Mixture of Acetonitrile + Tetra-N-butylammonium bromide + Water

Excel

Acetonitrile

Name
Acetonitrile
InChI
InChI=1S/C2H3N/c1-2-3/h1H3
InChI Key
WEVYAHXRMPXWCK-UHFFFAOYSA-N
Formula
C2H3N
SMILES
CC#N
Mol. Weight (g/mol)
41.05
CAS
75-05-8

Tetra-N-butylammonium bromide

Name
Tetra-N-butylammonium bromide
InChI
InChI=1S/C16H36N.BrH/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChI Key
JRMUNVKIHCOMHV-UHFFFAOYSA-M
Formula
C16H36BrN
SMILES
CCCC[N+](CCCC)(CCCC)CCCC.[Br-]
Mol. Weight (g/mol)
322.37
CAS
1643-19-2

Water

Name
Water
InChI
InChI=1S/H2O/h1H2
InChI Key
XLYOFNOQVPJJNP-UHFFFAOYSA-N
Formula
H2O
SMILES
O
Mol. Weight (g/mol)
18.02
CAS
7732-18-5
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Datasets

  1. Mole fraction (2)
  2. Pvap - Vapor or sublimation pressure, kPa (2)

Mole fraction of Acetonitrile (1) [ref]

Fixed Measured
Temperature, K - Liquid Molality, mol/kg of Tetra-N-butylammonium bromide (2) - Liquid Solvent: Mole fraction of Acetonitrile (1) - Liquid Mole fraction of Acetonitrile (1) - Gas
298.00 0.2000 0.0207 0.2937
298.00 0.2000 0.0514 0.4951
298.00 0.2000 0.1008 0.6068
298.00 0.2000 0.2011 0.6993
298.00 0.2000 0.2968 0.7186
298.00 0.2000 0.4024 0.7503
298.00 0.2000 0.4987 0.7737
298.00 0.2000 0.6546 0.7820
298.00 0.2000 0.7531 0.7903
298.00 0.2000 0.8496 0.8648
298.00 0.2000 0.9503 0.9379
298.00 0.4000 0.0207 0.2441
298.00 0.4000 0.0514 0.4193
298.00 0.4000 0.1008 0.5586
298.00 0.4000 0.2011 0.6703
298.00 0.4000 0.2968 0.6924
298.00 0.4000 0.4024 0.7268
298.00 0.4000 0.4987 0.7558
298.00 0.4000 0.6546 0.7641
298.00 0.4000 0.7531 0.7765
298.00 0.4000 0.8496 0.8441
298.00 0.4000 0.9503 0.9144
298.00 0.6000 0.0207 0.2248
298.00 0.6000 0.0514 0.3696
298.00 0.6000 0.1008 0.5048
298.00 0.6000 0.2011 0.6206
298.00 0.6000 0.2968 0.6606
298.00 0.6000 0.4024 0.6924
298.00 0.6000 0.4987 0.7351
298.00 0.6000 0.6546 0.7475
298.00 0.6000 0.7531 0.7586
298.00 0.6000 0.8496 0.8193
298.00 0.6000 0.9503 0.8924
298.00 0.8000 0.0207 0.1944
298.00 0.8000 0.0514 0.3186
298.00 0.8000 0.1008 0.4662
298.00 0.8000 0.2011 0.5931
