Mixture of Acetic acid, butyl ester + Water

Datasets

1. Activity coefficient (2)
2. Mole fraction (24)
3. η - Viscosity, Pa*s (2)
4. Interfacial tension, N/m (2)
5. n₀ - Refractive index (Na D-line) (2)
6. ρ_l - Mass density, kg/m3 (4)
7. γ - Surface tension liquid-gas, N/m (6)
8. Vapor Liquid Equilibrium at Constant Pressure
9. Vapor Liquid Equilibrium at Constant Temperature

Activity coefficient of Acetic acid, butyl ester (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of Acetic acid, butyl ester (1) - Liquid
273.35	613.0
283.15	799.0
293.15	942.0
298.15	1043.0
303.15	1081.0
313.15	1145.0
323.15	1161.0
333.15	1138.0

Activity coefficient of Acetic acid, butyl ester (1) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Mole fraction = 0 (Liquid)

Temperature, K - Liquid	Activity coefficient of Acetic acid, butyl ester (1) - Liquid
273.35	613.0
283.15	799.0
293.15	942.0
298.15	1043.0
303.15	1081.0
313.15	1145.0
323.15	1161.0
333.15	1138.0

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
293.20	0.0704
293.20	0.9988
313.20	0.0855
313.20	0.9988

Mole fraction of Acetic acid, butyl ester (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Acetic acid, butyl ester (1) - Liquid mixture 1
318.15	101.30	0.9190

Mole fraction of Acetic acid, butyl ester (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Acetic acid, butyl ester (1) - Liquid mixture 2
318.15	101.30	0.0060

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
10234.00	308.20	0.9976

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
348.15	0.0920
353.15	0.1180
358.15	0.1020
363.15	0.1290
368.15	0.1250
373.15	0.1500
378.15	0.1460
383.15	0.1660
388.15	0.2000
393.15	0.2100
398.15	0.2130

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
348.15	0.9950
353.15	0.9970
358.15	0.9900
363.15	0.9940
368.15	0.9920
373.15	0.9930
378.15	0.9940
383.15	0.9910
388.15	0.9850
393.15	0.9900
398.15	0.9940

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
298.15	0.9990
303.15	0.9990
308.15	0.9990
313.15	0.9991
318.15	0.9991
323.15	0.9991
328.15	0.9991
333.15	0.9991

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
298.15	0.0644
303.15	0.0680
308.15	0.0729
313.15	0.0784
318.15	0.0848
323.15	0.0927
328.15	0.1004
333.15	0.1073

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
304.15	0.1020
332.15	0.1316
366.15	0.1573

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
304.15	0.9995
332.15	0.9992
366.15	0.9991

Mole fraction of Water (2) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid mixture 2)
• Temperature, K = 323.15 (Liquid mixture 2)

Mole fraction of Water (2) - Liquid mixture 2
0.1210
0.1305

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 2	Pressure, kPa - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
323.15	101.00	0.9998

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 95 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
293.20	0.0704
293.20	0.9988
313.20	0.0855
313.20	0.9988

Mole fraction of Acetic acid, butyl ester (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Acetic acid, butyl ester (1) - Liquid mixture 1
318.15	101.30	0.9190

Mole fraction of Acetic acid, butyl ester (1) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 1	Pressure, kPa - Liquid mixture 1	Mole fraction of Acetic acid, butyl ester (1) - Liquid mixture 2
318.15	101.30	0.0060

Mole fraction of Water (2) [ref]

Fixed		Measured
Pressure, kPa - Liquid mixture 1	Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
10234.00	308.20	0.9976

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
348.15	0.0920
353.15	0.1180
358.15	0.1020
363.15	0.1290
368.15	0.1250
373.15	0.1500
378.15	0.1460
383.15	0.1660
388.15	0.2000
393.15	0.2100
398.15	0.2130

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
348.15	0.9950
353.15	0.9970
358.15	0.9900
363.15	0.9940
368.15	0.9920
373.15	0.9930
378.15	0.9940
383.15	0.9910
388.15	0.9850
393.15	0.9900
398.15	0.9940

