Mixture of Cyclohexanol + Cyclohexane + Water

Datasets

1. Temperature, K x Mass fraction (12)

Temperature, K x Mass fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Cyclohexanol (1) - Liquid mixture 2	Mass fraction of Cyclohexane (2) - Liquid mixture 2	Mass fraction of Cyclohexanol (1) - Liquid mixture 1	Mass fraction of Cyclohexane (2) - Liquid mixture 1
303.20	0.0000	0.0001	0.0000	0.9983
303.20	0.0162	0.0001	0.0855	0.9109
303.20	0.0199	0.0001	0.1919	0.8017
303.20	0.0218	0.0001	0.2901	0.6990
303.20	0.0233	0.0001	0.3932	0.5884
303.20	0.0252	0.0001	0.4919	0.4810
303.20	0.0266	0.0001	0.5841	0.3794
303.20	0.0287	0.0001	0.6744	0.2762
303.20	0.0313	0.0001	0.7554	0.1811
303.20	0.0349	0.0002	0.8324	0.0770
303.20	0.0391	0.0000	0.8796	0.0000
313.20	0.0000	0.0000	0.0000	0.9986
313.20	0.0147	0.0001	0.0895	0.9076
313.20	0.0183	0.0001	0.1964	0.7973
313.20	0.0207	0.0001	0.2936	0.6957
313.20	0.0220	0.0001	0.3970	0.5868
313.20	0.0229	0.0001	0.4916	0.4823
313.20	0.0242	0.0001	0.5893	0.3748
313.20	0.0257	0.0000	0.6867	0.2697
313.20	0.0278	0.0000	0.7622	0.1743
313.20	0.0315	0.0000	0.8418	0.0705
313.20	0.0354	0.0000	0.8778	0.0000
323.20	0.0000	0.0000	0.0000	0.9987
323.20	0.0139	0.0001	0.0942	0.9026
323.20	0.0169	0.0001	0.1989	0.7939
323.20	0.0191	0.0001	0.3003	0.6876
323.20	0.0208	0.0001	0.3969	0.5853
323.20	0.0222	0.0001	0.5092	0.4629
323.20	0.0222	0.0001	0.6081	0.3536
323.20	0.0237	0.0001	0.6969	0.2563
323.20	0.0251	0.0000	0.7733	0.1604
323.20	0.0290	0.0000	0.8530	0.0594
323.20	0.0329	0.0000	0.8769	0.0000
333.20	0.0000	0.0000	0.0000	0.9989
333.20	0.0127	0.0000	0.0876	0.9101
333.20	0.0161	0.0001	0.1999	0.7937
333.20	0.0180	0.0000	0.3022	0.6871
333.20	0.0187	0.0001	0.3999	0.5831
333.20	0.0208	0.0001	0.5026	0.4693
333.20	0.0223	0.0000	0.5988	0.3660
333.20	0.0234	0.0001	0.6874	0.2641
333.20	0.0249	0.0001	0.7852	0.1476
333.20	0.0282	0.0000	0.8402	0.0674
333.20	0.0325	0.0000	0.8699	0.0000

Mole fraction of Cyclohexanol (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1
298.15	0.0000	0.5610
298.15	0.0520	0.5810
298.15	0.1370	0.5680
298.15	0.2370	0.5420
298.15	0.2800	0.5150
298.15	0.3450	0.4850
298.15	0.4420	0.4300
298.15	0.5740	0.3420
298.15	0.6800	0.2660
298.15	0.8110	0.1650
323.15	0.0000	0.5340
323.15	0.0700	0.5470
323.15	0.1460	0.5360
323.15	0.2380	0.4990
323.15	0.3460	0.4600
323.15	0.3900	0.4370
323.15	0.4490	0.4030
323.15	0.5500	0.3450
323.15	0.6140	0.2990
323.15	0.6900	0.2390
323.15	0.7910	0.1690
323.15	0.9140	0.0740

