Mixture of Acetonitrile + Morpholine + Octane

Datasets

1. Mole fraction (8)

Mole fraction of Octane (3) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid mixture 1)
• Pressure, kPa = 10 (Liquid mixture 1)

Mole fraction of Acetonitrile (1) - Liquid mixture 2	Mole fraction of Octane (3) - Liquid mixture 2
0.9080	0.0261
0.4900	0.0840
0.7300	0.0451

Mole fraction of Acetonitrile (1) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid mixture 1)
• Pressure, kPa = 10 (Liquid mixture 1)

Mole fraction of Octane (3) - Liquid mixture 1	Mole fraction of Acetonitrile (1) - Liquid mixture 1
0.9180	0.0820
0.7000	0.0970
0.7840	0.0910

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Morpholine (2) - Liquid mixture 2	Mole fraction of Acetonitrile (1) - Liquid mixture 2	Mole fraction of Acetonitrile (1) - Liquid mixture 1	Mole fraction of Morpholine (2) - Liquid mixture 1
298.15	0.0888	0.8743	0.0746	0.0205
298.15	0.1351	0.8232	0.0799	0.0393
298.15	0.2130	0.7359	0.0859	0.0599
298.15	0.2632	0.6787	0.0895	0.0807
298.15	0.3332	0.5981	0.0945	0.1126
298.15	0.4061	0.5091	0.1019	0.1522
298.15	0.4658	0.4271	0.1081	0.1979
298.15	0.5176	0.3417	0.1131	0.2425
313.15	0.0855	0.8636	0.1083	0.0209
313.15	0.1318	0.8078	0.1165	0.0430
313.15	0.1654	0.7691	0.1217	0.0627
313.15	0.2228	0.6994	0.1310	0.0859
313.15	0.2975	0.6057	0.1553	0.1395
313.15	0.3378	0.5496	0.1591	0.1623
313.15	0.3791	0.4879	0.1706	0.1991
313.15	0.4226	0.4196	0.1779	0.2473

Mole fraction of Morpholine (2) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Acetonitrile (1) - Liquid mixture 1	Mole fraction of Morpholine (2) - Liquid mixture 1
298.15	0.0873	0.0733
298.15	0.1017	0.1269
298.15	0.1252	0.3583
298.15	0.1729	0.4902
298.15	0.2027	0.5214
298.15	0.3595	0.4970
313.15	0.1322	0.0730
313.15	0.1726	0.1897
313.15	0.2310	0.3689
313.15	0.3217	0.4286
313.15	0.4150	0.4273

Mole fraction of Octane (3) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid mixture 1)
• Pressure, kPa = 10 (Liquid mixture 1)

Mole fraction of Acetonitrile (1) - Liquid mixture 2	Mole fraction of Octane (3) - Liquid mixture 2
0.9080	0.0261
0.4900	0.0840
0.7300	0.0451

Mole fraction of Acetonitrile (1) [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid mixture 1)
• Pressure, kPa = 10 (Liquid mixture 1)

Mole fraction of Octane (3) - Liquid mixture 1	Mole fraction of Acetonitrile (1) - Liquid mixture 1
0.9180	0.0820
0.7000	0.0970
0.7840	0.0910

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Morpholine (2) - Liquid mixture 2	Mole fraction of Acetonitrile (1) - Liquid mixture 2	Mole fraction of Acetonitrile (1) - Liquid mixture 1	Mole fraction of Morpholine (2) - Liquid mixture 1
298.15	0.0888	0.8743	0.0746	0.0205
298.15	0.1351	0.8232	0.0799	0.0393
298.15	0.2130	0.7359	0.0859	0.0599
298.15	0.2632	0.6787	0.0895	0.0807
298.15	0.3332	0.5981	0.0945	0.1126
298.15	0.4061	0.5091	0.1019	0.1522
298.15	0.4658	0.4271	0.1081	0.1979
298.15	0.5176	0.3417	0.1131	0.2425
313.15	0.0855	0.8636	0.1083	0.0209
313.15	0.1318	0.8078	0.1165	0.0430
313.15	0.1654	0.7691	0.1217	0.0627
313.15	0.2228	0.6994	0.1310	0.0859
313.15	0.2975	0.6057	0.1553	0.1395
313.15	0.3378	0.5496	0.1591	0.1623
313.15	0.3791	0.4879	0.1706	0.1991
313.15	0.4226	0.4196	0.1779	0.2473

Mole fraction of Morpholine (2) [ref]

Operational condition: Pressure, kPa = 100 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Acetonitrile (1) - Liquid mixture 1	Mole fraction of Morpholine (2) - Liquid mixture 1
298.15	0.0873	0.0733
298.15	0.1017	0.1269
298.15	0.1252	0.3583
298.15	0.1729	0.4902
298.15	0.2027	0.5214
298.15	0.3595	0.4970
313.15	0.1322	0.0730
313.15	0.1726	0.1897
313.15	0.2310	0.3689
313.15	0.3217	0.4286
313.15	0.4150	0.4273

Sources

• Phase Equilibria in Systems of Morpholine, Acetonitrile, and n-Alkanes
• Liquid Liquid Equilibria for the Ternary Systems of 4-Methyl-1,3-dioxolan-2-one + 1,4-Dimethylbenzene + Octane, Decane, or Dodecane and the Ternary Systems of Acetonitrile + Morpholine + Octane, Decane, or Dodecane at 313.15 K or 298.15 K