Chemical Properties of sec-Butylamine (CAS 13952-84-6)

sec-Butylamine

InChI
InChI=1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3
InChI Key
BHRZNVHARXXAHW-UHFFFAOYSA-N
Formula
C4H11N
SMILES
CCC(C)N
Molecular Weight1
73.14
CAS
13952-84-6
Other Names
  • (.+/-.)-sec-Butylamine
  • (RS)-2-aminobutane
  • (RS)-sec-butylamine
  • 1-Methylpropanamine
  • 1-Methylpropylamine
  • 1-methyl-1-propanamine
  • 2-AB
  • 2-Aminobutane base
  • 2-Butanamine, (.+/-.)-
  • 2-Butylamine
  • 2-aminobutane
  • 2-butanamine
  • Butafume
  • Deccotane
  • Frucote
  • NSC 8030
  • Propylamine, 1-Methyl-
  • Secondary butylamine
  • Tutane
  • sec-Butanamine
  • sec-C4H9NH2
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Physical Properties

Property Value Unit Source
ω 0.2998 PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
PAff 929.70 kJ/mol NIST
BasG 895.70 kJ/mol NIST
ΔcH°liquid [-3008.60; -2979.00] kJ/mol Show Hide
ΔcH°liquid -3008.60 ± 0.92 kJ/mol NIST
ΔcH°liquid -2979.00 kJ/mol NIST
ΔfG° 46.81 kJ/mol Joback Calculated Property
ΔfH°gas [-155.50; -106.00] kJ/mol Show Hide
ΔfH°gas -106.00 ± 2.00 kJ/mol NIST
ΔfH°gas -155.50 kJ/mol NIST
ΔfH°liquid [-187.00; -137.50] kJ/mol Show Hide
ΔfH°liquid -137.50 ± 1.00 kJ/mol NIST
ΔfH°liquid -187.00 kJ/mol NIST
ΔfusH° 7.79 kJ/mol Joback Calculated Property
ΔvapH° [31.00; 32.70] kJ/mol Show Hide
ΔvapH° 32.70 ± 0.10 kJ/mol NIST
ΔvapH° 32.60 ± 0.10 kJ/mol NIST
ΔvapH° 32.64 ± 0.06 kJ/mol NIST
ΔvapH° 31.00 ± 1.00 kJ/mol NIST
ΔvapH° 31.50 kJ/mol NIST
IE [8.50; 8.70] eV Show Hide
IE 8.50 ± 0.10 eV NIST
IE 8.70 eV NIST
log10WS -0.41 Relay (1.0) Calculated Property
logPoct/wat 0.744 Crippen Calculated Property
McVol 77.200 ml/mol McGowan Calculated Property
Pc [3969.99; 5000.00] kPa Show Hide
Pc 5000.00 kPa IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 9 Compiled value
Pc 3969.99 kPa PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc 4200.00 kPa KDB
Pc 5000.00 ± 499.79 kPa NIST
Inp [471.00; 527.00]   Show Hide
Inp 471.00 NIST
Inp 527.00 NIST
Inp 517.00 NIST
Inp 515.00 NIST
Inp 471.00 NIST
Inp 471.00 NIST
Inp 471.00 NIST
Ip [815.00; 864.00]   Show Hide
Ip 826.00 NIST
Ip 821.00 NIST
Ip 825.00 NIST
Ip 815.00 NIST
Ip 816.00 NIST
Ip Outlier 864.00 NIST
Tboil [335.88; 336.70] K Show Hide
Tboil 335.88 K KDB
Tboil Outlier 336.70 K NIST
Tboil 336.00 K NIST
Tboil 336.15 ± 1.50 K NIST
Tboil 336.15 ± 2.00 K NIST
Tboil 336.15 ± 2.00 K NIST
Tc [511.00; 514.30] K Show Hide
Tc 514.00 K IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 9 Compiled value
Tc 511.00 K PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc 514.30 K KDB
Tc 514.30 ± 0.51 K NIST
Tfus [168.60; 169.15] K Show Hide
Tfus 169.15 K Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus 168.60 K KDB
Tfus 168.65 ± 0.60 K NIST
Vc [0.278; 0.282] m3/kmol Show Hide
