Chemical Properties of Dicyclopentadiene (CAS 77-73-6)

Dicyclopentadiene

InChI
InChI=1S/C10H12/c1-2-9-7-4-5-8(6-7)10(9)3-1/h1-2,4-5,7-10H,3,6H2/t7?,8?,9-,10+/m1/s1
InChI Key
HECLRDQVFMWTQS-BMNUFHGDSA-N
Formula
C10H12
SMILES
C1=CC2C3C=CC(C3)C2C1
Molecular Weight1
132.20
CAS
77-73-6
Other Names
  • 3a,4,7,7a-Tetrahydro-4,7-methano-1H-indene
  • 3a,4,7,7a-tetrahydro-4,7-methanoindene
  • 4,7-Methano-1H-indene, 3a,4,7,7a-tetrahydro-
  • 4,7-Methanoindene, 3a,4,7,7a-tetrahydro-
  • 4,7-methano-3a,4,7,7a-tetrahydro-1H-indene
  • Bicyclopentadiene
  • Bis[cyclopentadiene]
  • Cyclopentadiene dimer
  • Tricyclo[5.2.1.0
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Physical Properties

Property Value Unit Source
ω [0.2880; 0.3484]   Show Hide
ω 0.3484 PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω 0.2880 ChemSep v8.3 pure component data Compiled value
ΔfG° 375.00 kJ/mol ChemSep v8.3 pure component data Compiled value
ΔfH°gas 196.10 kJ/mol ChemSep v8.3 pure component data Compiled value
ΔfusH° 17.48 kJ/mol Joback Calculated Property
ΔvapH° 50.66 kJ/mol Relay (1.0) Calculated Property
IE 8.79 ± 0.05 eV NIST
logPoct/wat 2.385 Crippen Calculated Property
McVol 110.580 ml/mol McGowan Calculated Property
Pc [3060.00; 3755.11] kPa Show Hide
Pc 3755.11 kPa PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc 3060.00 kPa ChemSep v8.3 pure component data Compiled value
Ptriple 0.57 kPa ChemSep v8.3 pure component data Compiled value
Inp [993.30; 1047.30]   Show Hide
Inp 1007.00 NIST
Inp 1002.00 NIST
Inp Outlier 1043.00 NIST
Inp 1014.00 NIST
Inp Outlier 1047.30 NIST
Inp 993.30 NIST
Inp 1004.30 NIST
Inp 1014.00 NIST
Inp 1018.00 NIST
Inp 1000.00 NIST
Inp 1014.00 NIST
Inp 1011.00 NIST
Inp 1018.00 NIST
Inp 1018.00 NIST
Inp 1000.00 NIST
Inp 1007.00 NIST
Inp 993.30 NIST
Tboil [359.20; 443.20] K Show Hide
Tboil 443.00 K ChemSep v8.3 pure component data Compiled value
Tboil 443.20 K NIST
Tboil 359.20 ± 50.00 K NIST
Tc [660.00; 665.00] K Show Hide
Tc 665.00 K PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc 660.00 K ChemSep v8.3 pure component data Compiled value
Tfus [305.00; 306.80] K Show Hide
Tfus 305.15 K Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus 305.15 K ChemSep v8.3 pure component data Compiled value
Tfus 306.80 ± 0.50 K NIST
Tfus 305.00 ± 4.00 K NIST
Ttriple [304.80; 305.15] K Show Hide
Ttriple 305.15 K ChemSep v8.3 pure component data Compiled value
Ttriple 304.80 ± 0.20 K NIST
UQi 4.55 ChemSep v8.3 pure component data Compiled value
URi 5.82 ChemSep v8.3 pure component data Compiled value
Vc [0.445; 0.450] m3/kmol Show Hide
Vc 0.450 m3/kmol PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc 0.445 m3/kmol ChemSep v8.3 pure component data Compiled value
Zc 0.2480000 ChemSep v8.3 pure component data Compiled value

