Mixture of Butane, 1,4-dichloro- + Methane, nitro-

Datasets

1. Mole fraction (2)
2. P_vap - Vapor or sublimation pressure, kPa (2)
3. n₀ - Refractive index (Na D-line) (2)
4. ρ_l - Mass density, kg/m3 (2)
5. c_sound,fluid - Speed of Sound, m/s (2)

Mole fraction of Methane, nitro- (2) [ref]

Fixed		Measured
Mole fraction of Methane, nitro- (2) - Liquid	Temperature, K - Liquid	Mole fraction of Methane, nitro- (2) - Gas
0.0000	343.15	0.0000
0.0000	353.15	0.0000
0.0000	363.15	0.0000
0.0350	343.15	0.3481
0.0350	353.15	0.3068
0.0350	363.15	0.2920
0.0777	343.15	0.5070
0.0777	363.15	0.4720
0.0800	353.15	0.4934
0.1294	363.15	0.6016
0.1381	353.15	0.6279
0.1402	343.15	0.6533
0.1907	363.15	0.6900
0.2029	343.15	0.7273
0.2029	353.15	0.7054
0.2676	363.15	0.7529
0.2752	353.15	0.7703
0.2846	343.15	0.7882
0.3410	363.15	0.7955
0.3446	353.15	0.8108
0.3568	343.15	0.8267
0.4292	363.15	0.8385
0.4324	353.15	0.8442
0.4404	343.15	0.8594
0.5173	363.15	0.8613
0.5320	353.15	0.8706
0.5334	343.15	0.8770
0.6135	353.15	0.8942
0.6135	363.15	0.8843
0.6240	343.15	0.9039
0.7066	363.15	0.9083
0.7147	343.15	0.9195
0.7147	353.15	0.9144
0.8108	363.15	0.9390
0.8128	343.15	0.9439
0.8128	353.15	0.9415
0.9030	353.15	0.9642
0.9030	363.15	0.9634
0.9039	343.15	0.9658
0.9642	343.15	0.9862
0.9642	353.15	0.9855
0.9642	363.15	0.9855
1.0000	343.15	1.0000
1.0000	353.15	1.0000
1.0000	363.15	1.0000

Mole fraction of Methane, nitro- (2) [ref]

Fixed		Measured
Mole fraction of Methane, nitro- (2) - Liquid	Temperature, K - Liquid	Mole fraction of Methane, nitro- (2) - Gas
0.0000	343.15	0.0000
0.0000	353.15	0.0000
0.0000	363.15	0.0000
0.0350	343.15	0.3481
0.0350	353.15	0.3068
0.0350	363.15	0.2920
0.0777	343.15	0.5070
0.0777	363.15	0.4720
0.0800	353.15	0.4934
0.1294	363.15	0.6016
0.1381	353.15	0.6279
0.1402	343.15	0.6533
0.1907	363.15	0.6900
0.2029	343.15	0.7273
0.2029	353.15	0.7054
0.2676	363.15	0.7529
0.2752	353.15	0.7703
0.2846	343.15	0.7882
0.3410	363.15	0.7955
0.3446	353.15	0.8108
0.3568	343.15	0.8267
0.4292	363.15	0.8385
0.4324	353.15	0.8442
0.4404	343.15	0.8594
0.5173	363.15	0.8613
0.5320	353.15	0.8706
0.5334	343.15	0.8770
0.6135	353.15	0.8942
0.6135	363.15	0.8843
0.6240	343.15	0.9039
0.7066	363.15	0.9083
0.7147	343.15	0.9195
0.7147	353.15	0.9144
0.8108	363.15	0.9390
0.8128	343.15	0.9439
0.8128	353.15	0.9415
0.9030	353.15	0.9642
0.9030	363.15	0.9634
0.9039	343.15	0.9658
0.9642	343.15	0.9862
0.9642	353.15	0.9855
0.9642	363.15	0.9855
1.0000	343.15	1.0000
1.0000	353.15	1.0000
1.0000	363.15	1.0000

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Methane, nitro- (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	343.15	5.25
0.0000	353.15	8.20
0.0000	363.15	12.52
0.0350	343.15	7.87
0.0350	353.15	11.56
0.0350	363.15	16.99
0.0777	343.15	10.07
0.0777	363.15	21.73
0.0800	353.15	15.05
0.1294	363.15	27.21
0.1381	353.15	19.21
0.1402	343.15	13.36
0.1907	363.15	32.70
0.2029	343.15	16.23
0.2029	353.15	23.08
0.2676	363.15	38.12
0.2752	353.15	27.24
0.2846	343.15	19.04
0.3410	363.15	42.88
0.3446	353.15	30.70
0.3568	343.15	21.68
0.4292	363.15	47.82
0.4324	353.15	33.98
0.4404	343.15	23.84
0.5173	363.15	52.01
0.5320	353.15	36.94
0.5334	343.15	25.80
0.6135	353.15	39.73
0.6135	363.15	56.08
0.6240	343.15	27.77
0.7066	363.15	59.68
0.7147	343.15	29.49
0.7147	353.15	42.34
0.8108	363.15	63.57
0.8128	343.15	31.36
0.8128	353.15	45.04
0.9030	353.15	47.45
0.9030	363.15	66.97
0.9039	343.15	32.94
0.9642	343.15	34.12
0.9642	353.15	49.16
0.9642	363.15	69.37
1.0000	343.15	34.93
1.0000	353.15	50.14
1.0000	363.15	70.81