Vc 0.282 m3/kmol PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc 0.278 m3/kmol KDB
Vm 1.02e-04 m3/mol Thermodynamic study of (heptane + amine) mixtures. II. Excess and partial molar volumes at 298.15 K
Zc 0.2730490 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
ΔvapH [29.40; 34.10] kJ/mol [313.00; 343.00] Show Hide
ΔvapH 31.60 ± 0.10 kJ/mol 313.00 NIST
ΔvapH 34.10 kJ/mol 317.50 NIST
ΔvapH 32.40 kJ/mol 317.50 NIST
ΔvapH 30.50 ± 0.10 kJ/mol 328.00 NIST
ΔvapH 29.40 ± 0.10 kJ/mol 343.00 NIST
Pvap [6.80; 232.69] kPa [274.06; 363.15] Show Hide
Pvap 6.81 kPa 274.06 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 6.80 kPa 274.09 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 11.46 kPa 283.91 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 18.43 kPa 293.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 19.21 kPa 293.88 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 19.21 kPa 293.88 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 29.11 kPa 303.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 30.03 kPa 303.84 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 30.04 kPa 303.84 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 44.25 kPa 313.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 45.47 kPa 313.81 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 45.38 kPa 313.81 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 65.05 kPa 323.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 66.77 kPa 323.92 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 92.82 kPa 333.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 95.10 kPa 333.91 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 95.08 kPa 333.91 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 95.07 kPa 333.91 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 128.99 kPa 343.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 132.05 kPa 343.86 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 132.05 kPa 343.86 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 132.08 kPa 343.86 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 175.09 kPa 353.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 179.16 kPa 353.90 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 178.99 kPa 353.90 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
Pvap 232.69 kPa 363.15 Experimental determination of the isothermal (vapour + liquid) equilibria of binary aqueous solutions of sec-butylamine and cyclohexylamine at several temperatures
ρl [712.73; 727.87] kg/m3 [288.15; 303.15] Show Hide
ρl 727.87 kg/m3 288.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 722.86 kg/m3 293.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 717.81 kg/m3 298.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 712.73 kg/m3 303.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa

