Chemical Properties of 1-Butanamine (CAS 109-73-9)

1-Butanamine

InChI
InChI=1S/C4H11N/c1-2-3-4-5/h2-5H2,1H3
InChI Key
HQABUPZFAYXKJW-UHFFFAOYSA-N
Formula
C4H11N
SMILES
CCCCN
Molecular Weight1
73.14
CAS
109-73-9
Other Names
  • 1-AMINOBUTANE
  • 1-Amino-butaan
  • 1-Aminobutan
  • 1-Butylamine
  • BUTYLAMINE
  • Butanamine
  • Mono-n-butylamine
  • Monobutilamina
  • Monobutylamine
  • N-Butylamin
  • NORVALAMINE
  • NSC 8029
  • Norralamine
  • UN 1125
  • n-Butilamina
  • n-Butylamine
  • n-C4H9NH2
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Physical Properties

Property Value Unit Source
ω 0.3290 KDB
PAff 921.50 kJ/mol NIST
Tig 585.37 K KDB
BasG 886.60 kJ/mol NIST
Δcliquid [-3018.50; -2984.00] kJ/mol Show Hide
Δcliquid -3018.50 ± 1.10 kJ/mol NIST
Δcliquid -2984.00 kJ/mol NIST
Δcsolid -3018.00 kJ/mol NIST
μ 1.30 debye KDB
η [0.0004760; 0.0004930] Pa×s Show Hide
η 0.0004760 Pa×s A volumetric and viscosity study for the binary mixtures of 1-hexyl-3-methylimidazolium tetrafluoroborate with some molecular solvents
η 0.0004930 Pa×s Excess Molar Volumes and Viscosity Deviations of Binary Liquid Mixtures of 1,3-Dioxolane and 1,4-Dioxane with Butyl Acetate, Butyric Acid, Butylamine, and 2-Butanone at 298.15 K
LFL 1.70 % in Air KDB
UFL 9.80 % in Air KDB
Tflash,cc 272.04 K KDB
Tflash,oc 260.93 K KDB
Δf 49.24 kJ/mol KDB
Δfgas [-149.30; -92.11] kJ/mol Show Hide
Δfgas -92.11 kJ/mol KDB
Δfgas -95.00 ± 2.00 kJ/mol NIST
Δfgas -149.30 kJ/mol NIST
Δfliquid [-182.00; -127.70] kJ/mol Show Hide
Δfliquid -127.70 ± 1.20 kJ/mol NIST
Δfliquid -182.00 kJ/mol NIST
Δfus 11.31 kJ/mol Joback Calculated Property
Δvap 32.11 kJ/mol Relay (1.0) Calculated Property
IE [8.70; 9.40] eV Show Hide
IE 8.73 ± 0.04 eV NIST
IE 8.70 eV NIST
IE 8.79 eV NIST
IE 8.71 ± 0.03 eV NIST
IE 9.40 eV NIST
log10WS -0.37 Relay (1.0) Calculated Property
logPoct/wat 0.745 Crippen Calculated Property
McVol 77.200 ml/mol McGowan Calculated Property
NFPA Fire 3 KDB
NFPA Health 2 KDB
Pc [4154.33; 4250.00] kPa Show Hide
Pc 4250.00 kPa KDB
Pc 4200.00 ± 41.96 kPa NIST
Pc 4154.33 ± 1.50 kPa NIST
Inp [608.00; 629.00]   Show Hide
Inp 609.40 NIST
Inp 609.40 NIST
Inp 610.00 NIST
Inp 629.00 NIST
Inp 629.00 NIST
Inp 621.00 NIST
Inp 619.00 NIST
Inp 617.00 NIST
Inp 614.00 NIST
Inp 608.00 NIST
Inp 626.00 NIST
Inp 626.00 NIST
Inp 628.00 NIST
Inp 628.00 NIST
Inp 628.00 NIST
Inp 627.00 NIST
I [886.00; 918.00]   Show Hide
I 896.00 NIST
I 890.00 NIST
I 918.00 NIST
I 912.00 NIST
I 886.00 NIST
I 904.00 NIST
I 908.00 NIST
Tboil [350.00; 350.15] K Show Hide
Tboil 350.15 K KDB
Tboil 350.00 K Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Tc [524.00; 531.90] K Show Hide
Tc 531.90 K KDB
Tc 524.00 K NIST
Tc 531.90 ± 0.53 K NIST
Tc 524.15 ± 1.50 K NIST
Tfus [222.65; 224.05] K Show Hide
Tfus 224.05 K KDB
Tfus 224.00 ± 0.10 K NIST
Tfus 224.05 K NIST
Tfus 222.65 ± 0.50 K NIST
Vc 0.277 m3/kmol KDB
Vm 9.99e-05 m3/mol Thermodynamic study of (heptane + amine) mixtures. II. Excess and partial molar volumes at 298.15 K
Zc 0.2661960 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [138.68; 185.91] J/mol×K [363.45; 545.13] Show Hide
Cp,gas 138.68 J/mol×K 363.45 Joback Calculated Property
Cp,gas 147.36 J/mol×K 393.73 Joback Calculated Property
Cp,gas 155.70 J/mol×K 424.01 Joback Calculated Property
Cp,gas 163.72 J/mol×K 454.29 Joback Calculated Property
Cp,gas 171.42 J/mol×K 484.57 Joback Calculated Property
Cp,gas 178.82 J/mol×K 514.85 Joback Calculated Property
Cp,gas 185.91 J/mol×K 545.13 Joback Calculated Property
Cp,liquid 188.00 J/mol×K 298.15 NIST
η [0.0003600; 0.0005250] Pa×s [293.15; 323.15] Show Hide
η 0.0005250 Pa×s 293.15 Relative Permittivity, Viscosity, and Speed of Sound for 2-Methoxyethanol + Butylamine Mixtures
η 0.0004960 Pa×s 298.15 Relative Permittivity, Viscosity, and Speed of Sound for 2-Methoxyethanol + Butylamine Mixtures
