Chemical Properties of Trichloromonofluoromethane (CAS 75-69-4)

Trichloromonofluoromethane

InChI
InChI=1S/CCl3F/c2-1(3,4)5
InChI Key
CYRMSUTZVYGINF-UHFFFAOYSA-N
Formula
CCl3F
SMILES
FC(Cl)(Cl)Cl
Molecular Weight1
137.37
CAS
75-69-4
Other Names
  • Algofrene Type 1
  • Arcton 11
  • Arcton 9
  • CCl3F
  • CFCl3
  • Chladone 11
  • Chlorofluoromethane (CCl3F)
  • Daiflon 11
  • Daiflon S 1
  • Distillex DS6
  • Dymel 11
  • Electro-CF 11
  • F 11
  • F 11 (halocarbon)
  • F 11B
  • FC 11
  • FC 11, Halocarbon
  • FKW 11
  • Fluon 11
  • Fluorocarbon 11
  • Fluorochloroform
  • Freon 11
  • Freon 11A
  • Freon MF
  • Frigen 11
  • Frigen 11A
  • Frigen S 11
  • Genetron 11
  • Genetron 11SBA
  • Halon 11
  • Isceon 131
  • Isotron 11
  • Kaltron 11
  • Khladon 11
  • Ledon 11
  • Methane, fluorotrichloro-
  • Methane, trichlorofluoro-
  • Monofluorotrichloromethane
  • Propellant 11
  • R 11
  • R 11, Halocarbon
  • R-11
  • REFRIGERANT-11
  • Refrigerant 11
  • Refrigerant R11
  • Trichlorofluorocarbon
  • Trichloromethyl fluoride
  • Triclorofluormethane
  • fluorotrichloromethane
  • trichlorofluoromethane
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Physical Properties

Property Value Unit Source
ω 0.1890 KDB
μ 0.50 debye KDB
EA [1.02; 1.10] eV Show Hide
EA 1.02 eV NIST
EA 1.10 ± 0.30 eV NIST
εr 2.30 NCMS SOLV-DB
ΔfG° -245.50 kJ/mol KDB
ΔfH°gas [-290.00; -268.30] kJ/mol Show Hide
ΔfH°gas -284.70 kJ/mol KDB
ΔfH°gas -278.00 ± 8.80 kJ/mol NIST
ΔfH°gas -268.30 ± 8.40 kJ/mol NIST
ΔfH°gas -290.00 ± 20.00 kJ/mol NIST
ΔfusH° 6.60 kJ/mol Joback Calculated Property
ΔvapH° 25.02 kJ/mol NCMS SOLV-DB
IE [11.46; 11.90] eV Show Hide
IE 11.68 ± 0.13 eV NIST
IE 11.73 ± 0.02 eV NIST
IE Outlier 11.46 ± 0.02 eV NIST
IE 11.77 ± 0.01 eV NIST
IE 11.77 ± 0.02 eV NIST
IE 11.76 ± 0.01 eV NIST
IE 11.85 eV NIST
IE 11.90 eV NIST
log10WS -2.17 Relay (1.0) Calculated Property
logPoct/wat 2.530 NCMS SOLV-DB
McVol 63.440 ml/mol McGowan Calculated Property
Pc [4370.00; 4466.00] kPa Show Hide
Pc 4410.00 kPa KDB
Pc 4466.00 ± 12.00 kPa NIST
Pc 4370.00 ± 50.00 kPa NIST
Pc 4405.73 kPa NIST
ρc [553.59; 570.21] kg/m3 Show Hide
ρc 570.21 ± 0.55 kg/m3 NIST
ρc 553.59 ± 5.54 kg/m3 NIST
ρc 553.59 ± 1.37 kg/m3 NIST
Inp [460.00; 486.00]   Show Hide
Inp 486.00 NIST
Inp 470.00 NIST
Inp 485.00 NIST
Inp 486.00 NIST
Inp 482.00 NIST
Inp Outlier 460.00 NIST
Inp 478.00 NIST
Inp 478.00 NIST
Inp 484.00 NIST
Inp 482.00 NIST
Inp 484.00 NIST
Inp Outlier 460.00 NIST
Inp 484.00 NIST
Inp 470.00 NIST
I [605.00; 605.00]   Show Hide
I 605.00 NIST
I 605.00 NIST
S°liquid 225.60 J/mol×K NIST
Tboil [296.78; 296.92] K Show Hide
Tboil 296.90 K KDB
Tboil 296.78 K NCMS SOLV-DB
Tboil 296.90 K NIST
Tboil 296.80 ± 0.05 K NIST
Tboil 296.92 K NIST
Tc [471.10; 471.20] K Show Hide
Tc 471.20 K KDB
Tc 471.10 ± 0.50 K NIST
Tc 471.15 ± 0.10 K NIST
Tc 471.15 ± 0.04 K NIST
Tc 471.15 K NIST
Tc 471.15 ± 0.40 K NIST
Tfus [162.00; 165.40] K Show Hide
Tfus 162.04 K KDB
Tfus 162.67 K NCMS SOLV-DB
Tfus 162.00 ± 2.00 K NIST
Tfus 162.72 ± 0.01 K NIST
Tfus 162.70 ± 0.10 K NIST
Tfus Outlier 165.40 ± 0.20 K NIST
Tfus 162.67 ± 0.05 K NIST
Ttriple [162.10; 162.70] K Show Hide
Ttriple 162.19 ± 0.05 K NIST
Ttriple 162.69 ± 0.06 K NIST
Ttriple 162.67 ± 0.06 K NIST
Ttriple 162.68 ± 0.03 K NIST
Ttriple 162.65 ± 0.02 K NIST
Ttriple 162.69 ± 0.03 K NIST
Ttriple 162.70 ± 0.01 K NIST
Ttriple Outlier 162.10 ± 0.20 K NIST
Ttriple 162.68 ± 0.07 K NIST
Vc [0.247; 0.248] m3/kmol Show Hide
Vc 0.248 m3/kmol KDB
Vc 0.247 ± 0.006 m3/kmol NIST
Zc 0.2791570 KDB
Zra 0.27 KDB