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Gas	Mole fraction of Cyclohexane (2) - Gas
333.15	30.91	0.0790	0.7130	0.0260	0.4700
333.15	35.08	0.1740	0.7360	0.0190	0.7440
333.15	41.22	0.1950	0.6770	0.0170	0.6950
333.15	41.64	0.2960	0.6470	0.0170	0.8430
333.15	45.73	0.3960	0.5630	0.0140	0.8530
353.15	20.80	0.0330	0.9250	0.1660	0.4320
353.15	33.65	0.0380	0.8620	0.0970	0.3410
353.15	42.28	0.0920	0.8400	0.0770	0.5850
353.15	70.12	0.1950	0.7240	0.0300	0.7050
353.15	72.04	0.1160	0.7020	0.0350	0.5040
353.15	79.14	0.3020	0.6470	0.0270	0.7640
353.15	81.21	0.1830	0.6750	0.0260	0.6060
353.15	88.28	0.4060	0.5440	0.0230	0.8560

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Gas	Mole fraction of Cyclohexane (2) - Gas
333.15	23.22	0.0090	0.5480	0.0310	0.0840
333.15	48.42	0.1290	0.5410	0.0150	0.6090
333.15	54.99	0.2020	0.5190	0.0120	0.6380
333.15	62.63	0.3820	0.4460	0.0110	0.6880
333.15	63.37	0.4120	0.4220	0.0100	0.7110
333.15	65.82	0.5460	0.3480	0.0090	0.7240
333.15	66.87	0.6180	0.2960	0.0070	0.7470
333.15	67.70	0.6750	0.2570	0.0040	0.7670
333.15	68.39	0.7440	0.2090	0.0070	0.7690
333.15	69.04	0.7860	0.1780	0.0060	0.7740
333.15	69.54	0.8870	0.0980	0.0080	0.7760
353.15	50.78	0.0020	0.5290	0.0400	0.0080
353.15	85.88	0.0680	0.5190	0.0240	0.4230

Mole fraction of Cyclohexanol (1) [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1
333.15	23.22	0.0090	0.5480
333.15	69.04	0.7860	0.1780
333.15	69.54	0.8870	0.0980
353.15	50.78	0.0020	0.5290
353.15	85.88	0.0680	0.5190
333.15	48.42	0.1290	0.5410
333.15	54.99	0.2020	0.5190
333.15	62.63	0.3820	0.4460
333.15	63.37	0.4120	0.4220
333.15	65.82	0.5460	0.3480
333.15	66.87	0.6180	0.2960
333.15	67.70	0.6750	0.2570
333.15	68.39	0.7440	0.2090

Mole fraction [ref]

Operational conditions:

• Temperature, K = 295 (Liquid mixture 1)
• Pressure, kPa = 101.3 (Liquid mixture 1)

Fixed	Measured
Mole fraction of Cyclohexanol (1) - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 2	Mole fraction of Cyclohexanol (1) - Liquid mixture 2
0.5460	0.4540	0.9937	0.0063
0.5830	0.3850	0.9940	0.0060
0.5590	0.3790	0.9945	0.0055
0.5550	0.3510	0.9946	0.0053
0.5620	0.3140	0.9947	0.0053
0.5460	0.3030	0.9948	0.0052
0.5480	0.2740	0.9948	0.0052
0.5000	0.2510	0.9953	0.0047
0.4940	0.2260	0.9953	0.0047
0.4870	0.2000	0.9954	0.0046
0.4530	0.1620	0.9954	0.0046
0.4130	0.1480	0.9954	0.0046
0.3890	0.1340	0.9955	0.0045
0.3600	0.1130	0.9956	0.0044
0.3290	0.1000	0.9956	0.0044
0.2900	0.0750	0.9958	0.0042
0.2550	0.0550	0.9962	0.0038
0.1970	0.0340	0.9961	0.0038
0.1360	0.0200	0.9964	0.0035
0.0700	0.0077	0.9972	0.0028
0.0000	0.0004	1.0000	0.0000