298.00 0.8000 0.2968 0.6275
298.00 0.8000 0.4024 0.6772
298.00 0.8000 0.4987 0.7199
298.00 0.8000 0.6546 0.7337
298.00 0.8000 0.7531 0.7475
298.00 0.8000 0.8496 0.8013
298.00 0.8000 0.9503 0.8772
298.00 1.0000 0.0207 0.1558
298.00 1.0000 0.0514 0.2537
298.00 1.0000 0.1008 0.4262
298.00 1.0000 0.2011 0.5558
298.00 1.0000 0.2968 0.6055
298.00 1.0000 0.4024 0.6468
298.00 1.0000 0.4987 0.6993
298.00 1.0000 0.6546 0.7172
298.00 1.0000 0.7531 0.7324
298.00 1.0000 0.8496 0.7779
298.00 1.0000 0.9503 0.8606
323.00 0.2000 0.0207 0.3199
323.00 0.2000 0.0514 0.4455
323.00 0.2000 0.1008 0.6027
323.00 0.2000 0.2011 0.6744
323.00 0.2000 0.2968 0.6896
323.00 0.2000 0.4024 0.7089
323.00 0.2000 0.4987 0.7241
323.00 0.2000 0.6546 0.7379
323.00 0.2000 0.7531 0.7572
323.00 0.2000 0.8496 0.8606
323.00 0.2000 0.9503 0.9324
323.00 0.4000 0.0207 0.2689
323.00 0.4000 0.0514 0.3848
323.00 0.4000 0.1008 0.5337
323.00 0.4000 0.2011 0.6248
323.00 0.4000 0.2968 0.6439
323.00 0.4000 0.4024 0.6565
323.00 0.4000 0.4987 0.6744
323.00 0.4000 0.6546 0.6924
323.00 0.4000 0.7531 0.7172
323.00 0.4000 0.8496 0.8468
323.00 0.4000 0.9503 0.9186
323.00 0.6000 0.0207 0.2179
323.00 0.6000 0.0514 0.3365
323.00 0.6000 0.1008 0.4882
323.00 0.6000 0.2011 0.5724
323.00 0.6000 0.2968 0.5889
323.00 0.6000 0.4024 0.6068
323.00 0.6000 0.4987 0.6248
323.00 0.6000 0.6546 0.6468
323.00 0.6000 0.7531 0.6799
323.00 0.6000 0.8496 0.8317
323.00 0.6000 0.9503 0.9020
323.00 0.8000 0.0207 0.1627
323.00 0.8000 0.0514 0.2965
323.00 0.8000 0.1008 0.4537
323.00 0.8000 0.2011 0.5241
323.00 0.8000 0.2968 0.5420
323.00 0.8000 0.4024 0.5544
323.00 0.8000 0.4987 0.5779
323.00 0.8000 0.6546 0.6013
323.00 0.8000 0.7531 0.6400
323.00 0.8000 0.8496 0.8165
323.00 0.8000 0.9503 0.8910
323.00 1.0000 0.0207 0.1337
323.00 1.0000 0.0514 0.2648
323.00 1.0000 0.1008 0.4165
323.00 1.0000 0.2011 0.4731
323.00 1.0000 0.2968 0.4937
323.00 1.0000 0.4024 0.5144
323.00 1.0000 0.4987 0.5310
323.00 1.0000 0.6546 0.5572
323.00 1.0000 0.7531 0.6027
323.00 1.0000 0.8496 0.8082
323.00 1.0000 0.9503 0.8772

