Chemical Properties of Triphenylmethane (CAS 519-73-3)

Triphenylmethane

InChI
InChI=1S/C19H16/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H
InChI Key
AAAQKTZKLRYKHR-UHFFFAOYSA-N
Formula
C19H16
SMILES
c1ccc(C(c2ccccc2)c2ccccc2)cc1
Molecular Weight1
244.33
CAS
519-73-3
Other Names
  • 1,1',1''-Methylidynetris[benzene]
  • 1,1',1''-methylidynetrisbenzene
  • Benzene,1,1',1"-methylidynetris-
  • benzene, 1,1',1''-methylidynetris-
  • methane, triphenyl-
  • tritane
Cheméo is a service of Céondo GmbH, since 2007, we provide simulation, modelling and software development services for the industry. Do not hesitate to contact us for your projects.

Physical Properties

Property Value Unit Source
ω 0.4490 Relay (1.0) Calculated Property
ΔcH°solid [-9934.50; -9926.20] kJ/mol Show Hide
ΔcH°solid -9934.50 ± 1.30 kJ/mol NIST
ΔcH°solid -9926.20 ± 4.00 kJ/mol NIST
ΔfG° 443.89 kJ/mol Joback Calculated Property
ΔfH°gas 276.10 ± 5.00 kJ/mol NIST
ΔfH°solid [162.90; 167.70] kJ/mol Show Hide
ΔfH°solid 167.70 ± 4.10 kJ/mol NIST
ΔfH°solid 162.90 ± 4.00 kJ/mol NIST
ΔfusH° 23.57 kJ/mol Joback Calculated Property
ΔsubH° [100.70; 112.00] kJ/mol Show Hide
ΔsubH° 108.40 ± 2.80 kJ/mol NIST
ΔsubH° 109.10 ± 0.60 kJ/mol NIST
ΔsubH° 112.00 kJ/mol NIST
ΔsubH° 100.70 kJ/mol NIST
ΔsubH° 105.00 ± 0.80 kJ/mol NIST
ΔvapH° [93.20; 95.00] kJ/mol Show Hide
ΔvapH° 93.20 ± 2.20 kJ/mol NIST
ΔvapH° 94.60 kJ/mol NIST
ΔvapH° 95.00 kJ/mol NIST
IE [8.34; 8.40] eV Show Hide
IE 8.34 ± 0.03 eV NIST
IE 8.34 ± 0.04 eV NIST
IE 8.40 ± 0.05 eV NIST
log10WS -6.24 Relay (1.0) Calculated Property
logPoct/wat 4.867 Crippen Calculated Property
McVol 207.290 ml/mol McGowan Calculated Property
Pc 2400.57 kPa Joback Calculated Property
Inp [327.80; 1997.00]   Show Hide
Inp 1978.00 NIST
Inp 1982.00 NIST
Inp 1997.00 NIST
Inp 327.80 NIST
Inp 1982.00 NIST
Inp 1997.00 NIST
Inp 327.80 NIST
S°gas 541.00 J/mol×K NIST
S°solid,1 bar 312.10 J/mol×K NIST
Tboil [449.00; 632.00] K Show Hide
Tboil 449.00 ± 2.00 K NIST
Tboil 632.00 ± 1.00 K NIST
Tboil 632.00 ± 6.00 K NIST
Tboil 632.00 ± 1.00 K NIST
Tc 901.64 K Relay (1.0) Calculated Property
Tfus [361.00; 367.80] K Show Hide
Tfus 364.40 ± 3.00 K NIST
Tfus 365.70 ± 3.00 K NIST
Tfus 367.80 ± 3.00 K NIST
Tfus 366.40 ± 1.00 K NIST
Tfus 365.00 ± 6.00 K NIST
Tfus Outlier 361.00 ± 6.00 K NIST
Tfus Outlier 362.00 ± 7.00 K NIST
Tfus 363.00 ± 4.00 K NIST
Tfus 365.00 ± 4.00 K NIST
Tfus 365.70 ± 1.50 K NIST
Tfus 365.50 ± 1.00 K NIST
Tfus 365.20 ± 1.00 K NIST
Tfus 365.20 ± 0.50 K NIST
Tfus 365.00 ± 3.00 K NIST
Tfus 366.40 ± 1.50 K NIST
Tfus 365.60 ± 0.20 K NIST
Tfus 363.00 ± 2.00 K NIST
Tfus 365.00 ± 4.00 K NIST
Tfus 365.30 ± 0.20 K NIST
Tfus 366.00 ± 2.00 K NIST
Tfus 365.30 ± 1.00 K NIST
Tfus 366.85 ± 0.30 K NIST
Tfus 366.25 ± 0.20 K NIST
Tfus 365.50 ± 0.60 K NIST
Tfus 365.00 ± 0.10 K NIST
Tfus 365.99 ± 0.50 K NIST
Vc 0.746 m3/kmol Relay (1.0) Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,liquid [420.00; 659.00] J/mol×K [370.00; 600.00] Show Hide
Cp,liquid 420.00 J/mol×K 370.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 454.00 J/mol×K 373.00 NIST
Cp,liquid 429.00 J/mol×K 380.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 439.00 J/mol×K 390.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 448.00 J/mol×K 400.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 458.00 J/mol×K 410.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 468.00 J/mol×K 420.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 477.00 J/mol×K 430.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 487.00 J/mol×K 440.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 497.00 J/mol×K 450.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 507.00 J/mol×K 460.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 518.00 J/mol×K 470.