Temperature, K x Mass fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Cyclohexanol (1) - Liquid mixture 2	Mass fraction of Cyclohexane (2) - Liquid mixture 2	Mass fraction of Cyclohexanol (1) - Liquid mixture 1	Mass fraction of Cyclohexane (2) - Liquid mixture 1
303.20	0.0000	0.0001	0.0000	0.9983
303.20	0.0162	0.0001	0.0855	0.9109
303.20	0.0199	0.0001	0.1919	0.8017
303.20	0.0218	0.0001	0.2901	0.6990
303.20	0.0233	0.0001	0.3932	0.5884
303.20	0.0252	0.0001	0.4919	0.4810
303.20	0.0266	0.0001	0.5841	0.3794
303.20	0.0287	0.0001	0.6744	0.2762
303.20	0.0313	0.0001	0.7554	0.1811
303.20	0.0349	0.0002	0.8324	0.0770
303.20	0.0391	0.0000	0.8796	0.0000
313.20	0.0000	0.0000	0.0000	0.9986
313.20	0.0147	0.0001	0.0895	0.9076
313.20	0.0183	0.0001	0.1964	0.7973
313.20	0.0207	0.0001	0.2936	0.6957
313.20	0.0220	0.0001	0.3970	0.5868
313.20	0.0229	0.0001	0.4916	0.4823
313.20	0.0242	0.0001	0.5893	0.3748
313.20	0.0257	0.0000	0.6867	0.2697
313.20	0.0278	0.0000	0.7622	0.1743
313.20	0.0315	0.0000	0.8418	0.0705
313.20	0.0354	0.0000	0.8778	0.0000
323.20	0.0000	0.0000	0.0000	0.9987
323.20	0.0139	0.0001	0.0942	0.9026
323.20	0.0169	0.0001	0.1989	0.7939
323.20	0.0191	0.0001	0.3003	0.6876
323.20	0.0208	0.0001	0.3969	0.5853
323.20	0.0222	0.0001	0.5092	0.4629
323.20	0.0222	0.0001	0.6081	0.3536
323.20	0.0237	0.0001	0.6969	0.2563
323.20	0.0251	0.0000	0.7733	0.1604
323.20	0.0290	0.0000	0.8530	0.0594
323.20	0.0329	0.0000	0.8769	0.0000
333.20	0.0000	0.0000	0.0000	0.9989
333.20	0.0127	0.0000	0.0876	0.9101
333.20	0.0161	0.0001	0.1999	0.7937
333.20	0.0180	0.0000	0.3022	0.6871
333.20	0.0187	0.0001	0.3999	0.5831
333.20	0.0208	0.0001	0.5026	0.4693
333.20	0.0223	0.0000	0.5988	0.3660
333.20	0.0234	0.0001	0.6874	0.2641
333.20	0.0249	0.0001	0.7852	0.1476
333.20	0.0282	0.0000	0.8402	0.0674
333.20	0.0325	0.0000	0.8699	0.0000

Mole fraction of Cyclohexanol (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1
298.15	0.0000	0.5610
298.15	0.0520	0.5810
298.15	0.1370	0.5680
298.15	0.2370	0.5420
298.15	0.2800	0.5150
298.15	0.3450	0.4850
298.15	0.4420	0.4300
298.15	0.5740	0.3420
298.15	0.6800	0.2660
298.15	0.8110	0.1650
323.15	0.0000	0.5340
323.15	0.0700	0.5470
323.15	0.1460	0.5360
323.15	0.2380	0.4990
323.15	0.3460	0.4600
323.15	0.3900	0.4370
323.15	0.4490	0.4030
323.15	0.5500	0.3450
323.15	0.6140	0.2990
323.15	0.6900	0.2390
323.15	0.7910	0.1690
323.15	0.9140	0.0740

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Gas	Mole fraction of Cyclohexane (2) - Gas
333.15	30.91	0.0790	0.7130	0.0260	0.4700
333.15	35.08	0.1740	0.7360	0.0190	0.7440
333.15	41.22	0.1950	0.6770	0.0170	0.6950
333.15	41.64	0.2960	0.6470	0.0170	0.8430
333.15	45.73	0.3960	0.5630	0.0140	0.8530
353.15	20.80	0.0330	0.9250	0.1660	0.4320
353.15	33.65	0.0380	0.8620	0.0970	0.3410
353.15	42.28	0.0920	0.8400	0.0770	0.5850
353.15	70.12	0.1950	0.7240	0.0300	0.7050
353.15	72.04	0.1160	0.7020	0.0350	0.5040
353.15	79.14	0.3020	0.6470	0.0270	0.7640
353.15	81.21	0.1830	0.6750	0.0260	0.6060
353.15	88.28	0.4060	0.5440	0.0230	0.8560

