Chemical Properties of Trichloromethane (CAS 67-66-3)

Trichloromethane

InChI
InChI=1S/CHCl3/c2-1(3)4/h1H
InChI Key
HEDRZPFGACZZDS-UHFFFAOYSA-N
Formula
CHCl3
SMILES
ClC(Cl)Cl
Molecular Weight1
119.38
CAS
67-66-3
Other Names
  • CHCl3
  • Chloroforme
  • Cloroformio
  • F 20
  • Formyl trichloride
  • Methane trichloride
  • Methane, trichloro-
  • Methenyl trichloride
  • Methyl trichloride
  • NCI-C02686
  • NSC 77361
  • R 20
  • R 20 (refrigerant)
  • R-20
  • Rcra waste number U044
  • Trichloormethaan
  • Trichlormethan
  • Trichloroform
  • Triclorometano
  • UN 1888
  • chloroform
  • freon 20
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Contents

  1. Physical Properties
  2. Temperature Dependent Properties
  3. Pressure Dependent Properties
  4. Datasets
  5. Correlations
  6. Similar Compounds
  7. Mixtures
  8. Sources

Physical Properties

Property Value Unit Source
ω 0.2180 KDB
Δcliquid [-474.00; -473.21] kJ/mol Show Hide
Δcliquid -473.21 kJ/mol NIST
Δcliquid -474.00 ± 8.40 kJ/mol NIST
μ 1.10 debye KDB
EA [0.62; 1.76] eV Show Hide
EA 0.62 ± 0.16 eV NIST
EA 1.76 ± 0.05 eV NIST
Δf -68.58 kJ/mol KDB
Rg 3.1780 KDB
Δfgas [-102.90; -101.30] kJ/mol Show Hide
Δfgas -101.30 kJ/mol KDB
Δfgas -102.90 ± 2.50 kJ/mol NIST
Δfliquid [-134.30; -134.10] kJ/mol Show Hide
Δfliquid -134.10 ± 2.50 kJ/mol NIST
Δfliquid -134.30 kJ/mol NIST
Δfus 7.41 kJ/mol Joback Calculated Property
Δvap [30.50; 31.40] kJ/mol Show Hide
Δvap 31.40 kJ/mol NIST
Δvap 31.32 ± 0.08 kJ/mol NIST
Δvap 31.10 kJ/mol NIST
Δvap 30.50 ± 0.42 kJ/mol NIST
IE [11.30; 11.50] eV Show Hide
IE 11.37 ± 0.02 eV NIST
IE 11.41 ± 0.02 eV NIST
IE 11.30 eV NIST
IE 11.48 eV NIST
IE 11.37 ± 0.02 eV NIST
IE 11.40 eV NIST
IE 11.50 eV NIST
IE 11.42 ± 0.03 eV NIST
IE 11.50 eV NIST
IE 11.48 eV NIST
log10WS [-1.17; -1.17]   Show Hide
log10WS -1.17 Aq. Solubility Prediction
log10WS -1.17 Estimated Solubility
logPoct/wat 1.986 Crippen Calculated Property
McVol 61.670 ml/mol McGowan Calculated Property
NFPA Health 2 KDB
Pc [5328.68; 5470.00] kPa Show Hide
Pc 5470.00 kPa KDB
Pc 5328.68 ± 10.13 kPa NIST
Pc 5328.68 ± 6.07 kPa NIST
ρc [458.41; 495.42] kg/m3 Show Hide
ρc 490.64 ± 3.58 kg/m3 NIST
ρc 458.41 ± 2.39 kg/m3 NIST
ρc 495.42 ± 2.39 kg/m3 NIST
Inp [561.00; 630.00]   Show Hide
Inp 617.20 NIST
Inp 619.00 NIST
Inp 628.40 NIST
Inp 625.80 NIST
Inp 621.10 NIST
Inp 618.20 NIST
Inp 614.80 NIST
Inp 607.90 NIST
Inp 604.00 NIST
Inp 606.00 NIST
Inp 604.00 NIST
Inp 606.80 NIST
Inp 610.00 NIST
Inp 604.00 NIST
Inp 608.00 NIST
Inp 602.00 NIST
Inp Outlier 582.00 NIST
Inp 609.00 NIST
Inp Outlier 568.00 NIST
Inp 595.20 NIST
Inp 616.00 NIST
Inp 610.00 NIST
Inp 587.00 NIST
Inp 622.00 NIST
Inp 622.00 NIST
Inp 613.00 NIST
Inp 598.00 NIST
Inp 601.00 NIST
Inp 616.00 NIST
Inp 615.00 NIST
Inp 601.00 NIST
Inp 621.70 NIST
Inp 601.00 NIST
Inp 590.00 NIST
Inp 618.00 NIST
Inp 600.00 NIST
Inp Outlier 561.00 NIST
Inp Outlier 569.00 NIST
Inp 630.00 NIST
Inp 605.00 NIST
Inp 615.00 NIST
Inp 601.00 NIST
Inp 615.00 NIST
Inp 618.00 NIST
Inp 618.00 NIST
Inp 600.00 NIST
Inp 588.00 NIST
Inp 601.00 NIST
Inp 616.00 NIST
Inp 609.00 NIST
Inp 617.00 NIST
Inp 609.00 NIST
Inp 609.00 NIST
Inp 611.00 NIST
Inp 629.00 NIST
Inp 609.00 NIST
Inp 603.00 NIST
Inp 620.00 NIST
Inp 618.00 NIST
Inp 609.00 NIST
Inp 601.00 NIST
Inp 601.00 NIST
Inp 603.00 NIST
Inp 605.00 NIST
Inp 620.00 NIST
Inp 609.00 NIST
Inp 611.00 NIST
Inp 601.00 NIST
Inp 606.00 NIST
