Mixture of Ethyl formate + Ethanol + Water

Datasets

1. Mole fraction (4)

Mole fraction of Ethyl formate (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Ethanol (2) - Liquid mixture 1	Mole fraction of Ethyl formate (1) - Liquid mixture 1
298.15	0.1040	0.6790
298.15	0.1530	0.5450
298.15	0.1770	0.4530
298.15	0.1810	0.4250
298.15	0.1860	0.3950
298.15	0.1900	0.3570
298.15	0.1860	0.3120
298.15	0.1870	0.2840
298.15	0.1800	0.2250
298.15	0.1760	0.2120
298.15	0.1720	0.2000
298.15	0.1700	0.1840
298.15	0.1620	0.1500
298.15	0.1570	0.1330
298.15	0.1490	0.1100
298.15	0.1370	0.0860
298.15	0.1290	0.0700
298.15	0.0940	0.0400
308.15	0.0300	0.7860
308.15	0.0760	0.7060
308.15	0.1090	0.6380
308.15	0.1330	0.5880
308.15	0.1480	0.5320
308.15	0.1620	0.4800
308.15	0.1670	0.4430
308.15	0.1690	0.3910
308.15	0.1710	0.3520
308.15	0.1700	0.3220
308.15	0.1670	0.2850
308.15	0.1620	0.2540
308.15	0.1580	0.2270
308.15	0.1540	0.2100
308.15	0.1520	0.1920
308.15	0.1460	0.1730
308.15	0.1300	0.1210
308.15	0.1190	0.1000
308.15	0.1080	0.0790

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Ethyl formate (1) - Liquid mixture 2	Mole fraction of Ethanol (2) - Liquid mixture 2	Mole fraction of Ethanol (2) - Liquid mixture 1	Mole fraction of Ethyl formate (1) - Liquid mixture 1
298.15	0.7740	0.0370	0.0290	0.0160
308.15	0.7520	0.0450	0.0240	0.0130
308.15	0.6890	0.0790	0.0340	0.0180
308.15	0.6040	0.1210	0.0560	0.0210
298.15	0.8350	0.0000	0.0000	0.0170
308.15	0.8250	0.0000	0.0000	0.0200
308.15	0.5180	0.1550	0.0720	0.0320
298.15	0.1160	0.1480	0.1480	0.1160
308.15	0.1390	0.1450	0.1450	0.1390
308.15	0.3790	0.1700	0.0930	0.0400
298.15	0.7120	0.0750	0.0470	0.0220
298.15	0.6060	0.1200	0.0690	0.0260
298.15	0.4800	0.1520	0.0920	0.0290
298.15	0.3580	0.1740	0.1200	0.0480

Mole fraction of Ethyl formate (1) [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 1)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Ethanol (2) - Liquid mixture 1	Mole fraction of Ethyl formate (1) - Liquid mixture 1
298.15	0.1040	0.6790
298.15	0.1530	0.5450
298.15	0.1770	0.4530
298.15	0.1810	0.4250
298.15	0.1860	0.3950
298.15	0.1900	0.3570
298.15	0.1860	0.3120
298.15	0.1870	0.2840
298.15	0.1800	0.2250
298.15	0.1760	0.2120
298.15	0.1720	0.2000
298.15	0.1700	0.1840
298.15	0.1620	0.1500
298.15	0.1570	0.1330
298.15	0.1490	0.1100
298.15	0.1370	0.0860
298.15	0.1290	0.0700
298.15	0.0940	0.0400
308.15	0.0300	0.7860
308.15	0.0760	0.7060
308.15	0.1090	0.6380
308.15	0.1330	0.5880
308.15	0.1480	0.5320
308.15	0.1620	0.4800
308.15	0.1670	0.4430
308.15	0.1690	0.3910
308.15	0.1710	0.3520
308.15	0.1700	0.3220
308.15	0.1670	0.2850
308.15	0.1620	0.2540
308.15	0.1580	0.2270
308.15	0.1540	0.2100
308.15	0.1520	0.1920
308.15	0.1460	0.1730
308.15	0.1300	0.1210
308.15	0.1190	0.1000
308.15	0.1080	0.0790

Temperature, K x Mole fraction [ref]

Operational condition: Pressure, kPa = 101 (Liquid mixture 2)

Fixed		Measured
Temperature, K - Liquid mixture 1	Mole fraction of Ethyl formate (1) - Liquid mixture 2	Mole fraction of Ethanol (2) - Liquid mixture 2	Mole fraction of Ethanol (2) - Liquid mixture 1	Mole fraction of Ethyl formate (1) - Liquid mixture 1
298.15	0.7740	0.0370	0.0290	0.0160
308.15	0.7520	0.0450	0.0240	0.0130
308.15	0.6890	0.0790	0.0340	0.0180
308.15	0.6040	0.1210	0.0560	0.0210
298.15	0.8350	0.0000	0.0000	0.0170
308.15	0.8250	0.0000	0.0000	0.0200
308.15	0.5180	0.1550	0.0720	0.0320
298.15	0.1160	0.1480	0.1480	0.1160
308.15	0.1390	0.1450	0.1450	0.1390
308.15	0.3790	0.1700	0.0930	0.0400
298.15	0.7120	0.0750	0.0470	0.0220
298.15	0.6060	0.1200	0.0690	0.0260
298.15	0.4800	0.1520	0.0920	0.0290
298.15	0.3580	0.1740	0.1200	0.0480

Sources

• Solubility, liquid-liquid equilibrium and critical states for the quaternary system formic acid - ethanol - ethyl formate - water at 298.15 K and 308.15 K