Chemical Properties of Formic acid, propyl ester (CAS 110-74-7)

InChI

InChI=1S/C4H8O2/c1-2-3-6-4-5/h4H,2-3H2,1H3

InChI Key

KFNNIILCVOLYIR-UHFFFAOYSA-N

Formula

C4H8O2

SMILES

CCCOC=O

Molecular Weight¹

88.11

CAS

110-74-7

Other Names

• Formiate de propyle
• Formic acid propyl ester
• HCOOCH2CH2CH3
• PROPYL ESTER FORMIC ACID
• Propyl ester of formic acid
• Propylester kyseliny mravenci
• UN 1281
• methanoic acid, propyl ester
• n-propyl formate
• propyl formate
• propyl methanoate

• ω : Acentric Factor.
• PAff : Proton affinity (kJ/mol).
• BasG : Gas basicity (kJ/mol).
• Δ_cH°_solid : Standard solid enthalpy of combustion (kJ/mol).
• C_p,gas : Ideal gas heat capacity (J/mol×K).
• C_p,liquid : Liquid phase heat capacity (J/mol×K).
• μ : Dipole Moment (debye).
• η : Dynamic viscosity (Pa×s).
• Δ_fG° : Standard Gibbs free energy of formation (kJ/mol).
• Δ_fH°_gas : Enthalpy of formation at standard conditions (kJ/mol).
• Δ_fH°_solid : Solid phase enthalpy of formation at standard conditions (kJ/mol).
• Δ_fusH° : Enthalpy of fusion at standard conditions (kJ/mol).
• Δ_vapH° : Enthalpy of vaporization at standard conditions (kJ/mol).
• Δ_vapH : Enthalpy of vaporization at a given temperature (kJ/mol).
• IE : Ionization energy (eV).
• log₁₀WS : Log10 of Water solubility in mol/l.
• logP_oct/wat : Octanol/Water partition coefficient.
• McVol : McGowan's characteristic volume (ml/mol).
• NFPA Fire : NFPA Fire Rating.
• NFPA Health : NFPA Health Rating.
• P_c : Critical Pressure (kPa).
• P_triple : Triple Point Pressure (kPa).
• P_vap : Vapor pressure (kPa).
• n₀ : Refractive Index.
• ρ_c : Critical density (kg/m³).
• ρ_l : Liquid Density (kg/m³).
• I_np : Non-polar retention indices.
• I_p : Polar retention indices.
• γ : Surface Tension (N/m).
• T_boil : Normal Boiling Point Temperature (K).
• T_c : Critical Temperature (K).
• λ_gas : Gas thermal conductivity (W/m×K).
• λ_liquid : Liquid thermal conductivity (W/m×K).
• T_fus : Normal melting (fusion) point (K).
• T_triple : Triple Point Temperature (K).
• U_Qi : UNIQUAC Qi Parameter.
• U_Ri : UNIQUAC Ri Parameter.
• V_c : Critical Volume (m³/kmol).
• Z_c : Critical Compressibility.
• ¹: Molecular weight from the IUPAC atomic weights tables.

