Mixture of Carbon monoxide + Methyl formate

Datasets

1. Mole fraction (4)
2. P_vap - Vapor or sublimation pressure, kPa (2)
3. ρ_g - Mass density, kg/m3 (2)
4. ρ_l - Mass density, kg/m3 (2)

Mole fraction of Carbon monoxide (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa of Carbon monoxide (1) - Gas	Mole fraction of Carbon monoxide (1) - Liquid
299.72	243.00	0.0018
299.72	567.80	0.0034
299.72	1024.60	0.0063
299.72	1554.20	0.0098
299.72	2046.70	0.0130
299.72	2563.00	0.0165
299.72	3088.30	0.0197
322.82	435.60	0.0025
322.82	950.20	0.0062
322.82	1522.50	0.0101
322.82	2031.80	0.0136
322.82	2554.00	0.0177
322.82	3097.80	0.0213
347.88	664.90	0.0056
347.88	1033.20	0.0081
347.88	1434.50	0.0112
347.88	1933.30	0.0148
347.88	2474.50	0.0186
347.88	3027.40	0.0229
372.86	470.60	0.0038
372.86	805.50	0.0067
372.86	1189.50	0.0103
372.86	1678.70	0.0143
372.86	2205.20	0.0190
372.86	2747.00	0.0242

Mole fraction of Carbon monoxide (1) [ref]

Fixed		Measured
Mole fraction of Carbon monoxide (1) - Liquid	Temperature, K - Liquid	Mole fraction of Carbon monoxide (1) - Gas
0.0063	353.20	0.0103
0.0100	353.20	0.0112
0.0101	333.20	0.0123
0.0120	313.20	0.0132
0.0136	333.20	0.0140
0.0159	353.20	0.0169
0.0184	293.20	0.0192
0.0196	313.20	0.0189
0.0204	333.20	0.0208
0.0214	293.20	0.0215
0.0224	353.20	0.0259
0.0259	313.20	0.0267
0.0274	293.20	0.0252
0.0286	333.20	0.0332
0.0297	353.20	0.0346
0.0342	293.20	0.0356
0.0358	313.20	0.0391
0.0401	353.20	0.0493
0.0412	333.20	0.0455
0.0445	293.20	0.0482
0.0473	313.20	0.0548
0.0496	333.20	0.0603
0.0540	293.20	0.0613
0.0549	353.20	0.0736
0.0598	313.20	0.0742
0.0613	333.20	0.0826
0.0691	313.20	0.0941
0.0696	353.20	0.0984
0.0735	293.20	0.0943
0.0744	333.20	0.1043
0.0812	313.20	0.1112
0.0914	293.20	0.1161

Mole fraction of Carbon monoxide (1) [ref]

Fixed		Measured
Temperature, K - Liquid	Pressure, kPa of Carbon monoxide (1) - Gas	Mole fraction of Carbon monoxide (1) - Liquid
299.72	243.00	0.0018
299.72	567.80	0.0034
299.72	1024.60	0.0063
299.72	1554.20	0.0098
299.72	2046.70	0.0130
299.72	2563.00	0.0165
299.72	3088.30	0.0197
322.82	435.60	0.0025
322.82	950.20	0.0062
322.82	1522.50	0.0101
322.82	2031.80	0.0136
322.82	2554.00	0.0177
322.82	3097.80	0.0213
347.88	664.90	0.0056
347.88	1033.20	0.0081
347.88	1434.50	0.0112
347.88	1933.30	0.0148
347.88	2474.50	0.0186
347.88	3027.40	0.0229
372.86	470.60	0.0038
372.86	805.50	0.0067
372.86	1189.50	0.0103
372.86	1678.70	0.0143
372.86	2205.20	0.0190
372.86	2747.00	0.0242

Mole fraction of Carbon monoxide (1) [ref]

