Chemical Properties of Butane, 1-bromo- (CAS 109-65-9)

InChI

InChI=1S/C4H9Br/c1-2-3-4-5/h2-4H2,1H3

InChI Key

MPPPKRYCTPRNTB-UHFFFAOYSA-N

Formula

C4H9Br

SMILES

CCCCBr

Molecular Weight¹

137.02

CAS

109-65-9

Other Names

• 1-bromobutane
• UN 1126
• butyl bromide
• n-C4H9Br
• n-butyl bromide

• ω : Acentric Factor.
• Δ_cH°_liquid : Standard liquid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_liquid : Liquid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_fusH : Enthalpy of fusion at a given temperature (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• P_c : Critical Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• Δ_fusS : Entropy of fusion at a given temperature (J/mol×K).
• S°_liquid : Liquid phase molar entropy at standard conditions (J/mol×K).
• c_sound,fluid : Speed of sound in fluid (m/s).
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• T_fus : Normal melting (fusion) point (K).
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	[0.3390; 0.3471]
ω	0.3471		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω	0.3390		KDB
ΔcH°liquid	-2716.50 ± 1.30	kJ/mol	NIST
ΔfG°	-2.88	kJ/mol	Joback Calculated Property
ΔfH°gas	-107.00 ± 2.00	kJ/mol	NIST
ΔfH°liquid	[-148.00; -143.80]	kJ/mol
ΔfH°liquid	-148.00	kJ/mol	NIST
ΔfH°liquid	-143.80 ± 1.30	kJ/mol	NIST
ΔfusH°	9.12	kJ/mol	Thermodynamics of Ionic Liquid Precursors. 1-Bromobutane and Its Isomers
ΔvapH°	[36.40; 36.71]	kJ/mol
ΔvapH°	36.71	kJ/mol	NIST
ΔvapH°	36.40	kJ/mol	NIST
ΔvapH°	36.40	kJ/mol	NIST
ΔvapH°	36.60 ± 0.10	kJ/mol	NIST
ΔvapH°	36.60 ± 0.10	kJ/mol	NIST
ΔvapH°	36.70 ± 0.10	kJ/mol	NIST
ΔvapH°	36.70 ± 0.10	kJ/mol	NIST
IE	[10.11; 10.15]	eV
IE	10.13 ± 0.02	eV	NIST
IE	10.11	eV	NIST
IE	10.12	eV	NIST
IE	10.15	eV	NIST
IE	10.13 ± 0.01	eV	NIST
IE	10.13 ± 0.01	eV	NIST
log10WS	[-2.37; -2.37]
log10WS	-2.37		Aq. Solubility Prediction
log10WS	-2.37		Estimated Solubility
logPoct/wat	2.181		Crippen Calculated Property
McVol	84.720	ml/mol	McGowan Calculated Property
Pc	[4260.00; 4629.54]	kPa
Pc	4629.54	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc	4260.00	kPa	KDB
Inp	[698.00; 753.00]
Inp	701.90		NIST
Inp	703.60		NIST
Inp	712.20		NIST
Inp	710.00		NIST
Inp	706.90		NIST
Inp	705.40		NIST
Inp	703.50		NIST
Inp	731.40		NIST
Inp	730.40		NIST
Inp	732.00		NIST
Inp	716.80		NIST
Inp	704.00		NIST
Inp	706.00		NIST
Inp	715.00		NIST
Inp	738.00		NIST
Inp	Outlier 753.00		NIST
Inp	711.00		NIST
Inp	698.00		NIST
Inp	704.00		NIST
Inp	708.00		NIST
Inp	711.00		NIST
Inp	743.00		NIST
Inp	732.00		NIST
Inp	729.00		NIST
Inp	729.00		NIST
Inp	729.00		NIST
Inp	719.00		NIST
Inp	734.00		NIST
Inp	719.00		NIST
Inp	717.00		NIST
Inp	740.50		NIST
Inp	727.50		NIST
Inp	734.00		NIST
Inp	719.00		NIST
Ip	[944.00; 975.00]
Ip	Outlier 975.00		NIST
Ip	960.00		NIST
Ip	948.00		NIST
Ip	948.00		NIST
Ip	944.00		NIST
Ip	955.00		NIST
Ip	948.00		NIST
Ip	955.00		NIST
S°liquid	327.02	J/mol×K	NIST
Tboil	[311.40; 376.00]	K
Tboil	374.80	K	KDB
Tboil	375.00 ± 2.00	K	NIST
Tboil	374.80	K	NIST
Tboil	374.00	K	NIST
Tboil	374.70	K	NIST
Tboil	374.70	K	NIST
Tboil	374.65 ± 0.30	K	NIST
Tboil	374.80 ± 0.50	K	NIST
Tboil	373.00 ± 4.00	K	NIST
Tboil	372.00 ± 5.00	K	NIST
Tboil	373.40 ± 1.50	K	NIST
Tboil	374.77 ± 0.20	K	NIST
Tboil	374.55 ± 0.30	K	NIST
Tboil	Outlier 311.40 ± 0.20	K	NIST
Tboil	373.50 ± 0.50	K	NIST
Tboil	374.35 ± 0.25	K	NIST
Tboil	376.00 ± 4.00	K	NIST
Tc	[569.50; 577.50]	K
Tc	571.10	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc	569.50	K	KDB
Tc	577.50	K	NIST
Tfus	[160.40; 385.40]	K
Tfus	161.15	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	161.00	K	KDB
Tfus	161.02	K	Aq. Solubility Prediction
Tfus	Outlier 385.40	K	NIST
Tfus	160.70 ± 1.50	K	NIST
Tfus	160.80 ± 0.40	K	NIST
Tfus	160.40 ± 0.20	K	NIST
Tfus	160.75 ± 0.30	K	NIST
Tfus	160.40 ± 0.20	K	NIST
Vc	[0.322; 0.327]	m3/kmol
Vc	0.327	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc	0.322	m3/kmol	KDB
Zc	0.2892410		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[140.00; 175.47]	J/mol×K	[180.00; 353.15]
