Mixture of Formic acid, propyl ester + Decane

Datasets

1. Mole fraction (2)
2. Excess molar enthalpy (molar enthalpy (2)
3. ρ_l - Mass density, kg/m3 (2)
4. T_boil - Boiling temperature at pressure P, K (2)

Mole fraction of Formic acid, propyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Formic acid, propyl ester (1) - Liquid	Mole fraction of Formic acid, propyl ester (1) - Gas
0.0000	0.0000
0.0319	0.2575
0.0462	0.3710
0.0746	0.5462
0.1121	0.6904
0.1545	0.7836
0.1952	0.8360
0.2593	0.8892
0.3094	0.9108
0.3539	0.9268
0.4277	0.9421
0.5022	0.9551
0.5421	0.9597
0.5650	0.9632
0.6345	0.9707
0.7009	0.9748
0.7408	0.9759
0.7808	0.9783
0.8131	0.9803
0.8822	0.9847
0.9155	0.9874
0.9436	0.9911
0.9650	0.9940
0.9797	0.9956
0.9890	0.9967
0.9978	0.9993
1.0000	1.0000
0.0000	0.0000
0.0319	0.2575
0.0462	0.3710
0.0746	0.5462
0.1121	0.6904
0.1545	0.7836
0.1952	0.8360
0.2593	0.8892
0.3094	0.9108
0.3539	0.9268
0.4277	0.9421
0.5022	0.9551
0.5421	0.9597
0.5650	0.9632
0.6345	0.9707
0.7009	0.9748
0.7408	0.9759
0.7808	0.9783
0.8131	0.9803
0.8822	0.9847
0.9155	0.9874
0.9436	0.9911
0.9650	0.9940
0.9797	0.9956
0.9890	0.9967
0.9978	0.9993
1.0000	1.0000

Mole fraction of Formic acid, propyl ester (1) [ref]

Operational condition: Pressure, kPa = 101.32 (Gas)

Mole fraction of Formic acid, propyl ester (1) - Liquid	Mole fraction of Formic acid, propyl ester (1) - Gas
0.0000	0.0000
0.0319	0.2575
0.0462	0.3710
0.0746	0.5462
0.1121	0.6904
0.1545	0.7836
0.1952	0.8360
0.2593	0.8892
0.3094	0.9108
0.3539	0.9268
0.4277	0.9421
0.5022	0.9551
0.5421	0.9597
0.5650	0.9632
0.6345	0.9707
0.7009	0.9748
0.7408	0.9759
0.7808	0.9783
0.8131	0.9803
0.8822	0.9847
0.9155	0.9874
0.9436	0.9911
0.9650	0.9940
0.9797	0.9956
0.9890	0.9967
0.9978	0.9993
1.0000	1.0000
0.0000	0.0000
0.0319	0.2575
0.0462	0.3710
0.0746	0.5462
0.1121	0.6904
0.1545	0.7836
0.1952	0.8360
0.2593	0.8892
0.3094	0.9108
0.3539	0.9268
0.4277	0.9421
0.5022	0.9551
0.5421	0.9597
0.5650	0.9632
0.6345	0.9707
0.7009	0.9748
0.7408	0.9759
0.7808	0.9783
0.8131	0.9803
0.8822	0.9847
0.9155	0.9874
0.9436	0.9911
0.9650	0.9940
0.9797	0.9956
0.9890	0.9967
0.9978	0.9993
1.0000	1.0000

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, propyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.1222	0.6910
291.15	0.2398	1.133
291.15	0.3111	1.37
291.15	0.3728	1.494
291.15	0.4289	1.567
291.15	0.4807	1.603
291.15	0.5272	1.606
291.15	0.5698	1.589
291.15	0.5818	1.584
291.15	0.6235	1.541
291.15	0.6648	1.477
291.15	0.7081	1.386
291.15	0.7545	1.263
291.15	0.7992	1.116
291.15	0.8438	0.9380
291.15	0.8883	0.7160
291.15	0.9241	0.5130
291.15	0.9644	0.2650
318.15	0.1001	0.6020
318.15	0.1976	1.026
318.15	0.2949	1.383
318.15	0.3831	1.602
318.15	0.4596	1.709
318.15	0.5202	1.73
318.15	0.5678	1.706
318.15	0.6116	1.674
318.15	0.6118	1.665
318.15	0.6727	1.572
318.15	0.7363	1.417
318.15	0.8019	1.196
318.15	0.8610	0.9270
318.15	0.9192	0.6030
318.15	0.9663	0.2800

