Chemical Properties of Benzylamine (CAS 100-46-9)

InChI

InChI=1S/C7H9N/c8-6-7-4-2-1-3-5-7/h1-5H,6,8H2

InChI Key

WGQKYBSKWIADBV-UHFFFAOYSA-N

Formula

C7H9N

SMILES

NCc1ccccc1

Molecular Weight¹

107.15

CAS

100-46-9

Other Names

• (aminomethyl)benzene
• (phenylmethyl)amine
• .alpha.-aminotoluene
• Monobenzylamine
• N-Benzylamine
• NSC 8046
• Sumine 2005
• alpha-Aminotoluene
• aminomethylbenzene
• benzene, aminomethyl-
• benzenemethanamine
• «alpha»-Aminotoluene
• «omega»-Aminotoluene

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• S_Prot : Protonation entropy at 298K (J/mol×K).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_boilr : Boiling point at reduced pressure (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	0.4350		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
PAff	[913.30; 924.00]	kJ/mol
PAff	913.30	kJ/mol	NIST
PAff	922.70 ± 7.80	kJ/mol	NIST
PAff	924.00 ± 4.00	kJ/mol	NIST
BasG	879.40	kJ/mol	NIST
ΔcH°liquid	[-4075.00; -4058.00]	kJ/mol
ΔcH°liquid	-4075.00 ± 1.70	kJ/mol	NIST
ΔcH°liquid	-4058.00	kJ/mol	NIST
SProt	-3.00 ± 10.00	J/mol×K	NIST
ΔfG°	186.92	kJ/mol	Joback Calculated Property
ΔfH°gas	[56.60; 87.80]	kJ/mol
ΔfH°gas	87.80 ± 2.70	kJ/mol	NIST
ΔfH°gas	56.60	kJ/mol	NIST
ΔfH°liquid	[3.00; 34.20]	kJ/mol
ΔfH°liquid	34.20 ± 1.70	kJ/mol	NIST
ΔfH°liquid	3.00	kJ/mol	NIST
ΔfusH°	13.12	kJ/mol	Joback Calculated Property
ΔvapH°	[53.60; 60.16]	kJ/mol
ΔvapH°	60.16	kJ/mol	NIST
ΔvapH°	54.60 ± 0.30	kJ/mol	NIST
ΔvapH°	54.00 ± 2.00	kJ/mol	NIST
ΔvapH°	53.60	kJ/mol	NIST
IE	[8.49; 9.46]	eV
IE	8.49 ± 0.06	eV	NIST
IE	8.80	eV	NIST
IE	8.73	eV	NIST
IE	8.64 ± 0.05	eV	NIST
IE	9.46	eV	NIST
IE	9.10 ± 0.01	eV	NIST
log10WS	-1.53		Aq. Solubility Prediction
logPoct/wat	1.145		Crippen Calculated Property
McVol	95.710	ml/mol	McGowan Calculated Property
Pc	4802.81	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Inp	[983.90; 1035.00]
Inp	1035.00		NIST
Inp	1035.00		NIST
Inp	983.90		NIST
Inp	1019.20		NIST
Inp	994.00		NIST
Inp	995.00		NIST
Inp	983.90		NIST
Inp	1019.20		NIST
Ip	[1307.00; 1307.00]
Ip	1307.00		NIST
Ip	1307.00		NIST
Tboil	[358.00; 458.15]	K
Tboil	456.70	K	NIST
Tboil	457.00	K	NIST
Tboil	458.00	K	NIST
Tboil	Outlier 358.00 ± 2.00	K	NIST
Tboil	458.15 ± 0.30	K	NIST
Tboil	457.65 ± 0.50	K	NIST
Tc	686.00	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tfus	[260.65; 273.15]	K
Tfus	273.15	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	260.65	K	Aq. Solubility Prediction
Vc	0.347	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	207.18	J/mol×K	298.15	NIST
ΔvapH	[51.80; 52.70]	kJ/mol	[327.50; 380.00]
ΔvapH	52.70 ± 0.30	kJ/mol	327.50	NIST
ΔvapH	51.80	kJ/mol	380.00	NIST
Pvap	[0.01; 4.07]	kPa	[275.50; 362.67]
Pvap	0.01	kPa	275.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.01	kPa	276.70	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.02	kPa	276.70	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.02	kPa	278.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.02	kPa	279.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.02	kPa	279.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.02	kPa	281.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.03	kPa	282.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.03	kPa	282.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.03	kPa	284.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.03	kPa	285.70	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.03	kPa	285.70	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.04	kPa	287.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.04	kPa	288.00	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.04	kPa	288.00	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.05	kPa	290.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.05	kPa	291.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.05	kPa	291.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.06	kPa	292.74	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	0.06	kPa	293.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.06	kPa	294.20	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.06	kPa	294.20	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.08	kPa	296.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.08	kPa	297.70	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.08	kPa	297.70	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.09	kPa	298.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.10	kPa	300.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.10	kPa	300.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.11	kPa	301.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.13	kPa	302.68	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	0.13	kPa	303.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.13	kPa	303.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.13	kPa	303.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.13	kPa	303.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.14	kPa	304.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.15	kPa	306.10	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.15	kPa	306.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.17	kPa	307.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.18	kPa	308.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.18	kPa	308.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.19	kPa	309.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.20	kPa	309.50	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.21	kPa	310.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.23	kPa	312.20	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.23	kPa	312.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.23	kPa	312.30	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.26	kPa	312.69	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	0.25	kPa	313.40	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.30	kPa	315.60	The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