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 1	Mole fraction of Water (2) - Liquid mixture 1
298.15	0.9990
303.15	0.9990
308.15	0.9990
313.15	0.9991
318.15	0.9991
323.15	0.9991
328.15	0.9991
333.15	0.9991

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101.3 (Liquid mixture 1)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
298.15	0.0644
303.15	0.0680
308.15	0.0729
313.15	0.0784
318.15	0.0848
323.15	0.0927
328.15	0.1004
333.15	0.1073

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
304.15	0.1020
332.15	0.1316
366.15	0.1573

Mole fraction of Water (2) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Temperature, K - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 2
304.15	0.9995
332.15	0.9992
366.15	0.9991

Mole fraction of Water (2) [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid mixture 2)
• Temperature, K = 323.15 (Liquid mixture 2)

Mole fraction of Water (2) - Liquid mixture 2
0.1210
0.1305

Mole fraction of Water (2) [ref]

Fixed		Measured
Temperature, K - Liquid mixture 2	Pressure, kPa - Liquid mixture 2	Mole fraction of Water (2) - Liquid mixture 1
323.15	101.00	0.9998

Viscosity, Pa*s [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 323.15 (Liquid)

Mole fraction of Water (2) - Liquid	Viscosity, Pa*s - Liquid
0.0200	0.0005
0.0400	0.0005
0.0600	0.0005
0.0800	0.0005

Viscosity, Pa*s [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 323.15 (Liquid)

Mole fraction of Water (2) - Liquid	Viscosity, Pa*s - Liquid
0.0200	0.0005
0.0400	0.0005
0.0600	0.0005
0.0800	0.0005

Interfacial tension, N/m [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid mixture 1	Temperature, K - Liquid mixture 1	Interfacial tension, N/m - Liquid mixture 1
0.9998	323.15	0.0142

Interfacial tension, N/m [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid mixture 1	Temperature, K - Liquid mixture 1	Interfacial tension, N/m - Liquid mixture 1
0.9998	323.15	0.0142

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Water (2) - Liquid	Refractive index (Na D-line) - Liquid
293.20	0.0704	1.3939
293.20	0.9988	1.3337
313.20	0.0855	1.3843
313.20	0.9988	1.3307

Refractive index (Na D-line) [ref]

Operational condition: Pressure, kPa = 95 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Water (2) - Liquid	Refractive index (Na D-line) - Liquid
293.20	0.0704	1.3939
293.20	0.9988	1.3337
313.20	0.0855	1.3843
313.20	0.9988	1.3307

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
293.20	0.0704	882.76
293.20	0.9988	998.132
313.20	0.0855	862.224
313.20	0.9988	992.026

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 323.15 (Liquid)

Mole fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
0.0200	850.18
0.0400	850.62
0.0600	851.07
0.0800	851.57

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 95 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
293.20	0.0704	882.76
293.20	0.9988	998.132
313.20	0.0855	862.224
313.20	0.9988	992.026

Mass density, kg/m3 [ref]

Operational conditions:

• Pressure, kPa = 101 (Liquid)
• Temperature, K = 323.15 (Liquid)

Mole fraction of Water (2) - Liquid	Mass density, kg/m3 - Liquid
0.0200	850.18
0.0400	850.62
0.0600	851.07
0.0800	851.57

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 323.15 (Liquid)

Mole fraction of Water (2) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0200	0.0221
0.0400	0.0222
0.0600	0.0222
0.0800	0.0222

Surface tension liquid-gas, N/m [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid mixture 2	Temperature, K - Liquid mixture 2	Surface tension liquid-gas, N/m - Liquid mixture 2
0.1305	323.15	0.0217

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Acetic acid, butyl ester (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0000	0.0716
0.0001	0.0637
0.0001	0.0645
0.0001	0.0637
0.0001	0.0643
0.0001	0.0626
0.0001	0.0618
0.0001	0.0615
0.0001	0.0612
0.0002	0.0593
0.0002	0.0575
0.0003	0.0555
0.0003	0.0533
0.0004	0.0511
0.0005	0.0491
0.0007	0.0469
0.0008	0.0456
0.0008	0.0444
0.0009	0.0431
1.0000	0.0249