Excess molar enthalpy (molar enthalpy of mixing), kJ/mol [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, propyl ester (1) - Liquid	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol - Liquid
291.15	0.1222	0.6910
291.15	0.2398	1.133
291.15	0.3111	1.37
291.15	0.3728	1.494
291.15	0.4289	1.567
291.15	0.4807	1.603
291.15	0.5272	1.606
291.15	0.5698	1.589
291.15	0.5818	1.584
291.15	0.6235	1.541
291.15	0.6648	1.477
291.15	0.7081	1.386
291.15	0.7545	1.263
291.15	0.7992	1.116
291.15	0.8438	0.9380
291.15	0.8883	0.7160
291.15	0.9241	0.5130
291.15	0.9644	0.2650
318.15	0.1001	0.6020
318.15	0.1976	1.026
318.15	0.2949	1.383
318.15	0.3831	1.602
318.15	0.4596	1.709
318.15	0.5202	1.73
318.15	0.5678	1.706
318.15	0.6116	1.674
318.15	0.6118	1.665
318.15	0.6727	1.572
318.15	0.7363	1.417
318.15	0.8019	1.196
318.15	0.8610	0.9270
318.15	0.9192	0.6030
318.15	0.9663	0.2800

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, propyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	731.24
291.15	0.0462	734.81
291.15	0.0975	738.84
291.15	0.1628	744.42
291.15	0.1980	747.82
291.15	0.2551	753.47
291.15	0.3036	758.66
291.15	0.3987	770.08
291.15	0.5018	784.66
291.15	0.6082	802.52
291.15	0.7007	820.99
291.15	0.7520	832.38
291.15	0.8007	844.42
291.15	0.8496	858.03
291.15	0.8995	872.93
291.15	0.9521	890.53
291.15	1.0000	907.8
298.15	0.0000	726.26
298.15	0.0798	731.76
298.15	0.1057	733.56
298.15	0.1495	736.97
298.15	0.2011	741.55
298.15	0.2468	746.19
298.15	0.3049	752.35
298.15	0.3974	763.34
298.15	0.5035	777.85
298.15	0.5966	792.82
298.15	0.6972	811.78
298.15	0.7505	823.62
298.15	0.7984	834.9
298.15	0.8500	848.77
298.15	0.8988	862.85
298.15	0.9451	877.85
298.15	1.0000	899.08
308.15	0.0000	717.9
308.15	0.0303	720.66
308.15	0.1111	726.35
308.15	0.1463	729.18
308.15	0.2137	735.1
308.15	0.3006	743.44
308.15	0.3775	752.0
308.15	0.4546	761.78
308.15	0.5153	770.32
308.15	0.5826	780.87
308.15	0.6380	790.54
308.15	0.6907	800.5
308.15	0.7434	811.73
308.15	0.7917	822.76
308.15	0.8281	832.09
308.15	0.8662	842.44
308.15	0.9044	853.49
308.15	0.9379	864.36
308.15	0.9758	877.43
308.15	1.0000	888.36
318.15	0.0000	710.99
318.15	0.1032	717.87
318.15	0.2212	727.7
318.15	0.2964	734.79
318.15	0.3768	743.54
318.15	0.4559	753.18
318.15	0.5213	762.19
318.15	0.5832	771.62
318.15	0.6406	781.23
318.15	0.6917	790.77
318.15	0.7422	800.91
318.15	0.7872	810.94
318.15	0.8275	820.91
318.15	0.8681	831.82
318.15	0.9065	842.66
318.15	0.9402	853.69
318.15	0.9735	864.75
318.15	1.0000	875.32

