Mixture of Toluene + Phenol + Water

Datasets

1. Temperature, K x Mole fraction (8)
2. ρ_l - Mass density, kg/m3 (2)

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 85 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mole fraction of Phenol (2) - Liquid mixture 1	Mole fraction of Toluene (1) - Liquid mixture 1	Mole fraction of Phenol (2) - Liquid mixture 2	Mole fraction of Toluene (1) - Liquid mixture 2
300.00	0.0182	0.0001	0.4040	0.0330
340.00	0.0200	0.0001	0.4020	0.1140
340.00	0.0134	0.0001	0.3570	0.4520
340.00	0.0092	0.0002	0.2150	0.7040
360.00	0.0322	0.0003	0.2980	0.0460
360.00	0.0252	0.0002	0.3670	0.1030
360.00	0.0159	0.0002	0.3620	0.4210
360.00	0.0104	0.0001	0.2080	0.6980
300.00	0.0152	0.0001	0.4410	0.1400
300.00	0.0104	0.0001	0.3710	0.4660
300.00	0.0081	0.0001	0.2300	0.7060
320.00	0.0208	0.0001	0.3680	0.0300
320.00	0.0156	0.0002	0.4260	0.1270
320.00	0.0113	0.0001	0.3490	0.4760
320.00	0.0088	0.0001	0.2240	0.7060
340.00	0.0234	0.0001	0.3660	0.0460

Temperature, K x Mass fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 2	Mass fraction of Toluene (1) - Liquid mixture 2	Mass fraction of Toluene (1) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1
298.15	0.0120	0.0020	0.6110	0.0800
303.15	0.0160	0.0020	0.5320	0.2060
303.15	0.0220	0.0010	0.4770	0.2950
298.15	0.0120	0.0010	0.5840	0.0920
298.15	0.0290	0.0010	0.5000	0.2630
298.15	0.0350	0.0010	0.4340	0.3620
298.15	0.0330	0.0020	0.4700	0.3570
303.15	0.0230	0.0070	0.4110	0.3670
303.15	0.0010	0.0010	0.5730	0.0090
303.15	0.0120	0.0010	0.5710	0.1120

Mole fraction of Phenol (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Toluene (1) - Liquid mixture 1	Mole fraction of Phenol (2) - Liquid mixture 1
298.15	0.0000	0.3123
298.15	0.0520	0.3946
298.15	0.1003	0.4208
298.15	0.1583	0.4268
298.15	0.2041	0.4282
298.15	0.2691	0.4141
298.15	0.3894	0.3779
298.15	0.4767	0.3389
298.15	0.5371	0.3103
298.15	0.6338	0.2561
298.15	0.6809	0.2295
298.15	0.7656	0.1752
298.15	0.8772	0.0895
298.15	0.3894	0.3779
313.15	0.0000	0.2755
313.15	0.0519	0.3709
313.15	0.1012	0.3987
313.15	0.1423	0.4128
313.15	0.1965	0.4085
313.15	0.2356	0.4064
313.15	0.3068	0.3976
313.15	0.4004	0.3723
313.15	0.4666	0.3470
313.15	0.5537	0.2956
313.15	0.5940	0.2665

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Toluene (1) - Liquid	Mole fraction of Phenol (2) - Liquid	Mole fraction of Phenol (2) - Gas	Mole fraction of Toluene (1) - Gas
333.15	16.84	0.0935	0.6757	0.0239	0.3078
333.15	18.97	0.2637	0.6040	0.0213	0.5309
333.15	18.99	0.0674	0.6194	0.0186	0.2432
333.15	20.67	0.3001	0.5674	0.0139	0.5267
333.15	21.58	0.1321	0.5832	0.0183	0.3439
333.15	23.14	0.5648	0.3679	0.0117	0.6120
333.15	24.25	0.1065	0.5594	0.0127	0.3410
333.15	25.45	0.1714	0.5216	0.0121	0.3601
333.15	26.09	0.2752	0.5064	0.0101	0.4597
333.15	29.05	0.2505	0.4690	0.0084	0.4116
333.15	29.78	0.4393	0.3912	0.0076	0.4990
363.15	50.20	0.0849	0.6880	0.0431	0.2578
363.15	60.17	0.0726	0.6217	0.0319	0.2141
363.15	61.91	0.2670	0.5816	0.0262	0.4683
363.15	62.03	0.3132	0.5597	0.0258	0.5030
363.15	69.19	0.1394	0.5681	0.0239	0.3137
363.15	76.15	0.5532	0.3565	0.0167	0.5469
363.15	77.25	0.1360	0.5195	0.0195	0.2980
363.15	79.34	0.1752	0.5143	0.0186	0.3445
363.15	79.51	0.2741	0.5044	0.0174	0.4039
363.15	89.67	0.2396	0.4571	0.0147	0.3680
363.15	92.94	0.4412	0.3814	0.0125	0.4492