Cp,liquid	141.00	J/mol×K	180.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	140.00	J/mol×K	190.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	140.00	J/mol×K	200.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	140.00	J/mol×K	210.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	140.00	J/mol×K	220.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	141.00	J/mol×K	230.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	142.00	J/mol×K	240.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	144.00	J/mol×K	250.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	146.00	J/mol×K	260.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	148.00	J/mol×K	270.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	149.00	J/mol×K	273.15	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	151.00	J/mol×K	280.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	159.45	J/mol×K	284.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	159.98	J/mol×K	286.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	160.53	J/mol×K	289.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	154.00	J/mol×K	290.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	161.01	J/mol×K	291.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	152.21	J/mol×K	292.30	NIST
Cp,liquid	161.52	J/mol×K	294.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	162.08	J/mol×K	296.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	151.00	J/mol×K	298.00	NIST
Cp,liquid	157.00	J/mol×K	298.15	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	162.20	J/mol×K	298.15	NIST
Cp,liquid	162.60	J/mol×K	299.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	158.00	J/mol×K	300.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	163.08	J/mol×K	301.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	163.72	J/mol×K	304.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	164.22	J/mol×K	306.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	164.78	J/mol×K	309.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	162.00	J/mol×K	310.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	165.34	J/mol×K	311.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	165.94	J/mol×K	314.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	166.49	J/mol×K	316.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	167.09	J/mol×K	319.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	166.00	J/mol×K	320.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	167.67	J/mol×K	321.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	168.29	J/mol×K	324.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	168.83	J/mol×K	326.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	169.45	J/mol×K	329.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	171.00	J/mol×K	330.00	Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD
Cp,liquid	170.09	J/mol×K	331.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	170.63	J/mol×K	334.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	171.00	J/mol×K	336.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	171.94	J/mol×K	339.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	172.57	J/mol×K	341.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	173.26	J/mol×K	344.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	173.89	J/mol×K	346.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	174.51	J/mol×K	349.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	175.19	J/mol×K	351.65	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
Cp,liquid	175.47	J/mol×K	353.15	Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
η	[0.0004940; 0.0006770]	Pa×s	[288.15; 318.15]
η	0.0006770	Pa×s	288.15	Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
η	0.0006473	Pa×s	293.15	Densities and Viscosities of Binary and Ternary Mixtures of (Nitrobenzene + 1-Bromobutane), (1-Bromobutane + Methylcyclohexane), (Nitrobenzene + Methylcyclohexane), and (Methylcyclohexane + Nitrobenzene + 1-Bromobutane) from (293.15 to 308.15) K
η	0.0006070	Pa×s	298.15	Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
η	0.0006096	Pa×s	298.15	Densities and Viscosities of Binary and Ternary Mixtures of (Nitrobenzene + 1-Bromobutane), (1-Bromobutane + Methylcyclohexane), (Nitrobenzene + Methylcyclohexane), and (Methylcyclohexane + Nitrobenzene + 1-Bromobutane) from (293.15 to 308.15) K
η	0.0005750	Pa×s	303.15	Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
