Chemical Properties of Butane, 1,4-dichloro- (CAS 110-56-5)

Butane, 1,4-dichloro-

InChI
InChI=1S/C4H8Cl2/c5-3-1-2-4-6/h1-4H2
InChI Key
KJDRSWPQXHESDQ-UHFFFAOYSA-N
Formula
C4H8Cl2
SMILES
ClCCCCCl
Molecular Weight1
127.01
CAS
110-56-5
Other Names
  • 1,4-dichlorobutane
  • tetramethylene chloride
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Contents

  1. Physical Properties
  2. Temperature Dependent Properties
  3. Datasets
  4. Correlations
  5. Similar Compounds
  6. Mixtures
  7. Sources

Physical Properties

Property Value Unit Source
ω 0.3698 Relay (1.0) Calculated Property
Δcliquid -2534.80 ± 1.90 kJ/mol NIST
Δf -41.06 kJ/mol Joback Calculated Property
Δfgas -183.40 ± 1.90 kJ/mol NIST
Δfliquid [-229.80; -229.50] kJ/mol Show Hide
Δfliquid -229.80 ± 1.90 kJ/mol NIST
Δfliquid -229.50 kJ/mol NIST
Δfus 14.51 kJ/mol Joback Calculated Property
Δvap [46.36; 46.70] kJ/mol Show Hide
Δvap 46.36 kJ/mol NIST
Δvap Outlier 46.70 kJ/mol NIST
Δvap 46.50 ± 0.10 kJ/mol NIST
Δvap 46.40 kJ/mol NIST
Δvap 46.37 ± 0.02 kJ/mol NIST
Δvap 46.40 ± 0.10 kJ/mol NIST
Δvap 46.40 ± 0.10 kJ/mol NIST
Δvap 46.36 ± 0.02 kJ/mol NIST
IE 11.03 eV NIST
log10WS -2.45 Relay (1.0) Calculated Property
logPoct/wat 2.244 Crippen Calculated Property
McVol 91.700 ml/mol McGowan Calculated Property
Pc 3560.02 kPa Joback Calculated Property
Inp [867.40; 898.10]   Show Hide
Inp 867.40 NIST
Inp 895.00 NIST
Inp 874.00 NIST
Inp 874.00 NIST
Inp 874.00 NIST
Inp 874.00 NIST
Inp 898.10 NIST
Inp 894.10 NIST
Inp 874.00 NIST
Inp 894.10 NIST
Tboil [308.15; 435.20] K Show Hide
Tboil 428.15 K KDB
Tboil 435.20 K NIST
Tboil 433.00 K NIST
Tboil 427.10 K NIST
Tboil 428.15 ± 1.50 K NIST
Tboil Outlier 322.00 ± 3.00 K NIST
Tboil 427.15 ± 4.00 K NIST
Tboil 434.65 ± 5.00 K NIST
Tboil 426.25 ± 2.00 K NIST
Tboil Outlier 308.15 ± 2.50 K NIST
Tboil 427.05 ± 0.50 K NIST
Tboil 428.00 ± 1.00 K NIST
Tboil 426.65 ± 0.50 K NIST
Tc 612.52 K Relay (1.0) Calculated Property
Tfus 234.50 ± 0.40 K NIST
Vc 0.338 m3/kmol Relay (1.0) Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [141.67; 181.25] J/mol×K [365.78; 547.67] Show Hide
Cp,gas 141.67 J/mol×K 365.78 Joback Calculated Property
Cp,gas 149.02 J/mol×K 396.09 Joback Calculated Property
Cp,gas 156.05 J/mol×K 426.41 Joback Calculated Property
Cp,gas 162.78 J/mol×K 456.72 Joback Calculated Property
Cp,gas 169.22 J/mol×K 487.04 Joback Calculated Property
Cp,gas 175.37 J/mol×K 517.35 Joback Calculated Property
Cp,gas 181.25 J/mol×K 547.67 Joback Calculated Property
Cp,liquid [183.59; 184.00] J/mol×K [298.15; 298.15] Show Hide
Cp,liquid 184.00 J/mol×K 298.15 NIST
Cp,liquid 183.59 J/mol×K 298.15 NIST
Csat [181.25; 195.12] J/mol×K [284.16; 353.14] Show Hide
Csat 181.25 J/mol×K 284.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 181.71 J/mol×K 286.66 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 182.15 J/mol×K 289.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 182.62 J/mol×K 291.66 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 182.99 J/mol×K 294.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 183.49 J/mol×K 296.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 183.76 J/mol×K 298.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 183.89 J/mol×K 299.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 184.47 J/mol×K 301.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 184.80 J/mol×K 304.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 185.71 J/mol×K 308.56 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 185.83 J/mol×K 309.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 186.41 J/mol×K 311.66 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 186.88 J/mol×K 314.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 187.38 J/mol×K 316.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 187.89 J/mol×K 319.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 188.52 J/mol×K 321.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 188.85 J/mol×K 324.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 189.48 J/mol×K 326.