Mixture of Trichloromethane + Water

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Trichloromethane

Name
Trichloromethane
InChI
InChI=1S/CHCl3/c2-1(3)4/h1H
InChI Key
HEDRZPFGACZZDS-UHFFFAOYSA-N
Formula
CHCl3
SMILES
ClC(Cl)Cl
Mol. Weight (g/mol)
119.38
CAS
67-66-3

Water

Name
Water
InChI
InChI=1S/H2O/h1H2
InChI Key
XLYOFNOQVPJJNP-UHFFFAOYSA-N
Formula
H2O
SMILES
O
Mol. Weight (g/mol)
18.02
CAS
7732-18-5
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Datasets

  1. Mole fraction (30)
  2. Vapor Liquid Equilibrium at Constant Pressure

Mole fraction of Water (2) [ref]

Fixed Measured
Pressure, kPa - Liquid mixture 1 Temperature, K - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 1
101.30 293.15 0.9989

Mole fraction of Water (2) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 2
293.15 101.30 0.0092

Mole fraction of Trichloromethane (1) [ref]

Temperature, K - Gas Mole fraction of Trichloromethane (1) - Gas
328.95 0.8550
328.95 0.8600
328.95 0.8600
328.95 0.8490
328.95 0.8600
328.95 0.8490
328.95 0.8600
328.95 0.8550
329.15 0.8710
329.15 0.8540

Mole fraction of Trichloromethane (1) [ref]

Operational condition: Pressure, kPa = 101 (Gas)

Temperature, K - Gas Mole fraction of Trichloromethane (1) - Gas
329.65 0.8420
330.15 0.9000
330.15 0.8380
332.15 0.9510
334.15 0.9820
334.35 1.0000
335.15 0.8200
336.15 0.8050
342.15 0.7540
344.15 0.7360
348.15 0.7100
349.15 0.6880
351.15 0.6470
355.15 0.6190
357.15 0.5770
363.15 0.4720
366.15 0.4390
367.15 0.3380
370.15 0.1650
371.15 0.0950
372.15 0.0120
373.10 0.0000

Azeotropic composition: mole fraction of Trichloromethane (1) [ref]

Pressure, kPa - Liquid Azeotropic composition: mole fraction of Trichloromethane (1) - Liquid
101.30 0.8560

Azeotropic composition: mole fraction of Trichloromethane (1) [ref]

Temperature, K - Liquid Azeotropic composition: mole fraction of Trichloromethane (1) - Liquid
328.95 0.8560

Mass ratio of solute to solvent of Trichloromethane (1) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mass ratio of solute to solvent of Trichloromethane (1) - Liquid mixture 1
298.20 100.00 0.0075

Mass fraction of Water (2) [ref]

Operational conditions:

Mass fraction of Water (2) - Liquid mixture 1
0.0002
0.9926

Mass fraction of Water (2) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mass fraction of Water (2) - Liquid mixture 2
308.20 101.30 0.0010

Mass fraction of Trichloromethane (1) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mass fraction of Trichloromethane (1) - Liquid mixture 1
308.20 101.30 0.0051

Mass fraction of Trichloromethane (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2 Mass fraction of Trichloromethane (1) - Liquid mixture 1
308.20 0.0046
298.20 0.0059

Mass fraction of Trichloromethane (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2 Mass fraction of Trichloromethane (1) - Liquid mixture 2
308.20 0.9991
298.20 0.9992

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 2
283.15 0.0078
293.15 0.0093
298.15 0.0109
303.15 0.0130
313.15 0.0155
323.15 0.0183

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 1
283.15 0.9994
293.15 0.9989
298.15 0.9986
303.15 0.9978
313.15 0.9970
323.15 0.9961

Henry's Law constant (molality scale), kPa*kg/mol of Trichloromethane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid Henry's Law constant (molality scale), kPa*kg/mol of Trichloromethane (1) - Liquid
274.15 106.85
294.65 301.26
294.65 323.78
296.15 362.95
310.15 782.48
313.15 628.02
326.15 1165.7
331.15 1767.4

Mole fraction of Water (2) [ref]

Fixed Measured
Pressure, kPa - Liquid mixture 1 Temperature, K - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 1
101.30 293.15 0.9989

Mole fraction of Water (2) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 2
293.15 101.30 0.0092

Mole fraction of Trichloromethane (1) [ref]

