Chemical Properties of Butane, 1,4-dibromo- (CAS 110-52-1)

Butane, 1,4-dibromo-

InChI
InChI=1S/C4H8Br2/c5-3-1-2-4-6/h1-4H2
InChI Key
ULTHEAFYOOPTTB-UHFFFAOYSA-N
Formula
C4H8Br2
SMILES
BrCCCCBr
Molecular Weight1
215.91
CAS
110-52-1
Other Names
  • 1,4-Butylene bromide
  • 1,4-Dibrombutan
  • 1,4-dibromobutane
  • BrCH2CH2CH2CH2Br
  • DBB
  • Dibromo-1,4 butane
  • tetramethylene dibromide
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Physical Properties

Property Value Unit Source
ω 0.5240 Relay (1.0) Calculated Property
ΔfG° 11.44 kJ/mol Joback Calculated Property
ΔfH°gas -85.98 kJ/mol NIST
ΔfH°liquid -140.10 ± 5.10 kJ/mol NIST
ΔfusH° 16.69 kJ/mol Joback Calculated Property
ΔvapH° [52.60; 53.09] kJ/mol Show Hide
ΔvapH° 53.09 kJ/mol NIST
ΔvapH° 52.60 kJ/mol NIST
ΔvapH° 53.05 kJ/mol NIST
ΔvapH° 53.09 ± 0.12 kJ/mol NIST
IE [10.15; 10.27] eV Show Hide
IE 10.15 eV NIST
IE 10.27 eV NIST
log10WS -3.01 Relay (1.0) Calculated Property
logPoct/wat 2.556 Crippen Calculated Property
McVol 102.220 ml/mol McGowan Calculated Property
Pc 4665.71 kPa Joback Calculated Property
Inp [1042.00; 1114.00]   Show Hide
Inp 1094.00 NIST
Inp 1114.00 NIST
Inp 1057.00 NIST
Inp 1094.00 NIST
Inp 1042.00 NIST
Inp 1084.60 NIST
Inp 1057.70 NIST
Inp 1094.00 NIST
I [1559.00; 1584.00]   Show Hide
I 1559.00 NIST
I 1584.00 NIST
I 1561.00 NIST
I 1559.00 NIST
Tboil [466.00; 471.00] K Show Hide
Tboil 470.20 K NIST
Tboil 466.00 ± 3.00 K NIST
Tboil 471.00 ± 3.00 K NIST
Tc 648.52 K Relay (1.0) Calculated Property
Tfus 252.10 ± 0.50 K NIST
Vc 0.374 m3/kmol Relay (1.0) Calculated Property