η	0.0005811	Pa×s	303.15	Densities and Viscosities of Binary and Ternary Mixtures of (Nitrobenzene + 1-Bromobutane), (1-Bromobutane + Methylcyclohexane), (Nitrobenzene + Methylcyclohexane), and (Methylcyclohexane + Nitrobenzene + 1-Bromobutane) from (293.15 to 308.15) K
η	0.0005460	Pa×s	308.15	Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
η	0.0005500	Pa×s	308.15	Densities and Viscosities of Binary and Ternary Mixtures of (Nitrobenzene + 1-Bromobutane), (1-Bromobutane + Methylcyclohexane), (Nitrobenzene + Methylcyclohexane), and (Methylcyclohexane + Nitrobenzene + 1-Bromobutane) from (293.15 to 308.15) K
η	0.0005190	Pa×s	313.15	Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
η	0.0004940	Pa×s	318.15	Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
ΔfusH	[9.23; 9.23]	kJ/mol	[160.40; 160.40]
ΔfusH	9.23	kJ/mol	160.40	NIST
ΔfusH	9.23	kJ/mol	160.40	NIST
ΔfusH	9.23	kJ/mol	160.40	NIST
ΔfusH	9.23	kJ/mol	160.40	NIST
ΔvapH	[32.51; 37.50]	kJ/mol	[318.00; 374.80]
ΔvapH	33.50	kJ/mol	318.00	NIST
ΔvapH	35.60 ± 0.10	kJ/mol	322.00	NIST
ΔvapH	34.90 ± 0.10	kJ/mol	332.00	NIST
ΔvapH	37.50	kJ/mol	336.50	NIST
ΔvapH	34.50 ± 0.10	kJ/mol	339.00	NIST
ΔvapH	33.70 ± 0.10	kJ/mol	352.00	NIST
ΔvapH	34.60	kJ/mol	355.50	NIST
ΔvapH	33.00 ± 0.10	kJ/mol	366.00	NIST
ΔvapH	32.60	kJ/mol	372.40	NIST
ΔvapH	32.51	kJ/mol	374.70	NIST
ΔvapH	36.77	kJ/mol	374.80	KDB
Pvap	[1.86; 17.09]	kPa	[278.15; 323.15]
Pvap	1.86	kPa	278.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	1.86	kPa	278.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	2.48	kPa	283.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	2.48	kPa	283.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	3.27	kPa	288.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	3.27	kPa	288.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	4.26	kPa	293.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	4.26	kPa	293.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	5.51	kPa	298.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	5.51	kPa	298.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	7.04	kPa	303.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	7.04	kPa	303.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	8.90	kPa	308.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	8.90	kPa	308.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	11.15	kPa	313.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	11.15	kPa	313.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	13.87	kPa	318.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	13.87	kPa	318.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
Pvap	17.09	kPa	323.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
Pvap	17.09	kPa	323.15	Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
ρl	[1229.50; 1326.50]	kg/m3	[253.15; 323.15]
ρl	1326.50	kg/m3	253.15	Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
ρl	1313.80	kg/m3	263.15	Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
ρl	1300.50	kg/m3	273.15	Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
ρl	1286.40	kg/m3	283.15	Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
ρl	1265.70	kg/m3	298.15	Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
ρl	1229.50	kg/m3	323.15	Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
ΔfusS	[57.57; 57.57]	J/mol×K	[160.40; 160.40]
ΔfusS	57.57	J/mol×K	160.40	NIST
ΔfusS	57.57	J/mol×K	160.40	NIST
ΔfusS	57.57	J/mol×K	160.40	NIST
csound,fluid	[735.21; 1195.27]	m/s	[243.38; 383.31]
csound,fluid	1195.27	m/s	243.38	Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K
csound,fluid	1090.98	m/s	273.26	Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K
csound,fluid	925.99	m/s	323.22	Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K
csound,fluid	861.16	m/s	343.22	Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K
csound,fluid	797.60	m/s	363.23	Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K
csound,fluid	735.21	m/s	383.31	Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[104.32; 234.76]	J/mol×K	[273.00; 1000.00]	Joback Predicted correlation
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is Cp,gas in J/mol×K, T in K
Coefficient A			7.44300e+00
Coefficient B			4.22020e-01
