Chemical Properties of 1,3-Propanediamine, N-methyl- (CAS 6291-84-5)

InChI

InChI=1S/C4H12N2/c1-6-4-2-3-5/h6H,2-5H2,1H3

InChI Key

QHJABUZHRJTCAR-UHFFFAOYSA-N

Formula

C4H12N2

SMILES

CNCCCN

Molecular Weight¹

88.15

CAS

6291-84-5

Other Names

• (3-Aminopropyl)methylamine
• 1,3-Propanediamine, N1-methyl-
• 1-Amino-3-(methylamino)propane
• 3-Methylaminopropylamine
• 3-amino-1-(methylamino)propane
• N-Methyl-1,3-propanediamine
• N-methyl-1,3-diaminopropane
• N-methyl-1,3-propylenediamine
• N-methyltrimethylenediamine
• NSC 8160

• ω : Acentric Factor.
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[175.61; 227.44]	J/mol×K	[413.62; 600.57]
Cp,gas	175.61	J/mol×K	413.62	Joback Calculated Property
Cp,gas	185.23	J/mol×K	444.78	Joback Calculated Property
Cp,gas	194.44	J/mol×K	475.94	Joback Calculated Property
Cp,gas	203.25	J/mol×K	507.09	Joback Calculated Property
Cp,gas	211.69	J/mol×K	538.25	Joback Calculated Property
Cp,gas	219.74	J/mol×K	569.41	Joback Calculated Property
Cp,gas	227.44	J/mol×K	600.57	Joback Calculated Property
Cp,liquid	[243.50; 250.20]	J/mol×K	[303.15; 353.15]
Cp,liquid	243.50	J/mol×K	303.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	244.30	J/mol×K	308.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	244.40	J/mol×K	313.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	244.60	J/mol×K	318.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	245.10	J/mol×K	323.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	245.40	J/mol×K	328.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	246.00	J/mol×K	333.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	246.60	J/mol×K	338.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	247.70	J/mol×K	343.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	248.50	J/mol×K	348.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
Cp,liquid	250.20	J/mol×K	353.15	Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
ΔvapH	[45.90; 53.10]	kJ/mol	[298.15; 370.00]
ΔvapH	53.10	kJ/mol	298.15	Vapor pressure and enthalpy of vaporization of aliphatic propanediamines
ΔvapH	45.90	kJ/mol	370.00	NIST
Pvap	[0.09; 170.02]	kPa	[273.00; 432.40]
Pvap	0.09	kPa	273.00	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.09	kPa	273.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.20	kPa	283.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.20	kPa	283.37	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.43	kPa	293.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.43	kPa	293.47	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.86	kPa	303.11	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	0.85	kPa	303.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	1.59	kPa	313.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	1.61	kPa	313.18	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	2.81	kPa	323.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	2.83	kPa	323.26	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	2.83	kPa	323.26	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	3.46	kPa	326.81	Ebulliometric Determination of Vapor
Pvap	4.47	kPa	331.62	Ebulliometric Determination of Vapor
Pvap	4.75	kPa	333.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	4.76	kPa	333.23	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	4.76	kPa	333.25	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	5.97	kPa	337.36	Ebulliometric Determination of Vapor
Pvap	7.72	kPa	343.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	7.75	kPa	343.26	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	7.74	kPa	343.28	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	7.74	kPa	343.30	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	7.97	kPa	343.91	Ebulliometric Determination of Vapor
Pvap	11.85	kPa	352.54	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	11.85	kPa	352.54	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	12.08	kPa	353.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	12.14	kPa	353.24	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	12.48	kPa	353.78	Ebulliometric Determination of Vapor
Pvap	18.10	kPa	362.82	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	18.11	kPa	362.84	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	18.31	kPa	363.15	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	20.47	kPa	365.76	Ebulliometric Determination of Vapor
Pvap	26.61	kPa	372.74	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	26.61	kPa	372.76	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	27.96	kPa	372.77	Ebulliometric Determination of Vapor
Pvap	38.34	kPa	382.84	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	38.35	kPa	382.87	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	39.97	kPa	383.53	Ebulliometric Determination of Vapor
Pvap	53.96	kPa	392.92	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	53.96	kPa	392.95	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	64.98	kPa	397.99	Ebulliometric Determination of Vapor
Pvap	73.40	kPa	402.59	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	73.40	kPa	402.59	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	73.41	kPa	402.61	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	79.98	kPa	404.70	Ebulliometric Determination of Vapor
Pvap	101.27	kPa	412.50	Ebulliometric Determination of Vapor
Pvap	129.79	kPa	422.46	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	129.80	kPa	422.46	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	129.84	kPa	422.51	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	169.97	kPa	432.40	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
Pvap	170.02	kPa	432.40	Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
ρl	[787.72; 860.46]	kg/m3	[283.15; 363.15]
ρl	860.46	kg/m3	283.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	851.61	kg/m3	293.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	848.00	kg/m3	298.15	Study of CO2 Absorption into Phase Change Solvents MAPA and DEEA
ρl	849.10	kg/m3	303.15	Mutual diffusion coefficients, density, and viscosity of aqueoussolutions of new polyamine CO2absorbents
ρl	842.69	kg/m3	303.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	844.70	kg/m3	308.15	Mutual diffusion coefficients, density, and viscosity of aqueoussolutions of new polyamine CO2absorbents
ρl	833.72	kg/m3	313.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	840.30	kg/m3	313.15	Mutual diffusion coefficients, density, and viscosity of aqueoussolutions of new polyamine CO2absorbents
ρl	835.90	kg/m3	318.15	Mutual diffusion coefficients, density, and viscosity of aqueoussolutions of new polyamine CO2absorbents
ρl	831.50	kg/m3	323.15	Mutual diffusion coefficients, density, and viscosity of aqueoussolutions of new polyamine CO2absorbents
ρl	824.67	kg/m3	323.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	815.56	kg/m3	333.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	806.37	kg/m3	343.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	797.09	kg/m3	353.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
ρl	787.72	kg/m3	363.15	Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K