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 85 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 2	Mole fraction of Phenol (2) - Liquid mixture 1	Mole fraction of Toluene (1) - Liquid mixture 1	Mole fraction of Phenol (2) - Liquid mixture 2	Mole fraction of Toluene (1) - Liquid mixture 2
300.00	0.0182	0.0001	0.4040	0.0330
340.00	0.0200	0.0001	0.4020	0.1140
340.00	0.0134	0.0001	0.3570	0.4520
340.00	0.0092	0.0002	0.2150	0.7040
360.00	0.0322	0.0003	0.2980	0.0460
360.00	0.0252	0.0002	0.3670	0.1030
360.00	0.0159	0.0002	0.3620	0.4210
360.00	0.0104	0.0001	0.2080	0.6980
300.00	0.0152	0.0001	0.4410	0.1400
300.00	0.0104	0.0001	0.3710	0.4660
300.00	0.0081	0.0001	0.2300	0.7060
320.00	0.0208	0.0001	0.3680	0.0300
320.00	0.0156	0.0002	0.4260	0.1270
320.00	0.0113	0.0001	0.3490	0.4760
320.00	0.0088	0.0001	0.2240	0.7060
340.00	0.0234	0.0001	0.3660	0.0460

Temperature, K x Mass fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 2	Mass fraction of Toluene (1) - Liquid mixture 2	Mass fraction of Toluene (1) - Liquid mixture 1	Mass fraction of Phenol (2) - Liquid mixture 1
298.15	0.0120	0.0020	0.6110	0.0800
303.15	0.0160	0.0020	0.5320	0.2060
303.15	0.0220	0.0010	0.4770	0.2950
298.15	0.0120	0.0010	0.5840	0.0920
298.15	0.0290	0.0010	0.5000	0.2630
298.15	0.0350	0.0010	0.4340	0.3620
298.15	0.0330	0.0020	0.4700	0.3570
303.15	0.0230	0.0070	0.4110	0.3670
303.15	0.0010	0.0010	0.5730	0.0090
303.15	0.0120	0.0010	0.5710	0.1120

Mole fraction of Phenol (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Toluene (1) - Liquid mixture 1	Mole fraction of Phenol (2) - Liquid mixture 1
298.15	0.0000	0.3123
298.15	0.0520	0.3946
298.15	0.1003	0.4208
298.15	0.1583	0.4268
298.15	0.2041	0.4282
298.15	0.2691	0.4141
298.15	0.3894	0.3779
298.15	0.4767	0.3389
298.15	0.5371	0.3103
298.15	0.6338	0.2561
298.15	0.6809	0.2295
298.15	0.7656	0.1752
298.15	0.8772	0.0895
298.15	0.3894	0.3779
313.15	0.0000	0.2755
313.15	0.0519	0.3709
313.15	0.1012	0.3987
313.15	0.1423	0.4128
313.15	0.1965	0.4085
313.15	0.2356	0.4064
313.15	0.3068	0.3976
313.15	0.4004	0.3723
313.15	0.4666	0.3470
313.15	0.5537	0.2956
313.15	0.5940	0.2665

Temperature, K x Pressure, kPa x Mole fraction [ref]