Coefficient C			-2.65200e-04
Coefficient D			7.05000e-08
Coefficient E			0.00000e+00
Temperature range, min.			273.00
Temperature range, max.			1000.00
Cp,gas	104.32	J/mol×K	273.00	Calculated Property
Cp,gas	126.67	J/mol×K	353.78	Calculated Property
Cp,gas	146.54	J/mol×K	434.56	Calculated Property
Cp,gas	164.14	J/mol×K	515.33	Calculated Property
Cp,gas	179.71	J/mol×K	596.11	Calculated Property
Cp,gas	193.46	J/mol×K	676.89	Calculated Property
Cp,gas	205.62	J/mol×K	757.67	Calculated Property
Cp,gas	216.40	J/mol×K	838.44	Calculated Property
Cp,gas	226.05	J/mol×K	919.22	Calculated Property
Cp,gas	234.76	J/mol×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.63]	kPa	[274.54; 398.38]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.47590e+01
Coefficient B			-3.37027e+03
Coefficient C			-4.16480e+01
Temperature range, min.			274.54
Temperature range, max.			398.38
Pvap	1.33	kPa	274.54	Calculated Property
Pvap	2.99	kPa	288.30	Calculated Property
Pvap	6.15	kPa	302.06	Calculated Property
Pvap	11.78	kPa	315.82	Calculated Property
Pvap	21.20	kPa	329.58	Calculated Property
Pvap	36.15	kPa	343.34	Calculated Property
Pvap	58.85	kPa	357.10	Calculated Property
Pvap	91.98	kPa	370.86	Calculated Property
Pvap	138.70	kPa	384.62	Calculated Property
Pvap	202.63	kPa	398.38	Calculated Property
Pvap	[1.49e-06; 4781.82]	kPa	[160.75; 577.00]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			1.18191e+02
Coefficient B			-8.35117e+03
Coefficient C			-1.57561e+01
Coefficient D			1.48094e-05
Coefficient E			0.00000e+00
Temperature range, min.			160.75
Temperature range, max.			577.00
Pvap	1.49e-06	kPa	160.75	Calculated Property
Pvap	3.92e-03	kPa	207.00	Calculated Property
Pvap	0.35	kPa	253.25	Calculated Property
Pvap	6.00	kPa	299.50	Calculated Property
Pvap	40.50	kPa	345.75	Calculated Property
Pvap	160.49	kPa	392.00	Calculated Property
Pvap	463.09	kPa	438.25	Calculated Property
Pvap	1105.67	kPa	484.50	Calculated Property
Pvap	2366.24	kPa	530.75	Calculated Property
Pvap	4781.82	kPa	577.00	Calculated Property
Pvap	[8.95e-04; 4.62]	kPa	[195.18; 295.82]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.25727e+01
Coefficient B			-2.54639e+03
Coefficient C			-6.52030e+01
Reference			Milazzo, 1956
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			195.18
Temperature range, max.			295.82
Pvap	8.95e-04	kPa	195.18	Calculated Property
Pvap	4.23e-03	kPa	206.36	Calculated Property
Pvap	0.02	kPa	217.54	Calculated Property
Pvap	0.05	kPa	228.73	Calculated Property
Pvap	0.13	kPa	239.91	Calculated Property
Pvap	0.32	kPa	251.09	Calculated Property
Pvap	0.71	kPa	262.27	Calculated Property
Pvap	1.41	kPa	273.46	Calculated Property
Pvap	2.63	kPa	284.64	Calculated Property
Pvap	4.62	kPa	295.82	Calculated Property
Pvap	[10.88; 78.37]	kPa	[293.00; 343.00]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.33552e+01
Coefficient B			-2.49804e+03
Coefficient C			-6.52440e+01
Reference			Smyth and Engel, 1929
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			293.00
Temperature range, max.			343.00
Pvap	10.88	kPa	293.00	Calculated Property
Pvap	14.13	kPa	298.56	Calculated Property
Pvap	18.12	kPa	304.11	Calculated Property
Pvap	22.99	kPa	309.67	Calculated Property
Pvap	28.85	kPa	315.22	Calculated Property
Pvap	35.85	kPa	320.78	Calculated Property
Pvap	44.14	kPa	326.33	Calculated Property
Pvap	53.88	kPa	331.89	Calculated Property
Pvap	65.23	kPa	337.44	Calculated Property
Pvap	78.37	kPa	343.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 0.02]	N/m	[160.75; 374.75]	Jasper (1972), surface tension of pure liquid compounds Compiled value
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is γ in N/m, T in K
Coefficient A			5.94667e-02
Coefficient B			-1.12600e-04
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Temperature range, min.			160.75
Temperature range, max.			374.75
γ	0.04	N/m	160.75	Calculated Property
γ	0.04	N/m	184.53	Calculated Property
γ	0.04	N/m	208.31	Calculated Property
γ	0.03	N/m	232.08	Calculated Property
γ	0.03	N/m	255.86	Calculated Property
γ	0.03	N/m	279.64	Calculated Property
γ	0.03	N/m	303.42	Calculated Property
γ	0.02	N/m	327.19	Calculated Property
γ	0.02	N/m	350.97	Calculated Property
γ	0.02	N/m	374.75	Calculated Property