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,liquid [109.50; 129.30] J/mol×K [170.00; 350.00] Show Hide
Cp,liquid 109.50 J/mol×K 170.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 110.40 J/mol×K 180.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 111.20 J/mol×K 190.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 112.00 J/mol×K 200.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 112.90 J/mol×K 210.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 113.70 J/mol×K 220.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 114.60 J/mol×K 230.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 115.50 J/mol×K 240.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 116.50 J/mol×K 250.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 117.50 J/mol×K 260.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 118.50 J/mol×K 270.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 118.90 J/mol×K 273.15 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 119.60 J/mol×K 280.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 120.80 J/mol×K 290.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 121.80 J/mol×K 298.15 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 121.55 J/mol×K 298.15 NIST
Cp,liquid 126.70 J/mol×K 298.15 NIST
Cp,liquid 122.00 J/mol×K 300.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 122.50 J/mol×K 303.15 NIST
Cp,liquid 123.30 J/mol×K 310.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 124.70 J/mol×K 320.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 126.10 J/mol×K 330.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 127.70 J/mol×K 340.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid 129.30 J/mol×K 350.00 Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
η 0.0004430 Pa×s 298.15 NCMS SOLV-DB
ΔfusH [6.89; 7.90] kJ/mol [162.68; 165.40] Show Hide
ΔfusH 6.89 kJ/mol 162.68 NIST
ΔfusH 6.90 kJ/mol 162.70 NIST
ΔfusH 7.90 kJ/mol 165.40 NIST
ΔvapH [24.70; 28.50] kJ/mol [231.00; 446.00] Show Hide
ΔvapH 28.20 kJ/mol 231.00 NIST
ΔvapH 28.50 kJ/mol 257.00 NIST
ΔvapH 27.30 kJ/mol 265.00 NIST
ΔvapH 27.10 kJ/mol 265.00 NIST
ΔvapH 26.40 kJ/mol 289.00 NIST
ΔvapH 25.20 kJ/mol 290.00 NIST
ΔvapH 25.21 kJ/mol 290.40 NIST
ΔvapH 24.77 kJ/mol 297.10 KDB
ΔvapH 25.60 kJ/mol 329.00 NIST
ΔvapH 24.70 kJ/mol 393.00 NIST
ΔvapH 25.10 kJ/mol 446.00 NIST
Pvap 107.06 kPa 298.15 NCMS SOLV-DB
n0 1.37900 298.15 NCMS SOLV-DB
ρl 1494.00 kg/m3 290.00 KDB
ΔfusS [42.38; 47.80] J/mol×K [162.68; 165.40] Show Hide
ΔfusS 42.38 J/mol×K 162.68 NIST
ΔfusS 47.80 J/mol×K 165.40 NIST
γ [0.02; 0.02] N/m [277.60; 298.15] Show Hide
γ 0.02 N/m 277.60 KDB
γ 0.02 N/m 298.15 NCMS SOLV-DB
ΔvapS 86.81 J/mol×K 290.40 NIST