η 0.0004440 Pa×s 303.15 Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
η 0.0004670 Pa×s 303.15 Relative Permittivity, Viscosity, and Speed of Sound for 2-Methoxyethanol + Butylamine Mixtures
η 0.0004600 Pa×s 303.15 Density and Viscosity Measurement of n-Butylamine with Hexyl Alcohol Isomer Binary Systems
η 0.0003930 Pa×s 313.15 Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
η 0.0004000 Pa×s 313.15 Density and Viscosity Measurement of n-Butylamine with Hexyl Alcohol Isomer Binary Systems
η 0.0003600 Pa×s 323.15 Density and Viscosity Measurement of n-Butylamine with Hexyl Alcohol Isomer Binary Systems
ΔvapH [31.10; 35.50] kJ/mol [313.00; 358.00] Show Hide
ΔvapH 34.70 ± 0.10 kJ/mol 313.00 NIST
ΔvapH 35.20 kJ/mol 320.50 NIST
ΔvapH 35.50 kJ/mol 322.50 NIST
ΔvapH 33.50 ± 0.10 kJ/mol 323.00 NIST
ΔvapH 34.70 kJ/mol 331.50 NIST
ΔvapH 32.40 ± 0.10 kJ/mol 343.00 NIST
ΔvapH 32.09 kJ/mol 350.10 KDB
ΔvapH 31.81 kJ/mol 350.20 NIST
ΔvapH 31.10 ± 0.10 kJ/mol 358.00 NIST
Pvap [19.99; 101.33] kPa [308.30; 350.00] Show Hide
Pvap 19.99 kPa 308.30 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 26.66 kPa 314.70 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 33.33 kPa 319.90 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 46.66 kPa 328.20 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 59.99 kPa 334.80 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 66.66 kPa 337.90 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 86.66 kPa 345.10 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
Pvap 101.33 kPa 350.00 Evolution of the Liquid Vapor Equilibrium Properties of Several Unsymmetrical Amines: Determination of Their Binary Isobaric Diagrams and Applications to the Distillation
ρl [709.21; 741.72] kg/m3 [288.15; 323.15] Show Hide
ρl 741.72 kg/m3 288.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 739.00 kg/m3 293.00 KDB
ρl 737.12 kg/m3 293.15 Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl 737.05 kg/m3 293.15 Thermodynamics of amide + amine mixtures. 1. Volumetric, speed of sound, and refractive index data for N,Ndimethylformamide + N-propylpropan-1-amine, + N-butylbutan-1-amine, + butan-1-amine, or + hexan-1-amine systems at several temperatures
ρl 736.95 kg/m3 293.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 733.33 kg/m3 298.15 Excess Molar Properties for Binary Systems of CnMIM-BF4 Ionic Liquids with Alkylamines in the Temperature Range (298.15 to 318.15) K. Experimental Results and Theoretical Model Calculations
ρl 734.65 kg/m3 298.15 Volumetric properties for binary and ternary systems consist of 1-chlorobutane, n-butylamine and isobutanol at 298.15 K with application of the Prigogine-Flory-Patterson theory and ERAS-Model
ρl 732.15 kg/m3 298.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 732.33 kg/m3 298.15 Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl 732.23 kg/m3 298.15 Thermodynamics of amide + amine mixtures. 1. Volumetric, speed of sound, and refractive index data for N,Ndimethylformamide + N-propylpropan-1-amine, + N-butylbutan-1-amine, + butan-1-amine, or + hexan-1-amine systems at several temperatures
ρl 733.30 kg/m3 298.15 Volumetric, acoustic, viscometric, and spectroscopic properties for binary properties for binary mixtures of alkoxypropanol with mono, di-, and tri- alkylamines at a temperature of 298.15K
ρl 733.33 kg/m3 298.15 Binary mixtures of ([C4mim][NTf2] + molecular organic solvents): Thermophysical, acoustic and transport properties at various compositions and temperatures
ρl 732.18 kg/m3 298.15 Thermodynamics of amide + amine mixtures. 5. Excess molar enthalpies of N,N-dimethylformamide or N,N-dimethylacetamide + N-propylpropan-1-amine, + N-butylbutan-1-amine, + butan-1-amine, or + hexan-1-amine systems at 298.15 K. Application of the ERAS model