Fixed		Measured
Mole fraction of Carbon monoxide (1) - Liquid	Temperature, K - Liquid	Mole fraction of Carbon monoxide (1) - Gas
0.0063	353.20	0.0103
0.0100	353.20	0.0112
0.0101	333.20	0.0123
0.0120	313.20	0.0132
0.0136	333.20	0.0140
0.0159	353.20	0.0169
0.0184	293.20	0.0192
0.0196	313.20	0.0189
0.0204	333.20	0.0208
0.0214	293.20	0.0215
0.0224	353.20	0.0259
0.0259	313.20	0.0267
0.0274	293.20	0.0252
0.0286	333.20	0.0332
0.0297	353.20	0.0346
0.0342	293.20	0.0356
0.0358	313.20	0.0391
0.0401	353.20	0.0493
0.0412	333.20	0.0455
0.0445	293.20	0.0482
0.0473	313.20	0.0548
0.0496	333.20	0.0603
0.0540	293.20	0.0613
0.0549	353.20	0.0736
0.0598	313.20	0.0742
0.0613	333.20	0.0826
0.0691	313.20	0.0941
0.0696	353.20	0.0984
0.0735	293.20	0.0943
0.0744	333.20	0.1043
0.0812	313.20	0.1112
0.0914	293.20	0.1161

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Carbon monoxide (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0063	353.20	1890.00
0.0100	353.20	2710.00
0.0101	333.20	1780.00
0.0120	313.20	1650.00
0.0136	333.20	2630.00
0.0159	353.20	3650.00
0.0184	293.20	1760.00
0.0196	313.20	2850.00
0.0204	333.20	3560.00
0.0214	293.20	2500.00
0.0224	353.20	4430.00
0.0259	313.20	3730.00
0.0274	293.20	3150.00
0.0286	333.20	4660.00
0.0297	353.20	5210.00
0.0342	293.20	4080.00
0.0358	313.20	4810.00
0.0401	353.20	6360.00
0.0412	333.20	5740.00
0.0445	293.20	5100.00
0.0473	313.20	5950.00
0.0496	333.20	6580.00
0.0540	293.20	6060.00
0.0549	353.20	7750.00
0.0598	313.20	7100.00
0.0613	333.20	7790.00
0.0691	313.20	8060.00
0.0696	353.20	8980.00
0.0735	293.20	7830.00
0.0744	333.20	8860.00
0.0812	313.20	8960.00
0.0914	293.20	8950.00

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Carbon monoxide (1) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0063	353.20	1890.00
0.0100	353.20	2710.00
0.0101	333.20	1780.00
0.0120	313.20	1650.00
0.0136	333.20	2630.00
0.0159	353.20	3650.00
0.0184	293.20	1760.00
0.0196	313.20	2850.00
0.0204	333.20	3560.00
0.0214	293.20	2500.00
0.0224	353.20	4430.00
0.0259	313.20	3730.00
0.0274	293.20	3150.00
0.0286	333.20	4660.00
0.0297	353.20	5210.00
0.0342	293.20	4080.00
0.0358	313.20	4810.00
0.0401	353.20	6360.00
0.0412	333.20	5740.00
0.0445	293.20	5100.00
0.0473	313.20	5950.00
0.0496	333.20	6580.00
0.0540	293.20	6060.00
0.0549	353.20	7750.00
0.0598	313.20	7100.00
0.0613	333.20	7790.00
0.0691	313.20	8060.00
0.0696	353.20	8980.00
0.0735	293.20	7830.00
0.0744	333.20	8860.00
0.0812	313.20	8960.00
0.0914	293.20	8950.00

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Gas	Mole fraction of Carbon monoxide (1) - Liquid	Mass density, kg/m3 - Gas
293.20	0.0184	19.2
293.20	0.0214	21.5
293.20	0.0274	25.2
293.20	0.0342	35.6
293.20	0.0445	48.2
293.20	0.0540	61.3
293.20	0.0735	94.3
293.20	0.0914	116.1
313.20	0.0120	13.2
313.20	0.0196	18.9
313.20	0.0259	26.7
313.20	0.0358	39.1
313.20	0.0473	54.8
313.20	0.0598	74.2
313.20	0.0691	94.1
313.20	0.0812	111.2
333.20	0.0101	12.3
333.20	0.0136	14.0
333.20	0.0204	20.8
333.20	0.0286	33.2
333.20	0.0412	45.5
333.20	0.0496	60.3
333.20	0.0613	82.6
333.20	0.0744	104.3
353.20	0.0063	10.3
353.20	0.0100	11.2
353.20	0.0159	16.9
353.20	0.0224	25.9
353.20	0.0297	34.6
353.20	0.0401	49.3
353.20	0.0549	73.6
353.20	0.0696	98.4

