Mixture of Pentane, 2,2,4-trimethyl- + Acetic acid, methyl ester

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (4)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Acetic acid, methyl ester (2) [ref]

Fixed		Measured
Pressure, kPa - Gas	Mole fraction of Acetic acid, methyl ester (2) - Liquid	Mole fraction of Acetic acid, methyl ester (2) - Gas
100.00	0.0000	0.0000
100.00	0.0390	0.2740
100.00	0.0640	0.3720
100.00	0.0890	0.4480
100.00	0.1130	0.5190
100.00	0.1410	0.5680
100.00	0.1760	0.6150
100.00	0.1990	0.6470
100.00	0.2310	0.6780
100.00	0.2560	0.6980
100.00	0.2870	0.7190
100.00	0.3210	0.7390
100.00	0.3620	0.7560
100.00	0.3870	0.7670
100.00	0.4170	0.7780
100.00	0.4360	0.7860
100.00	0.4570	0.7940
100.00	0.5010	0.8010
100.00	0.5190	0.8100
100.00	0.5710	0.8220
100.00	0.6180	0.8340
100.00	0.6600	0.8450
100.00	0.6940	0.8530
100.00	0.7340	0.8620
100.00	0.7670	0.8700
100.00	0.7940	0.8790
100.00	0.8270	0.8890
100.00	0.8530	0.8990
100.00	0.8830	0.9110
100.00	0.9060	0.9240
100.00	0.9300	0.9370
100.00	0.9460	0.9480
100.00	0.9570	0.9580
100.00	0.9680	0.9670
100.00	0.9830	0.9820
100.00	0.9950	0.9940
100.00	1.0000	1.0000
1500.00	0.0000	0.0000
1500.00	0.0260	0.0840
1500.00	0.0770	0.2190
1500.00	0.1120	0.2960
1500.00	0.1390	0.3440
1500.00	0.1730	0.4020
1500.00	0.2010	0.4400
1500.00	0.2280	0.4780
1500.00	0.2530	0.5150
1500.00	0.3050	0.5750
1500.00	0.3590	0.6240
1500.00	0.3850	0.6470
1500.00	0.4120	0.6700
1500.00	0.4620	0.7070
1500.00	0.4850	0.7210
1500.00	0.5100	0.7350
1500.00	0.5290	0.7450
1500.00	0.5550	0.7560
1500.00	0.5780	0.7700
1500.00	0.6140	0.7840
1500.00	0.6380	0.7980
1500.00	0.6630	0.8110
1500.00	0.6920	0.8260
1500.00	0.7240	0.8390
1500.00	0.7520	0.8540
1500.00	0.7850	0.8690
1500.00	0.8250	0.8920
1500.00	0.8640	0.9070
1500.00	0.8960	0.9270
1500.00	0.9180	0.9420
1500.00	0.9480	0.9590
1500.00	0.9840	0.9880
1500.00	0.9950	0.9960
1500.00	1.0000	1.0000

Mole fraction of Acetic acid, methyl ester (2) [ref]

Fixed		Measured
Pressure, kPa - Gas	Mole fraction of Acetic acid, methyl ester (2) - Liquid	Mole fraction of Acetic acid, methyl ester (2) - Gas
100.00	0.0000	0.0000
100.00	0.0390	0.2740
100.00	0.0640	0.3720
100.00	0.0890	0.4480
100.00	0.1130	0.5190
100.00	0.1410	0.5680
100.00	0.1760	0.6150
100.00	0.1990	0.6470
100.00	0.2310	0.6780
100.00	0.2560	0.6980
100.00	0.2870	0.7190
100.00	0.3210	0.7390
100.00	0.3620	0.7560
100.00	0.3870	0.7670
100.00	0.4170	0.7780
100.00	0.4360	0.7860
100.00	0.4570	0.7940
100.00	0.5010	0.8010
100.00	0.5190	0.8100
100.00	0.5710	0.8220
100.00	0.6180	0.8340
100.00	0.6600	0.8450
100.00	0.6940	0.8530
100.00	0.7340	0.8620
100.00	0.7670	0.8700
100.00	0.7940	0.8790
100.00	0.8270	0.8890
100.00	0.8530	0.8990
100.00	0.8830	0.9110
100.00	0.9060	0.9240
100.00	0.9300	0.9370
100.00	0.9460	0.9480
100.00	0.9570	0.9580
100.00	0.9680	0.9670
100.00	0.9830	0.9820
100.00	0.9950	0.9940
100.00	1.0000	1.0000
1500.00	0.0000	0.0000
1500.00	0.0260	0.0840
1500.00	0.0770	0.2190
1500.00	0.1120	0.2960
1500.00	0.1390	0.3440
1500.00	0.1730	0.4020
1500.00	0.2010	0.4400
1500.00	0.2280	0.4780
1500.00	0.2530	0.5150
1500.00	0.3050	0.5750
1500.00	0.3590	0.6240
1500.00	0.3850	0.6470
1500.00	0.4120	0.6700
1500.00	0.4620	0.7070
1500.00	0.4850	0.7210
1500.00	0.5100	0.7350
1500.00	0.5290	0.7450
1500.00	0.5550	0.7560
1500.00	0.5780	0.7700
1500.00	0.6140	0.7840
1500.00	0.6380	0.7980
1500.00	0.6630	0.8110
1500.00	0.6920	0.8260
1500.00	0.7240	0.8390
1500.00	0.7520	0.8540
1500.00	0.7850	0.8690
1500.00	0.8250	0.8920
1500.00	0.8640	0.9070
1500.00	0.8960	0.9270
1500.00	0.9180	0.9420
1500.00	0.9480	0.9590
1500.00	0.9840	0.9880
1500.00	0.9950	0.9960
1500.00	1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0200	0.1550
0.0525	0.4140
0.0892	0.6600
0.1241	0.8580
0.1687	1.047
0.2084	1.217
0.2560	1.385
0.3079	1.544
0.3608	1.659
0.3915	1.712
0.4323	1.763
0.4764	1.789
0.5406	1.759
0.6163	1.644
0.6888	1.456
0.7833	1.149
0.8597	0.7920
0.9422	0.3560