ρl 728.50 kg/m3 303.15 Binary mixtures of ([C4mim][NTf2] + molecular organic solvents): Thermophysical, acoustic and transport properties at various compositions and temperatures
ρl 727.45 kg/m3 303.15 Thermodynamics of amide + amine mixtures. 1. Volumetric, speed of sound, and refractive index data for N,Ndimethylformamide + N-propylpropan-1-amine, + N-butylbutan-1-amine, + butan-1-amine, or + hexan-1-amine systems at several temperatures
ρl 727.34 kg/m3 303.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 727.51 kg/m3 303.15 Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl 728.65 kg/m3 303.15 Studies of partial molar volumes of alkylamine in non-electrolyte solvents I. Alkylamines in hydrocarbons at 303.15 and 313.15K
ρl 728.65 kg/m3 303.15 Studies of viscosities of dilute solutions of alkylamines in non-electrolyte solvents III. Alkylamines in butanols 303.15K
ρl 723.67 kg/m3 308.15 Binary mixtures of ([C4mim][NTf2] + molecular organic solvents): Thermophysical, acoustic and transport properties at various compositions and temperatures
ρl 722.66 kg/m3 308.15 Volumetric properties of binary mixtures of (acetonitrile + amines) at several temperatures with application of the ERAS model
ρl 723.67 kg/m3 308.15 Excess Molar Properties for Binary Systems of CnMIM-BF4 Ionic Liquids with Alkylamines in the Temperature Range (298.15 to 318.15) K. Experimental Results and Theoretical Model Calculations
ρl 719.17 kg/m3 313.15 Studies of partial molar volumes of alkylamine in non-electrolyte solvents I. Alkylamines in hydrocarbons at 303.15 and 313.15K
ρl 718.66 kg/m3 313.15 Binary mixtures of ([C4mim][NTf2] + molecular organic solvents): Thermophysical, acoustic and transport properties at various compositions and temperatures
ρl 714.10 kg/m3 318.15 Binary mixtures of ([C4mim][NTf2] + molecular organic solvents): Thermophysical, acoustic and transport properties at various compositions and temperatures
ρl 714.00 kg/m3 318.15 Excess Molar Properties for Binary Systems of CnMIM-BF4 Ionic Liquids with Alkylamines in the Temperature Range (298.15 to 318.15) K. Experimental Results and Theoretical Model Calculations
ρl 709.21 kg/m3 323.15 Binary mixtures of ([C4mim][NTf2] + molecular organic solvents): Thermophysical, acoustic and transport properties at various compositions and temperatures
csound,fluid [1205.72; 1296.08] m/s [288.15; 308.15] Show Hide
csound,fluid 1296.08 m/s 288.15 Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1296.08 m/s 288.15 Densities, Excess Molar Volumes, Speeds of Sound, and Isothermal Compressibilities for 2-(2-Hexyloxyethoxy)ethanol + n-Alkylamine at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1273.56 m/s 293.15 Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1273.56 m/s 293.15 Densities, Excess Molar Volumes, Speeds of Sound, and Isothermal Compressibilities for 2-(2-Hexyloxyethoxy)ethanol + n-Alkylamine at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1249.96 m/s 298.15 Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1249.96 m/s 298.15 Densities, Excess Molar Volumes, Speeds of Sound, and Isothermal Compressibilities for 2-(2-Hexyloxyethoxy)ethanol + n-Alkylamine at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1228.92 m/s 303.15 Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1228.92 m/s 303.15 Densities, Excess Molar Volumes, Speeds of Sound, and Isothermal Compressibilities for 2-(2-Hexyloxyethoxy)ethanol + n-Alkylamine at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1205.72 m/s 308.15 Volumetric and Acoustic Properties for Binary Mixtures of Dipropylene Glycol Monopropyl Ether with Alkylamines at Temperatures Between 288.15 K and 308.15 K
csound,fluid 1205.72 m/s 308.15 Densities, Excess Molar Volumes, Speeds of Sound, and Isothermal Compressibilities for 2-(2-Hexyloxyethoxy)ethanol + n-Alkylamine at Temperatures Between 288.15 K and 308.15 K
γ 0.02 N/m 293.20 KDB