Datasets

Mass density, kg/m3

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
293.15 100.00 725.3
293.15 10000.00 733.6
293.15 20000.00 741.2
293.15 30000.00 748.1
293.15 40000.00 754.5
293.15 50000.00 760.4
293.15 60000.00 766.1
293.15 70000.00 771.3
293.15 80000.00 776.3
293.15 90000.00 781.1
293.15 100000.00 785.5
293.15 110000.00 789.7
293.15 120000.00 793.9
293.15 130000.00 797.8
293.15 140000.00 801.5
303.15 100.00 715.1
303.15 10000.00 724.3
303.15 20000.00 732.4
303.15 30000.00 739.7
303.15 40000.00 746.3
303.15 50000.00 752.5
303.15 60000.00 758.3
303.15 70000.00 763.7
303.15 80000.00 768.9
303.15 90000.00 773.8
303.15 100000.00 778.4
303.15 110000.00 782.9
303.15 120000.00 787.2
303.15 130000.00 791.2
303.15 140000.00 795.2
313.15 100.00 705.0
313.15 10000.00 714.8
313.15 20000.00 723.4
313.15 30000.00 731.1
313.15 40000.00 738.2
313.15 50000.00 744.7
313.15 60000.00 750.8
313.15 70000.00 756.5
313.15 80000.00 761.9
313.15 90000.00 767.0
313.15 100000.00 771.8
313.15 110000.00 776.4
313.15 120000.00 780.8
313.15 130000.00 785.1
313.15 140000.00 789.1
323.15 100.00 694.7
323.15 10000.00 705.4
323.15 20000.00 714.5
323.15 30000.00 722.8
323.15 40000.00 730.4
323.15 50000.00 737.2
323.15 60000.00 743.6
323.15 70000.00 749.5
323.15 80000.00 755.2
323.15 90000.00 760.4
323.15 100000.00 765.4
323.15 110000.00 770.2
323.15 120000.00 774.7
323.15 130000.00 779.0
323.15 140000.00 783.2
333.15 10000.00 695.4
333.15 20000.00 705.2
333.15 30000.00 714.0
333.15 40000.00 722.0
333.15 50000.00 729.2
333.15 60000.00 735.8
333.15 70000.00 742.1
333.15 80000.00 748.0
333.15 90000.00 753.4
333.15 100000.00 758.6
333.15 110000.00 763.5
333.15 120000.00 768.1
333.15 130000.00 772.5
333.15 140000.00 776.9
343.15 10000.00 685.9
343.15 20000.00 696.6
343.15 30000.00 706.0
343.15 40000.00 714.3
343.15 50000.00 721.9
343.15 60000.00 728.8
343.15 70000.00 735.3
343.15 80000.00 741.3
343.15 90000.00 747.1
343.15 100000.00 752.4
343.15 110000.00 757.4
343.15 120000.00 762.3
343.15 130000.00 767.0
343.15 140000.00 771.3
353.15 10000.00 675.8
353.15 20000.00 687.1
353.15 30000.00 697.2
353.15 40000.00 705.8
353.15 50000.00 714.0
353.15 60000.00 721.2
353.15 70000.00 728.0
353.15 80000.00 734.2
353.15 90000.00 740.1
353.15 100000.00 745.7
353.15 110000.00 751.0
353.15 120000.00 756.0
353.15 130000.00 760.7
353.15 140000.00 765.3
363.15 10000.00 665.7
363.15 20000.00 678.0
363.15 30000.00 688.5
363.15 40000.00 697.8
363.15 50000.00 706.2
363.15 60000.00 713.9
363.15 70000.00 721.0
363.15 80000.00 727.5
363.15 90000.00 733.6
363.15 100000.00 739.4
363.15 110000.00 744.8
363.15 120000.00 749.9
363.15 130000.00 754.8
363.15 140000.00 759.5
373.15 10000.00 655.5
373.15 20000.00 668.9
373.15 30000.00 680.1
373.15 40000.00 690.0
373.15 50000.00 698.2
373.15 60000.00 707.0
373.15 70000.00 714.0
373.15 80000.00 720.9
373.15 90000.00 727.2
373.15 100000.00 733.2
373.15 110000.00 738.7
373.15 120000.00 744.0
373.15 130000.00 749.1
373.15 140000.00 753.9
383.15 10000.00 645.5
383.15 20000.00 659.9
383.15 30000.00 671.9
383.15 40000.00 682.3
383.15 50000.00 691.4
383.15 60000.00 699.6
383.15 70000.00 707.3
383.15 80000.00 714.4
383.15 90000.00 720.8
383.15 100000.00 726.9
383.15 110000.00 732.7
383.15 120000.00 738.2
383.15 130000.00 743.3
383.15 140000.00 748.2
393.15 10000.00 634.9
393.15 20000.00 650.5
393.15 30000.00 663.1
393.15 40000.00 674.3
393.15 50000.00 684.3
393.15 60000.00 693.0
393.15 70000.00 700.9
393.15 80000.00 708.2
393.15 90000.00 714.9
393.15 100000.00 721.2
393.15 110000.00 727.2
393.15 120000.00 732.8
393.15 130000.00 738.1
393.15 140000.00 742.9
403.15 10000.00 623.9
403.15 20000.00 640.6
403.15 30000.00 654.5
403.15 40000.00 666.1
403.15 50000.00 676.3
403.15 60000.00 685.3
403.15 70000.00 693.6
403.15 80000.00 701.1
403.15 90000.00 708.2
403.15 100000.00 714.9
403.15 110000.00 721.1
403.15 120000.00 726.9
403.15 130000.00 732.3
403.15 140000.00 737.4
Reference

