Mixture of Tetradecane + Methyl tetradecanoate

Datasets

1. Mole fraction (2)
2. P_vap - Vapor or sublimation pressure, kPa (2)
3. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Tetradecane (1) [ref]

Operational condition: Pressure, kPa = 5 (Liquid)

Mole fraction of Tetradecane (1) - Liquid	Mole fraction of Tetradecane (1) - Gas
1.0000	1.0000
0.9113	0.9790
0.8047	0.9500
0.6837	0.9105
0.5345	0.8447
0.4725	0.8107
0.3332	0.7153
0.2497	0.6320
0.1881	0.5435
0.1278	0.4252
0.0630	0.2520
0.0246	0.1107
0.0000	0.0000

Mole fraction of Tetradecane (1) [ref]

Operational condition: Pressure, kPa = 5 (Liquid)

Mole fraction of Tetradecane (1) - Liquid	Mole fraction of Tetradecane (1) - Gas
1.0000	1.0000
0.9113	0.9790
0.8047	0.9500
0.6837	0.9105
0.5345	0.8447
0.4725	0.8107
0.3332	0.7153
0.2497	0.6320
0.1881	0.5435
0.1278	0.4252
0.0630	0.2520
0.0246	0.1107
0.0000	0.0000

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Methyl tetradecanoate (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	353.15	0.14
0.1260	353.15	0.12
0.2520	353.15	0.10
0.3834	353.15	0.09
0.5099	353.15	0.08
0.6834	353.15	0.06
0.8615	353.15	0.04
1.0000	353.15	0.01
0.0000	363.15	0.25
0.1260	363.15	0.22
0.2520	363.15	0.19
0.3834	363.15	0.17
0.5099	363.15	0.15
0.6834	363.15	0.11
0.8615	363.15	0.07
1.0000	363.15	0.03
0.0000	373.15	0.45
0.1260	373.15	0.38
0.2520	373.15	0.34
0.3834	373.15	0.31
0.5099	373.15	0.26
0.6834	373.15	0.20
0.8615	373.15	0.13
1.0000	373.15	0.05
0.0000	383.15	0.76
0.1260	383.15	0.66
0.2520	383.15	0.58
0.3834	383.15	0.53
0.5099	383.15	0.45
0.6834	383.15	0.34
0.8615	383.15	0.23
1.0000	383.15	0.10
0.0000	393.15	1.25
0.1260	393.15	1.09
0.2520	393.15	0.97
0.3834	393.15	0.87
0.5099	393.15	0.74
0.6834	393.15	0.57
0.8615	393.15	0.38
1.0000	393.15	0.17
0.0000	403.15	2.00
0.1260	403.15	1.74
0.2520	403.15	1.56
0.3834	403.15	1.40
0.5099	403.15	1.20
0.6834	403.15	0.92
0.8615	403.15	0.64
1.0000	403.15	0.30
0.0000	413.15	3.09
0.1260	413.15	2.72
0.2520	413.15	2.43
0.3834	413.15	2.19
0.5099	413.15	1.89
0.6834	413.15	1.46
0.8615	413.15	1.02
1.0000	413.15	0.51
0.0000	423.15	4.64
0.1260	423.15	4.13
0.2520	423.15	3.71
0.3834	423.15	3.34
0.5099	423.15	2.89
0.6834	423.15	2.25
0.8615	423.15	1.60
1.0000	423.15	0.84
0.0000	433.15	6.81
0.1260	433.15	6.12
0.2520	433.15	5.51
0.3834	433.15	4.97
0.5099	433.15	4.33
0.6834	433.15	3.39
0.8615	433.15	2.44
1.0000	433.15	1.35
0.0000	443.15	9.78
0.1260	443.15	8.88
0.2520	443.15	8.02
0.3834	443.15	7.22
0.5099	443.15	6.33
0.6834	443.15	5.00
0.8615	443.15	3.63
1.0000	443.15	2.12
0.0000	453.15	13.75
0.1260	453.15	12.63
0.2520	453.15	11.44
0.3834	453.15	10.30
0.5099	453.15	9.10
0.6834	453.15	7.23
0.8615	453.15	5.31
1.0000	453.15	3.27

