Mixture of Zinc Chloride + Formic acid + 1,4-Dioxane

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Zinc Chloride

Name
Zinc Chloride
InChI
InChI=1S/2ClH.Zn/h2*1H;/q;;+2/p-2
InChI Key
JIAARYAFYJHUJI-UHFFFAOYSA-L
Formula
Cl2Zn
SMILES
Cl[Zn]Cl
Mol. Weight (g/mol)
136.29
CAS
7646-85-7

Formic acid

Name
Formic acid
InChI
InChI=1S/CH2O2/c2-1-3/h1H,(H,2,3)
InChI Key
BDAGIHXWWSANSR-UHFFFAOYSA-N
Formula
CH2O2
SMILES
O=CO
Mol. Weight (g/mol)
46.03
CAS
64-18-6

1,4-Dioxane

Name
1,4-Dioxane
InChI
InChI=1S/C4H8O2/c1-2-6-4-3-5-1/h1-4H2
InChI Key
RYHBNJHYFVUHQT-UHFFFAOYSA-N
Formula
C4H8O2
SMILES
C1COCCO1
Mol. Weight (g/mol)
88.11
CAS
123-91-1
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Datasets

  1. Excess molar enthalpy (molar enthalpy (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Fixed Measured
Mole fraction of 1,4-Dioxane (3) - Liquid Mole fraction of Zinc Chloride (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0570 0.0354 -0.1430
0.1170 0.0572 -0.4125
0.1190 0.0290 -0.3326
0.2250 0.0211 -0.6960
0.2260 0.0420 -1.007
0.3020 0.0160 -0.9780
0.3020 0.0308 -1.372
0.3820 0.0221 -1.667
0.3860 0.0117 -1.269
0.4750 0.0081 -1.475
0.4760 0.0148 -1.763
0.5850 0.0091 -1.546
0.5890 0.0051 -1.495
0.7030 0.0026 -1.248
0.7040 0.0057 -1.138
0.7720 0.0015 -0.9740
0.7730 0.0025 -0.8430
0.8310 0.0007 -0.6630
0.8320 0.0013 -0.5900
0.9160 0.0001 -0.2760
0.9180 0.0002 -0.2660

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Fixed Measured
Mole fraction of 1,4-Dioxane (3) - Liquid Mole fraction of Zinc Chloride (1) - Liquid Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0570 0.0354 -0.1430
0.1170 0.0572 -0.4125
0.1190 0.0290 -0.3326
0.2250 0.0211 -0.6960
0.2260 0.0420 -1.007
0.3020 0.0160 -0.9780
0.3020 0.0308 -1.372
0.3820 0.0221 -1.667
0.3860 0.0117 -1.269
0.4750 0.0081 -1.475
0.4760 0.0148 -1.763
0.5850 0.0091 -1.546
0.5890 0.0051 -1.495
0.7030 0.0026 -1.248
0.7040 0.0057 -1.138
0.7720 0.0015 -0.9740
0.7730 0.0025 -0.8430
0.8310 0.0007 -0.6630
0.8320 0.0013 -0.5900
0.9160 0.0001 -0.2760
0.9180 0.0002 -0.2660

Sources