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 190.01 J/mol×K 329.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 190.54 J/mol×K 331.66 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 190.99 J/mol×K 334.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 191.48 J/mol×K 336.66 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 192.00 J/mol×K 339.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 192.36 J/mol×K 341.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 193.05 J/mol×K 344.16 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 193.63 J/mol×K 346.65 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 194.00 J/mol×K 349.15 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 194.70 J/mol×K 351.66 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
Csat 195.12 J/mol×K 353.14 Heat Capacities of alpha,omega-Dichloroalkanes at Temperatures from 284.15 K to 353.15 K and a Group Additivity Analysis
η [0.0003469; 0.0041179] Pa×s [194.68; 365.78] Show Hide
η 0.0041179 Pa×s 194.68 Joback Calculated Property
η 0.0020950 Pa×s 223.20 Joback Calculated Property
η 0.0012422 Pa×s 251.71 Joback Calculated Property
η 0.0008192 Pa×s 280.23 Joback Calculated Property
η 0.0005835 Pa×s 308.75 Joback Calculated Property
η 0.0004401 Pa×s 337.26 Joback Calculated Property
η 0.0003469 Pa×s 365.78 Joback Calculated Property
ΔvapH 43.40 kJ/mol 380.50 NIST
Pvap [2.21; 2.21] kPa [323.15; 323.15] Show Hide
Pvap 2.21 kPa 323.15 Excess molar enthalpies and (vapour + liquid) equilibria for mixtures containing N,N-dialkylamides and a,x-dichloroalkanes
Pvap 2.21 kPa 323.15 Excess enthalpies and isothermal (vapour + liquid) equilibria of (1-methyl-2-pyrrolidone + 1-chloroalkane or +,?-dichloroalkane) mixtures
n0 [1.45190; 1.45220]   [298.15; 298.15] Show Hide
n0 1.45200 298.15 Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) I: HE and V E for 25 binary mixtures {xCu-1H2u-1CO2C2H5 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
n0 1.45190 298.15 Isothermal (vapour + liquid) equilibria and excess Gibbs free energies in some binary (cyclopentanone + chloroalkane) mixtures at temperatures from 298.15 K to 318.15 K
n0 1.45220 298.15 Isothermal (vapour + liquid) equilibria for (nitromethane or nitroethane + 1,4-dichlorobutane) binary systems at temperatures between (343.15 and 363.15) K
ρl [1110.54; 1143.49] kg/m3 [288.15; 318.15] Show Hide
ρl 1143.49 kg/m3 288.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1143.43 kg/m3 288.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1135.00 kg/m3 298.15 Volumetric and optical properties for some (2-butanone + chloroalkane) binary mixtures at T = 298.15 K
ρl 1133.94 kg/m3 298.15 Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
ρl 1132.57 kg/m3 298.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1132.50 kg/m3 298.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1123.00 kg/m3 308.15 Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
ρl 1121.61 kg/m3 308.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1121.54 kg/m3 308.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1112.00 kg/m3 318.15 Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
ρl 1110.61 kg/m3 318.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1110.54 kg/m3 318.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
csound,fluid [1215.66; 1286.64] m/s [298.15; 318.15] Show Hide
csound,fluid 1286.64 m/s 298.15 Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
csound,fluid 1251.00 m/s 308.15 Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
csound,fluid 1215.66 m/s 318.15 Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
γ [0.03; 0.03] N/m [293.15; 313.15] Show Hide
γ 0.03 N/m 293.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.03 N/m 298.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.03 N/m 303.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.03 N/m 308.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.03 N/m 313.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes

