Mixture of Hexadecanoic acid, ethyl ester + Tetradecanoic acid, ethyl ester

Datasets

1. Mole fraction (2)
2. T_boil - Boiling temperature at pressure P, K (2)
3. T_fus - Solid-liquid equilibrium temperature, K (8)

Mole fraction of Tetradecanoic acid, ethyl ester (2) [ref]

Fixed		Measured
Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Pressure, kPa - Gas	Mole fraction of Tetradecanoic acid, ethyl ester (2) - Gas
0.0000	0.50	0.0000
0.0794	0.50	0.2103
0.0998	0.50	0.2538
0.1420	0.50	0.3369
0.2222	0.50	0.4673
0.3126	0.50	0.5823
0.4304	0.50	0.6988
0.5193	0.50	0.7673
0.5843	0.50	0.8105
0.6338	0.50	0.8401
0.7618	0.50	0.9064
0.8665	0.50	0.9512
0.9271	0.50	0.9743
1.0000	0.50	1.0000
0.0000	1.00	0.0000
0.0829	1.00	0.2110
0.0999	1.00	0.2421
0.1569	1.00	0.3495
0.2543	1.00	0.4970
0.3691	1.00	0.6283
0.4882	1.00	0.7331
0.5282	1.00	0.7632
0.5907	1.00	0.8029
0.7077	1.00	0.8722
0.8114	1.00	0.9236
0.8675	1.00	0.9480
0.9264	1.00	0.9718
1.0000	1.00	1.0000
0.0000	1.50	0.0000
0.0961	1.50	0.2299
0.1162	1.50	0.2689
0.1678	1.50	0.3608
0.2360	1.50	0.4627
0.3502	1.50	0.5988
0.4475	1.50	0.6912
0.5032	1.50	0.7366
0.5542	1.50	0.7741
0.6900	1.50	0.8594
0.7693	1.50	0.9009
0.8231	1.50	0.9266
0.9320	1.50	0.9699
1.0000	1.50	1.0000

Mole fraction of Tetradecanoic acid, ethyl ester (2) [ref]

Fixed		Measured
Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Pressure, kPa - Gas	Mole fraction of Tetradecanoic acid, ethyl ester (2) - Gas
0.0000	0.50	0.0000
0.0794	0.50	0.2103
0.0998	0.50	0.2538
0.1420	0.50	0.3369
0.2222	0.50	0.4673
0.3126	0.50	0.5823
0.4304	0.50	0.6988
0.5193	0.50	0.7673
0.5843	0.50	0.8105
0.6338	0.50	0.8401
0.7618	0.50	0.9064
0.8665	0.50	0.9512
0.9271	0.50	0.9743
1.0000	0.50	1.0000
0.0000	1.00	0.0000
0.0829	1.00	0.2110
0.0999	1.00	0.2421
0.1569	1.00	0.3495
0.2543	1.00	0.4970
0.3691	1.00	0.6283
0.4882	1.00	0.7331
0.5282	1.00	0.7632
0.5907	1.00	0.8029
0.7077	1.00	0.8722
0.8114	1.00	0.9236
0.8675	1.00	0.9480
0.9264	1.00	0.9718
1.0000	1.00	1.0000
0.0000	1.50	0.0000
0.0961	1.50	0.2299
0.1162	1.50	0.2689
0.1678	1.50	0.3608
0.2360	1.50	0.4627
0.3502	1.50	0.5988
0.4475	1.50	0.6912
0.5032	1.50	0.7366
0.5542	1.50	0.7741
0.6900	1.50	0.8594
0.7693	1.50	0.9009
0.8231	1.50	0.9266
0.9320	1.50	0.9699
1.0000	1.50	1.0000

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Pressure, kPa - Gas	Boiling temperature at pressure P, K - Liquid
0.0000	0.50	442.68
0.0794	0.50	440.18
0.0998	0.50	439.46
0.1420	0.50	437.96
0.2222	0.50	435.52
0.3126	0.50	433.10
0.4304	0.50	430.33
0.5193	0.50	428.53
0.5843	0.50	427.18
0.6338	0.50	426.34
0.7618	0.50	424.16
0.8665	0.50	422.68
0.9271	0.50	421.79
1.0000	0.50	420.46
0.0000	1.00	457.98
0.0829	1.00	455.23
0.0999	1.00	454.10
0.1569	1.00	452.21
0.2543	1.00	449.20
0.3691	1.00	446.21
0.4882	1.00	443.40
0.5282	1.00	441.74
0.5907	1.00	440.64
0.7077	1.00	438.47
0.8114	1.00	436.91
0.8675	1.00	436.05
0.9264	1.00	435.58
1.0000	1.00	434.98
0.0000	1.50	468.07
0.0961	1.50	464.75
0.1162	1.50	463.97
0.1678	1.50	462.20
0.2360	1.50	460.15
0.3502	1.50	457.06
0.4475	1.50	454.73
0.5032	1.50	453.46
0.5542	1.50	452.38
0.6900	1.50	449.72
0.7693	1.50	448.38
0.8231	1.50	447.50
0.9320	1.50	445.91
1.0000	1.50	444.05

Boiling temperature at pressure P, K [ref]