Physical Properties

Property	Value	Unit	Source
ω	[0.3140; 0.3200]
ω	0.3150		PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
ω	0.3200		ChemSep v8.3 pure component data Compiled value
ω	0.3140		KDB
PAff	804.90	kJ/mol	NIST
BasG	773.90	kJ/mol	NIST
ΔcH°solid	-2217.00 ± 42.00	kJ/mol	NIST
μ	[1.90; 1.91]	debye
μ	1.91	debye	ChemSep v8.3 pure component data Compiled value
μ	1.90	debye	KDB
ΔfG°	-293.60	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfH°gas	-407.60	kJ/mol	ChemSep v8.3 pure component data Compiled value
ΔfH°solid	-500.00 ± 42.00	kJ/mol	NIST
ΔfusH°	12.17	kJ/mol	Joback Calculated Property
ΔvapH°	[32.50; 37.61]	kJ/mol
ΔvapH°	37.61	kJ/mol	NIST
ΔvapH°	37.50 ± 0.10	kJ/mol	NIST
ΔvapH°	32.50 ± 0.04	kJ/mol	NIST
IE	[10.30; 10.62]	eV
IE	10.54 ± 0.05	eV	NIST
IE	Outlier 10.30 ± 0.20	eV	NIST
IE	10.50 ± 0.05	eV	NIST
IE	10.50	eV	NIST
IE	10.62	eV	NIST
IE	10.54 ± 0.01	eV	NIST
log10WS	[-0.49; -0.49]
log10WS	-0.49		Aq. Solubility Prediction
log10WS	-0.49		Estimated Solubility
logPoct/wat	0.569		Crippen Calculated Property
McVol	74.660	ml/mol	McGowan Calculated Property
NFPA Fire	3		KDB
NFPA Health	2		KDB
Pc	[4060.00; 4330.00]	kPa
Pc	4060.00	kPa	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Pc	4063.13	kPa	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Pc	4060.00	kPa	ChemSep v8.3 pure component data Compiled value
Pc	4060.00	kPa	KDB
Pc	4061.00 ± 60.79	kPa	NIST
Pc	4061.00 ± 40.00	kPa	NIST
Pc	Outlier 4330.00 ± 303.98	kPa	NIST
Ptriple	2.11e-04	kPa	ChemSep v8.3 pure component data Compiled value
ρc	[304.84; 309.51]	kg/m3
ρc	309.34 ± 5.29	kg/m3	NIST
ρc	309.51 ± 4.41	kg/m3	NIST
ρc	304.84 ± 5.29	kg/m3	NIST
Inp	[559.00; 606.00]
Inp	564.00		NIST
Inp	572.00		NIST
Inp	576.00		NIST
Inp	570.00		NIST
Inp	602.00		NIST
Inp	559.00		NIST
Inp	592.00		NIST
Inp	574.00		NIST
Inp	570.00		NIST
Inp	602.00		NIST
Inp	604.00		NIST
Inp	605.00		NIST
Inp	604.00		NIST
Inp	602.00		NIST
Inp	602.00		NIST
Inp	606.00		NIST
Inp	602.00		NIST
Inp	606.00		NIST
Inp	606.00		NIST
Inp	603.00		NIST
Inp	603.00		NIST
Inp	564.00		NIST
Inp	559.00		NIST
Inp	602.00		NIST
Ip	[892.00; 916.00]
Ip	892.00		NIST
Ip	907.00		NIST
Ip	916.00		NIST
Ip	907.00		NIST
Ip	892.00		NIST
Tboil	[353.92; 354.69]	K
Tboil	353.92	K	Solutions of alkyl methanoates and alkanes: Simultaneous modeling of phase equilibria and mixing properties. Estimation of behavior by UNIFAC with recalculation of parameters
Tboil	353.92	K	Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Methanoates + Hexane
Tboil	Outlier 354.69	K	ChemSep v8.3 pure component data Compiled value
Tboil	354.00	K	KDB
Tboil	354.50	K	NIST
Tboil	354.00	K	NIST
Tboil	354.05 ± 0.20	K	NIST
Tboil	354.00 ± 0.10	K	NIST
Tboil	354.15 ± 2.00	K	NIST
Tboil	354.00 ± 0.50	K	NIST
Tboil	354.00 ± 0.50	K	NIST
Tboil	354.10 ± 0.40	K	NIST
Tboil	353.95 ± 1.00	K	NIST
Tboil	354.10 ± 1.00	K	NIST
Tboil	354.40 ± 0.30	K	NIST
Tboil	354.05 ± 0.50	K	NIST
Tboil	354.00 ± 1.00	K	NIST
Tboil	354.05 ± 0.50	K	NIST
Tboil	354.40 ± 0.70	K	NIST
Tboil	354.00 ± 2.00	K	NIST
Tboil	354.15 ± 2.00	K	NIST
Tc	[533.70; 538.00]	K
Tc	538.00	K	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Tc	538.00	K	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Tc	538.00	K	ChemSep v8.3 pure component data Compiled value
Tc	538.00	K	KDB
Tc	538.00	K	NIST
Tc	538.00 ± 1.00	K	NIST
Tc	538.00 ± 1.00	K	NIST
Tc	533.70 ± 4.00	K	NIST
Tc	534.00 ± 4.00	K	NIST
Tfus	[180.20; 180.30]	K
Tfus	180.20	K	Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) Compiled value
Tfus	180.25	K	ChemSep v8.3 pure component data Compiled value
Tfus	180.20	K	KDB
Tfus	180.20	K	Aq. Solubility Prediction
Tfus	180.30 ± 0.40	K	NIST
Ttriple	180.25	K	ChemSep v8.3 pure component data Compiled value
UQi	3.12		ChemSep v8.3 pure component data Compiled value
URi	3.49		ChemSep v8.3 pure component data Compiled value
Vc	[0.285; 0.285]	m3/kmol
Vc	0.285	m3/kmol	IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Vc	0.285	m3/kmol	PSRK revision IV (2005), critical constants and acentric factors of 1000 components Compiled value
Vc	0.285	m3/kmol	ChemSep v8.3 pure component data Compiled value
Vc	0.285	m3/kmol	KDB
Zc	[0.2586740; 0.2590000]
Zc	0.2590000		IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 Compiled value
Zc	0.2590000		ChemSep v8.3 pure component data Compiled value
Zc	0.2586740		KDB