Datasets

Viscosity, Pa*s

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
303.15 101.33 0.0004
Reference

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 202.63] kPa [258.47; 373.87] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.45389e+01
Coefficient B-3.02088e+03
Coefficient C-4.64950e+01
Temperature range, min.258.47
Temperature range, max.373.87
Pvap 1.33 kPa 258.47 Calculated Property
Pvap 3.01 kPa 271.29 Calculated Property
Pvap 6.21 kPa 284.11 Calculated Property
Pvap 11.90 kPa 296.94 Calculated Property
Pvap 21.42 kPa 309.76 Calculated Property
Pvap 36.49 kPa 322.58 Calculated Property
Pvap 59.31 kPa 335.40 Calculated Property
Pvap 92.49 kPa 348.23 Calculated Property
Pvap 139.10 kPa 361.05 Calculated Property
Pvap 202.63 kPa 373.87 Calculated Property
Pvap [0.08; 4205.44] kPa [224.05; 531.90] KDB Vapor Pressure Data Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A5.84534e+01
Coefficient B-6.04187e+03
Coefficient C-6.30480e+00
Coefficient D2.90389e-06
Temperature range, min.224.05
Temperature range, max.531.90
Pvap 0.08 kPa 224.05 Calculated Property
Pvap 1.27 kPa 258.26 Calculated Property
Pvap 9.42 kPa 292.46 Calculated Property
Pvap 43.36 kPa 326.67 Calculated Property
Pvap 143.05 kPa 360.87 Calculated Property
Pvap 371.25 kPa 395.08 Calculated Property
Pvap 807.37 kPa 429.28 Calculated Property
Pvap 1537.32 kPa 463.49 Calculated Property
Pvap 2644.55 kPa 497.69 Calculated Property
Pvap 4205.44 kPa 531.90 Calculated Property

Similar Compounds

1,4-Butanediamine. 1-Pentanamine. 1-Hexanamine. 1,5-Pentanediamine. 1-Heptanamine. 1-Octanamine. 1-Decanamine. 1-Dodecanamine. 1-Octadecanamine. 1-Hexadecanamine. 1-Nonanamine. Pentadecylamine. 1-Tetradecanamine. 1-Undecanamine. 1-Heptadecanamine.

Find more compounds similar to 1-Butanamine.

Mixtures

Find more mixtures with 1-Butanamine.

Sources

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