Similar Compounds

Find more compounds similar to Butane, 1-bromo-.

Mixtures

• Butane, 1-bromo- + 1-Butanol
• Butane, 1-bromo- + 1-Propanol, 2-methyl-
• 2-Propanol, 2-methyl- + Butane, 1-bromo-
• Carbon dioxide + Butane, 1-bromo-
• Benzene, nitro- + Butane, 1-bromo-
• Butane, 1-bromo- + Cyclohexane, methyl-
• Benzene, nitro- + Butane, 1-bromo- + Cyclohexane, methyl-
• Butane, 1-bromo- + 1-Octanol
• Butane, 1-bromo- + 1-Decanol

Sources

• KDB Vapor Pressure Data
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• Jasper (1972), surface tension of pure liquid compounds ChEDL chemicals 1.5.2, from Jasper, J. J. The Surface Tension of Pure Liquid Compounds. J. Phys. Chem. Ref. Data 1972, 1, 841-1010 (as transcribed in Lange's Handbook).
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• Crippen Method
• Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
• Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T ) 298.15 K for 1-Bromobutane with 1-Octanol or 1-Decanol
• Heat Capacities of 1-chloroalkanes and 1-bromoalkanes within the temperature range from 284.15 K to 353.15 K. A group additivity and molecular connectivity analysis
• Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures
• Densities and Viscosities of Binary and Ternary Mixtures of (Nitrobenzene + 1-Bromobutane), (1-Bromobutane + Methylcyclohexane), (Nitrobenzene + Methylcyclohexane), and (Methylcyclohexane + Nitrobenzene + 1-Bromobutane) from (293.15 to 308.15) K
• Thermodynamics of Ionic Liquid Precursors. 1-Bromobutane and Its Isomers
• Density of Some 1-Bromoalkanes within the Temperature Range from (243.15 to 423.15) K
• Speed of Sound, Densities, and Isentropic Compressibilities of Liquid 1-Bromoalkanes at Temperatures from (243.15 to 423.15) K
• Phase Behavior, Densities, and Isothermal Compressibility of Carbon Dioxide + 1-Bromobutane, Carbon Dioxide + 1-Chlorobutane, and Carbon Dioxide + 1-Methylimidazole
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure
• Zabransky, M., Ruzicka, V., Majer, V. and Domalski, E. (1997), Heat Capacity of Liquids: Critical Review and Recommended Values - Monograph No. 6, J. Phys. & Chem. Ref. Data (JPCRD), National Institute of Standards and Technology, Gaithersburg, MD

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