Temperature Dependent Properties

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[171.42; 172.10]	J/mol×K	[298.15; 298.15]
Cp,liquid	172.10	J/mol×K	298.15	NIST
Cp,liquid	171.42	J/mol×K	298.15	NIST
Cp,liquid	172.07	J/mol×K	298.15	NIST
η	[0.0004310; 0.0004770]	Pa×s	[303.15; 313.15]
η	0.0004770	Pa×s	303.15	Density and Viscosity of Propyl Formate + Aromatic Hydrocarbons at T = (303.15, 308.15, and 313.15) K
η	0.0004560	Pa×s	308.15	Density and Viscosity of Propyl Formate + Aromatic Hydrocarbons at T = (303.15, 308.15, and 313.15) K
η	0.0004310	Pa×s	313.15	Density and Viscosity of Propyl Formate + Aromatic Hydrocarbons at T = (303.15, 308.15, and 313.15) K
ΔvapH	[32.70; 36.80]	kJ/mol	[292.50; 436.00]
ΔvapH	36.80	kJ/mol	292.50	NIST
ΔvapH	36.50 ± 0.10	kJ/mol	313.00	NIST
ΔvapH	35.80 ± 0.10	kJ/mol	326.00	NIST
ΔvapH	35.60	kJ/mol	327.00	NIST
ΔvapH	35.30	kJ/mol	327.50	NIST
ΔvapH	35.40 ± 0.10	kJ/mol	331.00	NIST
ΔvapH	34.40 ± 0.10	kJ/mol	344.00	NIST
ΔvapH	33.80 ± 0.10	kJ/mol	351.00	NIST
ΔvapH	33.61	kJ/mol	354.00	NIST
ΔvapH	33.50 ± 0.10	kJ/mol	355.00	NIST
ΔvapH	32.90 ± 0.10	kJ/mol	363.00	NIST
ΔvapH	32.70	kJ/mol	436.00	NIST
Pvap	101.32	kPa	353.92	Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Methanoates + Hexane
n0	[1.37180; 1.37260]		[303.15; 303.15]
n0	1.37180		303.15	Correlation and Prediction of Excess Quantities and Vapor-Liquid Equilibria of Alkyl Esters + tert-Butyl Alcohol: Experimental Data for Propyl Esters + tert-Butyl Alcohol
n0	1.37260		303.15	Excess Volumes of Binary Solutions of Methyl Formate, Ethyl Formate, Propyl Formate, and Benzyl Acetate with Bromo-, Chloro-, and Nitrobenzenes at (303.15, 308.15, and 313.15) K
ρl	[899.81; 911.00]	kg/m3	[289.00; 298.15]
ρl	911.00	kg/m3	289.00	KDB
ρl	907.97	kg/m3	291.15	Experimentation and thermodynamic representations of binaries containing compounds of low boiling points: Pentane and alkylmethanoates
ρl	899.86	kg/m3	298.15	Experimentation and thermodynamic representations of binaries containing compounds of low boiling points: Pentane and alkylmethanoates
ρl	899.81	kg/m3	298.15	Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) VII. HE m and VE m for 20 binary mixtures {xCu 1H2u 1CO2C3H7 + (1 x)a,x-ClCH2(CH2)v 2CH2Cl}, where u = 1 to 4, a = 1 and v = x = 2 to 6. An analysis of behavior using the COSMO-RS methodology