Temperature, K - Gas Mole fraction of Trichloromethane (1) - Gas
328.95 0.8550
328.95 0.8600
328.95 0.8600
328.95 0.8490
328.95 0.8600
328.95 0.8490
328.95 0.8600
328.95 0.8550
329.15 0.8710
329.15 0.8540

Mole fraction of Trichloromethane (1) [ref]

Operational condition: Pressure, kPa = 101 (Gas)

Temperature, K - Gas Mole fraction of Trichloromethane (1) - Gas
329.65 0.8420
330.15 0.9000
330.15 0.8380
332.15 0.9510
334.15 0.9820
334.35 1.0000
335.15 0.8200
336.15 0.8050
342.15 0.7540
344.15 0.7360
348.15 0.7100
349.15 0.6880
351.15 0.6470
355.15 0.6190
357.15 0.5770
363.15 0.4720
366.15 0.4390
367.15 0.3380
370.15 0.1650
371.15 0.0950
372.15 0.0120
373.10 0.0000

Azeotropic composition: mole fraction of Trichloromethane (1) [ref]

Pressure, kPa - Liquid Azeotropic composition: mole fraction of Trichloromethane (1) - Liquid
101.30 0.8560

Azeotropic composition: mole fraction of Trichloromethane (1) [ref]

Temperature, K - Liquid Azeotropic composition: mole fraction of Trichloromethane (1) - Liquid
328.95 0.8560

Mass ratio of solute to solvent of Trichloromethane (1) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mass ratio of solute to solvent of Trichloromethane (1) - Liquid mixture 1
298.20 100.00 0.0075

Mass fraction of Water (2) [ref]

Operational conditions:

Mass fraction of Water (2) - Liquid mixture 1
0.0002
0.9926

Mass fraction of Water (2) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mass fraction of Water (2) - Liquid mixture 2
308.20 101.30 0.0010

Mass fraction of Trichloromethane (1) [ref]

Fixed Measured
Temperature, K - Liquid mixture 1 Pressure, kPa - Liquid mixture 1 Mass fraction of Trichloromethane (1) - Liquid mixture 1
308.20 101.30 0.0051

Mass fraction of Trichloromethane (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2 Mass fraction of Trichloromethane (1) - Liquid mixture 1
308.20 0.0046
298.20 0.0059

Mass fraction of Trichloromethane (1) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 2)

Temperature, K - Liquid mixture 2 Mass fraction of Trichloromethane (1) - Liquid mixture 2
308.20 0.9991
298.20 0.9992

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 2
283.15 0.0078
293.15 0.0093
298.15 0.0109
303.15 0.0130
313.15 0.0155
323.15 0.0183

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1 Mole fraction of Water (2) - Liquid mixture 1
283.15 0.9994
293.15 0.9989
298.15 0.9986
303.15 0.9978
313.15 0.9970
323.15 0.9961

Henry's Law constant (molality scale), kPa*kg/mol of Trichloromethane (1) [ref]

Operational condition: Mole fraction = 0 (Liquid)

Temperature, K - Liquid Henry's Law constant (molality scale), kPa*kg/mol of Trichloromethane (1) - Liquid
274.15 106.85
294.65 301.26
294.65 323.78
296.15 362.95
310.15 782.48
313.15 628.02
326.15 1165.7
331.15 1767.4

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 101.3 (VLE)

Fixed Measured
T [K] - VLE x1[mol/mol] of Trichloromethane (1) - Liquid y1[mol/mol] of Trichloromethane (1) - Vapour
334.35 1.0000 1.0000
334.15 0.9986 0.9820
332.15 0.9962 0.9510
330.15 0.9921 0.9000
329.15 0.9880 0.8710
328.95 0.9570 0.8550
328.95 0.0069 0.8550
329.15 0.0014 0.8540
329.65 0.0012 0.8420
330.15 0.0012 0.8380
335.15 0.0008 0.8200
336.15 0.0006 0.8050
342.15 0.0005 0.7540
344.15 0.0004 0.7360
348.15 0.0003 0.7100
349.15 0.0003 0.6880
351.15 0.0002 0.6470
355.15 0.0001 0.6190
357.15 0.0001 0.5770
363.15 0.0001 0.4720
366.15 0.0001 0.4390
367.15 0.0001 0.3380
370.15 0.0001 0.1650
371.15 0.0000 0.0950
372.15 0.0000 0.0120
373.15 0.0000 0.0000

Sources