Mole fraction of Acetonitrile (1) [ref]

Fixed Measured
Temperature, K - Liquid Molality, mol/kg of Tetra-N-butylammonium bromide (2) - Liquid Solvent: Mole fraction of Acetonitrile (1) - Liquid Mole fraction of Acetonitrile (1) - Gas
298.00 0.2000 0.0207 0.2937
298.00 0.2000 0.0514 0.4951
298.00 0.2000 0.1008 0.6068
298.00 0.2000 0.2011 0.6993
298.00 0.2000 0.2968 0.7186
298.00 0.2000 0.4024 0.7503
298.00 0.2000 0.4987 0.7737
298.00 0.2000 0.6546 0.7820
298.00 0.2000 0.7531 0.7903
298.00 0.2000 0.8496 0.8648
298.00 0.2000 0.9503 0.9379
298.00 0.4000 0.0207 0.2441
298.00 0.4000 0.0514 0.4193
298.00 0.4000 0.1008 0.5586
298.00 0.4000 0.2011 0.6703
298.00 0.4000 0.2968 0.6924
298.00 0.4000 0.4024 0.7268
298.00 0.4000 0.4987 0.7558
298.00 0.4000 0.6546 0.7641
298.00 0.4000 0.7531 0.7765
298.00 0.4000 0.8496 0.8441
298.00 0.4000 0.9503 0.9144
298.00 0.6000 0.0207 0.2248
298.00 0.6000 0.0514 0.3696
298.00 0.6000 0.1008 0.5048
298.00 0.6000 0.2011 0.6206
298.00 0.6000 0.2968 0.6606
298.00 0.6000 0.4024 0.6924
298.00 0.6000 0.4987 0.7351
298.00 0.6000 0.6546 0.7475
298.00 0.6000 0.7531 0.7586
298.00 0.6000 0.8496 0.8193
298.00 0.6000 0.9503 0.8924
298.00 0.8000 0.0207 0.1944
298.00 0.8000 0.0514 0.3186
298.00 0.8000 0.1008 0.4662
298.00 0.8000 0.2011 0.5931
298.00 0.8000 0.2968 0.6275
298.00 0.8000 0.4024 0.6772
298.00 0.8000 0.4987 0.7199
298.00 0.8000 0.6546 0.7337
298.00 0.8000 0.7531 0.7475
298.00 0.8000 0.8496 0.8013
298.00 0.8000 0.9503 0.8772
298.00 1.0000 0.0207 0.1558
298.00 1.0000 0.0514 0.2537
298.00 1.0000 0.1008 0.4262
298.00 1.0000 0.2011 0.5558
298.00 1.0000 0.2968 0.6055
298.00 1.0000 0.4024 0.6468
298.00 1.0000 0.4987 0.6993
298.00 1.0000 0.6546 0.7172
298.00 1.0000 0.7531 0.7324
298.00 1.0000 0.8496 0.7779
298.00 1.0000 0.9503 0.8606
323.00 0.2000 0.0207 0.3199
323.00 0.2000 0.0514 0.4455
323.00 0.2000 0.1008 0.6027
323.00 0.2000 0.2011 0.6744
323.00 0.2000 0.2968 0.6896
323.00 0.2000 0.4024 0.7089
323.00 0.2000 0.4987 0.7241
323.00 0.2000 0.6546 0.7379
323.00 0.2000 0.7531 0.7572
323.00 0.2000 0.8496 0.8606
323.00 0.2000 0.9503 0.9324
323.00 0.4000 0.0207 0.2689
323.00 0.4000 0.0514 0.3848
323.00 0.4000 0.1008 0.5337
323.00 0.4000 0.2011 0.6248
323.00 0.4000 0.2968 0.6439
323.00 0.4000 0.4024 0.6565
323.00 0.4000 0.4987 0.6744
323.00 0.4000 0.6546 0.6924
323.00 0.4000 0.7531 0.7172
323.00 0.4000 0.8496 0.8468
323.00 0.4000 0.9503 0.9186
323.00 0.6000 0.0207 0.2179
323.00 0.6000 0.0514 0.3365
323.00 0.6000 0.1008 0.4882
323.00 0.6000 0.2011 0.5724
323.00 0.6000 0.2968 0.5889
323.00 0.6000 0.4024 0.6068
323.00 0.6000 0.4987 0.6248
323.00 0.6000 0.6546 0.6468
323.00 0.6000 0.7531 0.6799
323.00 0.6000 0.8496 0.8317
323.00 0.6000 0.9503 0.9020
323.00 0.8000 0.0207 0.1627
323.00 0.8000 0.0514 0.2965
323.00 0.8000 0.1008 0.4537
323.00 0.8000 0.2011 0.5241
323.00 0.8000 0.2968 0.5420
323.00 0.8000 0.4024 0.5544
323.00 0.8000 0.4987 0.5779
323.00 0.8000 0.6546 0.6013
323.00 0.8000 0.7531 0.6400
323.00 0.8000 0.8496 0.8165
323.00 0.8000 0.9503 0.8910
323.00 1.0000 0.0207 0.1337
323.00 1.0000 0.0514 0.2648
323.00 1.0000 0.1008 0.4165
323.00 1.0000 0.2011 0.4731
323.00 1.0000 0.2968 0.4937
323.00 1.0000 0.4024 0.5144
323.00 1.0000 0.4987 0.5310
323.00 1.0000 0.6546 0.5572
323.00 1.0000 0.7531 0.6027
323.00 1.0000 0.8496 0.8082
323.00 1.0000 0.9503 0.8772

Vapor or sublimation pressure, kPa [ref]