Correlations

Property	Value	Unit	Temperature (K)	Source
Cp,gas	[110.01; 275.18]	J/mol×K	[298.15; 1500.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,gas in J/mol×K, T in K
Coefficient A			4.86550e+01
Coefficient B			-4.55540e+02
Coefficient C			5.62224e+00
Coefficient D			7.59170e-05
Coefficient E			-4.24600e-09
Temperature range, min.			298.15
Temperature range, max.			1500.00
Cp,gas	110.01	J/mol×K	298.15	Calculated Property
Cp,gas	148.04	J/mol×K	431.69	Calculated Property
Cp,gas	177.40	J/mol×K	565.23	Calculated Property
Cp,gas	200.26	J/mol×K	698.77	Calculated Property
Cp,gas	218.55	J/mol×K	832.31	Calculated Property
Cp,gas	233.58	J/mol×K	965.84	Calculated Property
Cp,gas	246.25	J/mol×K	1099.38	Calculated Property
Cp,gas	257.15	J/mol×K	1232.92	Calculated Property
Cp,gas	266.70	J/mol×K	1366.46	Calculated Property
Cp,gas	275.18	J/mol×K	1500.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Cp,liquid	[138.95; 231.49]	J/mol×K	[188.30; 433.30]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is Cp,liquid in J/mol×K, T in K
Coefficient A			7.64530e+01
Coefficient B			-4.18530e+01
Coefficient C			3.88924e+00
Coefficient D			2.17760e-03
Coefficient E			1.63750e-06
Temperature range, min.			188.30
Temperature range, max.			433.30
Cp,liquid	138.95	J/mol×K	188.30	Calculated Property
Cp,liquid	145.89	J/mol×K	215.52	Calculated Property
Cp,liquid	153.31	J/mol×K	242.74	Calculated Property
Cp,liquid	161.35	J/mol×K	269.97	Calculated Property
Cp,liquid	170.16	J/mol×K	297.19	Calculated Property
Cp,liquid	179.89	J/mol×K	324.41	Calculated Property
Cp,liquid	190.71	J/mol×K	351.63	Calculated Property
Cp,liquid	202.77	J/mol×K	378.86	Calculated Property
Cp,liquid	216.29	J/mol×K	406.08	Calculated Property
Cp,liquid	231.49	J/mol×K	433.30	Calculated Property