Pvap	0.49	kPa	322.67	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	0.88	kPa	332.70	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	1.52	kPa	342.68	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	2.51	kPa	352.67	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
Pvap	4.07	kPa	362.67	Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
ρl	[849.30; 983.66]	kg/m3	[293.15; 443.15]
ρl	983.40	kg/m3	293.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	983.00	kg/m3	293.15	Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation
ρl	983.66	kg/m3	293.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	979.35	kg/m3	298.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	978.00	kg/m3	298.15	Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation
ρl	978.34	kg/m3	298.15	THERMODYNAMICS OF MIXTURES CONTAINING AMINES. XIV. CpEm OF BENZYLAMINE WITH HEPTANE AT 293.15 K OR WITH METHANOL, 1-PROPANOL OR 1-PENTANOL AT (293.15-308.15) K
ρl	978.34	kg/m3	298.15	Thermodynamics of mixtures containing amines. XVI. CE pm of 1-butanol, 1-octanol or 1-decanol + benzylamine systems at (298.15, 308.15, 318.15 and 333.15) K
ρl	978.90	kg/m3	298.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	978.34	kg/m3	298.15	Thermodynamics of Mixtures Containing Amines. XV. Liquid Liquid Equilibria for Benzylamine + CH3(CH2)nCH3 (n = 8, 9, 10, 12, 14)
ρl	975.01	kg/m3	303.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	975.60	kg/m3	303.15	Unravelling various types of non-covalent interactions of benzyl amine with ethers in n-hexane at 303.15 K by ultrasonic and DFT methods
ρl	974.00	kg/m3	303.15	Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation
ρl	974.40	kg/m3	303.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	970.00	kg/m3	308.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	970.67	kg/m3	308.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	966.33	kg/m3	313.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	965.70	kg/m3	313.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	965.00	kg/m3	313.15	Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation
ρl	961.30	kg/m3	318.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	961.98	kg/m3	318.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	956.90	kg/m3	323.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	957.63	kg/m3	323.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	957.00	kg/m3	323.15	Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation
ρl	953.27	kg/m3	328.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	952.50	kg/m3	328.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	948.20	kg/m3	333.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	948.90	kg/m3	333.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	944.53	kg/m3	338.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	943.70	kg/m3	338.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	940.14	kg/m3	343.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	939.40	kg/m3	343.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	935.00	kg/m3	348.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	930.60	kg/m3	353.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	926.20	kg/m3	358.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	921.80	kg/m3	363.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	917.30	kg/m3	368.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	912.90	kg/m3	373.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	908.50	kg/m3	378.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	904.00	kg/m3	383.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	899.70	kg/m3	388.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	895.20	kg/m3	393.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	890.60	kg/m3	398.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	886.20	kg/m3	403.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	881.60	kg/m3	408.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	877.10	kg/m3	413.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	872.50	kg/m3	418.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	867.90	kg/m3	423.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	863.30	kg/m3	428.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	858.70	kg/m3	433.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	854.00	kg/m3	438.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
ρl	849.30	kg/m3	443.15	Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
γ	[0.04; 0.04]	N/m	[283.15; 323.15]
γ	0.04	N/m	283.15	Surface Tension and Refractive Index of Benzylamine and 1,2-Diaminopropane Aqueous Solutions from T = (283.15 to 323.15) K
γ	0.04	N/m	293.15	Surface Tension and Refractive Index of Benzylamine and 1,2-Diaminopropane Aqueous Solutions from T = (283.15 to 323.15) K
γ	0.04	N/m	303.15	Surface Tension and Refractive Index of Benzylamine and 1,2-Diaminopropane Aqueous Solutions from T = (283.15 to 323.15) K
γ	0.04	N/m	313.15	Surface Tension and Refractive Index of Benzylamine and 1,2-Diaminopropane Aqueous Solutions from T = (283.15 to 323.15) K
γ	0.04	N/m	323.15	Surface Tension and Refractive Index of Benzylamine and 1,2-Diaminopropane Aqueous Solutions from T = (283.15 to 323.15) K