Datasets

Mass density, kg/m3

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
288.15 100.00 1143.7
288.15 500.00 1144.1
288.15 1000.00 1144.5
288.15 1500.00 1144.8
288.15 2000.00 1145.2
288.15 2500.00 1145.5
288.15 3000.00 1145.9
288.15 3600.00 1146.4
288.15 4100.00 1146.7
288.15 4600.00 1147.0
288.15 5100.00 1147.4
288.15 5600.00 1147.7
288.15 6100.00 1148.1
288.15 6600.00 1148.5
288.15 7100.00 1148.9
288.15 7600.00 1149.2
288.15 8100.00 1149.5
288.15 8600.00 1149.9
288.15 9200.00 1150.3
288.15 9600.00 1150.7
288.15 10100.00 1151.0
288.15 10600.00 1151.3
288.15 11100.00 1151.7
288.15 11600.00 1152.0
288.15 12100.00 1152.4
288.15 12600.00 1152.7
288.15 13100.00 1153.1
288.15 13500.00 1153.3
288.15 14200.00 1153.8
288.15 14700.00 1154.1
288.15 15200.00 1154.4
288.15 15700.00 1154.8
288.15 16300.00 1155.2
288.15 16800.00 1155.6
288.15 17300.00 1155.9
288.15 17800.00 1156.2
288.15 18300.00 1156.5
288.15 18800.00 1156.8
288.15 19100.00 1157.1
288.15 19700.00 1157.4
288.15 20200.00 1157.8
298.15 100.00 1133.7
298.15 500.00 1134.0
298.15 1000.00 1134.4
298.15 1500.00 1134.8
298.15 2000.00 1135.2
298.15 2500.00 1135.6
298.15 3100.00 1136.1
298.15 3600.00 1136.4
298.15 4100.00 1136.8
298.15 4600.00 1137.2
298.15 5100.00 1137.6
298.15 5600.00 1137.9
298.15 6100.00 1138.4
298.15 6600.00 1138.7
298.15 7100.00 1139.1
298.15 7600.00 1139.4
298.15 8100.00 1139.8
298.15 8600.00 1140.2
298.15 9200.00 1140.6
298.15 9600.00 1141.0
298.15 10100.00 1141.4
298.15 10700.00 1141.8
298.15 11100.00 1142.1
298.15 11600.00 1142.4
298.15 12100.00 1142.8
298.15 12600.00 1143.2
298.15 13100.00 1143.6
298.15 13600.00 1143.9
298.15 14100.00 1144.2
298.15 14700.00 1144.6
298.15 15200.00 1145.0
298.15 15700.00 1145.4
298.15 16200.00 1145.8
298.15 16700.00 1146.1
298.15 17200.00 1146.5
298.15 17800.00 1146.9
298.15 18300.00 1147.2
298.15 18800.00 1147.6
298.15 19200.00 1147.9
298.15 19700.00 1148.2
298.15 20200.00 1148.7
308.15 100.00 1122.3
308.15 500.00 1122.7
308.15 1000.00 1123.1
308.15 1500.00 1123.5
308.15 2000.00 1123.9
308.15 2500.00 1124.3
308.15 3100.00 1124.8
308.15 3600.00 1125.2
308.15 4100.00 1125.6
308.15 4600.00 1126.0
308.15 5100.00 1126.4
308.15 5600.00 1126.9
308.15 6100.00 1127.2
308.15 6600.00 1127.5
308.15 7100.00 1128.0
308.15 7600.00 1128.4
308.15 8100.00 1128.8
308.15 8600.00 1129.2
308.15 9200.00 1129.6
308.15 9600.00 1130.0
308.15 10100.00 1130.4
308.15 10600.00 1130.9
308.15 11100.00 1131.2
308.15 11600.00 1131.5
308.15 12100.00 1131.9
308.15 12600.00 1132.4
308.15 13100.00 1132.6
308.15 13600.00 1133.1
308.15 14100.00 1133.5
308.15 14700.00 1133.9
308.15 15100.00 1134.2
308.15 15700.00 1134.6
308.15 16200.00 1135.0
308.15 16700.00 1135.3
308.15 17200.00 1135.7
308.15 17800.00 1136.1
308.15 18300.00 1136.5
308.15 18800.00 1136.8
308.15 19200.00 1137.2
308.15 19700.00 1137.6
308.15 20200.00 1138.0
318.15 100.00 1112.0
318.15 500.00 1112.4
318.15 1000.00 1112.8
318.15 1500.00 1113.2
318.15 2000.00 1113.7
318.15 2500.00 1114.1
318.15 3100.00 1114.7
318.15 3500.00 1115.0
318.15 4100.00 1115.5
318.15 4600.00 1115.9
318.15 5100.00 1116.3
318.15 5600.00 1116.8
318.15 6100.00 1117.3
318.15 6600.00 1117.7
318.15 7100.00 1118.1
318.15 7600.00 1118.4
318.15 8100.00 1118.9
318.15 8600.00 1119.3
318.15 9200.00 1119.8
318.15 9600.00 1120.2
318.15 10100.00 1120.6
318.15 10600.00 1121.0
318.15 11100.00 1121.4
318.15 11600.00 1121.8
318.15 12100.00 1122.1
318.15 12600.00 1122.6
318.15 13000.00 1123.0
318.15 13600.00 1123.3
318.15 14200.00 1123.9
318.15 14700.00 1124.4
318.15 15200.00 1124.7
318.15 15700.00 1125.1
318.15 16300.00 1125.4
318.15 16800.00 1126.0
318.15 17300.00 1126.3
318.15 17800.00 1126.5
318.15 18300.00 1127.0
318.15 18800.00 1127.4
318.15 19200.00 1127.7
318.15 19700.00 1128.0
318.15 20200.00 1128.4
Reference
Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Mass density, kg/m3 - Liquid
298.15 100.00 1133.7
Reference