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 323.15 (Liquid)

Mole fraction of Water (2) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0200	0.0221
0.0400	0.0222
0.0600	0.0222
0.0800	0.0222

Surface tension liquid-gas, N/m [ref]

Fixed		Measured
Mole fraction of Water (2) - Liquid mixture 2	Temperature, K - Liquid mixture 2	Surface tension liquid-gas, N/m - Liquid mixture 2
0.1305	323.15	0.0217

Surface tension liquid-gas, N/m [ref]

Operational condition: Temperature, K = 298.15 (Liquid)

Mole fraction of Acetic acid, butyl ester (1) - Liquid	Surface tension liquid-gas, N/m - Liquid
0.0000	0.0716
0.0001	0.0637
0.0001	0.0645
0.0001	0.0637
0.0001	0.0643
0.0001	0.0626
0.0001	0.0618
0.0001	0.0615
0.0001	0.0612
0.0002	0.0593
0.0002	0.0575
0.0003	0.0555
0.0003	0.0533
0.0004	0.0511
0.0005	0.0491
0.0007	0.0469
0.0008	0.0456
0.0008	0.0444
0.0009	0.0431
1.0000	0.0249

Vapor Liquid Equilibrium at Constant Pressure [ref]

Operational condition: Pressure, kPa = 13.332 (VLE)

Fixed	Measured
T [K] - VLE	x1[mol/mol] of Water (2) - Liquid	y1[mol/mol] of Water (2) - Vapour
341.85	0.0000	0.0000
335.15	0.0200	0.2680
330.15	0.0390	0.4260
324.95	0.0610	0.5600
320.15	0.0860	0.6590
318.15	0.0980	0.6950
318.15	0.9992	0.7130
320.15	0.9994	0.7880
324.95	1.0000	1.0000

Vapor Liquid Equilibrium at Constant Temperature [ref]

Operational condition: Temperature, K = 317.75 (VLE)

Fixed	Measured
P [kPa] - VLE	x1[mol/mol] of Water (2) - Liquid	y1[mol/mol] of Water (2) - Vapour
4.426	0.0000	0.0000
6.199	0.0200	0.3000
7.973	0.0400	0.4670
9.746	0.0600	0.5730
11.519	0.0800	0.6460
13.279	0.0999	0.7000
13.279	0.9991	0.7000
11.519	0.9995	0.8080

Sources

• Dortmund Data Bank Vapor-Liquid Equilibrium Data
• Temperature dependence of limiting activity coefficients, Henry's law constants, and related infinite dilution properties of C4-C6 isomeric n-alkyl ethanoates/ethyl n-alkanoates in water. Measurement, critical compilation, correlation, and recommended data
• Liquid-liquid equilibrium data for ternary systems of water + acetic acid + acetate esters at 293.2 K and 303.2 K and ~ 95 kPa
• Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure
• Liquid phase equilibria of (water + phosphoric acid + 1-butanol or butyl acetate) ternary systems at T = 308.2 K
• Thermodynamics of Phase and Chemical Equilibrium in a Strongly Nonideal Esterification System.
• Liquid-Liquid Equilibria for Water + Benzonitrile + Ethyl Acetate or + Butyl Acetate
• Liquid-Liquid Equilibria for the Ternary Systems Acetic Acid + Water + Butyl Acetate and Acetic Acid + Water + 2-Methyl Propyl Acetate at 304.15 K, 332.15 K, and 366.15 K
• Liquid-Liquid Equilibria, Density, Viscosity, and Surface and Interfacial Tension of the System Water + n-Butyl Acetate + 1-Propanol at 323.15 K and Atmospheric Pressure
• Surface Tension Data of Aqueous Binary Mixtures of Methyl, Ethyl, Propyl, and Butyl Acetates at 298.15 K