Property	Value	Unit	Temperature (K)	Source
η	[0.0058492; 0.0001415]	Pa×s	[180.25; 438.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is η in Pa×s, T in K
Coefficient A			-5.16490e+01
Coefficient B			2.31770e+03
Coefficient C			6.55560e+00
Coefficient D			-1.23960e-05
Coefficient E			2.00000e+00
Temperature range, min.			180.25
Temperature range, max.			438.00
η	0.0058492	Pa×s	180.25	Calculated Property
η	0.0022978	Pa×s	208.89	Calculated Property
η	0.0011948	Pa×s	237.53	Calculated Property
η	0.0007375	Pa×s	266.17	Calculated Property
η	0.0005068	Pa×s	294.81	Calculated Property
η	0.0003725	Pa×s	323.44	Calculated Property
η	0.0002854	Pa×s	352.08	Calculated Property
η	0.0002239	Pa×s	380.72	Calculated Property
η	0.0001777	Pa×s	409.36	Calculated Property
η	0.0001415	Pa×s	438.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ΔvapH	[44.33; 0.00]	kJ/mol	[180.25; 538.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·(1 − Tr)^(B + C·Tr + D·Tr² + E·Tr³), Tr = T/Tc Y is ΔvapH in kJ/mol, T in K
Coefficient A			5.41440e+01
Coefficient B			5.97341e-01
Coefficient C			-5.89234e-01
Coefficient D			1.00453e+00
Coefficient E			-6.02007e-01
Critical temperature, Tc (K)			5.38000e+02
Temperature range, min.			180.25
Temperature range, max.			538.00
ΔvapH	44.33	kJ/mol	180.25	Calculated Property
ΔvapH	42.00	kJ/mol	220.00	Calculated Property
ΔvapH	39.47	kJ/mol	259.75	Calculated Property
ΔvapH	36.74	kJ/mol	299.50	Calculated Property
ΔvapH	33.76	kJ/mol	339.25	Calculated Property
ΔvapH	30.52	kJ/mol	379.00	Calculated Property
ΔvapH	26.94	kJ/mol	418.75	Calculated Property
ΔvapH	22.81	kJ/mol	458.50	Calculated Property
ΔvapH	17.43	kJ/mol	498.25	Calculated Property
ΔvapH	0.00	kJ/mol	538.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
Pvap	[1.33; 202.63]	kPa	[263.26; 376.94]	The Yaws Handbook of Vapor Pressure
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.41082e+01
Coefficient B			-2.75112e+03
Coefficient C			-6.42010e+01
Temperature range, min.			263.26
Temperature range, max.			376.94
Pvap	1.33	kPa	263.26	Calculated Property
Pvap	3.04	kPa	275.89	Calculated Property
Pvap	6.32	kPa	288.52	Calculated Property
Pvap	12.16	kPa	301.15	Calculated Property
Pvap	21.88	kPa	313.78	Calculated Property
Pvap	37.20	kPa	326.42	Calculated Property
Pvap	60.25	kPa	339.05	Calculated Property
Pvap	93.54	kPa	351.68	Calculated Property
Pvap	139.93	kPa	364.31	Calculated Property
Pvap	202.63	kPa	376.94	Calculated Property
Pvap	[3.79e-04; 3957.23]	kPa	[180.25; 538.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = exp(A + B/T + C·ln(T) + D·T^E) Y is Pvap in kPa, T in K
Coefficient A			6.44449e+01
Coefficient B			-6.24456e+03
Coefficient C			-7.28009e+00
Coefficient D			4.22042e-06
Coefficient E			2.00000e+00
Temperature range, min.			180.25
Temperature range, max.			538.00
Pvap	3.79e-04	kPa	180.25	Calculated Property
Pvap	0.05	kPa	220.00	Calculated Property
Pvap	1.24	kPa	259.75	Calculated Property
Pvap	11.72	kPa	299.50	Calculated Property
Pvap	60.61	kPa	339.25	Calculated Property
Pvap	210.38	kPa	379.00	Calculated Property
Pvap	555.94	kPa	418.75	Calculated Property
Pvap	1212.54	kPa	458.50	Calculated Property
Pvap	2303.66	kPa	498.25	Calculated Property
Pvap	3957.23	kPa	538.00	Calculated Property
Pvap	[4.09e-04; 4001.42]	kPa	[180.25; 538.00]	KDB Vapor Pressure Data
Equation			ln(Y) = A + B/T + C·ln(T) + D·T² + E/T² Y is Pvap in kPa, T in K
Coefficient A			6.34798e+01
Coefficient B			-6.18307e+03
Coefficient C			-7.14597e+00
Coefficient D			4.28442e-06
Coefficient E			0.00000e+00
Temperature range, min.			180.25
Temperature range, max.			538.00
Pvap	4.09e-04	kPa	180.25	Calculated Property
Pvap	0.05	kPa	220.00	Calculated Property
Pvap	1.27	kPa	259.75	Calculated Property
Pvap	11.85	kPa	299.50	Calculated Property
Pvap	60.92	kPa	339.25	Calculated Property
Pvap	210.96	kPa	379.00	Calculated Property
Pvap	557.47	kPa	418.75	Calculated Property
Pvap	1217.89	kPa	458.50	Calculated Property
Pvap	2320.52	kPa	498.25	Calculated Property
Pvap	4001.42	kPa	538.00	Calculated Property
Pvap	[11.74; 107.39]	kPa	[299.40; 355.50]	NIST
Equation			ln(Y) = A + B/(T + C) Y is Pvap in kPa, T in K
Coefficient A			1.38937e+01
Coefficient B			-2.67010e+03
Coefficient C			-6.58150e+01
Reference			Nelson, 1928
Comment			Coefficents calculated by NIST from author's data.
Temperature range, min.			299.40
Temperature range, max.			355.50
Pvap	11.74	kPa	299.40	Calculated Property
Pvap	15.80	kPa	305.63	Calculated Property
Pvap	20.95	kPa	311.87	Calculated Property
Pvap	27.39	kPa	318.10	Calculated Property
Pvap	35.35	kPa	324.33	Calculated Property
Pvap	45.08	kPa	330.57	Calculated Property
Pvap	56.85	kPa	336.80	Calculated Property
Pvap	70.95	kPa	343.03	Calculated Property
Pvap	87.68	kPa	349.27	Calculated Property
Pvap	107.39	kPa	355.50	Calculated Property