Fixed		Measured
Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Pressure, kPa - Gas	Boiling temperature at pressure P, K - Liquid
0.0000	0.50	442.68
0.0794	0.50	440.18
0.0998	0.50	439.46
0.1420	0.50	437.96
0.2222	0.50	435.52
0.3126	0.50	433.10
0.4304	0.50	430.33
0.5193	0.50	428.53
0.5843	0.50	427.18
0.6338	0.50	426.34
0.7618	0.50	424.16
0.8665	0.50	422.68
0.9271	0.50	421.79
1.0000	0.50	420.46
0.0000	1.00	457.98
0.0829	1.00	455.23
0.0999	1.00	454.10
0.1569	1.00	452.21
0.2543	1.00	449.20
0.3691	1.00	446.21
0.4882	1.00	443.40
0.5282	1.00	441.74
0.5907	1.00	440.64
0.7077	1.00	438.47
0.8114	1.00	436.91
0.8675	1.00	436.05
0.9264	1.00	435.58
1.0000	1.00	434.98
0.0000	1.50	468.07
0.0961	1.50	464.75
0.1162	1.50	463.97
0.1678	1.50	462.20
0.2360	1.50	460.15
0.3502	1.50	457.06
0.4475	1.50	454.73
0.5032	1.50	453.46
0.5542	1.50	452.38
0.6900	1.50	449.72
0.7693	1.50	448.38
0.8231	1.50	447.50
0.9320	1.50	445.91
1.0000	1.50	444.05

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.0000	298.23
0.0518	297.12
0.0982	296.76
0.1955	294.94
0.3103	292.68
0.4036	290.50
0.4861	288.24

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.8999	284.38
0.9476	284.94
1.0000	287.23

Solid-liquid equilibrium temperature, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
100.00	0.0000	297.60
100.00	0.2009	294.60
100.00	0.3993	291.30
100.00	0.5006	288.80
100.00	0.5992	285.10
100.00	0.6981	283.40
20000.00	0.0000	302.00
20000.00	0.2009	299.30
20000.00	0.3993	296.20
20000.00	0.5006	293.30
20000.00	0.5992	289.20
20000.00	0.6981	287.70
40000.00	0.0000	306.40
40000.00	0.2009	303.70
40000.00	0.3993	301.10
40000.00	0.5006	298.00
40000.00	0.5992	293.90
40000.00	0.6981	292.10
60000.00	0.0000	310.30
60000.00	0.2009	307.80
60000.00	0.3993	305.40
60000.00	0.5006	302.40
60000.00	0.5992	297.90
60000.00	0.6981	295.80
80000.00	0.0000	314.30
80000.00	0.2009	311.80
80000.00	0.3993	309.20
80000.00	0.5006	306.30
80000.00	0.5992	301.50
80000.00	0.6981	299.10

Solid-liquid equilibrium temperature, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
100.00	0.7489	282.60
100.00	0.7996	282.80
100.00	0.8997	284.20
100.00	1.0000	285.80
20000.00	0.7489	286.80
20000.00	0.7996	287.10
20000.00	0.8997	288.60
20000.00	1.0000	289.90
40000.00	0.7489	290.80
40000.00	0.7996	291.30
40000.00	0.8997	292.20
40000.00	1.0000	294.10
60000.00	0.7489	294.50
60000.00	0.7996	295.20
60000.00	0.8997	296.00
60000.00	1.0000	298.00
80000.00	0.7489	298.50
80000.00	0.7996	298.90
80000.00	0.8997	299.50
80000.00	1.0000	301.90

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.0000	298.23
0.0518	297.12
0.0982	296.76
0.1955	294.94
0.3103	292.68
0.4036	290.50
0.4861	288.24

Solid-liquid equilibrium temperature, K [ref]

Operational condition: Pressure, kPa = 100 (Liquid)

Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
0.8999	284.38
0.9476	284.94
1.0000	287.23

Solid-liquid equilibrium temperature, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
100.00	0.0000	297.60
100.00	0.2009	294.60
100.00	0.3993	291.30
100.00	0.5006	288.80
100.00	0.5992	285.10
100.00	0.6981	283.40
20000.00	0.0000	302.00
20000.00	0.2009	299.30
20000.00	0.3993	296.20
20000.00	0.5006	293.30
20000.00	0.5992	289.20
20000.00	0.6981	287.70
40000.00	0.0000	306.40
40000.00	0.2009	303.70
40000.00	0.3993	301.10
40000.00	0.5006	298.00
40000.00	0.5992	293.90
40000.00	0.6981	292.10
60000.00	0.0000	310.30
60000.00	0.2009	307.80
60000.00	0.3993	305.40
60000.00	0.5006	302.40
60000.00	0.5992	297.90
60000.00	0.6981	295.80
80000.00	0.0000	314.30
80000.00	0.2009	311.80
80000.00	0.3993	309.20
80000.00	0.5006	306.30
80000.00	0.5992	301.50
80000.00	0.6981	299.10

Solid-liquid equilibrium temperature, K [ref]

Fixed		Measured
Pressure, kPa - Liquid	Mole fraction of Tetradecanoic acid, ethyl ester (2) - Liquid	Solid-liquid equilibrium temperature, K - Liquid
100.00	0.7489	282.60
100.00	0.7996	282.80
100.00	0.8997	284.20
100.00	1.0000	285.80
20000.00	0.7489	286.80
20000.00	0.7996	287.10
20000.00	0.8997	288.60
20000.00	1.0000	289.90
40000.00	0.7489	290.80
40000.00	0.7996	291.30
40000.00	0.8997	292.20
40000.00	1.0000	294.10
60000.00	0.7489	294.50
60000.00	0.7996	295.20
60000.00	0.8997	296.00
60000.00	1.0000	298.00
80000.00	0.7489	298.50
80000.00	0.7996	298.90
80000.00	0.8997	299.50
80000.00	1.0000	301.90

Sources

• Isobaric vapor liquid equilibrium for binary system of ethyl myristate + ethyl palmitate at 0.5, 1.0 and 1.5 kPa
• Solid-liquid equilibrium in ternary mixtures of ethyl laurate, ethyl palmitate and ethyl myristate
• High pressure solid-liquid equilibrium of fatty acid ethyl esters binary systems