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Mole fraction of Methyl tetradecanoate (2) - Liquid	Temperature, K - Liquid	Vapor or sublimation pressure, kPa - Liquid
0.0000	353.15	0.14
0.1260	353.15	0.12
0.2520	353.15	0.10
0.3834	353.15	0.09
0.5099	353.15	0.08
0.6834	353.15	0.06
0.8615	353.15	0.04
1.0000	353.15	0.01
0.0000	363.15	0.25
0.1260	363.15	0.22
0.2520	363.15	0.19
0.3834	363.15	0.17
0.5099	363.15	0.15
0.6834	363.15	0.11
0.8615	363.15	0.07
1.0000	363.15	0.03
0.0000	373.15	0.45
0.1260	373.15	0.38
0.2520	373.15	0.34
0.3834	373.15	0.31
0.5099	373.15	0.26
0.6834	373.15	0.20
0.8615	373.15	0.13
1.0000	373.15	0.05
0.0000	383.15	0.76
0.1260	383.15	0.66
0.2520	383.15	0.58
0.3834	383.15	0.53
0.5099	383.15	0.45
0.6834	383.15	0.34
0.8615	383.15	0.23
1.0000	383.15	0.10
0.0000	393.15	1.25
0.1260	393.15	1.09
0.2520	393.15	0.97
0.3834	393.15	0.87
0.5099	393.15	0.74
0.6834	393.15	0.57
0.8615	393.15	0.38
1.0000	393.15	0.17
0.0000	403.15	2.00
0.1260	403.15	1.74
0.2520	403.15	1.56
0.3834	403.15	1.40
0.5099	403.15	1.20
0.6834	403.15	0.92
0.8615	403.15	0.64
1.0000	403.15	0.30
0.0000	413.15	3.09
0.1260	413.15	2.72
0.2520	413.15	2.43
0.3834	413.15	2.19
0.5099	413.15	1.89
0.6834	413.15	1.46
0.8615	413.15	1.02
1.0000	413.15	0.51
0.0000	423.15	4.64
0.1260	423.15	4.13
0.2520	423.15	3.71
0.3834	423.15	3.34
0.5099	423.15	2.89
0.6834	423.15	2.25
0.8615	423.15	1.60
1.0000	423.15	0.84
0.0000	433.15	6.81
0.1260	433.15	6.12
0.2520	433.15	5.51
0.3834	433.15	4.97
0.5099	433.15	4.33
0.6834	433.15	3.39
0.8615	433.15	2.44
1.0000	433.15	1.35
0.0000	443.15	9.78
0.1260	443.15	8.88
0.2520	443.15	8.02
0.3834	443.15	7.22
0.5099	443.15	6.33
0.6834	443.15	5.00
0.8615	443.15	3.63
1.0000	443.15	2.12
0.0000	453.15	13.75
0.1260	453.15	12.63
0.2520	453.15	11.44
0.3834	453.15	10.30
0.5099	453.15	9.10
0.6834	453.15	7.23
0.8615	453.15	5.31
1.0000	453.15	3.27

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 5 (Liquid)

Mole fraction of Tetradecane (1) - Liquid	Boiling temperature at pressure P, K - Liquid
1.0000	425.67
0.9113	426.85
0.8047	429.05
0.6837	431.84
0.5345	435.99
0.4725	438.20
0.3332	442.80
0.2497	446.45
0.1881	450.07
0.1278	454.05
0.0630	458.95
0.0246	462.55
0.0000	465.35

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 5 (Liquid)

Mole fraction of Tetradecane (1) - Liquid	Boiling temperature at pressure P, K - Liquid
1.0000	425.67
0.9113	426.85
0.8047	429.05
0.6837	431.84
0.5345	435.99
0.4725	438.20
0.3332	442.80
0.2497	446.45
0.1881	450.07
0.1278	454.05
0.0630	458.95
0.0246	462.55
0.0000	465.35

Sources

• Isobaric vapor-liquid equilibrium for the three binary systems of C14 - C16 n-alkane + methyl myristate at 5.00 kPa
• Isothermal Vapor Pressures of Three Binary Systems: n-Tetradecane + Methyl Dodecanoate, Methyl Tetradecanoate, or Methyl Hexadecanoate between 353.15 and 453.15 K