Property	Value	Unit	Temperature (K)	Source
ρl	[1021.15; 308.47]	kg/m3	[180.25; 538.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A / B^(1 + (1 − T/C)^D) Y is ρl in kg/m3, T in K
Coefficient A			8.06162e+01
Coefficient B			2.61340e-01
Coefficient C			5.38000e+02
Coefficient D			2.80000e-01
Temperature range, min.			180.25
Temperature range, max.			538.00
ρl	1021.15	kg/m3	180.25	Calculated Property
ρl	982.26	kg/m3	220.00	Calculated Property
ρl	941.38	kg/m3	259.75	Calculated Property
ρl	898.04	kg/m3	299.50	Calculated Property
ρl	851.53	kg/m3	339.25	Calculated Property
ρl	800.74	kg/m3	379.00	Calculated Property
ρl	743.75	kg/m3	418.75	Calculated Property
ρl	676.72	kg/m3	458.50	Calculated Property
ρl	589.14	kg/m3	498.25	Calculated Property
ρl	308.47	kg/m3	538.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
γ	[0.04; 0.02]	N/m	[180.25; 354.05]	Jasper (1972), surface tension of pure liquid compounds Compiled value
Equation			Y = A + B·T + C·T² + D·T³ + E·T⁴ Y is γ in N/m, T in K
Coefficient A			5.73355e-02
Coefficient B			-1.11900e-04
Coefficient C			0.00000e+00
Coefficient D			0.00000e+00
Coefficient E			0.00000e+00
Temperature range, min.			180.25
Temperature range, max.			354.05
γ	0.04	N/m	180.25	Calculated Property
γ	0.04	N/m	199.56	Calculated Property
γ	0.03	N/m	218.87	Calculated Property
γ	0.03	N/m	238.18	Calculated Property
γ	0.03	N/m	257.49	Calculated Property
γ	0.03	N/m	276.81	Calculated Property
γ	0.02	N/m	296.12	Calculated Property
γ	0.02	N/m	315.43	Calculated Property
γ	0.02	N/m	334.74	Calculated Property
γ	0.02	N/m	354.05	Calculated Property
γ	[0.04; 2.86e-05]	N/m	[180.25; 536.21]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is γ in N/m, T in K
Coefficient A			-1.78310e-02
Coefficient B			2.82090e+01
Coefficient C			-2.94300e+00
Coefficient D			1.83060e-04
Coefficient E			-4.28830e-06
Comment			Range stopped where the equation turns negative; ChemSep gives it to 538 K.
Temperature range, min.			180.25
Temperature range, max.			536.21
γ	0.04	N/m	180.25	Calculated Property
γ	0.03	N/m	219.80	Calculated Property
γ	0.03	N/m	259.35	Calculated Property
γ	0.02	N/m	298.90	Calculated Property
γ	0.02	N/m	338.46	Calculated Property
γ	0.02	N/m	378.01	Calculated Property
γ	0.01	N/m	417.56	Calculated Property
γ	0.01	N/m	457.11	Calculated Property
γ	0.00	N/m	496.66	Calculated Property
γ	2.86e-05	N/m	536.21	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λgas	[0.00; 0.11]	W/m×K	[180.25; 1000.00]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A·T^B / (1 + C/T + D/T²) Y is λgas in W/m×K, T in K
Coefficient A			6.61080e+02
Coefficient B			9.92320e-01
Coefficient C			5.84490e+09
Coefficient D			-9.05970e+10
Temperature range, min.			180.25
Temperature range, max.			1000.00
λgas	0.00	W/m×K	180.25	Calculated Property
λgas	0.01	W/m×K	271.33	Calculated Property
λgas	0.01	W/m×K	362.42	Calculated Property
λgas	0.02	W/m×K	453.50	Calculated Property
λgas	0.03	W/m×K	544.58	Calculated Property
λgas	0.04	W/m×K	635.67	Calculated Property
λgas	0.06	W/m×K	726.75	Calculated Property
λgas	0.07	W/m×K	817.83	Calculated Property
λgas	0.09	W/m×K	908.92	Calculated Property
λgas	0.11	W/m×K	1000.00	Calculated Property