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Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ΔvapH 42.40 kJ/mol 373.50 NIST
n0 [1.49910; 1.50690]   [308.15; 323.15] Show Hide
n0 1.50690 308.15 Solubilities of Diethyl Phthalate, Dicyclopentadiene, and Styrene in Ionic Liquid 1-Ethyl-3-methylimidazolium Acetate
n0 1.50450 313.15 Solubilities of Diethyl Phthalate, Dicyclopentadiene, and Styrene in Ionic Liquid 1-Ethyl-3-methylimidazolium Acetate
n0 1.50190 318.15 Solubilities of Diethyl Phthalate, Dicyclopentadiene, and Styrene in Ionic Liquid 1-Ethyl-3-methylimidazolium Acetate
n0 1.49910 323.15 Solubilities of Diethyl Phthalate, Dicyclopentadiene, and Styrene in Ionic Liquid 1-Ethyl-3-methylimidazolium Acetate

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [138.67; 467.40] J/mol×K [273.00; 1500.15] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,gas in J/mol×K, T in K
Coefficient A3.87350e+01
Coefficient B-5.35990e+02
Coefficient C6.64524e+00
Coefficient D-3.12770e-04
Coefficient E1.07500e-07
Temperature range, min.273.00
Temperature range, max.1500.15
Cp,gas 138.67 J/mol×K 273.00 Calculated Property
Cp,gas 224.76 J/mol×K 409.35 Calculated Property
Cp,gas 289.46 J/mol×K 545.70 Calculated Property
Cp,gas 336.43 J/mol×K 682.05 Calculated Property
Cp,gas 371.14 J/mol×K 818.40 Calculated Property
Cp,gas 397.70 J/mol×K 954.75 Calculated Property
Cp,gas 418.94 J/mol×K 1091.10 Calculated Property
Cp,gas 436.81 J/mol×K 1227.45 Calculated Property
Cp,gas 452.63 J/mol×K 1363.80 Calculated Property
Cp,gas 467.40 J/mol×K 1500.15 Calculated Property
Property Value Unit Temperature (K) Source
Cp,liquid [195.62; 299.81] J/mol×K [226.76; 443.15] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is Cp,liquid in J/mol×K, T in K
Coefficient A8.39370e+01
Coefficient B-3.92220e+02
Coefficient C6.97824e+00
Coefficient D-3.11380e-03
Coefficient E3.36800e-06
Temperature range, min.226.76
Temperature range, max.443.15
Cp,liquid 195.62 J/mol×K 226.76 Calculated Property
Cp,liquid 211.08 J/mol×K 250.80 Calculated Property
Cp,liquid 225.08 J/mol×K 274.85 Calculated Property
Cp,liquid 237.82 J/mol×K 298.89 Calculated Property
Cp,liquid 249.50 J/mol×K 322.93 Calculated Property
Cp,liquid 260.37 J/mol×K 346.98 Calculated Property
Cp,liquid 270.63 J/mol×K 371.02 Calculated Property
Cp,liquid 280.49 J/mol×K 395.06 Calculated Property
Cp,liquid 290.16 J/mol×K 419.11 Calculated Property
Cp,liquid 299.81 J/mol×K 443.15 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0054295; 0.0001456] Pa×s [210.00; 528.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-1.16330e+01
Coefficient B1.27280e+03
Coefficient C6.76760e-02
Coefficient D-1.29990e-07
Coefficient E2.00000e+00
Temperature range, min.210.00
Temperature range, max.528.00
η 0.0054295 Pa×s 210.00 Calculated Property
η 0.0022873 Pa×s 245.33 Calculated Property
η 0.0011983 Pa×s 280.67 Calculated Property
η 0.0007255 Pa×s 316.00 Calculated Property
η 0.0004859 Pa×s 351.33 Calculated Property
η 0.0003500 Pa×s 386.67 Calculated Property
η 0.0002663 Pa×s 422.00 Calculated Property
η 0.0002112 Pa×s 457.33 Calculated Property