Fixed			Measured
Temperature, K - Liquid	Pressure, kPa - Liquid	Mole fraction of Toluene (1) - Liquid	Mole fraction of Phenol (2) - Liquid	Mole fraction of Phenol (2) - Gas	Mole fraction of Toluene (1) - Gas
333.15	16.84	0.0935	0.6757	0.0239	0.3078
333.15	18.97	0.2637	0.6040	0.0213	0.5309
333.15	18.99	0.0674	0.6194	0.0186	0.2432
333.15	20.67	0.3001	0.5674	0.0139	0.5267
333.15	21.58	0.1321	0.5832	0.0183	0.3439
333.15	23.14	0.5648	0.3679	0.0117	0.6120
333.15	24.25	0.1065	0.5594	0.0127	0.3410
333.15	25.45	0.1714	0.5216	0.0121	0.3601
333.15	26.09	0.2752	0.5064	0.0101	0.4597
333.15	29.05	0.2505	0.4690	0.0084	0.4116
333.15	29.78	0.4393	0.3912	0.0076	0.4990
363.15	50.20	0.0849	0.6880	0.0431	0.2578
363.15	60.17	0.0726	0.6217	0.0319	0.2141
363.15	61.91	0.2670	0.5816	0.0262	0.4683
363.15	62.03	0.3132	0.5597	0.0258	0.5030
363.15	69.19	0.1394	0.5681	0.0239	0.3137
363.15	76.15	0.5532	0.3565	0.0167	0.5469
363.15	77.25	0.1360	0.5195	0.0195	0.2980
363.15	79.34	0.1752	0.5143	0.0186	0.3445
363.15	79.51	0.2741	0.5044	0.0174	0.4039
363.15	89.67	0.2396	0.4571	0.0147	0.3680
363.15	92.94	0.4412	0.3814	0.0125	0.4492

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 313.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Fixed		Measured
Mole fraction of Toluene (1) - Liquid	Mole fraction of Phenol (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	0.3794	1038.84
0.0000	0.4653	1042.74
0.0000	0.6176	1048.12
0.0000	0.7052	1050.69
0.0000	0.8247	1054.06
0.0000	0.9099	1056.28
0.0000	1.0000	1058.3
0.0302	0.3679	1026.37
0.0302	0.4512	1030.77
0.0390	0.8743	1046.38
0.0417	0.5918	1034.82
0.0458	0.6729	1037.27
0.0471	0.7858	1041.13
0.0607	0.4370	1020.53
0.0669	0.8490	1039.62
0.0763	0.7618	1033.72
0.0873	0.5637	1020.6
0.0972	0.6366	1022.73
0.0979	0.4197	1008.07
0.0999	0.9001	1033.8
0.1012	0.3410	999.79
0.1015	0.8175	1030.9
0.1192	0.7264	1022.61
0.1362	0.5335	1006.93
0.1452	0.6028	1009.71
0.1489	0.3960	992.27
0.1504	0.7730	1018.95
0.1576	0.8424	1021.66
0.1633	0.3174	979.73
0.1803	0.6760	1007.41
0.1804	0.5062	994.58
0.1889	0.7380	1009.78
0.1907	0.5707	997.67
0.2176	0.4832	984.88
0.2222	0.7077	1002.03
0.2254	0.5462	989.16
0.2271	0.6374	996.07
0.2381	0.3545	967.77
0.2559	0.4596	975.31
0.2581	0.7419	998.46
0.2705	0.2767	951.39
0.2728	0.5997	985.37
0.2806	0.5073	975.83
0.3108	0.3206	950.3
0.3327	0.5503	971.68
0.3425	0.4061	955.19
0.3472	0.5940	973.44
0.3492	0.6508	978.14
0.3605	0.4509	957.56
0.3648	0.2955	938.53
0.3681	0.5212	963.84
0.4083	0.3654	941.05
0.4305	0.5182	955.45
0.4327	0.2152	917.18
0.4362	0.2623	924.21
0.4363	0.5637	959.22
0.4377	0.3965	941.1
0.4453	0.4575	947.23
0.4953	0.4592	941.46
0.5179	0.3976	932.26
0.5188	0.2972	919.25
0.5403	0.2139	905.69
0.5438	0.4562	936.46
0.5554	0.4045	929.15
0.5570	0.3124	917.65
0.6080	0.3233	914.63
0.6332	0.3337	913.93
0.6351	0.3649	917.72
0.6460	0.2186	897.36
0.6598	0.1583	887.3
0.6689	0.2730	903.22
0.6754	0.2289	896.53
0.6755	0.1231	880.3
0.7288	0.2712	898.99
0.7309	0.1662	883.7
0.7424	0.2125	889.97
0.7570	0.2211	890.41
0.7802	0.1023	871.67
0.7917	0.1469	877.48
0.8122	0.1549	877.81
0.8334	0.1666	878.75
0.8411	0.0981	868.13
0.8533	0.1210	871.08
0.8536	0.0681	862.88
0.8730	0.0896	865.52
0.8773	0.1117	868.78
0.9015	0.0985	865.97
0.9069	0.0353	855.82
0.9303	0.0575	858.62
0.9346	0.0404	855.59
0.9347	0.0460	856.65
0.9448	0.0455	856.32
0.9489	0.0238	852.3
0.9698	0.0275	852.98
0.9795	0.0187	851.3
0.9801	0.0164	850.96
1.0000	0.0000	848.07