Inp 603.00 NIST
Inp 609.00 NIST
Inp 616.00 NIST
Inp 595.00 NIST
Inp 605.00 NIST
Inp 605.00 NIST
Inp 615.00 NIST
Inp 618.00 NIST
Inp 598.00 NIST
I [992.00; 1045.00]   Show Hide
I 1037.00 NIST
I 1037.00 NIST
I 1034.00 NIST
I 1030.11 NIST
I 1028.95 NIST
I 1027.69 NIST
I 1026.00 NIST
I 1026.00 NIST
I 1024.00 NIST
I 1021.00 NIST
I 1020.00 NIST
I 1022.00 NIST
I 1026.00 NIST
I 1026.00 NIST
I 1013.00 NIST
I 1028.00 NIST
I 1010.00 NIST
I 1020.00 NIST
I 1021.00 NIST
I 1022.00 NIST
I 1022.00 NIST
I 1018.00 NIST
I 1020.00 NIST
I 1023.00 NIST
I 1022.00 NIST
I Outlier 999.00 NIST
I 1038.00 NIST
I 1010.00 NIST
I Outlier 1045.00 NIST
I 1007.00 NIST
I 1037.00 NIST
I 1037.00 NIST
I 1017.00 NIST
I 1025.00 NIST
I 1015.00 NIST
I 1016.00 NIST
I 1037.00 NIST
I 1037.00 NIST
I 1018.00 NIST
I 1020.00 NIST
I Outlier 992.00 NIST
I 1014.00 NIST
I 1014.00 NIST
I Outlier 1000.00 NIST
I Outlier 1000.00 NIST
I 1024.00 NIST
I 1037.00 NIST
I 1027.69 NIST
I 1010.00 NIST
I 1021.00 NIST
I 1013.00 NIST
I 1022.00 NIST
I 1014.00 NIST
I 1024.00 NIST
Tboil [333.95; 335.00] K Show Hide
Tboil Outlier 335.00 K The role of organic diluents in the aspects of equilibrium, kinetics and thermodynamic model for silver ion extraction using an extractant D2EHPA
Tboil 334.10 K Phase diagrams of (vapour + liquid) equilibrium for binary mixtures of a,a,a-trifluorotoluene with ethanol, or benzene, or chloroform at pressure 101.4 kPa
Tboil 334.35 K Separation of azeotrope (2,2,3,3-tetrafluoro-1-propanol + water): Isobaric vapour-liquid phase equilibrium measurements and azeotropic distillation
Tboil 334.12 K Isobaric Vapor-Liquid Phase Equilibrium Measurements for Allyl Alcohol with Chloroform, Ethyl Acetate, and Methyl Propionate at 101.3 kPa
Tboil 334.32 K KDB
Tboil 334.30 K NIST
Tboil 334.37 ± 0.15 K NIST
Tboil 334.45 ± 0.50 K NIST
Tboil 334.10 ± 0.30 K NIST
Tboil 334.35 ± 0.06 K NIST
Tboil 334.34 ± 0.25 K NIST
Tboil 334.39 ± 0.30 K NIST
Tboil 334.30 ± 0.20 K NIST
Tboil 334.35 ± 0.10 K NIST
Tboil 334.24 ± 0.15 K NIST
Tboil Outlier 333.95 ± 0.40 K NIST
Tboil 334.42 ± 0.35 K NIST
Tboil 334.42 ± 0.30 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.30 ± 0.20 K NIST
Tboil 334.30 ± 0.50 K NIST
Tboil 334.45 ± 0.50 K NIST
Tboil 334.20 ± 1.00 K NIST
Tboil 334.50 ± 0.20 K NIST
Tboil 334.22 ± 0.50 K NIST
Tboil 334.27 ± 0.30 K NIST
Tboil 334.30 ± 0.25 K NIST
Tboil 334.30 ± 0.50 K NIST
Tboil 334.23 ± 0.06 K NIST
Tboil 334.30 ± 0.30 K NIST
Tboil 334.40 ± 0.50 K NIST
Tboil 334.37 ± 0.20 K NIST
Tboil 334.20 ± 0.30 K NIST
Tboil 334.22 ± 0.20 K NIST
Tboil 334.35 ± 0.30 K NIST
Tboil 334.30 ± 0.50 K NIST
Tboil 334.15 ± 0.50 K NIST
Tboil 334.40 ± 0.30 K NIST
Tboil 334.35 ± 0.20 K NIST
Tboil 334.45 ± 0.60 K NIST
Tc [535.65; 538.90] K Show Hide
Tc 536.40 K KDB
Tc 536.40 K NIST
Tc Outlier 538.90 ± 0.80 K NIST
Tc 536.10 ± 0.20 K NIST
Tc 536.05 ± 0.50 K NIST
Tc 536.30 ± 0.25 K NIST
Tc 535.65 ± 0.30 K NIST
Tfus [209.50; 212.15] K Show Hide
Tfus 209.50 K KDB
Tfus 209.95 K Aq. Solubility Prediction
Tfus 209.73 ± 0.01 K NIST
Tfus 209.64 ± 0.10 K NIST
Tfus 210.15 ± 1.00 K NIST
Tfus 209.61 ± 0.08 K NIST
Tfus 209.65 ± 0.20 K NIST
Tfus 211.05 ± 0.30 K NIST
Tfus 209.50 ± 0.70 K NIST
Tfus 210.00 ± 2.00 K NIST
Tfus 209.65 ± 0.20 K NIST
Tfus 211.59 ± 0.50 K NIST
Tfus 209.90 ± 0.30 K NIST
Tfus Outlier 212.15 ± 1.00 K NIST
Tfus 210.46 ± 0.20 K NIST
Tfus 210.00 ± 2.00 K NIST
Ttriple 209.61 ± 0.20 K NIST
Vc 0.239 m3/kmol KDB
