Mixture of Butane, 1-bromo- + 1-Propanol, 2-methyl-

Datasets

1. Azeotropic composition: mole fraction (2)
2. η - Viscosity, Pa*s (2)
3. Excess molar enthalpy (molar enthalpy (2)
4. P_vap - Vapor or sublimation pressure, kPa (2)
5. ρ_l - Mass density, kg/m3 (2)
6. Azeotropic pressure, kPa (2)
7. Excess molar volume, m3/mol (2)

Azeotropic composition: mole fraction of 1-Propanol, 2-methyl- (2) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of 1-Propanol, 2-methyl- (2) - Liquid
278.15	0.0869
283.15	0.0990
288.15	0.1092
293.15	0.1187
298.15	0.1293
303.15	0.1425
308.15	0.1549
313.15	0.1687
318.15	0.1816
323.15	0.1951

Azeotropic composition: mole fraction of 1-Propanol, 2-methyl- (2) [ref]

Temperature, K - Liquid	Azeotropic composition: mole fraction of 1-Propanol, 2-methyl- (2) - Liquid
278.15	0.0869
283.15	0.0990
288.15	0.1092
293.15	0.1187
298.15	0.1293
303.15	0.1425
308.15	0.1549
313.15	0.1687
318.15	0.1816
323.15	0.1951

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Viscosity, Pa*s - Liquid
288.15	0.1010	0.0007
288.15	0.2014	0.0008
288.15	0.3080	0.0009
288.15	0.4025	0.0010
288.15	0.5066	0.0012
288.15	0.6100	0.0015
288.15	0.7006	0.0018
288.15	0.8004	0.0024
288.15	0.8984	0.0033
298.15	0.1010	0.0006
298.15	0.2014	0.0007
298.15	0.3080	0.0007
298.15	0.4025	0.0008
298.15	0.5066	0.0010
298.15	0.6100	0.0012
298.15	0.7006	0.0014
298.15	0.8004	0.0018
298.15	0.8984	0.0024
308.15	0.1010	0.0005
308.15	0.2014	0.0006
308.15	0.3080	0.0006
308.15	0.4025	0.0007
308.15	0.5066	0.0008
308.15	0.6100	0.0009
308.15	0.7006	0.0011
308.15	0.8004	0.0014
308.15	0.8984	0.0018
318.15	0.1010	0.0005
318.15	0.2014	0.0005
318.15	0.3080	0.0006
318.15	0.4025	0.0006
318.15	0.5066	0.0007
318.15	0.6100	0.0008
318.15	0.7006	0.0009
318.15	0.8004	0.0011
318.15	0.8984	0.0014

Viscosity, Pa*s [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Viscosity, Pa*s - Liquid
288.15	0.1010	0.0007
288.15	0.2014	0.0008
288.15	0.3080	0.0009
288.15	0.4025	0.0010
288.15	0.5066	0.0012
288.15	0.6100	0.0015
288.15	0.7006	0.0018
288.15	0.8004	0.0024
288.15	0.8984	0.0033
298.15	0.1010	0.0006
298.15	0.2014	0.0007
298.15	0.3080	0.0007
298.15	0.4025	0.0008
298.15	0.5066	0.0010
298.15	0.6100	0.0012
298.15	0.7006	0.0014
298.15	0.8004	0.0018
298.15	0.8984	0.0024
308.15	0.1010	0.0005
308.15	0.2014	0.0006
308.15	0.3080	0.0006
308.15	0.4025	0.0007
308.15	0.5066	0.0008
308.15	0.6100	0.0009
308.15	0.7006	0.0011
308.15	0.8004	0.0014
308.15	0.8984	0.0018
318.15	0.1010	0.0005
318.15	0.2014	0.0005
318.15	0.3080	0.0006
318.15	0.4025	0.0006
318.15	0.5066	0.0007
318.15	0.6100	0.0008
318.15	0.7006	0.0009
318.15	0.8004	0.0011
318.15	0.8984	0.0014

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0421	0.5300
0.0942	0.8510
0.1932	1.125
0.2938	1.248
0.3468	1.271
0.3957	1.272
0.4476	1.245
0.4990	1.207
0.6000	1.081
0.7021	0.8910
0.8052	0.6360
0.9060	0.3300
0.9587	0.1590

