Mixture of 1-Propanol + 2-Butene, (E)-

Datasets

1. Activity coefficient (2)
2. Henry's Law constant (mole fraction scale), kPa (2)
3. P_vap - Vapor or sublimation pressure, kPa (4)

Activity coefficient of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 2-Butene, (E)- (2) - Liquid
260.02	4.2
280.03	4.15
299.99	4.1
320.09	4.06
340.06	3.98

Activity coefficient of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of 2-Butene, (E)- (2) - Liquid
260.02	4.2
280.03	4.15
299.99	4.1
320.09	4.06
340.06	3.98

Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) - Liquid
260.02	236.0
280.03	501.0
299.99	936.0
320.09	1586.0
340.06	2441.0

Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Henry's Law constant (mole fraction scale), kPa of 2-Butene, (E)- (2) - Liquid
260.02	236.0
280.03	501.0
299.99	936.0
320.09	1586.0
340.06	2441.0

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
332.05	0.0000	19.17
332.05	0.0372	92.17
332.05	0.0524	119.47
332.05	0.1472	260.26
332.05	0.1963	315.96
332.05	0.2970	401.75
332.05	0.8978	579.64
332.05	0.9480	590.34
332.05	0.9680	595.54
332.05	0.9886	602.24
332.05	1.0000	606.54
332.06	0.1018	198.96
332.06	0.2466	363.15
332.06	0.3476	433.35
332.06	0.3981	459.15
332.06	0.4495	480.55
332.06	0.5004	498.05
332.06	0.5981	523.65
332.06	0.6976	543.94
332.06	0.7474	553.04
332.06	0.7976	561.84
332.06	0.8476	570.54
332.07	0.4998	497.55
332.07	0.5491	511.65
332.07	0.6478	534.25

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
364.51	0.0510	255.30
364.51	0.0989	395.00
364.51	0.4975	985.60
364.51	0.8963	1200.80
364.52	0.0365	208.50
364.52	0.1448	510.40
364.52	0.1926	612.70
364.52	0.2420	702.00
364.52	0.3434	844.00
364.52	0.3938	898.10
364.52	0.4457	945.30
364.52	0.4986	986.30
364.52	0.5467	1019.00
364.52	0.5958	1048.70
364.52	0.6448	1075.70
364.52	0.6940	1100.80
364.52	0.7936	1149.20
364.52	0.8446	1173.90
364.52	0.9476	1231.20
364.52	0.9682	1245.20
364.52	0.9806	1254.10
364.52	1.0000	1268.00
364.53	0.0000	81.20
364.53	0.2928	779.40
364.53	0.7435	1125.30
364.53	0.9885	1259.90

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
332.05	0.0000	19.17
332.05	0.0372	92.17
332.05	0.0524	119.47
332.05	0.1472	260.26
332.05	0.1963	315.96
332.05	0.2970	401.75
332.05	0.8978	579.64
332.05	0.9480	590.34
332.05	0.9680	595.54
332.05	0.9886	602.24
332.05	1.0000	606.54
332.06	0.1018	198.96
332.06	0.2466	363.15
332.06	0.3476	433.35
332.06	0.3981	459.15
332.06	0.4495	480.55
332.06	0.5004	498.05
332.06	0.5981	523.65
332.06	0.6976	543.94
332.06	0.7474	553.04
332.06	0.7976	561.84
332.06	0.8476	570.54
332.07	0.4998	497.55
332.07	0.5491	511.65
332.07	0.6478	534.25

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 2-Butene, (E)- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
364.51	0.0510	255.30
364.51	0.0989	395.00
364.51	0.4975	985.60
364.51	0.8963	1200.80
364.52	0.0365	208.50
364.52	0.1448	510.40
364.52	0.1926	612.70
364.52	0.2420	702.00
364.52	0.3434	844.00
364.52	0.3938	898.10
364.52	0.4457	945.30
364.52	0.4986	986.30
364.52	0.5467	1019.00
364.52	0.5958	1048.70
364.52	0.6448	1075.70
364.52	0.6940	1100.80
364.52	0.7936	1149.20
364.52	0.8446	1173.90
364.52	0.9476	1231.20
364.52	0.9682	1245.20
364.52	0.9806	1254.10
364.52	1.0000	1268.00
364.53	0.0000	81.20
364.53	0.2928	779.40
364.53	0.7435	1125.30
364.53	0.9885	1259.90

Sources

• Henry's constants and infinite dilution activity coefficients of propane, propene, butane, isobutene, 1-butene, isobutane, trans-2-butene and 1,3-butadiene in 1-propanol at T=(260 to 340) K
• Vapor-Liquid Equilibrium for 1-Propanol + 1-Butene, + cis-2-Butene, + 2-Methyl-propene, + trans-2-Butene, + n-Butane, and + 2-Methyl-propane
• Vapor Liquid Equilibrium for the Systems trans-2-Butene + Methanol, + 1-Propanol, + 2-Propanol, + 2-Butanol, and + 2-Methyl-2-propanol at 364.5 K