Property	Value	Unit	Temperature (K)	Source
λliquid	[0.18; 0.10]	W/m×K	[180.00; 483.15]	ChemSep v8.3 pure component data Compiled value
Equation			Y = A + exp(B/T + C + D·T + E·T²) Y is λliquid in W/m×K, T in K
Coefficient A			1.72420e-02
Coefficient B			-2.24740e+01
Coefficient C			-1.44780e+00
Coefficient D			-1.12780e-03
Coefficient E			-2.07160e-06
Temperature range, min.			180.00
Temperature range, max.			483.15
λliquid	0.18	W/m×K	180.00	Calculated Property
λliquid	0.17	W/m×K	213.68	Calculated Property
λliquid	0.16	W/m×K	247.37	Calculated Property
λliquid	0.15	W/m×K	281.05	Calculated Property
λliquid	0.14	W/m×K	314.73	Calculated Property
λliquid	0.13	W/m×K	348.42	Calculated Property
λliquid	0.12	W/m×K	382.10	Calculated Property
λliquid	0.11	W/m×K	415.78	Calculated Property
λliquid	0.11	W/m×K	449.47	Calculated Property
λliquid	0.10	W/m×K	483.15	Calculated Property

Similar Compounds

Find more compounds similar to Formic acid, propyl ester.

Mixtures

• Formic acid, propyl ester + Ethane, 1,2-dichloro-
• Formic acid, propyl ester + Propane, 1,3-dichloro-
• Formic acid, propyl ester + Butane, 1,4-dichloro-
• Formic acid, propyl ester + Pentane, 1,5-dichloro-
• Formic acid, propyl ester + Hexane, 1,6-dichloro-
• Formic acid, propyl ester + Pentane
• Formic acid, propyl ester + Heptane
• Formic acid, propyl ester + Octane
• Formic acid, propyl ester + Nonane
• Formic acid, propyl ester + Decane
• Formic acid, propyl ester + Benzene, chloro-
• Formic acid, propyl ester + Benzene, bromo-
• Formic acid, propyl ester + Benzene, nitro-
• Formic acid, propyl ester + 2-Propanol, 2-methyl-
• Formic acid, propyl ester + n-Hexane
• Formic acid, propyl ester + Benzene
• Formic acid, propyl ester + Benzene, (1-methylethyl)-
• Formic acid, propyl ester + Benzene, (2-methylpropyl)-
• Formic acid, propyl ester + Benzene, n-butyl-