Vm 8.07e-05 m3/mol Excess Gibbs energies and volumes of the ternary system chloroform + tetrahydrofuran + cyclohexane at 298.15 K
Zc 0.2931300 KDB
Zra 0.28 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,gas [71.18; 82.74] J/mol×K [334.13; 532.11] Show Hide
Cp,gas 71.18 J/mol×K 334.13 Joback Calculated Property
Cp,gas 73.44 J/mol×K 367.13 Joback Calculated Property
Cp,gas 75.56 J/mol×K 400.12 Joback Calculated Property
Cp,gas 77.54 J/mol×K 433.12 Joback Calculated Property
Cp,gas 79.40 J/mol×K 466.12 Joback Calculated Property
Cp,gas 81.13 J/mol×K 499.12 Joback Calculated Property
Cp,gas 82.74 J/mol×K 532.11 Joback Calculated Property
Cp,liquid [110.00; 139.70] J/mol×K [240.00; 330.00] Show Hide
Cp,liquid 110.00 J/mol×K 240.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 110.00 J/mol×K 250.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 111.00 J/mol×K 260.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 112.00 J/mol×K 270.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 112.00 J/mol×K 273.15 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 112.00 J/mol×K 280.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 113.00 J/mol×K 290.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 116.20 J/mol×K 293.00 NIST
Cp,liquid 115.50 J/mol×K 293.20 NIST
Cp,liquid 117.10 J/mol×K 298.00 NIST
Cp,liquid 114.18 J/mol×K 298.00 NIST
Cp,liquid 113.00 J/mol×K 298.10 NIST
Cp,liquid 114.00 J/mol×K 298.15 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 114.25 J/mol×K 298.15 NIST
Cp,liquid 114.32 J/mol×K 298.15 NIST
Cp,liquid 114.35 J/mol×K 298.15 NIST
Cp,liquid 115.50 J/mol×K 298.15 NIST
Cp,liquid 113.85 J/mol×K 298.15 NIST
Cp,liquid 115.50 J/mol×K 298.15 NIST
Cp,liquid 113.73 J/mol×K 298.15 NIST
Cp,liquid 114.26 J/mol×K 298.15 NIST
Cp,liquid 113.20 J/mol×K 298.15 NIST
Cp,liquid 113.40 J/mol×K 300.00 NIST
Cp,liquid 114.00 J/mol×K 300.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 116.70 J/mol×K 303.00 NIST
Cp,liquid 114.00 J/mol×K 303.20 NIST
Cp,liquid 139.70 J/mol×K 303.60 NIST
Cp,liquid 116.00 J/mol×K 310.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 117.00 J/mol×K 320.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 119.00 J/mol×K 330.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
η [0.0004710; 0.0007130] Pa×s [273.15; 318.15] Show Hide
η 0.0007130 Pa×s 273.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
η 0.0006510 Pa×s 283.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
η 0.0006000 Pa×s 293.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
η 0.0005560 Pa×s 298.15 Densities, viscosities, and ultrasonic velocity studies of binary mixtures of trichloromethane with methanol, ethanol, propan-1-ol, and butan-1-ol at T=(298.15 and 308.15) K
η 0.0005760 Pa×s 298.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
η 0.0005340 Pa×s 303.15 Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Octan-1-ol and Decan-1-ol at (303.15 and 313.15) K
η 0.0005340 Pa×s 303.15 Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Propan-1-ol and Butan-1-ol at (303.15 and 313.15) K
η 0.0005200 Pa×s 303.15 Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
η 0.0005520 Pa×s 303.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
η 0.0005130 Pa×s 308.15 Densities, viscosities, and ultrasonic velocity studies of binary mixtures of trichloromethane with methanol, ethanol, propan-1-ol, and butan-1-ol at T=(298.15 and 308.15) K
