 0.7492 0.6910
0.1342 0.7232 0.7420
0.1538 0.6827 0.7840
0.1766 0.6357 0.8090
0.2012 0.5850 0.8230
0.2328 0.5198 0.8090
0.2691 0.4449 0.7570
0.3085 0.3637 0.6650
0.3509 0.2762 0.5360
0.3939 0.1875 0.3770
0.4331 0.1067 0.2130
0.4617 0.0477 0.0890
0.1668 0.7482 0.5530
0.1844 0.7216 0.5940
0.2077 0.6864 0.6330
0.2362 0.6434 0.6630
0.2689 0.5940 0.6810
0.3063 0.5375 0.6880
0.3523 0.4680 0.6710
0.4046 0.3891 0.6210
0.4580 0.3084 0.5380
0.5182 0.2175 0.4190
0.5693 0.1404 0.2970
0.6206 0.0629 0.1630
0.2334 0.7002 0.4650
0.2615 0.6641 0.4920
0.2953 0.6207 0.5110
0.3339 0.5711 0.5200
0.3808 0.5109 0.5140
0.4322 0.4449 0.4890
0.4889 0.3721 0.4440
0.5529 0.2898 0.3740
0.6205 0.2030 0.2770
0.6870 0.1176 0.1620
0.7469 0.0407 0.0570

Mass density, kg/m3 [ref]

Operational conditions:

Fixed Measured
Mole fraction of Methyl valerate (2) - Liquid Mole fraction of Methyl formate (1) - Liquid Mass density, kg/m3 - Liquid
0.0000 1.0000 966.28
0.0097 0.9605 961.26
0.0190 0.9224 956.25
0.0352 0.8557 947.43
0.0480 0.8035 940.51
0.0595 0.7561 934.22
0.0716 0.7069 927.72
0.0827 0.6611 921.67
0.0949 0.6112 915.09
0.1189 0.5130 902.25
0.1417 0.4194 890.13
0.1560 0.3609 882.62
0.1679 0.3122 876.39
0.1890 0.2261 865.47
0.2055 0.1583 856.93
0.2177 0.1083 850.65
0.0000 1.0000 966.28
0.0209 0.9481 958.88
0.0418 0.8963 951.68
0.0585 0.8548 945.98
0.0769 0.8093 939.94
0.1018 0.7475 931.91
0.1121 0.7218 928.62
0.1451 0.6401 918.6
0.1802 0.5529 908.44
0.2057 0.4898 901.41
0.2182 0.4586 898.04
0.2597 0.3558 887.35
0.3020 0.2508 877.03
0.3225 0.1999 872.27
0.3436 0.1476 867.43
0.3570 0.1143 864.43
0.3788 0.0603 859.62
0.0000 1.0000 966.28
0.0320 0.9460 957.92
0.0630 0.8936 950.16
0.0980 0.8345 941.91
0.1213 0.7952 936.81
0.1456 0.7542 931.64
0.1793 0.6972 924.89
0.2438 0.5883 913.16
0.2970 0.4985 904.5
0.3199 0.4598 901.04
0.3563 0.3983 895.8
0.3806 0.3573 892.49
0.4481 0.2433 883.9
0.4179 0.2943 887.6
0.4692 0.2077 881.36
0.4909 0.1710 878.87
0.5292 0.1064 874.57
0.5521 0.0677 872.1
0.5610 0.0527 871.23
0.0000 1.0000 966.28
0.0506 0.9353 955.31
0.0785 0.8996 949.82
0.1181 0.8489 942.53
0.1753 0.7758 933.1
0.2286 0.7076 925.27
0.2836 0.6372 918.11
0.3239 0.5857 913.33
0.3973 0.4918 905.54
0.4191 0.4639 903.4
0.4848 0.3799 897.52
0.5488 0.2980 892.37
0.5893 0.2462 889.4
0.6185 0.2089 887.35
0.6698 0.1433 884.0
0.7028 0.1010 881.92
0.0000 1.0000 966.28
0.0473 0.9461 956.79
0.0928 0.8943 948.38
0.1403 0.8402 940.79
0.2139 0.7564 930.5
0.2638 0.6995 924.38
0.3317 0.6222 916.97
0.3953 0.5497 910.9
0.4309 0.5092 907.81
0.4743 0.4597 904.27
0.5584 0.3639 898.15
0.6482 0.2616 892.48
0.6933 0.2103 889.95
0.7383 0.1590 887.59
0.7692 0.1238 886.03
0.8152 0.0714 883.8

Mass density, kg/m3 [ref]

Operational conditions:

Fixed Measured
Mole fraction of Methyl valerate (2) - Liquid Mole fraction of Methyl formate (1) - Liquid Mass density, kg/m3 - Liquid
0.0000 1.0000 966.28
0.0097 0.9605 961.26
0.0190 0.9224 956.25
0.0352 0.8557 947.43
0.0480 0.8035 940.51
0.0595 0.7561 934.22
0.0716 0.7069 927.72
0.0827 0.6611 921.67
0.0949 0.6112 915.09
0.1189 0.5130 902.25
0.1417 0.4194 890.13
0.1560 0.3609 882.62
0.1679 0.3122 876.39
0.1890 0.2261 865.47
0.2055 0.1583 856.93
0.2177 0.1083 850.65
0.0000 1.0000 966.28
0.0209 0.9481 958.88
0.0418 0.8963 951.68
0.0585 0.8548 945.98
0.0769 0.8093 939.94
0.1018 0.7475 931.91
0.1121 0.7218 928.62
0.1451 0.6401 918.6
0.1802 0.5529 908.44
0.2057 0.4898 901.41
0.2182 0.4586 898.04
0.2597 0.3558 887.35
0.3020 0.2508 877.03
0.3225 0.1999 872.27
0.3436 0.1476 867.43
0.3570 0.1143 864.43
0.3788 0.0603 859.62
0.0000 1.0000 966.28
0.0320 0.9460 957.92
0.0630 0.8936 950.16
0.0980 0.8345 941.91
0.1213 0.7952 936.81
0.1456 0.7542 931.64
0.1793 0.6972 924.89
0.2438 0.5883 913.16
0.2970 0.4985 904.5
0.3199 0.4598 901.04
0.3563 0.3983 895.8
0.3806 0.3573 892.49
0.4481 0.2433 883.9
0.4179 0.2943 887.6
0.4692 0.2077 881.36
0.4909 0.1710 878.87
0.5292 0.1064 874.57
0.5521 0.0677 872.1
0.5610 0.0527 871.23
0.0000 1.0000 966.28
0.0506 0.9353 955.31
0.0785 0.8996 949.82
0.1181 0.8489 942.53
0.1753 0.7758 933.1
0.2286 0.7076 925.27
0.2836 0.6372 918.11
0.3239 0.5857 913.33
0.3973 0.4918 905.54
0.4191 0.4639 903.4
0.4848 0.3799 897.52
0.5488 0.2980 892.37
0.5893 0.2462 889.4
0.6185 0.2089 887.35
0.6698 0.1433 884.0
0.7028 0.1010 881.92
0.0000 1.0000 966.28
0.0473 0.9461 956.79
0.0928 0.8943 948.38
0.1403 0.8402 940.79
0.2139 0.7564 930.5
0.2638 0.6995 924.38
0.3317 0.6222 916.97
0.3953 0.5497 910.9
0.4309 0.5092 907.81
0.4743 0.4597 904.27
0.5584 0.3639 898.15
0.6482 0.2616 892.48
0.6933 0.2103 889.95
0.7383 0.1590 887.59
0.7692 0.1238 886.03
0.8152 0.0714 883.8

Sources