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 528.00 J/mol×K 480.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 538.00 J/mol×K 490.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 549.00 J/mol×K 500.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 559.00 J/mol×K 510.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 570.00 J/mol×K 520.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 581.00 J/mol×K 530.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 592.00 J/mol×K 540.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 603.00 J/mol×K 550.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 614.00 J/mol×K 560.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 625.00 J/mol×K 570.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 636.00 J/mol×K 580.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 648.00 J/mol×K 590.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 659.00 J/mol×K 600.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,solid [261.10; 333.50] J/mol×K [294.30; 303.00] Show Hide
Cp,solid 294.60 J/mol×K 294.30 NIST
Cp,solid 333.50 J/mol×K 298.10 NIST
Cp,solid 295.60 J/mol×K 298.15 NIST
Cp,solid 295.40 J/mol×K 298.15 NIST
Cp,solid 261.10 J/mol×K 298.15 NIST
Cp,solid 308.80 J/mol×K 303.00 NIST
ΔfusH [18.20; 21.98] kJ/mol [365.30; 367.20] Show Hide
ΔfusH 21.98 kJ/mol 365.30 NIST
ΔfusH 21.97 kJ/mol 365.30 NIST
ΔfusH 21.97 kJ/mol 365.30 NIST
ΔfusH 18.20 kJ/mol 365.50 NIST
ΔfusH 20.92 kJ/mol 365.60 NIST
ΔfusH 20.70 kJ/mol 367.20 NIST
ΔsubH [100.00; 113.90] kJ/mol [330.50; 367.00] Show Hide
ΔsubH 106.80 kJ/mol 330.50 NIST
ΔsubH 100.00 ± 0.40 kJ/mol 337.00 NIST
ΔsubH 100.00 ± 0.40 kJ/mol 337.00 NIST
ΔsubH 106.70 ± 0.60 kJ/mol 338.00 NIST
ΔsubH 113.90 kJ/mol 353.00 NIST
ΔsubH 100.10 ± 0.59 kJ/mol 367.00 NIST
ΔvapH [58.60; 82.00] kJ/mol [402.50; 577.50] Show Hide
ΔvapH 82.00 kJ/mol 402.50 NIST
ΔvapH 58.60 kJ/mol 577.50 NIST
Pvap [1.30e-07; 0.92] kPa [298.15; 510.00] Show Hide
Pvap 1.30e-07 kPa 298.15 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 1.69e-07 kPa 300.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 6.70e-07 kPa 310.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 2.39e-06 kPa 320.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 7.76e-06 kPa 330.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 2.31e-05 kPa 340.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 6.36e-05 kPa 350.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 1.63e-04 kPa 360.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 3.91e-04 kPa 370.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 8.85e-04 kPa 380.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 1.90e-03 kPa 390.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 3.87e-03 kPa 400.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 7.52e-03 kPa 410.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.01 kPa 420.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.03 kPa 430.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.04 kPa 440.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.07 kPa 450.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.12 kPa 460.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.19 kPa 470.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.29 kPa 480.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.44 kPa 490.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.64 kPa 500.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
Pvap 0.92 kPa 510.00 Hypothetical Thermodynamic Properties. Subcooled Vaporization Enthalpies and Vapor Pressures of Polyaromatic Hydrocarbons
ΔfusS [49.80; 60.20] J/mol×K [365.30; 365.60] Show Hide
ΔfusS 60.20 J/mol×K 365.30 NIST
ΔfusS 49.80 J/mol×K 365.50 NIST
ΔfusS 57.20 J/mol×K 365.60 NIST