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Methane, nitro- (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	343.15	5.25
0.0000	353.15	8.20
0.0000	363.15	12.52
0.0350	343.15	7.87
0.0350	353.15	11.56
0.0350	363.15	16.99
0.0777	343.15	10.07
0.0777	363.15	21.73
0.0800	353.15	15.05
0.1294	363.15	27.21
0.1381	353.15	19.21
0.1402	343.15	13.36
0.1907	363.15	32.70
0.2029	343.15	16.23
0.2029	353.15	23.08
0.2676	363.15	38.12
0.2752	353.15	27.24
0.2846	343.15	19.04
0.3410	363.15	42.88
0.3446	353.15	30.70
0.3568	343.15	21.68
0.4292	363.15	47.82
0.4324	353.15	33.98
0.4404	343.15	23.84
0.5173	363.15	52.01
0.5320	353.15	36.94
0.5334	343.15	25.80
0.6135	353.15	39.73
0.6135	363.15	56.08
0.6240	343.15	27.77
0.7066	363.15	59.68
0.7147	343.15	29.49
0.7147	353.15	42.34
0.8108	363.15	63.57
0.8128	343.15	31.36
0.8128	353.15	45.04
0.9030	353.15	47.45
0.9030	363.15	66.97
0.9039	343.15	32.94
0.9642	343.15	34.12
0.9642	353.15	49.16
0.9642	363.15	69.37
1.0000	343.15	34.93
1.0000	353.15	50.14
1.0000	363.15	70.81

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Butane, 1,4-dichloro- (1) - Liquid	Refractive index (Na D-line) - Liquid
298.15	0.0000	1.3796
298.15	0.0825	1.3897
298.15	0.1759	1.3999
298.15	0.2825	1.4099
298.15	0.3815	1.418
298.15	0.4815	1.4251
298.15	0.5911	1.432
298.15	0.6898	1.4377
298.15	0.8208	1.4443
298.15	0.9262	1.4491
298.15	1.0000	1.4522
308.15	0.0000	1.3748
308.15	0.0825	1.3851
308.15	0.1759	1.3961
308.15	0.2825	1.4065
308.15	0.3815	1.4145
308.15	0.4815	1.4213
308.15	0.5911	1.4279
308.15	0.6898	1.4333
308.15	0.8208	1.4397
308.15	0.9262	1.4444
308.15	1.0000	1.4476
318.15	0.0000	1.37
318.15	0.0825	1.3808
318.15	0.1759	1.3917
318.15	0.2825	1.4022
318.15	0.3815	1.4101
318.15	0.4815	1.4168
318.15	0.5911	1.4236
318.15	0.6898	1.429
318.15	0.8208	1.4351
318.15	0.9262	1.4397
318.15	1.0000	1.4428

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Butane, 1,4-dichloro- (1) - Liquid	Refractive index (Na D-line) - Liquid
298.15	0.0000	1.3796
298.15	0.0825	1.3897
298.15	0.1759	1.3999
298.15	0.2825	1.4099
298.15	0.3815	1.418
298.15	0.4815	1.4251
298.15	0.5911	1.432
298.15	0.6898	1.4377
298.15	0.8208	1.4443
298.15	0.9262	1.4491
298.15	1.0000	1.4522
308.15	0.0000	1.3748
308.15	0.0825	1.3851
308.15	0.1759	1.3961
308.15	0.2825	1.4065
308.15	0.3815	1.4145
308.15	0.4815	1.4213
308.15	0.5911	1.4279
308.15	0.6898	1.4333
308.15	0.8208	1.4397
308.15	0.9262	1.4444
308.15	1.0000	1.4476
318.15	0.0000	1.37
318.15	0.0825	1.3808
318.15	0.1759	1.3917
318.15	0.2825	1.4022
318.15	0.3815	1.4101
318.15	0.4815	1.4168
318.15	0.5911	1.4236
318.15	0.6898	1.429
318.15	0.8208	1.4351
318.15	0.9262	1.4397
318.15	1.0000	1.4428