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [78.00; 96.75] J/mol×K [298.00; 600.00] NIST Show Hide
EquationY = A + B·t + C·t² + D·t³ + E/t², t = T/1000
Y is Cp,gas in J/mol×K, T in K
Coefficient A3.40665e+01
Coefficient B2.30431e+02
Coefficient C-2.89456e+02
Coefficient D1.35525e+02
Coefficient E-2.32263e-01
ReferenceChase, 1998
CommentF=-307.5847, G=292.6202, H=-288.6964; Data last reviewed in June, 1970
Temperature range, min.298.00
Temperature range, max.600.00
Cp,gas 78.00 J/mol×K 298.00 Calculated Property
Cp,gas 81.47 J/mol×K 331.56 Calculated Property
Cp,gas 84.47 J/mol×K 365.11 Calculated Property
Cp,gas 87.05 J/mol×K 398.67 Calculated Property
Cp,gas 89.29 J/mol×K 432.22 Calculated Property
Cp,gas 91.22 J/mol×K 465.78 Calculated Property
Cp,gas 92.90 J/mol×K 499.33 Calculated Property
Cp,gas 94.35 J/mol×K 532.89 Calculated Property
Cp,gas 95.63 J/mol×K 566.44 Calculated Property
Cp,gas 96.75 J/mol×K 600.00 Calculated Property
Cp,gas [96.61; 108.00] J/mol×K [600.00; 6000.00] NIST Show Hide
EquationY = A + B·t + C·t² + D·t³ + E/t², t = T/1000
Y is Cp,gas in J/mol×K, T in K
Coefficient A1.06269e+02
Coefficient B1.24528e+00
Coefficient C-2.92652e-01
Coefficient D2.26580e-02
Coefficient E-3.71008e+00
ReferenceChase, 1998
CommentF=-331.8887, G=419.8728, H=-288.6964; Data last reviewed in June, 1970
Temperature range, min.600.00
Temperature range, max.6000.00
Cp,gas 96.61 J/mol×K 600.00 Calculated Property
Cp,gas 104.81 J/mol×K 1200.00 Calculated Property
Cp,gas 106.55 J/mol×K 1800.00 Calculated Property
Cp,gas 107.24 J/mol×K 2400.00 Calculated Property
Cp,gas 107.57 J/mol×K 3000.00 Calculated Property
Cp,gas 107.73 J/mol×K 3600.00 Calculated Property
Cp,gas 107.81 J/mol×K 4200.00 Calculated Property
Cp,gas 107.85 J/mol×K 4800.00 Calculated Property
Cp,gas 107.90 J/mol×K 5400.00 Calculated Property
Cp,gas 108.00 J/mol×K 6000.00 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 4420.29] kPa [214.36; 471.11] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.40921e+01
Coefficient B-2.49136e+03
Coefficient C-3.38850e+01
Temperature range, min.214.36
Temperature range, max.471.11
Pvap 1.33 kPa 214.36 Calculated Property
Pvap 8.77 kPa 242.89 Calculated Property
Pvap 36.73 kPa 271.42 Calculated Property
Pvap 113.08 kPa 299.94 Calculated Property
Pvap 280.04 kPa 328.47 Calculated Property
Pvap 590.88 kPa 357.00 Calculated Property
Pvap 1104.49 kPa 385.53 Calculated Property
Pvap 1879.56 kPa 414.05 Calculated Property
Pvap 2969.72 kPa 442.58 Calculated Property
Pvap 4420.29 kPa 471.11 Calculated Property
Pvap [4.88e-03; 4467.78] kPa [162.04; 471.20] KDB Vapor Pressure Data Show Hide
Equationln(Y) = A + B/T + C·ln(T) + D·T² + E/T²
Y is Pvap in kPa, T in K
Coefficient A7.72409e+01
Coefficient B-5.39795e+03
Coefficient C-9.73971e+00
Coefficient D1.15758e-05
Coefficient E0.00000e+00
Temperature range, min.162.04
Temperature range, max.471.20
Pvap 4.88e-03 kPa 162.04 Calculated Property
Pvap 0.29 kPa 196.39 Calculated Property