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
0.0421	0.5300
0.0942	0.8510
0.1932	1.125
0.2938	1.248
0.3468	1.271
0.3957	1.272
0.4476	1.245
0.4990	1.207
0.6000	1.081
0.7021	0.8910
0.8052	0.6360
0.9060	0.3300
0.9587	0.1590

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
278.15	0.0513	1.94
278.15	0.1003	1.97
278.15	0.1992	1.93
278.15	0.3031	1.90
278.15	0.3865	1.86
278.15	0.4782	1.82
278.15	0.5834	1.73
278.15	0.6959	1.61
278.15	0.7947	1.39
278.15	0.8393	1.28
278.15	0.9219	0.88
283.15	0.0513	2.61
283.15	0.1003	2.64
283.15	0.1992	2.61
283.15	0.3031	2.56
283.15	0.3865	2.51
283.15	0.4783	2.44
283.15	0.5835	2.33
283.15	0.6959	2.17
283.15	0.7948	1.88
283.15	0.8394	1.69
283.15	0.9219	1.22
288.15	0.0512	3.44
288.15	0.1003	3.50
288.15	0.1993	3.45
288.15	0.3031	3.40
288.15	0.3866	3.33
288.15	0.4783	3.23
288.15	0.5835	3.09
288.15	0.6960	2.89
288.15	0.7949	2.51
288.15	0.8394	2.25
288.15	0.9220	1.65
293.15	0.0512	4.50
293.15	0.1003	4.58
293.15	0.1993	4.51
293.15	0.3031	4.44
293.15	0.3866	4.36
293.15	0.4784	4.25
293.15	0.5836	4.06
293.15	0.6961	3.80
293.15	0.7949	3.32
293.15	0.8395	2.99
293.15	0.9220	2.22
298.15	0.0512	5.82
298.15	0.1003	5.93
298.15	0.1993	5.87
298.15	0.3032	5.77
298.15	0.3867	5.67
298.15	0.4784	5.52
298.15	0.5837	5.29
298.15	0.6962	4.94
298.15	0.7950	4.34
298.15	0.8396	3.92
298.15	0.9221	2.98
303.15	0.0511	7.46
303.15	0.1003	7.63
303.15	0.1993	7.55
303.15	0.3032	7.46
303.15	0.3867	7.31
303.15	0.4785	7.12
303.15	0.5838	6.82
303.15	0.6964	6.38
303.15	0.7952	5.62
303.15	0.8397	5.11
303.15	0.9222	3.93
308.15	0.0510	9.47
308.15	0.1002	9.69
308.15	0.1993	9.63
308.15	0.3033	9.51
308.15	0.3868	9.35
308.15	0.4786	9.13
308.15	0.5840	8.72
308.15	0.6965	8.18
308.15	0.7953	7.22
308.15	0.8398	6.50
308.15	0.9222	5.15
313.15	0.0509	11.90
313.15	0.1002	12.20
313.15	0.1993	12.15
313.15	0.3033	12.02
313.15	0.3869	11.81
313.15	0.4788	11.58
313.15	0.5841	11.05
313.15	0.6968	10.38
313.15	0.7955	9.21
313.15	0.8400	8.42
313.15	0.9224	6.68
318.15	0.0508	14.78
318.15	0.1001	15.22
318.15	0.1992	15.20
318.15	0.3034	15.18
318.15	0.3870	14.82
318.15	0.4790	14.54
318.15	0.5844	13.89
318.15	0.6971	13.07
318.15	0.7958	11.62
318.15	0.8402	10.69
318.15	0.9225	8.60
323.15	0.0506	18.24
323.15	0.1001	18.81
323.15	0.1992	18.88
323.15	0.3034	18.71
323.15	0.3872	18.44
323.15	0.4792	18.00
323.15	0.5847	17.31
323.15	0.6975	16.28
323.15	0.7961	14.61
323.15	0.8405	13.48
323.15	0.9227	10.97

Vapor or sublimation pressure, kPa [ref]