Mass density, kg/m3 [ref]

Operational conditions:

• Temperature, K = 313.15 (Liquid)
• Pressure, kPa = 101 (Liquid)

Fixed		Measured
Mole fraction of Toluene (1) - Liquid	Mole fraction of Phenol (2) - Liquid	Mass density, kg/m3 - Liquid
0.0000	0.3794	1038.84
0.0000	0.4653	1042.74
0.0000	0.6176	1048.12
0.0000	0.7052	1050.69
0.0000	0.8247	1054.06
0.0000	0.9099	1056.28
0.0000	1.0000	1058.3
0.0302	0.3679	1026.37
0.0302	0.4512	1030.77
0.0390	0.8743	1046.38
0.0417	0.5918	1034.82
0.0458	0.6729	1037.27
0.0471	0.7858	1041.13
0.0607	0.4370	1020.53
0.0669	0.8490	1039.62
0.0763	0.7618	1033.72
0.0873	0.5637	1020.6
0.0972	0.6366	1022.73
0.0979	0.4197	1008.07
0.0999	0.9001	1033.8
0.1012	0.3410	999.79
0.1015	0.8175	1030.9
0.1192	0.7264	1022.61
0.1362	0.5335	1006.93
0.1452	0.6028	1009.71
0.1489	0.3960	992.27
0.1504	0.7730	1018.95
0.1576	0.8424	1021.66
0.1633	0.3174	979.73
0.1803	0.6760	1007.41
0.1804	0.5062	994.58
0.1889	0.7380	1009.78
0.1907	0.5707	997.67
0.2176	0.4832	984.88
0.2222	0.7077	1002.03
0.2254	0.5462	989.16
0.2271	0.6374	996.07
0.2381	0.3545	967.77
0.2559	0.4596	975.31
0.2581	0.7419	998.46
0.2705	0.2767	951.39
0.2728	0.5997	985.37
0.2806	0.5073	975.83
0.3108	0.3206	950.3
0.3327	0.5503	971.68
0.3425	0.4061	955.19
0.3472	0.5940	973.44
0.3492	0.6508	978.14
0.3605	0.4509	957.56
0.3648	0.2955	938.53
0.3681	0.5212	963.84
0.4083	0.3654	941.05
0.4305	0.5182	955.45
0.4327	0.2152	917.18
0.4362	0.2623	924.21
0.4363	0.5637	959.22
0.4377	0.3965	941.1
0.4453	0.4575	947.23
0.4953	0.4592	941.46
0.5179	0.3976	932.26
0.5188	0.2972	919.25
0.5403	0.2139	905.69
0.5438	0.4562	936.46
0.5554	0.4045	929.15
0.5570	0.3124	917.65
0.6080	0.3233	914.63
0.6332	0.3337	913.93
0.6351	0.3649	917.72
0.6460	0.2186	897.36
0.6598	0.1583	887.3
0.6689	0.2730	903.22
0.6754	0.2289	896.53
0.6755	0.1231	880.3
0.7288	0.2712	898.99
0.7309	0.1662	883.7
0.7424	0.2125	889.97
0.7570	0.2211	890.41
0.7802	0.1023	871.67
0.7917	0.1469	877.48
0.8122	0.1549	877.81
0.8334	0.1666	878.75
0.8411	0.0981	868.13
0.8533	0.1210	871.08
0.8536	0.0681	862.88
0.8730	0.0896	865.52
0.8773	0.1117	868.78
0.9015	0.0985	865.97
0.9069	0.0353	855.82
0.9303	0.0575	858.62
0.9346	0.0404	855.59
0.9347	0.0460	856.65
0.9448	0.0455	856.32
0.9489	0.0238	852.3
0.9698	0.0275	852.98
0.9795	0.0187	851.3
0.9801	0.0164	850.96
1.0000	0.0000	848.07

Sources

• Liquid-Liquid Equilibrium Measurements for Model Systems Related to Catalytic Fast Pyrolysis of Biomass
• Ternary and Quaternary Liquid + Liquid Equilibria for Systems of (Water + Toluene + m-Xylene + Phenol)
• Liquid-Liquid Equilibria in Ternary Systems of Aromatic Hydrocarbons (Toluene or Ethylbenzene) + Phenols + Water
• Vapor-Liquid Equilibria in Ternary Systems of Toluene or Octane + Phenols + Water