Mixture of n-Hexane + n-Propyl acetate

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of n-Propyl acetate (2) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of n-Propyl acetate (2) - Liquid	Mole fraction of n-Propyl acetate (2) - Gas
0.0000	0.0000
0.0088	0.0070
0.0253	0.0196
0.0470	0.0354
0.0767	0.0540
0.1100	0.0715
0.1485	0.0905
0.1959	0.1100
0.2372	0.1301
0.2860	0.1492
0.3385	0.1699
0.3866	0.1959
0.4332	0.2175
0.4773	0.2415
0.5184	0.2641
0.5629	0.2904
0.6104	0.3179
0.6403	0.3396
0.6643	0.3599
0.6922	0.3833
0.7209	0.4104
0.7493	0.4371
0.7772	0.4721
0.8080	0.5161
0.8422	0.5680
0.8746	0.6264
0.9015	0.6857
0.9265	0.7465
0.9423	0.7914
0.9629	0.8567
0.9787	0.9082
0.9899	0.9507
1.0000	1.0000

Mole fraction of n-Propyl acetate (2) [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of n-Propyl acetate (2) - Liquid	Mole fraction of n-Propyl acetate (2) - Gas
0.0000	0.0000
0.0088	0.0070
0.0253	0.0196
0.0470	0.0354
0.0767	0.0540
0.1100	0.0715
0.1485	0.0905
0.1959	0.1100
0.2372	0.1301
0.2860	0.1492
0.3385	0.1699
0.3866	0.1959
0.4332	0.2175
0.4773	0.2415
0.5184	0.2641
0.5629	0.2904
0.6104	0.3179
0.6403	0.3396
0.6643	0.3599
0.6922	0.3833
0.7209	0.4104
0.7493	0.4371
0.7772	0.4721
0.8080	0.5161
0.8422	0.5680
0.8746	0.6264
0.9015	0.6857
0.9265	0.7465
0.9423	0.7914
0.9629	0.8567
0.9787	0.9082
0.9899	0.9507
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.0740	0.2750
291.15	0.1514	0.5440
291.15	0.2307	0.7510
291.15	0.3056	0.9220
291.15	0.3758	1.038
291.15	0.4417	1.087
291.15	0.4984	1.109
291.15	0.5492	1.09
291.15	0.5528	1.087
291.15	0.6101	1.029
291.15	0.6705	0.9520
291.15	0.7361	0.8170
291.15	0.8064	0.6550
291.15	0.8762	0.4640
291.15	0.9422	0.2460
298.15	0.0319	0.1030
298.15	0.0736	0.2710
298.15	0.1450	0.5290
298.15	0.2223	0.7430
298.15	0.3011	0.9310
298.15	0.3660	1.038
298.15	0.4223	1.104
298.15	0.5030	1.122
298.15	0.5590	1.094
298.15	0.6073	1.044
298.15	0.6518	0.9790
298.15	0.7091	0.8740
298.15	0.7653	0.7410
298.15	0.8334	0.5690
298.15	0.8989	0.3760
298.15	0.9494	0.1950
318.15	0.0748	0.2890
318.15	0.1298	0.5110
318.15	0.2004	0.7360
318.15	0.2777	0.9410
318.15	0.3479	1.058
318.15	0.4119	1.119
318.15	0.4746	1.146
318.15	0.5084	1.142
318.15	0.5582	1.127
318.15	0.6039	1.08
318.15	0.6543	1.012
318.15	0.7123	0.9140
318.15	0.7753	0.7740
318.15	0.8288	0.6130
318.15	0.8906	0.4170
318.15	0.9452	0.2240