η 0.0004910 Pa×s 313.15 Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Propan-1-ol and Butan-1-ol at (303.15 and 313.15) K
η 0.0004910 Pa×s 313.15 Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Octan-1-ol and Decan-1-ol at (303.15 and 313.15) K
η 0.0004710 Pa×s 313.15 Studies of viscosities of dilute solutions of alkylamine in non-electrolyte solvents. II. Haloalkanes and other polar solvents
η 0.0005090 Pa×s 313.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
η 0.0004910 Pa×s 318.15 Density, Viscosity, Vapor-Liquid Equilibrium, and Excess Molar Enthalpy of [Chloroform + Methyl tert-Butyl Ether]
ΔfusH [8.80; 8.80] kJ/mol [209.60; 209.60] Show Hide
ΔfusH 8.80 kJ/mol 209.60 NIST
ΔfusH 8.80 kJ/mol 209.60 NIST
ΔvapH [28.90; 35.00] kJ/mol [248.00; 501.00] Show Hide
ΔvapH 31.80 kJ/mol 248.00 NIST
ΔvapH 35.00 kJ/mol 274.50 NIST
ΔvapH 32.50 kJ/mol 296.50 NIST
ΔvapH 30.90 kJ/mol 320.50 NIST
ΔvapH 29.71 kJ/mol 334.30 KDB
ΔvapH 29.24 kJ/mol 334.30 NIST
ΔvapH 30.80 kJ/mol 366.50 NIST
ΔvapH 30.40 kJ/mol 374.50 NIST
ΔvapH 28.90 kJ/mol 445.50 NIST
ΔvapH 30.10 kJ/mol 501.00 NIST
ν [0.0000003; 0.0000004] m2/s [303.15; 313.15] Show Hide
ν 0.0000004 m2/s 303.15 Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Pentan-1-ol, Hexan-1-ol, and Heptan-1-ol at (303.15 and 313.15) K
ν 0.0000003 m2/s 313.15 Densities, Viscosities, and Ultrasonic Velocity Studies of Binary Mixtures of Chloroform with Pentan-1-ol, Hexan-1-ol, and Heptan-1-ol at (303.15 and 313.15) K
Pvap [32.19; 129.28] kPa [303.15; 342.00] Show Hide
Pvap 32.19 kPa 303.15 Density, Viscosity, Vapor-Liquid Equilibrium, Excess Molar Volume, Viscosity Deviation, and Their Correlations for the Chloroform + 2-Butanone Binary System
Pvap 32.19 kPa 303.15 Density, viscosity, isothermal (vapour + liquid) equilibrium, excess molar volume, viscosity deviation, and their correlations for chloroform + methyl isobutyl ketone binary system
Pvap 32.41 kPa 303.15 Total Vapor Pressure Measurements for 2-Ethoxyethanol with Carbon Tetrachloride, Chloroform, and Dichloromethane at 303.15 K
Pvap 34.81 kPa 305.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 42.47 kPa 310.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 51.43 kPa 315.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 61.85 kPa 320.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 73.88 kPa 325.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 87.71 kPa 330.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 101.30 kPa 334.12 Isobaric Vapor-Liquid Phase Equilibrium Measurements for Allyl Alcohol with Chloroform, Ethyl Acetate, and Methyl Propionate at 101.3 kPa
Pvap 101.30 kPa 334.35 Separation of azeotrope (2,2,3,3-tetrafluoro-1-propanol + water): Isobaric vapour-liquid phase equilibrium measurements and azeotropic distillation
Pvap 103.50 kPa 335.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 121.45 kPa 340.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
Pvap 129.28 kPa 342.00 Isobaric Vapor-Liquid and Liquid-Liquid Equilibria for Chloroform + Ethanol + 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate at 100 kPa
n0 [1.44100; 1.45000]   [283.15; 303.15] Show Hide
n0 1.45000 283.15 Partial Molar Volumes of N,N'-1,2-Ethyl-bis(salicyladimine) Schiff Base (Salen) in Organic Solvents at T = (283.15 to 318.15) K