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Gas	Mole fraction of Carbon monoxide (1) - Liquid	Mass density, kg/m3 - Gas
293.20	0.0184	19.2
293.20	0.0214	21.5
293.20	0.0274	25.2
293.20	0.0342	35.6
293.20	0.0445	48.2
293.20	0.0540	61.3
293.20	0.0735	94.3
293.20	0.0914	116.1
313.20	0.0120	13.2
313.20	0.0196	18.9
313.20	0.0259	26.7
313.20	0.0358	39.1
313.20	0.0473	54.8
313.20	0.0598	74.2
313.20	0.0691	94.1
313.20	0.0812	111.2
333.20	0.0101	12.3
333.20	0.0136	14.0
333.20	0.0204	20.8
333.20	0.0286	33.2
333.20	0.0412	45.5
333.20	0.0496	60.3
333.20	0.0613	82.6
333.20	0.0744	104.3
353.20	0.0063	10.3
353.20	0.0100	11.2
353.20	0.0159	16.9
353.20	0.0224	25.9
353.20	0.0297	34.6
353.20	0.0401	49.3
353.20	0.0549	73.6
353.20	0.0696	98.4

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Carbon monoxide (1) - Liquid	Mass density, kg/m3 - Liquid
293.20	0.0184	976.3
293.20	0.0214	976.1
293.20	0.0274	974.9
293.20	0.0342	971.3
293.20	0.0445	964.7
293.20	0.0540	954.7
293.20	0.0735	932.5
293.20	0.0914	911.2
313.20	0.0120	972.1
313.20	0.0196	971.5
313.20	0.0259	969.3
313.20	0.0358	962.4
313.20	0.0473	950.8
313.20	0.0598	937.3
313.20	0.0691	924.7
313.20	0.0812	904.3
333.20	0.0101	969.2
333.20	0.0136	968.7
333.20	0.0204	967.6
333.20	0.0286	960.7
333.20	0.0412	947.8
333.20	0.0496	937.5
333.20	0.0613	923.0
333.20	0.0744	901.3
353.20	0.0063	964.6
353.20	0.0100	964.2
353.20	0.0159	963.2
353.20	0.0224	956.8
353.20	0.0297	948.7
353.20	0.0401	935.3
353.20	0.0549	916.8
353.20	0.0696	895.8

Mass density, kg/m3 [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Carbon monoxide (1) - Liquid	Mass density, kg/m3 - Liquid
293.20	0.0184	976.3
293.20	0.0214	976.1
293.20	0.0274	974.9
293.20	0.0342	971.3
293.20	0.0445	964.7
293.20	0.0540	954.7
293.20	0.0735	932.5
293.20	0.0914	911.2
313.20	0.0120	972.1
313.20	0.0196	971.5
313.20	0.0259	969.3
313.20	0.0358	962.4
313.20	0.0473	950.8
313.20	0.0598	937.3
313.20	0.0691	924.7
313.20	0.0812	904.3
333.20	0.0101	969.2
333.20	0.0136	968.7
333.20	0.0204	967.6
333.20	0.0286	960.7
333.20	0.0412	947.8
333.20	0.0496	937.5
333.20	0.0613	923.0
333.20	0.0744	901.3
353.20	0.0063	964.6
353.20	0.0100	964.2
353.20	0.0159	963.2
353.20	0.0224	956.8
353.20	0.0297	948.7
353.20	0.0401	935.3
353.20	0.0549	916.8
353.20	0.0696	895.8

Sources

• Solubility of Carbon Monoxide and Hydrogen in Methanol and Methyl Formate: 298-373 K and 0.3-3.3 MPa
• Experiments and Correlations of the Vapor Liquid Equilibria for Carbon Monoxide + Propionic Acid and Carbon Monoxide + Methyl Formate Systems