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.0740	0.2750
291.15	0.1514	0.5440
291.15	0.2307	0.7510
291.15	0.3056	0.9220
291.15	0.3758	1.038
291.15	0.4417	1.087
291.15	0.4984	1.109
291.15	0.5492	1.09
291.15	0.5528	1.087
291.15	0.6101	1.029
291.15	0.6705	0.9520
291.15	0.7361	0.8170
291.15	0.8064	0.6550
291.15	0.8762	0.4640
291.15	0.9422	0.2460
298.15	0.0319	0.1030
298.15	0.0736	0.2710
298.15	0.1450	0.5290
298.15	0.2223	0.7430
298.15	0.3011	0.9310
298.15	0.3660	1.038
298.15	0.4223	1.104
298.15	0.5030	1.122
298.15	0.5590	1.094
298.15	0.6073	1.044
298.15	0.6518	0.9790
298.15	0.7091	0.8740
298.15	0.7653	0.7410
298.15	0.8334	0.5690
298.15	0.8989	0.3760
298.15	0.9494	0.1950
318.15	0.0748	0.2890
318.15	0.1298	0.5110
318.15	0.2004	0.7360
318.15	0.2777	0.9410
318.15	0.3479	1.058
318.15	0.4119	1.119
318.15	0.4746	1.146
318.15	0.5084	1.142
318.15	0.5582	1.127
318.15	0.6039	1.08
318.15	0.6543	1.012
318.15	0.7123	0.9140
318.15	0.7753	0.7740
318.15	0.8288	0.6130
318.15	0.8906	0.4170
318.15	0.9452	0.2240

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (2) - Liquid	Mass density, kg/m3 - Liquid
328.15	0.0000	627.2
328.15	0.0253	631.3
328.15	0.0749	640.2
328.15	0.1369	651.6
328.15	0.2052	664.7
328.15	0.2719	677.8
328.15	0.3322	690.1
328.15	0.3986	704.0
328.15	0.4614	717.6
328.15	0.5209	730.7
328.15	0.5809	744.3
328.15	0.6200	753.3
328.15	0.6944	770.8
328.15	0.7605	786.8
328.15	0.8114	799.4
328.15	0.8707	814.4
328.15	0.9235	828.0
328.15	1.0000	848.3
318.15	0.0000	636.7
318.15	0.0304	641.7
318.15	0.0796	650.7
318.15	0.1381	661.7
318.15	0.2079	675.3
318.15	0.2642	686.6
318.15	0.3318	700.5
318.15	0.3997	714.9
318.15	0.4505	725.9
318.15	0.5124	739.7
318.15	0.5708	752.9
318.15	0.6220	764.8
318.15	0.6815	778.9
318.15	0.7426	793.7
318.15	0.7992	807.7
318.15	0.8648	824.4
318.15	0.9227	839.3
318.15	1.0000	859.8
298.15	0.0000	654.8
298.15	0.0175	658.0
298.15	0.0350	661.2
298.15	0.0831	670.3
298.15	0.1535	683.9
298.15	0.2218	697.6
298.15	0.2836	710.3
298.15	0.3539	724.9
298.15	0.4197	739.4
298.15	0.4795	752.7
298.15	0.5417	766.9
298.15	0.6040	781.5
298.15	0.6583	794.5
298.15	0.7242	810.6
298.15	0.7772	823.9
298.15	0.8357	838.9
298.15	0.8934	853.9
298.15	0.9187	860.5
298.15	0.9749	875.7
298.15	1.0000	882.5
291.15	0.0000	661.2
291.15	0.0120	663.4
291.15	0.0372	668.0
291.15	0.0924	678.5
291.15	0.1648	692.7
291.15	0.2357	707.0
291.15	0.3085	722.2
291.15	0.3804	737.7
291.15	0.4420	751.4
291.15	0.5117	767.2
291.15	0.5781	782.6
291.15	0.6400	797.3
291.15	0.7020	812.3
291.15	0.7697	829.1
291.15	0.8208	842.2
291.15	0.8835	858.4
291.15	0.9247	869.3
291.15	1.0000	889.6