η 0.0001731 Pa×s 492.67 Calculated Property
η 0.0001456 Pa×s 528.00 Calculated Property
Property Value Unit Temperature (K) Source
ΔvapH [48.53; 14.64] kJ/mol [215.37; 641.32] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc
Y is ΔvapH in kJ/mol, T in K
Coefficient A7.05430e+01
Coefficient B1.98670e+00
Coefficient C-4.65450e+00
Coefficient D5.17720e+00
Coefficient E-2.08310e+00
Critical temperature, Tc (K)6.60000e+02
Temperature range, min.215.37
Temperature range, max.641.32
ΔvapH 48.53 kJ/mol 215.37 Calculated Property
ΔvapH 46.46 kJ/mol 262.70 Calculated Property
ΔvapH 44.49 kJ/mol 310.03 Calculated Property
ΔvapH 42.38 kJ/mol 357.35 Calculated Property
ΔvapH 39.94 kJ/mol 404.68 Calculated Property
ΔvapH 37.03 kJ/mol 452.01 Calculated Property
ΔvapH 33.52 kJ/mol 499.34 Calculated Property
ΔvapH 29.25 kJ/mol 546.66 Calculated Property
ΔvapH 23.76 kJ/mol 593.99 Calculated Property
ΔvapH 14.64 kJ/mol 641.32 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [7.21e-03; 3050.43] kPa [243.37; 660.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is Pvap in kPa, T in K
Coefficient A6.54072e+01
Coefficient B-7.29283e+03
Coefficient C-7.38829e+00
Coefficient D3.74690e-06
Coefficient E2.00000e+00
Temperature range, min.243.37
Temperature range, max.660.00
Pvap 7.21e-03 kPa 243.37 Calculated Property
Pvap 0.26 kPa 289.66 Calculated Property
Pvap 3.14 kPa 335.95 Calculated Property
Pvap 19.00 kPa 382.25 Calculated Property
Pvap 73.81 kPa 428.54 Calculated Property
Pvap 212.61 kPa 474.83 Calculated Property
Pvap 497.32 kPa 521.12 Calculated Property
Pvap 1003.25 kPa 567.42 Calculated Property
Pvap 1818.76 kPa 613.71 Calculated Property
Pvap 3050.43 kPa 660.00 Calculated Property
Pvap [0.13; 101.53] kPa [280.15; 443.00] KDB Vapor Pressure Data Show Hide
Equationln(Y) = A + B/T + C·ln(T) + D·T² + E/T²
Y is Pvap in kPa, T in K
Coefficient A-6.47025e+01
Coefficient B-2.32780e+03
Coefficient C1.28698e+01
Coefficient D-1.95969e-05
Coefficient E0.00000e+00
Temperature range, min.280.15
Temperature range, max.443.00
Pvap 0.13 kPa 280.15 Calculated Property
Pvap 0.40 kPa 298.24 Calculated Property
Pvap 1.07 kPa 316.34 Calculated Property
Pvap 2.59 kPa 334.43 Calculated Property
Pvap 5.71 kPa 352.53 Calculated Property
Pvap 11.62 kPa 370.62 Calculated Property
Pvap 21.96 kPa 388.72 Calculated Property
Pvap 38.82 kPa 406.81 Calculated Property
Pvap 64.56 kPa 424.91 Calculated Property
Pvap 101.53 kPa 443.00 Calculated Property
Property Value Unit Temperature (K) Source
ρl [977.63; 431.57] kg/m3 [299.82; 641.32] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A / B^(1 + (1 − T/C)^D)
Y is ρl in kg/m3, T in K
Coefficient A5.53914e+01
Coefficient B2.05390e-01
Coefficient C6.60000e+02
Coefficient D3.40530e-01
Temperature range, min.299.82
Temperature range, max.641.32
ρl 977.63 kg/m3 299.82 Calculated Property
ρl 931.90 kg/m3 337.76 Calculated Property
ρl 884.87 kg/m3 375.71 Calculated Property
ρl 836.20 kg/m3 413.65 Calculated Property
ρl 785.42 kg/m3 451.60 Calculated Property
ρl 731.80 kg/m3 489.54 Calculated Property
ρl 674.16 kg/m3 527.49 Calculated Property