Pressure Dependent Properties

Property	Value	Unit	Pressure (kPa)	Source
Tboilr	[363.00; 363.20]	K	[1.60; 1.60]
Tboilr	363.20	K	1.60	NIST
Tboilr	363.00	K	1.60	NIST

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[117.10; 297.91]	J/mol×K	[273.00; 1000.00]	Joback Predicted correlation
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K
Coefficient A			-3.08890e+01
Coefficient B			6.51800e-01
Coefficient C			-4.31600e-04
Coefficient D			1.08600e-07
Coefficient E			0.00000e+00
Temperature range, min.			273.00
Temperature range, max.			1000.00
Cp,gas	117.10	J/mol×K	273.00	Calculated Property
Cp,gas	150.49	J/mol×K	353.78	Calculated Property
Cp,gas	179.76	J/mol×K	434.56	Calculated Property
Cp,gas	205.25	J/mol×K	515.33	Calculated Property
Cp,gas	227.29	J/mol×K	596.11	Calculated Property
Cp,gas	246.24	J/mol×K	676.89	Calculated Property
Cp,gas	262.43	J/mol×K	757.67	Calculated Property
Cp,gas	276.21	J/mol×K	838.44	Calculated Property
Cp,gas	287.92	J/mol×K	919.22	Calculated Property
Cp,gas	297.91	J/mol×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.64]	kPa	[339.90; 486.90]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.49879e+01
Coefficient B			-4.16213e+03
Coefficient C			-5.67710e+01
Temperature range, min.			339.90
Temperature range, max.			486.90
Pvap	1.33	kPa	339.90	Calculated Property
Pvap	2.97	kPa	356.23	Calculated Property
Pvap	6.10	kPa	372.57	Calculated Property
Pvap	11.66	kPa	388.90	Calculated Property
Pvap	20.98	kPa	405.23	Calculated Property
Pvap	35.82	kPa	421.57	Calculated Property
Pvap	58.40	kPa	437.90	Calculated Property
Pvap	91.48	kPa	454.23	Calculated Property
Pvap	138.31	kPa	470.57	Calculated Property
Pvap	202.64	kPa	486.90	Calculated Property
Pvap	[7.50e-05; 4238.78]	kPa	[227.15; 683.50]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			7.85699e+01
Coefficient B			-8.96094e+03
Coefficient C			-8.99328e+00
Coefficient D			3.41134e-06
Coefficient E			0.00000e+00
Temperature range, min.			227.15
Temperature range, max.			683.50
Pvap	7.50e-05	kPa	227.15	Calculated Property
Pvap	0.02	kPa	277.86	Calculated Property
Pvap	0.64	kPa	328.56	Calculated Property
Pvap	7.61	kPa	379.27	Calculated Property
Pvap	45.93	kPa	429.97	Calculated Property
Pvap	177.77	kPa	480.68	Calculated Property
Pvap	509.05	kPa	531.38	Calculated Property
Pvap	1181.43	kPa	582.09	Calculated Property
Pvap	2361.45	kPa	632.79	Calculated Property
Pvap	4238.78	kPa	683.50	Calculated Property
Pvap	[0.13; 101.80]	kPa	[302.00; 457.70]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.57200e+01
Coefficient B			-4.61329e+03
Coefficient C			-4.19730e+01
Reference			Stull, 1947
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			302.00
Temperature range, max.			457.70
Pvap	0.13	kPa	302.00	Calculated Property
Pvap	0.40	kPa	319.30	Calculated Property
Pvap	1.06	kPa	336.60	Calculated Property
Pvap	2.54	kPa	353.90	Calculated Property
Pvap	5.52	kPa	371.20	Calculated Property
Pvap	11.10	kPa	388.50	Calculated Property
Pvap	20.91	kPa	405.80	Calculated Property
Pvap	37.17	kPa	423.10	Calculated Property
Pvap	62.88	kPa	440.40	Calculated Property
Pvap	101.80	kPa	457.70	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 0.02]	N/m	[283.15; 453.15]	Jasper (1972), surface tension of pure liquid compounds Compiled value
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is γ in N/m, T in K
Coefficient A			7.54631e-02
Coefficient B			-1.21300e-04
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Temperature range, min.			283.15
Temperature range, max.			453.15
γ	0.04	N/m	283.15	Calculated Property
γ	0.04	N/m	302.04	Calculated Property
γ	0.04	N/m	320.93	Calculated Property
γ	0.03	N/m	339.82	Calculated Property
γ	0.03	N/m	358.71	Calculated Property
γ	0.03	N/m	377.59	Calculated Property
γ	0.03	N/m	396.48	Calculated Property
γ	0.03	N/m	415.37	Calculated Property
γ	0.02	N/m	434.26	Calculated Property
γ	0.02	N/m	453.15	Calculated Property