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of n-Propyl acetate (2) - Liquid	Mass density, kg/m3 - Liquid
328.15	0.0000	627.2
328.15	0.0253	631.3
328.15	0.0749	640.2
328.15	0.1369	651.6
328.15	0.2052	664.7
328.15	0.2719	677.8
328.15	0.3322	690.1
328.15	0.3986	704.0
328.15	0.4614	717.6
328.15	0.5209	730.7
328.15	0.5809	744.3
328.15	0.6200	753.3
328.15	0.6944	770.8
328.15	0.7605	786.8
328.15	0.8114	799.4
328.15	0.8707	814.4
328.15	0.9235	828.0
328.15	1.0000	848.3
318.15	0.0000	636.7
318.15	0.0304	641.7
318.15	0.0796	650.7
318.15	0.1381	661.7
318.15	0.2079	675.3
318.15	0.2642	686.6
318.15	0.3318	700.5
318.15	0.3997	714.9
318.15	0.4505	725.9
318.15	0.5124	739.7
318.15	0.5708	752.9
318.15	0.6220	764.8
318.15	0.6815	778.9
318.15	0.7426	793.7
318.15	0.7992	807.7
318.15	0.8648	824.4
318.15	0.9227	839.3
318.15	1.0000	859.8
298.15	0.0000	654.8
298.15	0.0175	658.0
298.15	0.0350	661.2
298.15	0.0831	670.3
298.15	0.1535	683.9
298.15	0.2218	697.6
298.15	0.2836	710.3
298.15	0.3539	724.9
298.15	0.4197	739.4
298.15	0.4795	752.7
298.15	0.5417	766.9
298.15	0.6040	781.5
298.15	0.6583	794.5
298.15	0.7242	810.6
298.15	0.7772	823.9
298.15	0.8357	838.9
298.15	0.8934	853.9
298.15	0.9187	860.5
298.15	0.9749	875.7
298.15	1.0000	882.5
291.15	0.0000	661.2
291.15	0.0120	663.4
291.15	0.0372	668.0
291.15	0.0924	678.5
291.15	0.1648	692.7
291.15	0.2357	707.0
291.15	0.3085	722.2
291.15	0.3804	737.7
291.15	0.4420	751.4
291.15	0.5117	767.2
291.15	0.5781	782.6
291.15	0.6400	797.3
291.15	0.7020	812.3
291.15	0.7697	829.1
291.15	0.8208	842.2
291.15	0.8835	858.4
291.15	0.9247	869.3
291.15	1.0000	889.6

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of n-Propyl acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	341.89
0.0088	341.95
0.0253	342.07
0.0470	342.25
0.0767	342.50
0.1100	342.91
0.1485	343.32
0.1959	343.84
0.2372	344.43
0.2860	345.08
0.3385	345.80
0.3866	346.64
0.4332	347.46
0.4773	348.30
0.5184	349.16
0.5629	350.20
0.6104	351.25
0.6403	352.13
0.6643	352.98
0.6922	353.97
0.7209	355.22
0.7493	356.36
0.7772	357.75
0.8080	359.48
0.8422	361.45
0.8746	363.46
0.9015	365.36
0.9265	367.41
0.9423	368.79
0.9629	370.65
0.9787	372.07
0.9899	373.16
1.0000	374.34

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of n-Propyl acetate (2) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	341.89
0.0088	341.95
0.0253	342.07
0.0470	342.25
0.0767	342.50
0.1100	342.91
0.1485	343.32
0.1959	343.84
0.2372	344.43
0.2860	345.08
0.3385	345.80
0.3866	346.64
0.4332	347.46
0.4773	348.30
0.5184	349.16
0.5629	350.20
0.6104	351.25
0.6403	352.13
0.6643	352.98
0.6922	353.97
0.7209	355.22
0.7493	356.36
0.7772	357.75
0.8080	359.48
0.8422	361.45
0.8746	363.46
0.9015	365.36
0.9265	367.41
0.9423	368.79
0.9629	370.65
0.9787	372.07
0.9899	373.16
1.0000	374.34

Sources

• Multiproperty Correlation of Experimental Data of the Binaries Propyl Ethanoate + Alkanes (Pentane to Decane). New Experimental Information for Vapor Liquid Equilibrium and Mixing Properties