Mixture of 2-Propanol, 2-methyl- + 2-Butene, (E)-

Datasets

1. Activity coefficient (2)
2. Henry's Law constant (mole fraction scale), kPa (4)
3. P_vap - Vapor or sublimation pressure, kPa (4)

Activity coefficient of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 2-Butene, (E)- (2) - Liquid
300.03	3.12
310.00	3.01
320.00	2.87
330.00	2.75

Activity coefficient of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 2-Butene, (E)- (2) - Liquid
300.03	3.12
310.00	3.01
320.00	2.87
330.00	2.75

Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) - Liquid
300.03	717.0
310.00	915.0
320.00	1130.0
330.00	1380.0

Mole fraction of 2-Butene, (E)- (2) [ref]

Fixed		Measured
Mole fraction of 2-Butene, (E)- (2) - Liquid	Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Gas
0.0000	332.06	0.0000
0.0220	332.07	0.4560
0.0360	332.07	0.5700
0.0680	332.07	0.7098
0.1010	332.08	0.7815
0.1380	332.08	0.8261
0.1750	332.08	0.8551
0.2140	332.07	0.8763
0.2560	332.08	0.8927
0.2990	332.08	0.9052
0.3450	332.09	0.9156
0.3920	332.09	0.9240
0.5040	332.13	0.9391
0.5530	332.13	0.9444
0.6020	332.12	0.9492
0.6520	332.11	0.9537
0.7010	332.12	0.9578
0.7500	332.11	0.9618
0.8000	332.10	0.9659
0.8490	332.09	0.9703
0.9000	332.08	0.9758
0.9490	332.08	0.9841
0.9890	332.08	0.9956
1.0000	332.08	1.0000

Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) - Liquid
300.03	717.0
310.00	915.0
320.00	1130.0
330.00	1380.0

Mole fraction of 2-Butene, (E)- (2) [ref]

Fixed		Measured
Mole fraction of 2-Butene, (E)- (2) - Liquid	Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Gas
0.0000	332.06	0.0000
0.0220	332.07	0.4560
0.0360	332.07	0.5700
0.0680	332.07	0.7098
0.1010	332.08	0.7815
0.1380	332.08	0.8261
0.1750	332.08	0.8551
0.2140	332.07	0.8763
0.2560	332.08	0.8927
0.2990	332.08	0.9052
0.3450	332.09	0.9156
0.3920	332.09	0.9240
0.5040	332.13	0.9391
0.5530	332.13	0.9444
0.6020	332.12	0.9492
0.6520	332.11	0.9537
0.7010	332.12	0.9578
0.7500	332.11	0.9618
0.8000	332.10	0.9659
0.8490	332.09	0.9703
0.9000	332.08	0.9758
0.9490	332.08	0.9841
0.9890	332.08	0.9956
1.0000	332.08	1.0000

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of 2-Butene, (E)- (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	332.06	36.97
0.0220	332.07	67.37
0.0360	332.07	84.37
0.0680	332.07	123.27
0.1010	332.08	161.27
0.1380	332.08	198.46
0.1750	332.08	233.16
0.2140	332.07	266.66
0.2560	332.08	299.46
0.2990	332.08	329.76
0.3450	332.09	359.45
0.3920	332.09	386.75
0.5040	332.13	443.25
0.5530	332.13	463.95
0.6020	332.12	482.75
0.6520	332.11	500.45
0.7010	332.12	516.55
0.7500	332.11	531.65
0.8000	332.10	545.94
0.8490	332.09	559.64
0.9000	332.08	573.34
0.9490	332.08	587.64
0.9890	332.08	601.64
1.0000	332.08	606.14

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
364.51	0.3476	728.40
364.51	0.3983	786.70
364.51	0.4491	840.30
364.51	0.5002	890.30
364.51	0.7440	1084.80
364.52	0.0000	143.30
364.52	0.0237	196.80
364.52	0.0430	238.80
364.52	0.0592	272.70
364.52	0.1049	362.50
364.52	0.1511	445.60
364.52	0.1992	524.70
364.52	0.2480	597.80
364.52	0.2979	666.20
364.52	0.4987	889.10
364.52	0.5469	932.40
364.52	0.5955	973.30
364.52	0.6445	1011.90
364.52	0.6945	1049.50
364.52	0.7941	1119.70
364.52	0.8444	1154.40
364.52	0.9694	1244.30
364.52	0.9792	1251.80
364.52	1.0000	1268.10
364.53	0.8963	1190.50
364.53	0.9488	1228.70
364.53	0.9898	1260.50

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of 2-Butene, (E)- (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	332.06	36.97
0.0220	332.07	67.37
0.0360	332.07	84.37
0.0680	332.07	123.27
0.1010	332.08	161.27
0.1380	332.08	198.46
0.1750	332.08	233.16
0.2140	332.07	266.66
0.2560	332.08	299.46
0.2990	332.08	329.76
0.3450	332.09	359.45
0.3920	332.09	386.75
0.5040	332.13	443.25
0.5530	332.13	463.95
0.6020	332.12	482.75
0.6520	332.11	500.45
0.7010	332.12	516.55
0.7500	332.11	531.65
0.8000	332.10	545.94
0.8490	332.09	559.64
0.9000	332.08	573.34
0.9490	332.08	587.64
0.9890	332.08	601.64
1.0000	332.08	606.14

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
364.51	0.3476	728.40
364.51	0.3983	786.70
364.51	0.4491	840.30
364.51	0.5002	890.30
364.51	0.7440	1084.80
364.52	0.0000	143.30
364.52	0.0237	196.80
364.52	0.0430	238.80
364.52	0.0592	272.70
364.52	0.1049	362.50
364.52	0.1511	445.60
364.52	0.1992	524.70
364.52	0.2480	597.80
364.52	0.2979	666.20
364.52	0.4987	889.10
364.52	0.5469	932.40
364.52	0.5955	973.30
364.52	0.6445	1011.90
364.52	0.6945	1049.50
364.52	0.7941	1119.70
364.52	0.8444	1154.40
364.52	0.9694	1244.30
364.52	0.9792	1251.80
364.52	1.0000	1268.10
364.53	0.8963	1190.50
364.53	0.9488	1228.70
364.53	0.9898	1260.50

Sources

• Henry's constants and infinite dilution activity coefficients of propane, propene, butane, isobutane, 1-butene, isobutene, trans-2-butene, and 1,3-butadiene in isobutanol and tert-butanol
• Vapor Liquid Equilibrium for the Trans-2-Butene + Methanol, + Ethanol, + 2-Propanol, + 2-Butanol and + 2-Methyl-2-Propanol Systems at 332 K
• Vapor Liquid Equilibrium for the Systems trans-2-Butene + Methanol, + 1-Propanol, + 2-Propanol, + 2-Butanol, and + 2-Methyl-2-propanol at 364.5 K