Similar Compounds

Find more compounds similar to Benzylamine.

Mixtures

• 1-Butanol + Benzylamine
• 1-Octanol + Benzylamine
• 1-Decanol + Benzylamine
• Dimethyl Sulfoxide + Benzylamine
• Benzylamine + Water
• n-Hexane + Benzylamine + Tetrahydrofuran
• n-Hexane + 1,4-Dioxane + Benzylamine
• Heptane + Benzylamine
• Benzylamine + Methyl Alcohol
• 1-Propanol + Benzylamine
• 1-Pentanol + Benzylamine
• Decane + Benzylamine
• Undecane + Benzylamine
• Dodecane + Benzylamine
• Tetradecane + Benzylamine
• Hexadecane + Benzylamine
• Carbon dioxide + Benzylamine + Water
• Ethanol, 2-[(2-aminoethyl)amino]- + Benzylamine + Water

Sources

• KDB Vapor Pressure Data
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• Jasper (1972), surface tension of pure liquid compounds ChEDL chemicals 1.5.2, from Jasper, J. J. The Surface Tension of Pure Liquid Compounds. J. Phys. Chem. Ref. Data 1972, 1, 841-1010 (as transcribed in Lange's Handbook).
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• Crippen Method
• Unravelling various types of non-covalent interactions of benzyl amine with ethers in n-hexane at 303.15 K by ultrasonic and DFT methods
• Phase equilibrium properties of binary aqueous solutions of benzylamine, 1,2-bis(2-aminoethoxy)ethane, or 2-[2-(dimethylamino)ethoxy]ethanol
• Volumetric, acoustic and transport properties of mixtures containing dimethyl sulfoxide and some amines or alkanolamines: Measurement and correlation
• THERMODYNAMICS OF MIXTURES CONTAINING AMINES. XIV. CpEm OF BENZYLAMINE WITH HEPTANE AT 293.15 K OR WITH METHANOL, 1-PROPANOL OR 1-PENTANOL AT (293.15-308.15) K
• Thermodynamics of mixtures containing amines. XVI. CE pm of 1-butanol, 1-octanol or 1-decanol + benzylamine systems at (298.15, 308.15, 318.15 and 333.15) K
• Measurement and Correlation for Acoustic, Transport, Refractive, and High-Temperature Volumetric Data of Substituted Benzylamines
• Heat of Absorption of CO2 and Heat Capacity Measurements in Aqueous Solutions of Benzylamine, N-(2-Aminoethyl)-ethanolamine, and Their Blends Using a Reaction Calorimeter
• Thermodynamic Properties of Mixtures Containing Ionic Liquids. 7. Activity Coefficients of Aliphatic and Aromatic Esters and Benzylamine in 1-Methyl-3-ethylimidazolium Bis(trifluoromethylsulfonyl) Imide Using the Transpiration Method
• Surface Tension and Refractive Index of Benzylamine and 1,2-Diaminopropane Aqueous Solutions from T = (283.15 to 323.15) K
• The Vaporization Enthalpy and Vapor Pressure of (d)-Amphetamine and of Several Primary Amines Used as Standards at T/K = 298 As Evaluated by Correlation Gas Chromatography and Transpiration
• Thermodynamics of Mixtures Containing Amines. XV. Liquid Liquid Equilibria for Benzylamine + CH3(CH2)nCH3 (n = 8, 9, 10, 12, 14)
• Experimental Vapor Pressures of 2-Phenylethylamine, Benzylamine, Triethylamine, and cis-2,6-Dimethylpiperidine in the Range between 0.2 Pa and 75 kPa
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

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