Sources

• KDB Vapor Pressure Data
• Jean-Claude Bradley Open Melting Point Dataset (2014, CC0) ChEDL chemicals 1.5.2, from Bradley, J.-C.; Williams, A.; Lang, A. Jean-Claude Bradley Open Melting Point Dataset. Figshare, 2014 (CC0).
• IUPAC Vapor-Liquid Critical Properties of Elements and Compounds, part 7 ChEDL chemicals 1.5.2, from Kudchadker, A. P.; Ambrose, D.; Tsonopoulos, C. Vapor-Liquid Critical Properties of Elements and Compounds. 7. Oxygen Compounds Other Than Alkanols and Cycloalkanols. J. Chem. Eng. Data 2001, 46, 457-479.
• Jasper (1972), surface tension of pure liquid compounds ChEDL chemicals 1.5.2, from Jasper, J. J. The Surface Tension of Pure Liquid Compounds. J. Phys. Chem. Ref. Data 1972, 1, 841-1010 (as transcribed in Lange's Handbook).
• PSRK revision IV (2005), critical constants and acentric factors of 1000 components ChEDL chemicals 1.5.2, from Horstmann, S.; Jabłoniec, A.; Krafczyk, J.; Fischer, K.; Gmehling, J. PSRK Group Contribution Equation of State: Comprehensive Revision and Extension IV, Including Critical Constants and α-Function Parameters for 1000 Components. Fluid Phase Equilib. 2005, 227, 157-164.
• ChemSep v8.3 pure component data Converted from ChemSep v8.3 pure component data, H. Kooijman and R. Taylor (2021, 2022), Artistic License 2.0; see how the values differ.
• Crippen Method
• Excess properties and isobaric vapor liquid equilibria for four binary systems of alkyl (methyl to butyl) methanoates with decane
• Experimentation and thermodynamic representations of binaries containing compounds of low boiling points: Pentane and alkylmethanoates
• Solutions of alkyl methanoates and alkanes: Simultaneous modeling of phase equilibria and mixing properties. Estimation of behavior by UNIFAC with recalculation of parameters
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) V. Hex and Vex for 25 binary mixtures {xCu-1H2u-1CO2CH3 + (1-x)a,x-ClCH2(CH2)v-2CH2Cl}, where u = 1 to 5, a = 1 and v = x = 2 to 6
• Thermodynamic study of (alkyl esters + a,x-alkyl dihalides) VII. HE m and VE m for 20 binary mixtures {xCu 1H2u 1CO2C3H7 + (1 x)a,x-ClCH2(CH2)v 2CH2Cl}, where u = 1 to 4, a = 1 and v = x = 2 to 6. An analysis of behavior using the COSMO-RS methodology
• Correlation and Prediction of Excess Quantities and Vapor-Liquid Equilibria of Alkyl Esters + tert-Butyl Alcohol: Experimental Data for Propyl Esters + tert-Butyl Alcohol
• Isobaric Vapor-Liquid Equilibrium Data and Excess Properties of Binary Systems Comprised of Alkyl Methanoates + Hexane
• Excess Volumes of Binary Solutions of Methyl Formate, Ethyl Formate, Propyl Formate, and Benzyl Acetate with Bromo-, Chloro-, and Nitrobenzenes at (303.15, 308.15, and 313.15) K
• Density and Viscosity of Propyl Formate + Aromatic Hydrocarbons at T = (303.15, 308.15, and 313.15) K
• Joback Method
• KDB
• Aqueous Solubility Prediction Method
• Estimated Solubility Method
• McGowan Method
• NIST Webbook
• The Yaws Handbook of Vapor Pressure

Note: Cheméo is only indexing the data, follow the source links to retrieve the latest data. The source is also providing more information like the publication year, authors and more. Take the time to validate and double check the source of the data.
Outlier This icon means that the value is more than 2 standard deviations away from the property mean.
Calculated This icon marks a calculated value or equation: a prediction, not a measurement.
Compiled This icon marks a compiled value or equation: taken from a data compilation such as ChemSep, not from an original measurement report.
These property values are available through the Cheméo API. A free account gives you an access key.