n0 1.44710 288.15 Partial Molar Volumes of N,N'-1,2-Ethyl-bis(salicyladimine) Schiff Base (Salen) in Organic Solvents at T = (283.15 to 318.15) K
n0 1.44760 293.15 Solubilities of Phosphorus-Containing Compounds in Selected Solvents
n0 1.44390 293.15 Partial Molar Volumes of N,N'-1,2-Ethyl-bis(salicyladimine) Schiff Base (Salen) in Organic Solvents at T = (283.15 to 318.15) K
n0 1.44280 298.15 Vapour pressure and excess Gibbs energy of binary 1,2-dichloroethane + cyclohexanone, chloroform + cyclopentanone and chloroform + cyclohexanone mixtures at temperatures from 298.15 to 318.15 K
n0 1.44200 298.15 Partial Molar Volumes of N,N'-1,2-Ethyl-bis(salicyladimine) Schiff Base (Salen) in Organic Solvents at T = (283.15 to 318.15) K
n0 1.44300 298.15 Liquid-Liquid Equilibrium, Solid-Liquid Equilibrium, Densities, and Refractivity of a Water, Chloroform, and Acetylacetone Mixture
n0 1.44290 298.15 Study of Vapor-Liquid Equilibrium for Binary Mixtures (Chloroform + 2,2,2-Trifluoroethanol) and (r,r,r-Trifluorotoluene + 2,2,2-Trifluoroethanol) at Pressure 102 kPa
n0 1.44100 303.15 Densities, speeds of sound, isentropic compressibilities, refractive indexes, and viscosities of tetrahydrofuran with haloalkane or alkyl ethanoate at T = 303.15 K
ρl [1429.89; 1498.14] kg/m3 [288.15; 323.15] Show Hide
ρl 1498.08 kg/m3 288.15 Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K
ρl 1498.08 kg/m3 288.15 Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)
ρl 1498.08 kg/m3 288.15 Volumetric Properties of the Binary Methanol + Chloroform and Ternary Methanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K
ρl 1498.14 kg/m3 288.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 1492.31 kg/m3 288.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1491.86 kg/m3 288.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1498.08 kg/m3 288.15 Volumetric properties of the ternary system ethanol + chloroform + benzene at temperature range (288.15 313.15) K: Experimental data, correlation and prediction by cubic EOS
ρl 1489.00 kg/m3 293.00 KDB
ρl 1488.64 kg/m3 293.15 Volumetric properties of the ternary system ethanol + chloroform + benzene at temperature range (288.15 313.15) K: Experimental data, correlation and prediction by cubic EOS
ρl 1488.70 kg/m3 293.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 1488.64 kg/m3 293.15 Volumetric Properties of the Binary Methanol + Chloroform and Ternary Methanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K
ρl 1488.70 kg/m3 293.15 Excess volumes, Viscosities, and Excess Gibbs Energy of Activation for Viscous Flow, for binary and ternary mixtures 1- propanol + N-N dimethylformamid + chloroform at different temperatures
ρl 1488.64 kg/m3 293.15 Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)
ρl 1488.64 kg/m3 293.15 Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K
ρl 1487.63 kg/m3 293.15 Speed of sound, density and related thermodynamic excess properties of binary mixtures of butan-2-one with C1-C4 nalkanols and chloroform
ρl 1483.02 kg/m3 293.20 Isobaric vapour liquid equilibria for binary mixtures of 1,2-dibromoethane with 1,2-dichloroethane, trichloromethane, and 1,1,2,2-tetrachloroethane at atmospheric pressure
ρl 1478.16 kg/m3 298.15 Speed of sound, density and related thermodynamic excess properties of binary mixtures of butan-2-one with C1-C4 nalkanols and chloroform
