Mixture of Methyl formate + Butane, 1,4-dibromo-

Name: Methyl formate
InChI: InChI=1S/C2H4O2/c1-4-2-3/h2H,1H3
InChI Key: TZIHFWKZFHZASV-UHFFFAOYSA-N
Formula: C2H4O2
SMILES: COC=O
Mol. Weight (g/mol): 60.05
CAS: 107-31-3

Name: Butane, 1,4-dibromo-
InChI: InChI=1S/C4H8Br2/c5-3-1-2-4-6/h1-4H2
InChI Key: ULTHEAFYOOPTTB-UHFFFAOYSA-N
Formula: C4H8Br2
SMILES: BrCCCCBr
Mol. Weight (g/mol): 215.91
CAS: 110-52-1

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Datasets

Excess molar enthalpy (molar enthalpy (2)
ρ_l - Mass density, kg/m3 (2)

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Methyl formate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.1163	0.3949
0.2218	0.6355
0.3327	0.8586
0.4395	0.9849
0.5180	1.0243
0.5810	1.0147
0.5984	1.0078
0.6591	0.9447
0.7346	0.8185
0.8107	0.6485
0.8851	0.4337
0.9503	0.2099

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Methyl formate (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.1163	0.3949
0.2218	0.6355
0.3327	0.8586
0.4395	0.9849
0.5180	1.0243
0.5810	1.0147
0.5984	1.0078
0.6591	0.9447
0.7346	0.8185
0.8107	0.6485
0.8851	0.4337
0.9503	0.2099

Mass density, kg/m3 [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Methyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
0.0901	1776.76
0.1948	1721.83
0.2830	1670.26
0.3632	1619.15
0.4351	1569.44
0.5042	1517.68
0.5678	1466.2
0.6267	1414.75
0.6804	1364.36
0.7742	1267.13
0.8172	1217.73
0.8611	1164.21
0.8985	1115.55
0.9370	1062.14
0.9687	1015.8

Mass density, kg/m3 [ref]

Operational conditions:

Temperature, K = 298.15 (Liquid)
Pressure, kPa = 101 (Liquid)

Mole fraction of Methyl formate (1) - Liquid	Mass density, kg/m3 - Liquid
0.0901	1776.76
0.1948	1721.83
0.2830	1670.26
0.3632	1619.15
0.4351	1569.44
0.5042	1517.68
0.5678	1466.2
0.6267	1414.75
0.6804	1364.36
0.7742	1267.13
0.8172	1217.73
0.8611	1164.21
0.8985	1115.55
0.9370	1062.14
0.9687	1015.8

Sources

Thermodynamic study of (alkyl esters + alpha,omega-alkyl dihalides) IV: Hex and Vex for 25 binary mixtures {xC(u-1)H(2u-1)CO2CH3 + (1-x)alpha,omega-BrCH2(CH2)(v-2)CH2Br}, where u = 1 to 5, alpha = 1 and v = omega = 2 to 6