Similar Compounds

Find more compounds similar to 1,3-Propanediamine, N-methyl-.

Mixtures

• 1,3-Propanediamine, N-methyl- + Water
• 1-Propanol, 3-(dimethylamino)- + 1,3-Propanediamine, N-methyl- + Water
• 1,3-Propanediamine, N-methyl- + N-«beta»-Hydroxyethylpyrrolidine + Water
• 1-Propanol, 3-(diethylamino)- + 1,3-Propanediamine, N-methyl- + Water
• Piperazine + 1,3-Propanediamine, N-methyl- + Water
• 1,3-Propanediamine, N-methyl- + Methyldiethanolamine
• 1,3-Propanediamine, N-methyl- + N,N-Diethyl-2-aminoethanol
• 1,3-Propanediamine, N-methyl- + N,N-Dimethylaminoethanol
• 1,3-Propanediamine, N-methyl- + Methyldiethanolamine + Water
• 1,3-Propanediamine, N-methyl- + N-Methylglycine + Water
• 1,3-Propanediamine, N-methyl- + N,N-Diethyl-2-aminoethanol + Water
• Carbon dioxide + 1,3-Propanediamine, N-methyl- + Water

Sources

• Cheméo Relay (1.0)
• Crippen Method
• Crippen Method
• Mutual diffusion coefficients, density, and viscosity of aqueoussolutions of new polyamine CO2absorbents
• Density, viscosity, and N2O solubility of aqueous amino acid salt and amine amino acid salt solutions
• Vapor pressure and enthalpy of vaporization of aliphatic propanediamines
• Phase equilibrium measurements and thermodynamic modeling of aqueous solutions of polyamines CO2 absorbents: 3-aminopropylmethylamine, 3-aminopropyldimethylamine and N,N-diethyl 1,3-propanediamine at temperatures from 273 K to 363 K
• Vapour-liquid equilibrium study of tertiary amines, single and in blend with 3-(methylamino)propylamine, for post-combustion CO2 capture
• Molar heat capacities of diethylenetriamine and 3-(methylamino)propylamine, their aqueous binaries, and aqueous ternaries with piperazine
• Study of CO2 Absorption into Phase Change Solvents MAPA and DEEA
• Freezing Point Depressions of Phase Change CO2 Solvents
• Volumetric Properties of Binary Mixtures of 3-(Methylamino)propylamine with Water, N-Methyldiethanolamine, N,N-Dimethylethanolamine, and N,N-Diethylethanolamine from (283.15 to 363.15) K
• Equilibrium Total Pressure and CO2 Solubility in Binary and Ternary Aqueous Solutions of 2-(Diethylamino)ethanol (DEEA) and 3-(Methylamino)propylamine (MAPA)
• Ebulliometric Determination of Vapor
• Joback Method
• McGowan Method
• NIST Webbook

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