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Butane, 1,4-dichloro- (1) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.0000	1130.95
298.15	0.0825	1128.17
298.15	0.1759	1126.77
298.15	0.2825	1126.33
298.15	0.3815	1126.62
298.15	0.4815	1127.33
298.15	0.5911	1128.46
298.15	0.6898	1129.64
298.15	0.8208	1131.38
298.15	0.9262	1132.86
298.15	1.0000	1133.94
308.15	0.0000	1117.32
308.15	0.0825	1114.98
308.15	0.1759	1113.92
308.15	0.2825	1113.86
308.15	0.3815	1114.44
308.15	0.4815	1115.42
308.15	0.5911	1116.8
308.15	0.6898	1118.18
308.15	0.8208	1120.16
308.15	0.9262	1121.81
308.15	1.0000	1123.0
318.15	0.0000	1103.57
318.15	0.0825	1101.65
318.15	0.1759	1100.97
318.15	0.2825	1101.28
318.15	0.3815	1102.17
318.15	0.4815	1103.42
318.15	0.5911	1105.05
318.15	0.6898	1106.65
318.15	0.8208	1108.88
318.15	0.9262	1110.7
318.15	1.0000	1112.0

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Butane, 1,4-dichloro- (1) - Liquid	Mass density, kg/m3 - Liquid
298.15	0.0000	1130.95
298.15	0.0825	1128.17
298.15	0.1759	1126.77
298.15	0.2825	1126.33
298.15	0.3815	1126.62
298.15	0.4815	1127.33
298.15	0.5911	1128.46
298.15	0.6898	1129.64
298.15	0.8208	1131.38
298.15	0.9262	1132.86
298.15	1.0000	1133.94
308.15	0.0000	1117.32
308.15	0.0825	1114.98
308.15	0.1759	1113.92
308.15	0.2825	1113.86
308.15	0.3815	1114.44
308.15	0.4815	1115.42
308.15	0.5911	1116.8
308.15	0.6898	1118.18
308.15	0.8208	1120.16
308.15	0.9262	1121.81
308.15	1.0000	1123.0
318.15	0.0000	1103.57
318.15	0.0825	1101.65
318.15	0.1759	1100.97
318.15	0.2825	1101.28
318.15	0.3815	1102.17
318.15	0.4815	1103.42
318.15	0.5911	1105.05
318.15	0.6898	1106.65
318.15	0.8208	1108.88
318.15	0.9262	1110.7
318.15	1.0000	1112.0

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Butane, 1,4-dichloro- (1) - Liquid	Speed of sound, m/s - Liquid
298.15	0.0000	1321.49
298.15	0.0825	1308.13
298.15	0.1759	1298.27
298.15	0.2825	1291.32
298.15	0.3815	1287.23
298.15	0.4815	1285.01
298.15	0.5911	1283.97
298.15	0.6898	1283.89
298.15	0.8208	1284.64
298.15	0.9262	1285.72
298.15	1.0000	1286.64
308.15	0.0000	1281.9
308.15	0.0825	1269.31
308.15	0.1759	1259.98
308.15	0.2825	1253.45
308.15	0.3815	1249.89
308.15	0.4815	1248.02
308.15	0.5911	1247.29
308.15	0.6898	1247.48
308.15	0.8208	1248.58
308.15	0.9262	1249.91
308.15	1.0000	1251.0
318.15	0.0000	1242.5
318.15	0.0825	1230.56
318.15	0.1759	1221.8
318.15	0.2825	1215.8
318.15	0.3815	1212.67
318.15	0.4815	1211.19
318.15	0.5911	1210.83
318.15	0.6898	1211.31
318.15	0.8208	1212.77
318.15	0.9262	1214.38
318.15	1.0000	1215.66

Speed of sound, m/s [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Butane, 1,4-dichloro- (1) - Liquid	Speed of sound, m/s - Liquid
298.15	0.0000	1321.49
298.15	0.0825	1308.13
298.15	0.1759	1298.27
298.15	0.2825	1291.32
298.15	0.3815	1287.23
298.15	0.4815	1285.01
298.15	0.5911	1283.97
298.15	0.6898	1283.89
298.15	0.8208	1284.64
298.15	0.9262	1285.72
298.15	1.0000	1286.64
308.15	0.0000	1281.9
308.15	0.0825	1269.31
308.15	0.1759	1259.98
308.15	0.2825	1253.45
308.15	0.3815	1249.89
308.15	0.4815	1248.02
308.15	0.5911	1247.29
308.15	0.6898	1247.48
308.15	0.8208	1248.58
308.15	0.9262	1249.91
308.15	1.0000	1251.0
318.15	0.0000	1242.5
318.15	0.0825	1230.56
318.15	0.1759	1221.8
318.15	0.2825	1215.8
318.15	0.3815	1212.67
318.15	0.4815	1211.19
318.15	0.5911	1210.83
318.15	0.6898	1211.31
318.15	0.8208	1212.77
318.15	0.9262	1214.38
318.15	1.0000	1215.66

Sources

• Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
• Isothermal (vapour + liquid) equilibria for (nitromethane or nitroethane + 1,4-dichlorobutane) binary systems at temperatures between (343.15 and 363.15) K
• Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K