Fixed Measured
Temperature, K - Liquid Mole fraction of Acetonitrile (1) - Liquid Molality, mol/kg of Tetra-N-butylammonium bromide (2) - Liquid Vapor or sublimation pressure, kPa - Liquid
298.15 0.0200 0.0000 5.49
298.15 0.0200 0.2000 4.02
298.15 0.0200 0.4000 3.72
298.15 0.0200 0.6000 3.55
298.15 0.0200 0.8000 3.34
298.15 0.0200 1.0000 3.26
298.15 0.0500 0.0000 8.40
298.15 0.0500 0.2000 6.24
298.15 0.0500 0.4000 5.42
298.15 0.0500 0.6000 4.92
298.15 0.0500 0.8000 4.61
298.15 0.0500 1.0000 4.27
298.15 0.1000 0.0000 11.13
298.15 0.1000 0.2000 7.92
298.15 0.1000 0.4000 7.19
298.15 0.1000 0.6000 6.34
298.15 0.1000 0.8000 5.77
298.15 0.1000 1.0000 5.18
298.15 0.2000 0.0000 12.44
298.15 0.2000 0.2000 10.87
298.15 0.2000 0.4000 9.84
298.15 0.2000 0.6000 8.74
298.15 0.2000 0.8000 7.66
298.15 0.2000 1.0000 6.93
298.15 0.3000 0.0000 12.66
298.15 0.3000 0.2000 11.12
298.15 0.3000 0.4000 10.28
298.15 0.3000 0.6000 9.53
298.15 0.3000 0.8000 8.76
298.15 0.3000 1.0000 8.10
298.15 0.4000 0.0000 12.70
298.15 0.4000 0.2000 11.80
298.15 0.4000 0.4000 11.12
298.15 0.4000 0.6000 10.43
298.15 0.4000 0.8000 9.74
298.15 0.4000 1.0000 8.98
298.15 0.5000 0.0000 12.75
298.15 0.5000 0.2000 12.12
298.15 0.5000 0.4000 11.62
298.15 0.5000 0.6000 11.14
298.15 0.5000 0.8000 10.66
298.15 0.5000 1.0000 10.18
298.15 0.6500 0.0000 12.79
298.15 0.6500 0.2000 12.27
298.15 0.6500 0.4000 11.79
298.15 0.6500 0.6000 11.30
298.15 0.6500 0.8000 10.86
298.15 0.6500 1.0000 10.33
298.15 0.7500 0.0000 12.90
298.15 0.7500 0.2000 12.46
298.15 0.7500 0.4000 11.99
298.15 0.7500 0.6000 11.48
298.15 0.7500 0.8000 11.04
298.15 0.7500 1.0000 10.61
298.15 0.8500 0.0000 12.80
298.15 0.8500 0.2000 12.33
298.15 0.8500 0.4000 11.89
298.15 0.8500 0.6000 11.43
298.15 0.8500 0.8000 11.02
298.15 0.8500 1.0000 10.65
298.15 0.9500 0.0000 12.26
298.15 0.9500 0.2000 11.87
298.15 0.9500 0.4000 11.53
298.15 0.9500 0.6000 11.19
298.15 0.9500 0.8000 10.86
298.15 0.9500 1.0000 10.58
323.15 0.0200 0.0000 18.62
323.15 0.0200 0.2000 14.13
323.15 0.0200 0.4000 12.94
323.15 0.0200 0.6000 12.16
323.15 0.0200 0.8000 11.16
323.15 0.0200 1.0000 10.46
323.15 0.0500 0.0000 27.00
323.15 0.0500 0.2000 17.92
323.15 0.0500 0.4000 15.92
323.15 0.0500 0.6000 14.93
323.15 0.0500 0.8000 14.20
323.15 0.0500 1.0000 13.64
323.15 0.1000 0.0000 32.27
323.15 0.1000 0.2000 21.07
323.15 0.1000 0.4000 18.30
323.15 0.1000 0.6000 16.84
323.15 0.1000 0.8000 15.41
323.15 0.1000 1.0000 14.71
323.15 0.2000 0.0000 35.89
323.15 0.2000 0.2000 27.84
323.15 0.2000 0.4000 24.55
323.15 0.2000 0.6000 21.86
323.15 0.2000 0.8000 20.06
323.15 0.2000 1.0000 18.04
323.15 0.3000 0.0000 36.79
323.15 0.3000 0.2000 29.98
323.15 0.3000 0.4000 26.24
323.15 0.3000 0.6000 24.05
323.15 0.3000 0.8000 22.02
323.15 0.3000 1.0000 20.67
323.15 0.4000 0.0000 37.46
323.15 0.4000 0.2000 31.55
323.15 0.4000 0.4000 29.45
323.15 0.4000 0.6000 27.57
323.15 0.4000 0.8000 26.06
323.15 0.4000 1.0000 25.08
323.15 0.5000 0.0000 37.60
323.15 0.5000 0.2000 34.19
323.15 0.5000 0.4000 31.57
323.15 0.5000 0.6000 30.09
323.15 0.5000 0.8000 28.62
323.15 0.5000 1.0000 27.29
323.15 0.6500 0.0000 37.99
323.15 0.6500 0.2000 36.04
323.15 0.6500 0.4000 35.56
323.15 0.6500 0.6000 32.98
323.15 0.6500 0.8000 31.38
323.15 0.6500 1.0000 30.08
323.15 0.7500 0.0000 38.12
323.15 0.7500 0.2000 36.73
323.15 0.7500 0.4000 35.29
323.15 0.7500 0.6000 34.22
323.15 0.7500 0.8000 33.24
323.15 0.7500 1.0000 32.21
323.15 0.8500 0.0000 37.63
323.15 0.8500 0.2000 36.29
323.15 0.8500 0.4000 35.00
323.15 0.8500 0.6000 33.59
323.15 0.8500 0.8000 32.32
323.15 0.8500 1.0000 31.01
323.15 0.9500 0.0000 35.34
323.15 0.9500 0.2000 34.23
323.15 0.9500 0.4000 33.23
323.15 0.9500 0.6000 32.07
323.15 0.9500 0.8000 31.16
323.15 0.9500 1.0000 30.06