Mass density, kg/m3 [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Fixed		Measured
Temperature, K - Liquid	Mole fraction of Formic acid, propyl ester (1) - Liquid	Mass density, kg/m3 - Liquid
291.15	0.0000	731.24
291.15	0.0462	734.81
291.15	0.0975	738.84
291.15	0.1628	744.42
291.15	0.1980	747.82
291.15	0.2551	753.47
291.15	0.3036	758.66
291.15	0.3987	770.08
291.15	0.5018	784.66
291.15	0.6082	802.52
291.15	0.7007	820.99
291.15	0.7520	832.38
291.15	0.8007	844.42
291.15	0.8496	858.03
291.15	0.8995	872.93
291.15	0.9521	890.53
291.15	1.0000	907.8
298.15	0.0000	726.26
298.15	0.0798	731.76
298.15	0.1057	733.56
298.15	0.1495	736.97
298.15	0.2011	741.55
298.15	0.2468	746.19
298.15	0.3049	752.35
298.15	0.3974	763.34
298.15	0.5035	777.85
298.15	0.5966	792.82
298.15	0.6972	811.78
298.15	0.7505	823.62
298.15	0.7984	834.9
298.15	0.8500	848.77
298.15	0.8988	862.85
298.15	0.9451	877.85
298.15	1.0000	899.08
308.15	0.0000	717.9
308.15	0.0303	720.66
308.15	0.1111	726.35
308.15	0.1463	729.18
308.15	0.2137	735.1
308.15	0.3006	743.44
308.15	0.3775	752.0
308.15	0.4546	761.78
308.15	0.5153	770.32
308.15	0.5826	780.87
308.15	0.6380	790.54
308.15	0.6907	800.5
308.15	0.7434	811.73
308.15	0.7917	822.76
308.15	0.8281	832.09
308.15	0.8662	842.44
308.15	0.9044	853.49
308.15	0.9379	864.36
308.15	0.9758	877.43
308.15	1.0000	888.36
318.15	0.0000	710.99
318.15	0.1032	717.87
318.15	0.2212	727.7
318.15	0.2964	734.79
318.15	0.3768	743.54
318.15	0.4559	753.18
318.15	0.5213	762.19
318.15	0.5832	771.62
318.15	0.6406	781.23
318.15	0.6917	790.77
318.15	0.7422	800.91
318.15	0.7872	810.94
318.15	0.8275	820.91
318.15	0.8681	831.82
318.15	0.9065	842.66
318.15	0.9402	853.69
318.15	0.9735	864.75
318.15	1.0000	875.32

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Formic acid, propyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	446.93
0.0319	435.96
0.0462	430.26
0.0746	419.85
0.1121	408.45
0.1545	398.47
0.1952	391.40
0.2593	382.69
0.3094	378.05
0.3539	374.47
0.4277	370.70
0.5022	367.22
0.5421	365.85
0.5650	364.76
0.6345	362.44
0.7009	361.10
0.7408	360.66
0.7808	359.72
0.8131	359.00
0.8822	357.09
0.9155	356.00
0.9436	355.30
0.9650	354.75
0.9797	354.35
0.9890	354.05
0.9978	353.76
1.0000	353.92
0.0000	446.93
0.0319	435.96
0.0462	430.26
0.0746	419.85
0.1121	408.45
0.1545	398.47
0.1952	391.40
0.2593	382.69
0.3094	378.05
0.3539	374.47
0.4277	370.70
0.5022	367.22
0.5421	365.85
0.5650	364.76
0.6345	362.44
0.7009	361.10
0.7408	360.66
0.7808	359.72
0.8131	359.00
0.8822	357.09
0.9155	356.00
0.9436	355.30
0.9650	354.75
0.9797	354.35
0.9890	354.05
0.9978	353.76
1.0000	353.92

Boiling temperature at pressure P, K [ref]

Operational condition: Pressure, kPa = 101.32 (Liquid)

Mole fraction of Formic acid, propyl ester (1) - Liquid	Boiling temperature at pressure P, K - Liquid
0.0000	446.93
0.0319	435.96
0.0462	430.26
0.0746	419.85
0.1121	408.45
0.1545	398.47
0.1952	391.40
0.2593	382.69
0.3094	378.05
0.3539	374.47
0.4277	370.70
0.5022	367.22
0.5421	365.85
0.5650	364.76
0.6345	362.44
0.7009	361.10
0.7408	360.66
0.7808	359.72
0.8131	359.00
0.8822	357.09
0.9155	356.00
0.9436	355.30
0.9650	354.75
0.9797	354.35
0.9890	354.05
0.9978	353.76
1.0000	353.92
0.0000	446.93
0.0319	435.96
0.0462	430.26
0.0746	419.85
0.1121	408.45
0.1545	398.47
0.1952	391.40
0.2593	382.69
0.3094	378.05
0.3539	374.47
0.4277	370.70
0.5022	367.22
0.5421	365.85
0.5650	364.76
0.6345	362.44
0.7009	361.10
0.7408	360.66
0.7808	359.72
0.8131	359.00
0.8822	357.09
0.9155	356.00
0.9436	355.30
0.9650	354.75
0.9797	354.35
0.9890	354.05
0.9978	353.76
1.0000	353.92

Sources

• Excess properties and isobaric vapor liquid equilibria for four binary systems of alkyl (methyl to butyl) methanoates with decane