ρl 1478.75 kg/m3 298.15 Densities, viscosities, and refractive indices of binary and ternary mixtures of methanol, acetone, and chloroform at temperatures from (298.15-318.15) K and ambient pressure
ρl 1479.15 kg/m3 298.15 Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K
ρl 1479.21 kg/m3 298.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 1473.16 kg/m3 298.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1479.15 kg/m3 298.15 Volumetric properties of the ternary system ethanol + chloroform + benzene at temperature range (288.15 313.15) K: Experimental data, correlation and prediction by cubic EOS
ρl 1473.42 kg/m3 298.15 Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
ρl 1479.15 kg/m3 298.15 Volumetric Properties of the Binary Methanol + Chloroform and Ternary Methanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K
ρl 1473.43 kg/m3 298.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1479.15 kg/m3 298.15 Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)
ρl 1480.34 kg/m3 298.20 The choice of solvent and liquid liquid equilibrium for ternary water + 2-methylaziridine + chloroform system: Experimental data and modeling
ρl 1475.30 kg/m3 303.00 Thermo-physical properties of 1,3,4-oxadiazole derivatives in pure solvents
ρl 1475.30 kg/m3 303.00 Thermo-acoustical studies of 1,3,4-oxadiazole as binary mixture at three different temperatures
ρl 1468.61 kg/m3 303.15 Speed of sound, density and related thermodynamic excess properties of binary mixtures of butan-2-one with C1-C4 nalkanols and chloroform
ρl 1469.16 kg/m3 303.15 Densities, viscosities, and refractive indices of binary and ternary mixtures of methanol, acetone, and chloroform at temperatures from (298.15-318.15) K and ambient pressure
ρl 1469.61 kg/m3 303.15 Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)
ρl 1470.50 kg/m3 303.15 Viscosity and Density for Binary Mixtures of Carbon Tetrachloride + Chloroform, Carbon Tetrachloride + Dichloromethane, and Chloroform + Dichloromethane and One Ternary Mixture of Chloroform + 1:1 (Carbon Tetrachloride + Dichloromethane) at 303.15 K
ρl 1469.69 kg/m3 303.15 Excess volumes, Viscosities, and Excess Gibbs Energy of Activation for Viscous Flow, for binary and ternary mixtures 1- propanol + N-N dimethylformamid + chloroform at different temperatures
ρl 1469.61 kg/m3 303.15 Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K
ρl 1469.61 kg/m3 303.15 Volumetric Properties of the Binary Methanol + Chloroform and Ternary Methanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K
ρl 1469.61 kg/m3 303.15 Volumetric properties of the ternary system ethanol + chloroform + benzene at temperature range (288.15 313.15) K: Experimental data, correlation and prediction by cubic EOS
ρl 1469.63 kg/m3 303.15 Volumetric behaviour of binary mixtures of (trichloromethane + amines) at temperatures between T = (288.15 and 303.15) K at p = 0.1 MPa
ρl 1470.80 kg/m3 308.00 Thermo-physical properties of 1,3,4-oxadiazole derivatives in pure solvents
ρl 1470.80 kg/m3 308.00 Thermo-acoustical studies of 1,3,4-oxadiazole as binary mixture at three different temperatures
ρl 1459.00 kg/m3 308.15 Speed of sound, density and related thermodynamic excess properties of binary mixtures of butan-2-one with C1-C4 nalkanols and chloroform
ρl 1454.33 kg/m3 308.15 Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
ρl 1460.03 kg/m3 308.15 Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)