Pressure Dependent Properties

Property Value Unit Pressure (kPa) Source
Tboilr 631.70 K 101.00 NIST

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [236.46; 644.52] J/mol×K [273.00; 1000.00] Joback Predicted correlation Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,gas in J/mol×K, T in K
Coefficient A-1.17780e+02
Coefficient B1.57800e+00
Coefficient C-1.10660e-03
Coefficient D2.90900e-07
Coefficient E0.00000e+00
Temperature range, min.273.00
Temperature range, max.1000.00
Cp,gas 236.46 J/mol×K 273.00 Calculated Property
Cp,gas 314.86 J/mol×K 353.78 Calculated Property
Cp,gas 382.85 J/mol×K 434.56 Calculated Property
Cp,gas 441.35 J/mol×K 515.33 Calculated Property
Cp,gas 491.28 J/mol×K 596.11 Calculated Property
Cp,gas 533.55 J/mol×K 676.89 Calculated Property
Cp,gas 569.09 J/mol×K 757.67 Calculated Property
Cp,gas 598.82 J/mol×K 838.44 Calculated Property
Cp,gas 623.66 J/mol×K 919.22 Calculated Property
Cp,gas 644.52 J/mol×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0020556; 0.0001166] Pa×s [365.42; 687.70] Joback Predicted correlation Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-1.23105e+01
Coefficient B2.23756e+03
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
CommentLiquid phase. Joback/Reid (1987), valid from Tf to 0.7·Tc.
Temperature range, min.365.42
Temperature range, max.687.70
η 0.0020556 Pa×s 365.42 Calculated Property
η 0.0011901 Pa×s 401.23 Calculated Property
η 0.0007536 Pa×s 437.04 Calculated Property
η 0.0005114 Pa×s 472.85 Calculated Property
η 0.0003665 Pa×s 508.66 Calculated Property
η 0.0002744 Pa×s 544.47 Calculated Property
η 0.0002130 Pa×s 580.28 Calculated Property
η 0.0001702 Pa×s 616.08 Calculated Property
η 0.0001394 Pa×s 651.89 Calculated Property
η 0.0001166 Pa×s 687.70 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [0.13; 97.24] kPa [442.90; 532.40] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A3.65007e+01
Coefficient B-1.67046e+04
Coefficient C-9.13300e+00
ReferenceStull, 1947
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.442.90
Temperature range, max.532.40
Pvap 0.13 kPa 442.90 Calculated Property
Pvap 0.32 kPa 452.84 Calculated Property
Pvap 0.73 kPa 462.79 Calculated Property
Pvap 1.60 kPa 472.73 Calculated Property
Pvap 3.40 kPa 482.68 Calculated Property
Pvap 7.03 kPa 492.62 Calculated Property
Pvap 14.11 kPa 502.57 Calculated Property
Pvap 27.55 kPa 512.51 Calculated Property
Pvap 52.39 kPa 522.46 Calculated Property
Pvap 97.24 kPa 532.40 Calculated Property

Similar Compounds

Diphenylmethyl radical. Triphenylmethane, 4,4'-dichloro. Triphenylmethane, 4-chloro. Triphenylmethane, 4,4',4''-trichloro. Diphenylmethane. Triphenylmethane, 3-chloro. Tetraphenylmethane. Benzene, 1,4-bis(phenylmethyl)-. Benzene, 1-methyl-4-(phenylmethyl)-. triphenylmethane, 3,4-dichloro. Triphenylmethane, 3,4,4'-trichloro. 9,10[1',2']-Benzenoanthracene, 9,10-dihydro-. Benzene, 1,1'-methylenebis[4-methyl-. TRIS(4-NITROPHENYL)METHANE. Triphenylmethane, 2-chloro.

Find more compounds similar to Triphenylmethane.

Sources

Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data.
Outlier This icon means that the value is more than 2 standard deviations away from the property mean.
These property values are available through the Cheméo API. A free account gives you an access key.