Vapor or sublimation pressure, kPa [ref]

Fixed Measured
Temperature, K - Liquid Mole fraction of Acetonitrile (1) - Liquid Molality, mol/kg of Tetra-N-butylammonium bromide (2) - Liquid Vapor or sublimation pressure, kPa - Liquid
298.15 0.0200 0.0000 5.49
298.15 0.0200 0.2000 4.02
298.15 0.0200 0.4000 3.72
298.15 0.0200 0.6000 3.55
298.15 0.0200 0.8000 3.34
298.15 0.0200 1.0000 3.26
298.15 0.0500 0.0000 8.40
298.15 0.0500 0.2000 6.24
298.15 0.0500 0.4000 5.42
298.15 0.0500 0.6000 4.92
298.15 0.0500 0.8000 4.61
298.15 0.0500 1.0000 4.27
298.15 0.1000 0.0000 11.13
298.15 0.1000 0.2000 7.92
298.15 0.1000 0.4000 7.19
298.15 0.1000 0.6000 6.34
298.15 0.1000 0.8000 5.77
298.15 0.1000 1.0000 5.18
298.15 0.2000 0.0000 12.44
298.15 0.2000 0.2000 10.87
298.15 0.2000 0.4000 9.84
298.15 0.2000 0.6000 8.74
298.15 0.2000 0.8000 7.66
298.15 0.2000 1.0000 6.93
298.15 0.3000 0.0000 12.66
298.15 0.3000 0.2000 11.12
298.15 0.3000 0.4000 10.28
298.15 0.3000 0.6000 9.53
298.15 0.3000 0.8000 8.76
298.15 0.3000 1.0000 8.10
298.15 0.4000 0.0000 12.70
298.15 0.4000 0.2000 11.80
298.15 0.4000 0.4000 11.12
298.15 0.4000 0.6000 10.43
298.15 0.4000 0.8000 9.74
298.15 0.4000 1.0000 8.98
298.15 0.5000 0.0000 12.75
298.15 0.5000 0.2000 12.12
298.15 0.5000 0.4000 11.62
298.15 0.5000 0.6000 11.14
298.15 0.5000 0.8000 10.66
298.15 0.5000 1.0000 10.18
298.15 0.6500 0.0000 12.79
298.15 0.6500 0.2000 12.27
298.15 0.6500 0.4000 11.79
298.15 0.6500 0.6000 11.30
298.15 0.6500 0.8000 10.86
298.15 0.6500 1.0000 10.33
298.15 0.7500 0.0000 12.90
298.15 0.7500 0.2000 12.46
298.15 0.7500 0.4000 11.99
298.15 0.7500 0.6000 11.48
298.15 0.7500 0.8000 11.04
298.15 0.7500 1.0000 10.61
298.15 0.8500 0.0000 12.80
298.15 0.8500 0.2000 12.33
298.15 0.8500 0.4000 11.89
298.15 0.8500 0.6000 11.43
298.15 0.8500 0.8000 11.02
298.15 0.8500 1.0000 10.65
298.15 0.9500 0.0000 12.26
298.15 0.9500 0.2000 11.87