ρl 1454.33 kg/m3 308.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1454.07 kg/m3 308.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1460.03 kg/m3 308.15 Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K
ρl 1460.03 kg/m3 308.15 Volumetric Properties of the Binary Methanol + Chloroform and Ternary Methanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K
ρl 1460.01 kg/m3 308.15 Densities, viscosities, and refractive indices of binary and ternary mixtures of methanol, acetone, and chloroform at temperatures from (298.15-318.15) K and ambient pressure
ρl 1460.03 kg/m3 308.15 Volumetric properties of the ternary system ethanol + chloroform + benzene at temperature range (288.15 313.15) K: Experimental data, correlation and prediction by cubic EOS
ρl 1465.80 kg/m3 313.00 Thermo-physical properties of 1,3,4-oxadiazole derivatives in pure solvents
ρl 1465.80 kg/m3 313.00 Thermo-acoustical studies of 1,3,4-oxadiazole as binary mixture at three different temperatures
ρl 1450.41 kg/m3 313.15 Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K
ρl 1450.39 kg/m3 313.15 Excess volumes, Viscosities, and Excess Gibbs Energy of Activation for Viscous Flow, for binary and ternary mixtures 1- propanol + N-N dimethylformamid + chloroform at different temperatures
ρl 1450.41 kg/m3 313.15 Volumetric properties of the ternary system ethanol + chloroform + benzene at temperature range (288.15 313.15) K: Experimental data, correlation and prediction by cubic EOS
ρl 1450.39 kg/m3 313.15 Densities, viscosities, and refractive indices of binary and ternary mixtures of methanol, acetone, and chloroform at temperatures from (298.15-318.15) K and ambient pressure
ρl 1450.41 kg/m3 313.15 Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)
ρl 1450.41 kg/m3 313.15 Volumetric Properties of the Binary Methanol + Chloroform and Ternary Methanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K
ρl 1440.03 kg/m3 318.15 Densities, viscosities, and refractive indices of binary and ternary mixtures of methanol, acetone, and chloroform at temperatures from (298.15-318.15) K and ambient pressure
ρl 1434.72 kg/m3 318.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclohexanone with Chloroalkanes at Temperatures between (288.15 and 318.15) K
ρl 1434.98 kg/m3 318.15 Volumetric Study for the Binary Nitromethane with Chloroalkane Mixtures at Temperatures in the Range (298.15 to 318.15) K
ρl 1434.97 kg/m3 318.15 Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K
ρl 1429.89 kg/m3 323.15 Excess volumes, Viscosities, and Excess Gibbs Energy of Activation for Viscous Flow, for binary and ternary mixtures 1- propanol + N-N dimethylformamid + chloroform at different temperatures
csound,fluid [916.63; 984.42] m/s [298.15; 318.15] Show Hide
csound,fluid 984.42 m/s 298.15 Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
csound,fluid 950.45 m/s 308.15 Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
csound,fluid 916.63 m/s 318.15 Speeds of sound, isentropic compressibilities and refractive indices for some binary mixtures of nitromethane with chloroalkane at temperatures from 298.15 to 318.15 K. Comparison with theories
γ [0.03; 0.03] N/m [293.15; 298.20] Show Hide
γ 0.03 N/m 293.15 Investigation of Surface Properties and Solubility of 1-Vinyl-3-alkyl/Esterimidazolium Halide Ionic Liquids by Density Functional Methods
γ 0.03 N/m 298.20 KDB