Temperature Dependent Properties

Property Value Unit Temperature (K) Source
Cp,liquid [189.62; 202.14] J/mol×K [285.15; 355.15] Show Hide
Cp,liquid 189.62 J/mol×K 285.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 189.85 J/mol×K 286.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 190.08 J/mol×K 288.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 190.32 J/mol×K 289.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 190.55 J/mol×K 291.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 190.79 J/mol×K 292.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 191.03 J/mol×K 294.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 191.27 J/mol×K 295.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 191.52 J/mol×K 297.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 191.68 J/mol×K 298.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 191.20 J/mol×K 298.15 NIST
Cp,liquid 191.76 J/mol×K 298.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 192.01 J/mol×K 300.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 192.26 J/mol×K 301.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 192.51 J/mol×K 303.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 192.76 J/mol×K 304.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 193.01 J/mol×K 306.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 193.26 J/mol×K 307.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 193.52 J/mol×K 309.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 193.78 J/mol×K 310.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 194.04 J/mol×K 312.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 194.30 J/mol×K 313.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 194.56 J/mol×K 315.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 194.82 J/mol×K 316.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 195.09 J/mol×K 318.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 195.35 J/mol×K 319.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 195.62 J/mol×K 321.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 195.89 J/mol×K 322.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 196.16 J/mol×K 324.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 196.44 J/mol×K 325.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 196.71 J/mol×K 327.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 196.99 J/mol×K 328.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 197.27 J/mol×K 330.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 197.55 J/mol×K 331.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 197.83 J/mol×K 333.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 198.11 J/mol×K 334.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 198.40 J/mol×K 336.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 198.68 J/mol×K 337.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 198.97 J/mol×K 339.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 199.26 J/mol×K 340.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 199.55 J/mol×K 342.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 199.84 J/mol×K 343.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 200.14 J/mol×K 345.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 200.43 J/mol×K 346.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 200.73 J/mol×K 348.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 201.03 J/mol×K 349.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 201.33 J/mol×K 351.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 201.63 J/mol×K 352.65 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 201.93 J/mol×K 354.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
Cp,liquid 202.14 J/mol×K 355.15 Heat Capacity of alpha,omega-Bromochloroalkanes and ?,?-Dibromoalkanes: Their Dependence on the Hydrocarbon Chain Length and Temperature (285.15 to 355.15) K
ΔvapH [49.40; 51.40] kJ/mol [387.50; 447.50] Show Hide
ΔvapH 49.40 kJ/mol 387.50 NIST
ΔvapH 51.40 kJ/mol 447.50 NIST
n0 1.51630 298.15 Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) II: HE m and V E m for 25 binary mixtures {xCu-1H2u-1CO2C2H5 + (1 - x)a,x-BrCH2(CH2)v-2CH2Br}, where u = 1 to 5, a = 1 and v = x = 2 to 6
γ [0.04; 0.04] N/m [293.15; 313.15] Show Hide
γ 0.04 N/m 293.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.04 N/m 298.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.04 N/m 303.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.04 N/m 308.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes
γ 0.04 N/m 313.15 The additivity of surface and volumetric properties of alpha,omega-dihalogenoalkanes

Pressure Dependent Properties

Property Value Unit Pressure (kPa) Source
Tboilr [337.20; 338.00] K [0.80; 0.80] Show Hide
Tboilr 337.20 K 0.80 NIST
Tboilr 338.00 K 0.80 NIST

