Mixture of Formic acid, butyl ester + Pentane, 1,5-dibromo-

Name: Formic acid, butyl ester
InChI: InChI=1S/C5H10O2/c1-2-3-4-7-5-6/h5H,2-4H2,1H3
InChI Key: NMJJFJNHVMGPGM-UHFFFAOYSA-N
Formula: C5H10O2
SMILES: CCCCOC=O
Mol. Weight (g/mol): 102.13
CAS: 592-84-7

Name: Pentane, 1,5-dibromo-
InChI: InChI=1S/C5H10Br2/c6-4-2-1-3-5-7/h1-5H2
InChI Key: IBODDUNKEPPBKW-UHFFFAOYSA-N
Formula: C5H10Br2
SMILES: BrCCCCCBr
Mol. Weight (g/mol): 229.94
CAS: 111-24-0

Cheméo is a service of Céondo GmbH, since 2007, we provide simulation, modelling and software development services for the industry. Do not hesitate to contact us for your projects.

Datasets

Excess molar enthalpy (molar enthalpy (2)
ρ_l - Mass density, kg/m3 (2)
Excess molar volume, m3/mol (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Pressure, kPa = 101 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0868	0.0970
0.1853	0.1650
0.2872	0.2220
0.3842	0.2500
0.4656	0.2530
0.5328	0.2420
0.5803	0.2330
0.6291	0.2180
0.7084	0.1870
0.7902	0.1390
0.8713	0.0900
0.9437	0.0470

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Pressure, kPa = 101 (Liquid)
Temperature, K = 298.15 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0868	0.0970
0.1853	0.1650
0.2872	0.2220
0.3842	0.2500
0.4656	0.2530
0.5328	0.2420
0.5803	0.2330
0.6291	0.2180
0.7084	0.1870
0.7902	0.1390
0.8713	0.0900
0.9437	0.0470

Mass density, kg/m3 [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
0.0756	1642.01
0.1366	1599.08
0.2027	1551.59
0.2682	1503.58
0.3259	1460.47
0.3871	1413.8
0.4492	1365.54
0.5143	1313.85
0.5679	1270.35
0.6274	1221.19
0.6870	1170.94
0.7958	1076.48
0.8434	1033.97
0.9499	936.18

Mass density, kg/m3 [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
0.0756	1642.01
0.1366	1599.08
0.2027	1551.59
0.2682	1503.58
0.3259	1460.47
0.3871	1413.8
0.4492	1365.54
0.5143	1313.85
0.5679	1270.35
0.6274	1221.19
0.6870	1170.94
0.7958	1076.48
0.8434	1033.97
0.9499	936.18

Excess molar volume, m3/mol [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0756	0.0000
0.1366	0.0000
0.2027	-0.0000
0.2682	-0.0000
0.3259	-1.4000e-08
0.3871	-1.9000e-08
0.4492	-2.6000e-08
0.5143	-3.1000e-08
0.5679	-3.3000e-08
0.6274	-3.4000e-08
0.6870	-3.5000e-08
0.7958	-3.0000e-08
0.8434	-2.6000e-08
0.9499	-1.5000e-08

Excess molar volume, m3/mol [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Formic acid, butyl ester (1) - Liquid	Excess molar volume, m3/mol - Liquid
0.0756	0.0000
0.1366	0.0000
0.2027	-0.0000
0.2682	-0.0000
0.3259	-1.4000e-08
0.3871	-1.9000e-08
0.4492	-2.6000e-08
0.5143	-3.1000e-08
0.5679	-3.3000e-08
0.6274	-3.4000e-08
0.6870	-3.5000e-08
0.7958	-3.0000e-08
0.8434	-2.6000e-08
0.9499	-1.5000e-08

Sources

Thermodynamic study of (alkyl esters + alpha,beta-alkyl dihalides) VI.H and V for 20 binary mixtures {xCu-1H2u-1CO2(CH2)3CH3 + (1 - x)alpha,omega-BrCH2(CH2)v-2CH2Br}, where u = 1 to 5, alpha = 1, and v = omega = 2 to 6