Pressure Dependent Properties

Property Value Unit Pressure (kPa) Source
Tboil 334.25 K 96.60 Low cost apparatus for rapid boiling point determination of small air sensitive samples under inert atmosphere

Datasets

Viscosity, Pa*s

Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
303.15 101.30 0.0005
Reference
Fixed Measured
Temperature, K - Liquid Pressure, kPa - Liquid Viscosity, Pa*s - Liquid
303.15 101.30 0.0005
Reference

Correlations

Property Value Unit Temperature (K) Source
Pvap [1.33; 5482.48] kPa [244.65; 536.40] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Pvp) = A + B/(T + C)
Coefficient A1.43630e+01
Coefficient B-2.83926e+03
Coefficient C-4.29370e+01
Temperature range, min.244.65
Temperature range, max.536.40
Pvap 1.33 kPa 244.65 Calculated Property
Pvap 9.36 kPa 277.07 Calculated Property
Pvap 40.90 kPa 309.48 Calculated Property
Pvap 129.81 kPa 341.90 Calculated Property
Pvap 328.67 kPa 374.32 Calculated Property
Pvap 705.23 kPa 406.73 Calculated Property
Pvap 1335.51 kPa 439.15 Calculated Property
Pvap 2296.22 kPa 471.57 Calculated Property
Pvap 3658.33 kPa 503.98 Calculated Property
Pvap 5482.48 kPa 536.40 Calculated Property
Pvap [0.08; 5628.11] kPa [209.63; 536.40] KDB Vapor Pressure Data Show Hide
Equationln(Pvp) = A + B/T + C*ln(T) + D*T^2
Coefficient A8.11439e+01
Coefficient B-6.35114e+03
Coefficient C-1.00709e+01
Coefficient D9.12761e-06
Temperature range, min.209.63
Temperature range, max.536.40
Pvap 0.08 kPa 209.63 Calculated Property
Pvap 1.54 kPa 245.94 Calculated Property
Pvap 12.69 kPa 282.25 Calculated Property
Pvap 59.51 kPa 318.55 Calculated Property
Pvap 192.92 kPa 354.86 Calculated Property
Pvap 487.71 kPa 391.17 Calculated Property
Pvap 1039.15 kPa 427.48 Calculated Property
Pvap 1965.80 kPa 463.78 Calculated Property
Pvap 3422.90 kPa 500.09 Calculated Property
Pvap 5628.11 kPa 536.40 Calculated Property

Similar Compounds

Chloroform, deutero-. Methane-d, trichloro-. Dichloromethyl radical. Methylene chloride. Methane-D2-, dichloro-. Chloromethylene. Trichloromethyl radical. BROMODICHLOROMETHANE. Fluorodichloromethane. Carbon Tetrachloride. Chloromethyl radical. Dichloromethylene. Trichloromonofluoromethane. Chlorofluoromethyl radical. Chloromethane.

Find more compounds similar to Trichloromethane.

Mixtures

Find more mixtures with Trichloromethane.

Sources

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