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Pressure, kPa = 100 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0200	0.1550
0.0525	0.4140
0.0892	0.6600
0.1241	0.8580
0.1687	1.047
0.2084	1.217
0.2560	1.385
0.3079	1.544
0.3608	1.659
0.3915	1.712
0.4323	1.763
0.4764	1.789
0.5406	1.759
0.6163	1.644
0.6888	1.456
0.7833	1.149
0.8597	0.7920
0.9422	0.3560

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 100 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (1) - Liquid	Mass density, kg/m3 - Liquid
0.0000	927.16
0.0375	906.89
0.1025	876.58
0.1652	851.09
0.1775	846.59
0.2189	832.07
0.2615	818.03
0.3020	805.95
0.3902	782.41
0.4061	778.52
0.4249	774.09
0.4627	765.54
0.5239	752.92
0.5411	749.57
0.6100	737.18
0.6612	728.76
0.6786	726.1
0.7359	717.6
0.8086	708.07
0.8803	699.86
0.9521	692.07
1.0000	687.75

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Acetic acid, methyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	687.8
0.0646	693.5
0.0822	695.3
0.0859	695.7
0.0992	697.0
0.1566	703.6
0.1941	707.9
0.2080	709.7
0.2240	711.7
0.2636	717.1
0.2688	717.7
0.2957	721.6
0.3211	725.4
0.3319	727.0
0.3956	737.4
0.5015	757.3
0.5780	774.0
0.5792	774.3
0.6528	792.8
0.6958	804.5
0.7268	813.9
0.7611	824.8
0.7834	832.2
0.8161	843.6
0.8466	855.3
0.8480	855.8
0.8628	861.6
0.8632	861.9
0.8889	872.5
0.9179	885.5
0.9388	895.1
0.9406	895.7
0.9456	898.3
0.9574	904.3
1.0000	927.1

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 100 (Liquid)

Mole fraction of Pentane, 2,2,4-trimethyl- (1) - Liquid	Mass density, kg/m3 - Liquid
0.0000	927.16
0.0375	906.89
0.1025	876.58
0.1652	851.09
0.1775	846.59
0.2189	832.07
0.2615	818.03
0.3020	805.95
0.3902	782.41
0.4061	778.52
0.4249	774.09
0.4627	765.54
0.5239	752.92
0.5411	749.57
0.6100	737.18
0.6612	728.76
0.6786	726.1
0.7359	717.6
0.8086	708.07
0.8803	699.86
0.9521	692.07
1.0000	687.75

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101.3 (Liquid)
• Temperature, K = 298.15 (Liquid)

Mole fraction of Acetic acid, methyl ester (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	687.8
0.0646	693.5
0.0822	695.3
0.0859	695.7
0.0992	697.0
0.1566	703.6
0.1941	707.9
0.2080	709.7
0.2240	711.7
0.2636	717.1
0.2688	717.7
0.2957	721.6
0.3211	725.4
0.3319	727.0
0.3956	737.4
0.5015	757.3
0.5780	774.0
0.5792	774.3
0.6528	792.8
0.6958	804.5
0.7268	813.9
0.7611	824.8
0.7834	832.2
0.8161	843.6
0.8466	855.3
0.8480	855.8
0.8628	861.6
0.8632	861.9
0.8889	872.5
0.9179	885.5
0.9388	895.1
0.9406	895.7
0.9456	898.3
0.9574	904.3
1.0000	927.1