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Gas	Mole fraction of Cyclohexane (2) - Gas
333.15	23.22	0.0090	0.5480	0.0310	0.0840
333.15	48.42	0.1290	0.5410	0.0150	0.6090
333.15	54.99	0.2020	0.5190	0.0120	0.6380
333.15	62.63	0.3820	0.4460	0.0110	0.6880
333.15	63.37	0.4120	0.4220	0.0100	0.7110
333.15	65.82	0.5460	0.3480	0.0090	0.7240
333.15	66.87	0.6180	0.2960	0.0070	0.7470
333.15	67.70	0.6750	0.2570	0.0040	0.7670
333.15	68.39	0.7440	0.2090	0.0070	0.7690
333.15	69.04	0.7860	0.1780	0.0060	0.7740
333.15	69.54	0.8870	0.0980	0.0080	0.7760
353.15	50.78	0.0020	0.5290	0.0400	0.0080
353.15	85.88	0.0680	0.5190	0.0240	0.4230

Mole fraction of Cyclohexanol (1) [ref]

Fixed			Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Cyclohexane (2) - Liquid mixture 1	Mole fraction of Cyclohexanol (1) - Liquid mixture 1
333.15	23.22	0.0090	0.5480
333.15	69.04	0.7860	0.1780
333.15	69.54	0.8870	0.0980
353.15	50.78	0.0020	0.5290
353.15	85.88	0.0680	0.5190
333.15	48.42	0.1290	0.5410
333.15	54.99	0.2020	0.5190
333.15	62.63	0.3820	0.4460
333.15	63.37	0.4120	0.4220
333.15	65.82	0.5460	0.3480
333.15	66.87	0.6180	0.2960
333.15	67.70	0.6750	0.2570
333.15	68.39	0.7440	0.2090

Mole fraction [ref]

Operational conditions:

• Temperature, K = 295 (Liquid mixture 1)
• Pressure, kPa = 101.3 (Liquid mixture 1)

Fixed	Measured
Mole fraction of Cyclohexanol (1) - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 1	Mole fraction of Water (3) - Liquid mixture 2	Mole fraction of Cyclohexanol (1) - Liquid mixture 2
0.5460	0.4540	0.9937	0.0063
0.5830	0.3850	0.9940	0.0060
0.5590	0.3790	0.9945	0.0055
0.5550	0.3510	0.9946	0.0053
0.5620	0.3140	0.9947	0.0053
0.5460	0.3030	0.9948	0.0052
0.5480	0.2740	0.9948	0.0052
0.5000	0.2510	0.9953	0.0047
0.4940	0.2260	0.9953	0.0047
0.4870	0.2000	0.9954	0.0046
0.4530	0.1620	0.9954	0.0046
0.4130	0.1480	0.9954	0.0046
0.3890	0.1340	0.9955	0.0045
0.3600	0.1130	0.9956	0.0044
0.3290	0.1000	0.9956	0.0044
0.2900	0.0750	0.9958	0.0042
0.2550	0.0550	0.9962	0.0038
0.1970	0.0340	0.9961	0.0038
0.1360	0.0200	0.9964	0.0035
0.0700	0.0077	0.9972	0.0028
0.0000	0.0004	1.0000	0.0000

Sources

• Distribution of cyclohexanol and cyclohexanone between water and cyclohexane
• Measurement and prediction of liquid-liquid equilibria in ternary systems containing water, an organic component, and cyclohexanol
• Measurement and Prediction of Vapor Liquid(-Liquid) Equilibria in Ternary Systems Containing Water, an Organic Component, and Cyclohexanol
• VLE and LLE Data for the System Cyclohexane + Cyclohexene + Water + Cyclohexanol