Pvap 4.33 kPa 230.74 Calculated Property
Pvap 28.32 kPa 265.09 Calculated Property
Pvap 111.85 kPa 299.44 Calculated Property
Pvap 319.38 kPa 333.80 Calculated Property
Pvap 735.39 kPa 368.15 Calculated Property
Pvap 1464.61 kPa 402.50 Calculated Property
Pvap 2643.90 kPa 436.85 Calculated Property
Pvap 4467.78 kPa 471.20 Calculated Property
Pvap [6.31; 88.57] kPa [236.48; 293.04] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.38802e+01
Coefficient B-2.42194e+03
Coefficient C-3.52870e+01
ReferenceOsborne, Garner, et al., 1941
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.236.48
Temperature range, max.293.04
Pvap 6.31 kPa 236.48 Calculated Property
Pvap 9.09 kPa 242.76 Calculated Property
Pvap 12.81 kPa 249.05 Calculated Property
Pvap 17.70 kPa 255.33 Calculated Property
Pvap 24.03 kPa 261.62 Calculated Property
Pvap 32.08 kPa 267.90 Calculated Property
Pvap 42.19 kPa 274.19 Calculated Property
Pvap 54.71 kPa 280.47 Calculated Property
Pvap 70.03 kPa 286.76 Calculated Property
Pvap 88.57 kPa 293.04 Calculated Property
Pvap [9.37; 323.52] kPa [243.50; 334.30] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.38488e+01
Coefficient B-2.40229e+03
Coefficient C-3.66020e+01
ReferenceBenning and McHarness, 1940
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.243.50
Temperature range, max.334.30
Pvap 9.37 kPa 243.50 Calculated Property
Pvap 16.08 kPa 253.59 Calculated Property
Pvap 26.30 kPa 263.68 Calculated Property
Pvap 41.25 kPa 273.77 Calculated Property
Pvap 62.36 kPa 283.86 Calculated Property
Pvap 91.27 kPa 293.94 Calculated Property
Pvap 129.80 kPa 304.03 Calculated Property
Pvap 179.93 kPa 314.12 Calculated Property
Pvap 243.76 kPa 324.21 Calculated Property
Pvap 323.52 kPa 334.30 Calculated Property
Pvap [9.37; 323.52] kPa [243.50; 334.30] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.38488e+01
Coefficient B-2.40229e+03
Coefficient C-3.66020e+01
ReferenceBenning and McHarness, 1940, 2
CommentCoefficents calculated by NIST from author's data.
Temperature range, min.243.50
Temperature range, max.334.30
Pvap 9.37 kPa 243.50 Calculated Property
Pvap 16.08 kPa 253.59 Calculated Property
Pvap 26.30 kPa 263.68 Calculated Property
Pvap 41.25 kPa 273.77 Calculated Property
Pvap 62.36 kPa 283.86 Calculated Property
Pvap 91.27 kPa 293.94 Calculated Property
Pvap 129.80 kPa 304.03 Calculated Property
Pvap 179.93 kPa 314.12 Calculated Property
Pvap 243.76 kPa 324.21 Calculated Property
Pvap 323.52 kPa 334.30 Calculated Property

Similar Compounds

Dichlorodifluoromethane. Trichloromethyl radical. Chlorofluoromethylene. Fluorodichloromethane. Carbon Tetrachloride. Methane, bromodichlorofluoro-. Dichloromethylene. Carbonic chloride fluoride. Methane, bromotrichloro-. Chlorotrifluoromethane. Chloroform, deutero-. Methane-d, trichloro-. Trichloromethane. Chlorofluoromethyl radical. METHANE, TRICHLOROIODO-.

Find more compounds similar to Trichloromonofluoromethane.

Mixtures

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