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Vapor or sublimation pressure, kPa - Liquid
278.15	0.0513	1.94
278.15	0.1003	1.97
278.15	0.1992	1.93
278.15	0.3031	1.90
278.15	0.3865	1.86
278.15	0.4782	1.82
278.15	0.5834	1.73
278.15	0.6959	1.61
278.15	0.7947	1.39
278.15	0.8393	1.28
278.15	0.9219	0.88
283.15	0.0513	2.61
283.15	0.1003	2.64
283.15	0.1992	2.61
283.15	0.3031	2.56
283.15	0.3865	2.51
283.15	0.4783	2.44
283.15	0.5835	2.33
283.15	0.6959	2.17
283.15	0.7948	1.88
283.15	0.8394	1.69
283.15	0.9219	1.22
288.15	0.0512	3.44
288.15	0.1003	3.50
288.15	0.1993	3.45
288.15	0.3031	3.40
288.15	0.3866	3.33
288.15	0.4783	3.23
288.15	0.5835	3.09
288.15	0.6960	2.89
288.15	0.7949	2.51
288.15	0.8394	2.25
288.15	0.9220	1.65
293.15	0.0512	4.50
293.15	0.1003	4.58
293.15	0.1993	4.51
293.15	0.3031	4.44
293.15	0.3866	4.36
293.15	0.4784	4.25
293.15	0.5836	4.06
293.15	0.6961	3.80
293.15	0.7949	3.32
293.15	0.8395	2.99
293.15	0.9220	2.22
298.15	0.0512	5.82
298.15	0.1003	5.93
298.15	0.1993	5.87
298.15	0.3032	5.77
298.15	0.3867	5.67
298.15	0.4784	5.52
298.15	0.5837	5.29
298.15	0.6962	4.94
298.15	0.7950	4.34
298.15	0.8396	3.92
298.15	0.9221	2.98
303.15	0.0511	7.46
303.15	0.1003	7.63
303.15	0.1993	7.55
303.15	0.3032	7.46
303.15	0.3867	7.31
303.15	0.4785	7.12
303.15	0.5838	6.82
303.15	0.6964	6.38
303.15	0.7952	5.62
303.15	0.8397	5.11
303.15	0.9222	3.93
308.15	0.0510	9.47
308.15	0.1002	9.69
308.15	0.1993	9.63
308.15	0.3033	9.51
308.15	0.3868	9.35
308.15	0.4786	9.13
308.15	0.5840	8.72
308.15	0.6965	8.18
308.15	0.7953	7.22
308.15	0.8398	6.50
308.15	0.9222	5.15
313.15	0.0509	11.90
313.15	0.1002	12.20
313.15	0.1993	12.15
313.15	0.3033	12.02
313.15	0.3869	11.81
313.15	0.4788	11.58
313.15	0.5841	11.05
313.15	0.6968	10.38
313.15	0.7955	9.21
313.15	0.8400	8.42
313.15	0.9224	6.68
318.15	0.0508	14.78
318.15	0.1001	15.22
318.15	0.1992	15.20
318.15	0.3034	15.18
318.15	0.3870	14.82
318.15	0.4790	14.54
318.15	0.5844	13.89
318.15	0.6971	13.07
318.15	0.7958	11.62
318.15	0.8402	10.69
318.15	0.9225	8.60
323.15	0.0506	18.24
323.15	0.1001	18.81
323.15	0.1992	18.88
323.15	0.3034	18.71
323.15	0.3872	18.44
323.15	0.4792	18.00
323.15	0.5847	17.31
323.15	0.6975	16.28
323.15	0.7961	14.61
323.15	0.8405	13.48
323.15	0.9227	10.97