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 202.65] kPa [312.79; 432.68] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.62874e+01
Coefficient B-4.19096e+03
Coefficient C-5.08480e+01
Temperature range, min.312.79
Temperature range, max.432.68
Pvap 1.33 kPa 312.79 Calculated Property
Pvap 2.89 kPa 326.11 Calculated Property
Pvap 5.84 kPa 339.43 Calculated Property
Pvap 11.09 kPa 352.75 Calculated Property
Pvap 19.93 kPa 366.07 Calculated Property
Pvap 34.17 kPa 379.40 Calculated Property
Pvap 56.17 kPa 392.72 Calculated Property
Pvap 88.96 kPa 406.04 Calculated Property
Pvap 136.28 kPa 419.36 Calculated Property
Pvap 202.65 kPa 432.68 Calculated Property
Pvap [3.53e-03; 3577.43] kPa [235.85; 641.00] KDB Vapor Pressure Data Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A7.77758e+01
Coefficient B-7.95407e+03
Coefficient C-9.14431e+00
Coefficient D4.66169e-06
Temperature range, min.235.85
Temperature range, max.641.00
Pvap 3.53e-03 kPa 235.85 Calculated Property
Pvap 0.18 kPa 280.87 Calculated Property
Pvap 2.58 kPa 325.88 Calculated Property
Pvap 17.72 kPa 370.90 Calculated Property
Pvap 74.69 kPa 415.92 Calculated Property
Pvap 227.10 kPa 460.93 Calculated Property
Pvap 550.91 kPa 505.95 Calculated Property
Pvap 1139.60 kPa 550.97 Calculated Property
Pvap 2103.57 kPa 595.98 Calculated Property
Pvap 3577.43 kPa 641.00 Calculated Property

Similar Compounds

Butane, 1-chloro-. Pentane, 1,5-dichloro-. Pentane, 1-chloro-. 4-CHLOROBUTYRYL CHLORIDE. Butanenitrile, 4-chloro-. Hexane, 1,6-dichloro-. 1,7-Dichloroheptane. 1,8-Dichlorooctane. 1,9-Dichlorononane. 1,10-Dichlorodecane. Butane, 1,3-dichloro-. Tetramethylene chloroiodide. 5-Chlorovaleronitrile. Butane, 1,1-dichloro-. 1-chloro-4-fluorobutane.

Find more compounds similar to Butane, 1,4-dichloro-.

Mixtures

Find more mixtures with Butane, 1,4-dichloro-.

Sources

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