Correlations

Property Value Unit Temperature (K) Source
Cp,gas [118.31; 243.83] J/mol×K [273.00; 1000.00] Joback Predicted correlation Show Hide
EquationY = A + B·T + C·T² + D·T³ + E·T⁴
Y is Cp,gas in J/mol×K, T in K
Coefficient A1.56340e+01
Coefficient B4.60200e-01
Coefficient C-3.36600e-04
Coefficient D1.04600e-07
Coefficient E0.00000e+00
Temperature range, min.273.00
Temperature range, max.1000.00
Cp,gas 118.31 J/mol×K 273.00 Calculated Property
Cp,gas 140.95 J/mol×K 353.78 Calculated Property
Cp,gas 160.64 J/mol×K 434.56 Calculated Property
Cp,gas 177.72 J/mol×K 515.33 Calculated Property
Cp,gas 192.51 J/mol×K 596.11 Calculated Property
Cp,gas 205.36 J/mol×K 676.89 Calculated Property
Cp,gas 216.58 J/mol×K 757.67 Calculated Property
Cp,gas 226.51 J/mol×K 838.44 Calculated Property
Cp,gas 235.49 J/mol×K 919.22 Calculated Property
Cp,gas 243.83 J/mol×K 1000.00 Calculated Property
Property Value Unit Temperature (K) Source
η [0.0032981; 0.0003900] Pa×s [252.10; 440.97] Joback Predicted correlation Show Hide
EquationY = exp(A + B/T + C·ln(T) + D·T^E)
Y is η in Pa×s, T in K
Coefficient A-1.06991e+01
Coefficient B1.25664e+03
Coefficient C0.00000e+00
Coefficient D0.00000e+00
Coefficient E0.00000e+00
Temperature range, min.252.10
Temperature range, max.440.97
η 0.0032981 Pa×s 252.10 Calculated Property
η 0.0022486 Pa×s 273.09 Calculated Property
η 0.0016192 Pa×s 294.07 Calculated Property
η 0.0012181 Pa×s 315.06 Calculated Property
η 0.0009495 Pa×s 336.04 Calculated Property
η 0.0007622 Pa×s 357.03 Calculated Property
η 0.0006269 Pa×s 378.01 Calculated Property
η 0.0005263 Pa×s 399.00 Calculated Property
η 0.0004497 Pa×s 419.98 Calculated Property
η 0.0003900 Pa×s 440.97 Calculated Property
Property Value Unit Temperature (K) Source
Pvap [1.33; 202.66] kPa [353.08; 498.51] The Yaws Handbook of Vapor Pressure Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.51599e+01
Coefficient B-4.23974e+03
Coefficient C-6.80070e+01
Temperature range, min.353.08
Temperature range, max.498.51
Pvap 1.33 kPa 353.08 Calculated Property
Pvap 2.96 kPa 369.24 Calculated Property
Pvap 6.06 kPa 385.40 Calculated Property
Pvap 11.58 kPa 401.56 Calculated Property
Pvap 20.83 kPa 417.72 Calculated Property
Pvap 35.58 kPa 433.87 Calculated Property
Pvap 58.08 kPa 450.03 Calculated Property
Pvap 91.12 kPa 466.19 Calculated Property
Pvap 138.03 kPa 482.35 Calculated Property
Pvap 202.66 kPa 498.51 Calculated Property
Pvap [4.00; 320.55] kPa [375.15; 520.15] KDB Vapor Pressure Data Show Hide
Equationln(Y) = A + B/T + C·ln(T) + D·T² + E/T²
Y is Pvap in kPa, T in K
Coefficient A9.74283e+01
Coefficient B-1.01050e+04
Coefficient C-1.17919e+01
Coefficient D5.60527e-06
Coefficient E0.00000e+00
Temperature range, min.375.15
Temperature range, max.520.15
Pvap 4.00 kPa 375.15 Calculated Property
Pvap 7.92 kPa 391.26 Calculated Property
Pvap 14.69 kPa 407.37 Calculated Property
Pvap 25.76 kPa 423.48 Calculated Property
Pvap 42.98 kPa 439.59 Calculated Property
Pvap 68.71 kPa 455.71 Calculated Property
Pvap 105.76 kPa 471.82 Calculated Property
Pvap 157.45 kPa 487.93 Calculated Property
Pvap 227.60 kPa 504.04 Calculated Property
Pvap 320.55 kPa 520.15 Calculated Property
Pvap [0.13; 100.11] kPa [305.00; 470.70] NIST Show Hide
Equationln(Y) = A + B/(T + C)
Y is Pvap in kPa, T in K
Coefficient A1.52214e+01
Coefficient B-4.58197e+03
Coefficient C-3.90570e+01
ReferenceStull, 1947
Temperature range, min.305.00
Temperature range, max.470.70
Pvap 0.13 kPa 305.00 Calculated Property
Pvap 0.41 kPa 323.41 Calculated Property
Pvap 1.09 kPa 341.82 Calculated Property
Pvap 2.60 kPa 360.23 Calculated Property
Pvap 5.63 kPa 378.64 Calculated Property
Pvap 11.28 kPa 397.06 Calculated Property
Pvap 21.09 kPa 415.47 Calculated Property
Pvap 37.20 kPa 433.88 Calculated Property
Pvap 62.38 kPa 452.29 Calculated Property
Pvap 100.11 kPa 470.70 Calculated Property

Similar Compounds

Butane, 1-bromo-. Pentane, 1,5-dibromo-. Pentane, 1-bromo-. 1,6-DIBROMOHEXANE. 1,7-DIBROMOHEPTANE. 1,11-Dibromoundecane. 1,16-Dibromohexadecane. 1,14-dibromotetradecane. Decane, 1,10-dibromo-. Nonane, 1,9-dibromo-. Dodecane, 1,12-dibromo-. Octane, 1,8-dibromo-. Butanenitrile, 4-bromo-. Cyclobutyl bromide. Hexane, 1-bromo-.

Find more compounds similar to Butane, 1,4-dibromo-.

Mixtures

Sources

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