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Acetic acid, methyl ester (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	100.00	371.91
0.0390	100.00	362.72
0.0640	100.00	358.41
0.0890	100.00	354.98
0.1130	100.00	351.68
0.1410	100.00	349.05
0.1760	100.00	346.17
0.1990	100.00	344.54
0.2310	100.00	342.49
0.2560	100.00	341.16
0.2870	100.00	339.82
0.3210	100.00	338.45
0.3620	100.00	337.32
0.3870	100.00	336.53
0.4170	100.00	335.80
0.4360	100.00	335.33
0.4570	100.00	334.85
0.5010	100.00	334.28
0.5190	100.00	333.77
0.5710	100.00	333.06
0.6180	100.00	332.41
0.6600	100.00	331.85
0.6940	100.00	331.50
0.7340	100.00	331.10
0.7670	100.00	330.79
0.7940	100.00	330.47
0.8270	100.00	330.20
0.8530	100.00	330.06
0.8830	100.00	329.84
0.9060	100.00	329.73
0.9300	100.00	329.61
0.9460	100.00	329.54
0.9570	100.00	329.52
0.9680	100.00	329.57
0.9830	100.00	329.71
0.9950	100.00	329.89
1.0000	100.00	329.99
0.0000	1500.00	504.65
0.0260	1500.00	499.45
0.0770	1500.00	490.75
0.1120	1500.00	485.75
0.1390	1500.00	482.05
0.1730	1500.00	477.95
0.2010	1500.00	474.85
0.2280	1500.00	471.76
0.2530	1500.00	468.88
0.3050	1500.00	464.20
0.3590	1500.00	459.75
0.3850	1500.00	457.78
0.4120	1500.00	456.09
0.4620	1500.00	452.91
0.4850	1500.00	451.60
0.5100	1500.00	450.36
0.5290	1500.00	449.62
0.5550	1500.00	448.73
0.5780	1500.00	447.79
0.6140	1500.00	446.38
0.6380	1500.00	445.63
0.6630	1500.00	444.45
0.6920	1500.00	443.54
0.7240	1500.00	442.73
0.7520	1500.00	441.92
0.7850	1500.00	441.01
0.8250	1500.00	439.94
0.8640	1500.00	438.80
0.8960	1500.00	437.97
0.9180	1500.00	437.59
0.9480	1500.00	436.85
0.9840	1500.00	436.34
0.9950	1500.00	436.17
1.0000	1500.00	436.08

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Acetic acid, methyl ester (2) - Liquid	Pressure, kPa - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	100.00	371.91
0.0390	100.00	362.72
0.0640	100.00	358.41
0.0890	100.00	354.98
0.1130	100.00	351.68
0.1410	100.00	349.05
0.1760	100.00	346.17
0.1990	100.00	344.54
0.2310	100.00	342.49
0.2560	100.00	341.16
0.2870	100.00	339.82
0.3210	100.00	338.45
0.3620	100.00	337.32
0.3870	100.00	336.53
0.4170	100.00	335.80
0.4360	100.00	335.33
0.4570	100.00	334.85
0.5010	100.00	334.28
0.5190	100.00	333.77
0.5710	100.00	333.06
0.6180	100.00	332.41
0.6600	100.00	331.85
0.6940	100.00	331.50
0.7340	100.00	331.10
0.7670	100.00	330.79
0.7940	100.00	330.47
0.8270	100.00	330.20
0.8530	100.00	330.06
0.8830	100.00	329.84
0.9060	100.00	329.73
0.9300	100.00	329.61
0.9460	100.00	329.54
0.9570	100.00	329.52
0.9680	100.00	329.57
0.9830	100.00	329.71
0.9950	100.00	329.89
1.0000	100.00	329.99
0.0000	1500.00	504.65
0.0260	1500.00	499.45
0.0770	1500.00	490.75
0.1120	1500.00	485.75
0.1390	1500.00	482.05
0.1730	1500.00	477.95
0.2010	1500.00	474.85
0.2280	1500.00	471.76
0.2530	1500.00	468.88
0.3050	1500.00	464.20
0.3590	1500.00	459.75
0.3850	1500.00	457.78
0.4120	1500.00	456.09
0.4620	1500.00	452.91
0.4850	1500.00	451.60
0.5100	1500.00	450.36
0.5290	1500.00	449.62
0.5550	1500.00	448.73
0.5780	1500.00	447.79
0.6140	1500.00	446.38
0.6380	1500.00	445.63
0.6630	1500.00	444.45
0.6920	1500.00	443.54
0.7240	1500.00	442.73
0.7520	1500.00	441.92
0.7850	1500.00	441.01
0.8250	1500.00	439.94
0.8640	1500.00	438.80
0.8960	1500.00	437.97
0.9180	1500.00	437.59
0.9480	1500.00	436.85
0.9840	1500.00	436.34
0.9950	1500.00	436.17
1.0000	1500.00	436.08

Sources

• A Study on Alkane + Ester + Ester Systems. Physicochemical Behavior of Binaries and Ternaries of Octane or Iso-octane with Methyl Esters (Ethanoate, Butanoate, Pentanoate)
• Measurement of VLE Data by Using an Experimental Installation with Automatic Control: Modeling of Binary Systems of Methyl Acetate or Ethyl Acetate with n-Heptane or 2,2,4-Trimethylpentane at Both 0.1 and 1.5 MPa