298.15 0.9500 0.4000 11.53
298.15 0.9500 0.6000 11.19
298.15 0.9500 0.8000 10.86
298.15 0.9500 1.0000 10.58
323.15 0.0200 0.0000 18.62
323.15 0.0200 0.2000 14.13
323.15 0.0200 0.4000 12.94
323.15 0.0200 0.6000 12.16
323.15 0.0200 0.8000 11.16
323.15 0.0200 1.0000 10.46
323.15 0.0500 0.0000 27.00
323.15 0.0500 0.2000 17.92
323.15 0.0500 0.4000 15.92
323.15 0.0500 0.6000 14.93
323.15 0.0500 0.8000 14.20
323.15 0.0500 1.0000 13.64
323.15 0.1000 0.0000 32.27
323.15 0.1000 0.2000 21.07
323.15 0.1000 0.4000 18.30
323.15 0.1000 0.6000 16.84
323.15 0.1000 0.8000 15.41
323.15 0.1000 1.0000 14.71
323.15 0.2000 0.0000 35.89
323.15 0.2000 0.2000 27.84
323.15 0.2000 0.4000 24.55
323.15 0.2000 0.6000 21.86
323.15 0.2000 0.8000 20.06
323.15 0.2000 1.0000 18.04
323.15 0.3000 0.0000 36.79
323.15 0.3000 0.2000 29.98
323.15 0.3000 0.4000 26.24
323.15 0.3000 0.6000 24.05
323.15 0.3000 0.8000 22.02
323.15 0.3000 1.0000 20.67
323.15 0.4000 0.0000 37.46
323.15 0.4000 0.2000 31.55
323.15 0.4000 0.4000 29.45
323.15 0.4000 0.6000 27.57
323.15 0.4000 0.8000 26.06
323.15 0.4000 1.0000 25.08
323.15 0.5000 0.0000 37.60
323.15 0.5000 0.2000 34.19
323.15 0.5000 0.4000 31.57
323.15 0.5000 0.6000 30.09
323.15 0.5000 0.8000 28.62
323.15 0.5000 1.0000 27.29
323.15 0.6500 0.0000 37.99
323.15 0.6500 0.2000 36.04
323.15 0.6500 0.4000 35.56
323.15 0.6500 0.6000 32.98
323.15 0.6500 0.8000 31.38
323.15 0.6500 1.0000 30.08
323.15 0.7500 0.0000 38.12
323.15 0.7500 0.2000 36.73
323.15 0.7500 0.4000 35.29
323.15 0.7500 0.6000 34.22
323.15 0.7500 0.8000 33.24
323.15 0.7500 1.0000 32.21
323.15 0.8500 0.0000 37.63
323.15 0.8500 0.2000 36.29
323.15 0.8500 0.4000 35.00
323.15 0.8500 0.6000 33.59
323.15 0.8500 0.8000 32.32
323.15 0.8500 1.0000 31.01
323.15 0.9500 0.0000 35.34
323.15 0.9500 0.2000 34.23
323.15 0.9500 0.4000 33.23
323.15 0.9500 0.6000 32.07
323.15 0.9500 0.8000 31.16
323.15 0.9500 1.0000 30.06

Sources