ρl 610.36 kg/m3 565.43 Calculated Property
ρl 535.47 kg/m3 603.38 Calculated Property
ρl 431.57 kg/m3 641.32 Calculated Property
Property Value Unit Temperature (K) Source
γ [0.03; 1.02e-04] N/m [289.37; 641.32] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is γ in N/m, T in K
Coefficient A-3.67070e-03
Coefficient B-1.11230e+02
Coefficient C-2.54190e+00
Coefficient D1.15650e-03
Coefficient E-8.76840e-06
Temperature range, min.289.37
Temperature range, max.641.32
γ 0.03 N/m 289.37 Calculated Property
γ 0.03 N/m 328.48 Calculated Property
γ 0.02 N/m 367.58 Calculated Property
γ 0.02 N/m 406.69 Calculated Property
γ 0.01 N/m 445.79 Calculated Property
γ 0.01 N/m 484.90 Calculated Property
γ 0.01 N/m 524.00 Calculated Property
γ 0.00 N/m 563.11 Calculated Property
γ 0.00 N/m 602.21 Calculated Property
γ 1.02e-04 N/m 641.32 Calculated Property
Property Value Unit Temperature (K) Source
λgas [0.01; 0.08] W/m×K [305.15; 1000.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A·T^B / (1 + C/T + D/T²)
Y is λgas in W/m×K, T in K
Coefficient A2.58780e-04
Coefficient B8.60400e-01
Coefficient C5.11400e+01
Coefficient D2.44020e+05
Temperature range, min.305.15
Temperature range, max.1000.00
λgas 0.01 W/m×K 305.15 Calculated Property
λgas 0.02 W/m×K 382.36 Calculated Property
λgas 0.02 W/m×K 459.56 Calculated Property
λgas 0.03 W/m×K 536.77 Calculated Property
λgas 0.04 W/m×K 613.97 Calculated Property
λgas 0.05 W/m×K 691.18 Calculated Property
λgas 0.05 W/m×K 768.38 Calculated Property
λgas 0.06 W/m×K 845.59 Calculated Property
λgas 0.07 W/m×K 922.79 Calculated Property
λgas 0.08 W/m×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
λliquid [0.15; 0.11] W/m×K [215.37; 443.00] ChemSep v8.3 pure component data Compiled value Show Hide
EquationY = A + exp(B/T + C + D·T + E·T²)
Y is λliquid in W/m×K, T in K
Coefficient A2.98480e-02
Coefficient B4.71780e+01
Coefficient C-2.53630e+00
Coefficient D2.35720e-03
Coefficient E-5.88930e-06
Temperature range, min.215.37
Temperature range, max.443.00
λliquid 0.15 W/m×K 215.37 Calculated Property
λliquid 0.15 W/m×K 240.66 Calculated Property
λliquid 0.15 W/m×K 265.95 Calculated Property
λliquid 0.14 W/m×K 291.25 Calculated Property
λliquid 0.14 W/m×K 316.54 Calculated Property
λliquid 0.13 W/m×K 341.83 Calculated Property
λliquid 0.13 W/m×K 367.12 Calculated Property
λliquid 0.12 W/m×K 392.42 Calculated Property
λliquid 0.11 W/m×K 417.71 Calculated Property
λliquid 0.11 W/m×K 443.00 Calculated Property

Similar Compounds

(3a«alpha»,4«alpha»,7«alpha»,7a«alpha»)-3a,4,7,7a-tetrahydro-4,7-methano-1H-indene. Dicyclopentadiene, exo. endo-Dicyclopentadiene. Dicyclopentadiene (endo). exo-1H-Indene, 3a,4,7,7a-tetrahydro-4,7-ethano. endo-1H-Indene, 3a,4,7,7a-tetrahydro, 4,7-ethano. Tetra-cyclopentadiene. Dl 3,3'-bis(cyclopentenyl). 3,3'-Bicyclopentenyl. Endo-5-vinylbicyclo[2.2.1]hept-2-ene. Exo-5-vinylbicyclo[2.2.1]hept-2-ene. Bicyclo[2.2.1]hept-2-ene, 5-ethenyl-. 5-Vinyl-2-norbornene (endo). Exo-5-vinylbicyclo[2.2.1]hept-2-ene. Di-cyclohexadiene.

Find more compounds similar to Dicyclopentadiene.

Sources

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