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0278	1269.4
288.15	0.0624	1254.6
288.15	0.1314	1225.12
288.15	0.2047	1193.36
288.15	0.2862	1157.47
288.15	0.3542	1126.98
288.15	0.4107	1101.21
288.15	0.4499	1083.17
288.15	0.5347	1043.44
288.15	0.5743	1024.55
288.15	0.6930	966.57
288.15	0.7389	943.57
288.15	0.7991	912.89
288.15	0.8566	883.02
288.15	0.9030	858.35
288.15	0.9444	835.99
288.15	0.9516	832.05
308.15	0.0981	1211.21
308.15	0.1965	1169.47
308.15	0.2793	1133.98
308.15	0.3949	1083.44
308.15	0.4989	1036.68
308.15	0.5936	992.85
308.15	0.6956	944.28
308.15	0.7937	896.28
308.15	0.9005	842.19
318.15	0.0581	1213.35
318.15	0.0947	1198.04
318.15	0.1896	1158.5
318.15	0.2827	1119.03
318.15	0.3863	1074.39
318.15	0.4919	1027.54
318.15	0.6160	970.79
318.15	0.6927	934.7
318.15	0.7860	889.86
318.15	0.8930	836.77

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.325 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Mass density, kg/m3 - Liquid
288.15	0.0278	1269.4
288.15	0.0624	1254.6
288.15	0.1314	1225.12
288.15	0.2047	1193.36
288.15	0.2862	1157.47
288.15	0.3542	1126.98
288.15	0.4107	1101.21
288.15	0.4499	1083.17
288.15	0.5347	1043.44
288.15	0.5743	1024.55
288.15	0.6930	966.57
288.15	0.7389	943.57
288.15	0.7991	912.89
288.15	0.8566	883.02
288.15	0.9030	858.35
288.15	0.9444	835.99
288.15	0.9516	832.05
308.15	0.0981	1211.21
308.15	0.1965	1169.47
308.15	0.2793	1133.98
308.15	0.3949	1083.44
308.15	0.4989	1036.68
308.15	0.5936	992.85
308.15	0.6956	944.28
308.15	0.7937	896.28
308.15	0.9005	842.19
318.15	0.0581	1213.35
318.15	0.0947	1198.04
318.15	0.1896	1158.5
318.15	0.2827	1119.03
318.15	0.3863	1074.39
318.15	0.4919	1027.54
318.15	0.6160	970.79
318.15	0.6927	934.7
318.15	0.7860	889.86
318.15	0.8930	836.77

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
278.15	1.94
283.15	2.61
288.15	3.45
293.15	4.51
298.15	5.86
303.15	7.54
308.15	9.62
313.15	12.14
318.15	15.21
323.15	18.83

Azeotropic pressure, kPa [ref]

Temperature, K - Liquid	Azeotropic pressure, kPa - Liquid
278.15	1.94
283.15	2.61
288.15	3.45
293.15	4.51
298.15	5.86
303.15	7.54
308.15	9.62
313.15	12.14
318.15	15.21
323.15	18.83

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0576	7.7000e-08
0.1063	1.2400e-07
0.1475	1.4600e-07
0.2348	1.9000e-07
0.2586	1.9800e-07
0.3910	2.2100e-07
0.4368	2.1900e-07
0.5451	1.9800e-07
0.5655	1.8600e-07
0.6332	1.5700e-07
0.6772	1.2600e-07
0.7160	1.0200e-07
0.8210	5.1000e-08
0.8385	4.4000e-08
0.8690	2.5000e-08
0.9469	0.0000

Excess molar volume, m3/mol [ref]

Operational conditions:

• Temperature, K = 298.15 (Liquid)
• Pressure, kPa = 101.3 (Liquid)

Mole fraction of 1-Propanol, 2-methyl- (2) - Liquid	Excess molar volume, m3/mol - Liquid
0.0576	7.7000e-08
0.1063	1.2400e-07
0.1475	1.4600e-07
0.2348	1.9000e-07
0.2586	1.9800e-07
0.3910	2.2100e-07
0.4368	2.1900e-07
0.5451	1.9800e-07
0.5655	1.8600e-07
0.6332	1.5700e-07
0.6772	1.2600e-07
0.7160	1.0200e-07
0.8210	5.1000e-08
0.8385	4.4000e-08
0.8690	2.5000e-08
0.9469	0.0000

Sources

• Vapor Liquid Equilibrium between (278.15 and 323.15) K and Excess Functions at T = 298.15 K for 1-Bromobutane with 2-Methyl-1-propanol or 2-Butanol
• Densities and Viscosities of Binary Mixtures of 1-Bromobutane with Butanol Isomers at Several Temperatures