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [110.40; 262.20] J/mol×K [273.00; 1000.00] Joback Predicted correlation Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,gas in J/mol×K, T in K
Coefficient A4.06100e+00
Coefficient B4.51640e-01
Coefficient C-2.40400e-04
Coefficient D4.69000e-08
Coefficient E0.00000e+00
Temperature range, min.273.00
Temperature range, max.1000.00
Cp,gas 110.40 J/mol×K 273.00 Calculated Property
Cp,gas 135.83 J/mol×K 353.78 Calculated Property
Cp,gas 158.78 J/mol×K 434.56 Calculated Property
Cp,gas 179.38 J/mol×K 515.33 Calculated Property
Cp,gas 197.80 J/mol×K 596.11 Calculated Property
Cp,gas 214.17 J/mol×K 676.89 Calculated Property
Cp,gas 228.65 J/mol×K 757.67 Calculated Property
Cp,gas 241.38 J/mol×K 838.44 Calculated Property
Cp,gas 252.52 J/mol×K 919.22 Calculated Property
Cp,gas 262.20 J/mol×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 202.66] kPa [250.70; 357.25] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.55051e+01
Coefficient B-3.28970e+03
Coefficient C-3.45250e+01
Temperature range, min.250.70
Temperature range, max.357.25
Pvap 1.33 kPa 250.70 Calculated Property
Pvap 2.94 kPa 262.54 Calculated Property
Pvap 5.99 kPa 274.38 Calculated Property
Pvap 11.41 kPa 286.22 Calculated Property
Pvap 20.53 kPa 298.06 Calculated Property
Pvap 35.11 kPa 309.89 Calculated Property
Pvap 57.46 kPa 321.73 Calculated Property
Pvap 90.42 kPa 333.57 Calculated Property
Pvap 137.47 kPa 345.41 Calculated Property
Pvap 202.66 kPa 357.25 Calculated Property
Pvap [4.04e-04; 3922.51] kPa [168.65; 514.30] KDB Vapor Pressure Data Show Hide
Equationln(Y) = A + B/T + C·ln(T) + D·T² + E/T²
Y is Pvap in kPa, T in K
Coefficient A5.75882e+01
Coefficient B-5.56943e+03
Coefficient C-6.33708e+00
Coefficient D4.07040e-06
Coefficient E0.00000e+00
Temperature range, min.168.65
Temperature range, max.514.30
Pvap 4.04e-04 kPa 168.65 Calculated Property
Pvap 0.05 kPa 207.06 Calculated Property
Pvap 1.31 kPa 245.46 Calculated Property
Pvap 12.20 kPa 283.87 Calculated Property
Pvap 62.18 kPa 322.27 Calculated Property
Pvap 213.47 kPa 360.68 Calculated Property
Pvap 559.50 kPa 399.08 Calculated Property
Pvap 1212.77 kPa 437.49 Calculated Property
Pvap 2292.93 kPa 475.89 Calculated Property
Pvap 3922.51 kPa 514.30 Calculated Property
Property Value Unit Temperature (K) Source
γ [0.03; 0.02] N/m [169.15; 336.15] Jasper (1972), surface tension of pure liquid compounds Compiled value Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is γ in N/m, T in K
Coefficient A5.26220e-02
Coefficient B-1.05700e-04
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Temperature range, min.169.15
Temperature range, max.336.15
γ 0.03 N/m 169.15 Calculated Property
γ 0.03 N/m 187.71 Calculated Property
γ 0.03 N/m 206.26 Calculated Property
γ 0.03 N/m 224.82 Calculated Property
γ 0.03 N/m 243.37 Calculated Property
γ 0.02 N/m 261.93 Calculated Property
γ 0.02 N/m 280.48 Calculated Property
γ 0.02 N/m 299.04 Calculated Property
γ 0.02 N/m 317.59 Calculated Property
γ 0.02 N/m 336.15 Calculated Property

Similar Compounds

2-Butanamine, (S)-. (R)-sec-butylamine. 3-Pentanamine. 2-Pentanamine. CYCLOBUTYLAMINE. 1,3-BUTANEDIAMINE. 2-Butanamine, 3-methyl-. 3-Hexanamine. .beta.-Aminobutyronitrile. 2-Hexanamine. 4-Aminoheptane. (+)-2-Aminoheptane. Tuaminoheptane. 1-Methyldodecylamine. 2-Octanamine, (.+/-.)-.

Find more compounds similar to sec-Butylamine.

Mixtures

Sources

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